Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “transient detection”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 739 records · Page 41
All sourcesNASA NTRSDOE OSTI
DOE OSTI2020

From core collapse to superluminous: the rates of massive stellar explosions from the Palomar Transient Factory

ABSTRACT We present measurements of the local core-collapse supernova (CCSN) rate using SN discoveries from the Palomar Transient Factory (PTF). We use a Monte Carlo simulation of hundreds of millions of SN light-curve realizations coupled with the detailed PTF survey detection efficiencies to forward model the SN rates in PTF. Using a sample of 86 CCSNe, including 26 stripped-envelope SNe (SESNe), we show that the overall CCSN volumetric rate is $r^\mathrm{CC}_v=9.10_{-1.27}^{+1.56}\times 10^{-5}\, \text{SNe yr}^{-1}\, \text{Mpc}^{-3}\, h_{70}^{3}$ at 〈z〉 = 0.028, and the SESN volumetric rate is $r^\mathrm{SE}_v=2.41_{-0.64}^{+0.81}\times 10^{-5}\, \text{SNe yr}^{-1}\, \text{Mpc}^{-3}\, h_{70}^{3}$. We further measure a volumetric rate for hydrogen-free superluminous SNe (SLSNe-I) using eight events at z ≤ 0.2 of $r^\mathrm{SLSN-I}_v=35_{-13}^{+25}\, \text{SNe yr}^{-1}\text{Gpc}^{-3}\, h_{70}^{3}$, which represents the most precise SLSN-I rate measurement to date. Using a simple cosmic star formation history to adjust these volumetric rate measurements to the same redshift, we measure a local ratio of SLSN-I to SESN of ${\sim}1/810^{+1500}_{-94}$, and of SLSN-I to all CCSN types of ${\sim}1/3500^{+2800}_{-720}$. However, using host galaxy stellar mass as a proxy for metallicity, we also show that this ratio is strongly metallicity dependent: in low-mass (logM* < 9.5 M⊙) galaxies, which are the only environments that host SLSN-I in our sample, we measure an SLSN-I to SESN fraction of $1/300^{+380}_{-170}$ and $1/1700^{+1800}_{-720}$ for all CCSN. We further investigate the SN rates a function of host galaxy stellar mass, and show that the specific rates of all CCSNe decrease with increasing stellar mass.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2024

Long-term follow-up observations of extreme coronal line emitting galaxies

We present new spectroscopic and photometric follow-up observations of the known sample of extreme coronal line-emitting galaxies (ECLEs) identified in the Sloan Digital Sky Survey (SDSS). With these new data, observations of the ECLE sample now span a period of two decades following their initial SDSS detections. We confirm the non-recurrence of the iron coronal line signatures in five of the seven objects, further supporting their identification as the transient light echoes of tidal disruption events (TDEs). Photometric observations of these objects in optical bands show little overall evolution. In contrast, mid-infrared (MIR) observations show ongoing long-term declines consistent with power-law decay. The remaining two objects had been classified as active galactic nuclei (AGNs) with unusually strong coronal lines rather than being TDE related, given the persistence of the coronal lines in earlier follow-up spectra. We confirm this classification, with our spectra continuing to show the presence of strong, unchanged coronal line features and AGN-like MIR colors and behavior. We have constructed spectral templates of both subtypes of ECLE to aid in distinguishing the likely origin of newly discovered ECLEs. We highlight the need for higher cadence, and more rapid, follow-up observations of such objects to better constrain their properties and evolution. We also discuss the relationships between ECLEs, TDEs, and other identified transients having significant MIR variability.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2022

Design, Deployment, and Characterization of the World’s First Flexible Large Power Transformer

GE Research and its partner Prolec GE have designed, built and deployed in the field the world’s first flexible power transformer. The flexible power transformer is a transmission class 3-phase autotransformer configurable in impedance and in voltage which allows it to serve as a universal spare for multiple units in a given fleet. However, the key innovation in this new concept is the online adjustable leakage impedance which allows the transformer to change its impedance without interrupting the transmission line operation. The flexible power transformer can be designed with up to three low voltage transmission class ratings and up to 12 impedance values changeable both online and offline. This report provides an overview of the design, manufacturing, testing, and commissioning of the 165kV, 60MVA prototype built including the results of the field performance validation tests. The prototype was specified in collaboration with Cooperative Energy, the utility host. It was designed and tested in the factory according to IEEE standard C57.12.00 and followed all protocols for transportation, installation, and commissioning of a power transformer. In addition to the prototype, a flexible protection system capable of automatically adjusting its settings upon the transformer impedance was also developed and deployed in the for testing and validation. On September 3, 2021 the prototype was energized in Cooperative Energy’s substation in Columbia, Mississippi to become the world’s first flexible power transformer in operation. Its performances and impact on the grid operation were demonstrated through different field tests. Results obtained confirm that the impedance of the flexible transformer can be varied under load through its full range, from 4.3% to 9.3%, without adverse impacts on the line operation, the protection system, the transformer stability and health condition. Results also proved that the flexible transformer is very effective in controlling power transfer through the line or load sharing between units operating in parallel. Indeed, it was proven that higher impedances decrease the thruput power of the transformer while lower impedances increase it. Up to 26MW was controllable on a line loading of 45MVA. It was also possible to demonstrate that the variation of the transformer impedance has no effect on the circulating current between units in parallel, except a minor transient during the impedance change. It was also proven that the flexible protection relay can update its protection settings automatically when the impedance change was detected. The prototype has operated continuously for more than 12 months now with a peak load exceeding 50MVA corresponding to >80% of its ONAN power rating. No alarm, trip or sign of failure has been reported by the utility. In addition to the development and deployment of the flexible transformer prototype, investigations were carried out on new nanodielectric fluids to replace the mineral oil used in power transformers with the goal of reducing their footprint and weight. The key parameters that were targeted for improvement included the breakdown voltage to reduce clearances between windings and tank hence the footprint; viscosity and thermal conductivity to increase the cooling efficiency and therefore to reduce the winding material. Several nanodielectric mixtures with mineral oil including with alumina (Al2O3), titania (TiO2) and Borum Nitrate (BN) with different surfactants have been analyzed and tested. Unfortunately, despite encouraging results no nanofluid candidate has been found viable to replace mineral oil. With the formulations tested, breakdown voltages are generally similar to mineral oil at lower particle contents and worse at higher particle contents. Viscosity appreciably increased at particles concertation over 2 wt% and thermal conductivity increased slightly at 5wt% and appears to be 10-15% higher at 10 wt% particle content. It is recommended to continue investigations to find solutions that can help increase the power density of future flexible power transformers. Flexible power transformers can significantly help the future power grid by providing more flexibility and resiliency. Indeed, by providing voltage and impedance flexibility, flexible power transformers reduce the need for multiple spares, hence inventory costs for utilities. With their online controllable impedance, they can provide support to the grid and help manage short-circuit currents, power flow, line congestion, and grid stability which will become more important with higher penetrations of intermittent renewable resources. During the field validation tests, it was demonstrated that up to 26MW was controllable on a line loading of 45MVA when the transformer impedance was varied from its minimum to its maximum range. Also, with the impedance range, the short-circuit currents could be reduced by up to 38% at the load side of the transformer. With its controllable impedance, flexible transformers can be used in future strategies of grid resilience to help better prepare the grid to face forecasted severe events including storms, heat waves and contingencies. The flexible power transformers can also find role in other applications including high voltage transmission cables such as offshore wind farms where solutions for energizing the cables and managing the reactive power are of critical importance. The designed flexible power transformer is now fully validated and ready for commercialization. Further analysis on the benefits of flexible power transformers for grid stability and short-circuit management including current limiting capability, reclosure and line restoration, control of inrush current, sizing of flexible AC components (FACTS) would help its rapid adoption by the industry.

24 POWER TRANSMISSION AND DISTRIBUTION↗
DOE OSTI2021

Constraints on the Electromagnetic Counterpart of the Neutron-star–Black-hole Merger GW200115

We report the results of our follow-up campaign for the neutron-star—black-hole (NSBH) merger GW200115 detected during the O3 run of the Advanced LIGO and Advanced Virgo detectors. We obtained wide-field observations with the Deca-Degree Optical Transient Imager covering ~20% of the total probability area down to a limiting magnitude of w = 20.5 AB at ~23 hr after the merger. Our search for counterparts returns a single candidate (AT2020aeo), likely not associated with the merger. In total, only 25 sources of interest were identified by the community and later discarded as unrelated to the GW event. We compare our upper limits with the emission predicted by state-of-the-art kilonova simulations and disfavor high-mass ejecta (>0.1 M⊙), indicating that the spin of the system is not particularly high. By combining our optical limits with gamma-ray constraints from Swift and Fermi, we disfavor the presence of a standard short-duration burst for viewing angles ≲15° from the jet axis. Our conclusions are, however, limited by the large localization region of this GW event, and accurate prompt positions remain crucial to improving the efficiency of follow-up efforts.

79 ASTRONOMY AND ASTROPHYSICS↗
NASA NTRS1974

Observation of a cosmic gamma-ray burst on Apollo 16. II - X-ray time profile and source location

A burst of X-rays was detected during the trans-earth coast phase of Apollo 16 on Apr. 27, 1972 at 10:68 UT, simultaneously with the observation of a transient event by a gamma-ray spectrometer aboard the same spacecraft. The two instruments provide a broad energy range of more than three orders of magnitude for describing the spectral distribution of this event. The conclusion that the incident flux was X-rays and not charged particles is based on the fact that the particle flux detectors in the Apollo gamma ray spectrometer and on the Vela 6A, which also observed the event, did not respond. The time variation of the total count rate in the X-ray range before and after corrections for detector geometry and the analysis for source direction is presented.

Trombka, J. I.↗
NASA NTRS1996

VLF long-range lightning location using the arrival time difference technique (ATD)

A new network of VLF receiving systems is currently being developed in the USA to support NASA's Tropical Rain Measuring Mission (TRMM). The new network will be deployed in the east coast of the US, including Puerto Rico, and will be operational in late 1995. The system should give affordable, near real-time, accurate lightning locating capabilities at long ranges and with extended coverage. It is based on the Arrival Time Difference (ATD) method of Lee (1986; 1990). The ATD technique is based on the estimation of the time of arrival of sferics detected over an 18 kHz bandwith. The ground system results will be compared and complemented with satellite optical measurements gathered with the already operational Optical Transient Detector (OTD) instrument and in due course with its successor the Lightning Imaging Sensor (LIS). Lightning observations are important to understand atmospheric electrification phenomena, discharge processes, associated phenomena on earth (e.g. whistlers, explosive Spread-F) and other planets. In addition, lightning is a conspicuous indicator of atmospheric activity whose potential is just beginning to be recognized and utilized. On more prosaic grounds, lightning observations are important for protection of life, property and services.

Ierkic, H. Mario↗
NASA NTRS1976

Gamma-ray astronomy: Nuclear transition region

This monograph reviews the major theoretical and experimental efforts made during the past 12 years in gamma-ray astronomy over the energy range from 10 keV to about 100 MeV, where nuclear-transition lines are expected. Early attempts to detect celestial gamma rays are recounted, mechanisms of gamma-ray line and continuum production are examined, and formulas giving the various possible differential gamma-ray spectral shapes are provided. Predicted fluxes are discussed for solar gamma rays as well as for gamma emission from supernova remnants, supernovae, neutron stars, flare stars, the galactic core and disk, black holes, and diffuse sources. Gamma-ray interactions with matter are analyzed, particularly the photoelectric effect, Compton scattering from free electrons, and pair production in nuclear fields. Significant results are summarized for observations of gamma rays from the sun as well as from point and extended sources within and beyond the Galaxy, including diffuse fluxes and transient gamma-ray bursts. Factors pertaining to the design of gamma-ray astronomy experiments are considered, especially detector background limitations, gamma-ray production within instruments, and present-day detection methods.

Chupp, E. L.↗
DOE OSTI2024

Broadband Rotational Spectroscopy in Uniform Supersonic Flows: Chirped Pulse/Uniform Flow for Reaction Dynamics and Low Temperature Kinetics

ConspectusThe study of gas-phase chemical reactions at very low temperatures first became possible with the development and implementation of the CRESU (French acronym for Reaction Kinetics in Uniform Supersonic Flows) technique. CRESU relies on a uniform supersonic flow produced by expansion of a gas through a Laval (convergent-divergent) nozzle to produce a wall-less reactor at temperatures from 10 to 200 K and densities of 1016-1018 cm-3 for the study of low temperature kinetics, with particular application to astrochemistry. In recent years, we have combined uniform flows with revolutionary advances in broadband rotational spectroscopy to yield an instrument that affords near-universal detection for novel applications in photodissociation, reaction dynamics, and kinetics. This combination of uniform supersonic flows with chirped-pulse Fourier-transform microwave spectroscopy (Chirped-Pulse/Uniform Flow, CPUF) permits detection of any species with a modest dipole moment, thermalized to the uniform temperature of the gas flow, with isomer, conformer, and vibrational state specificity. In addition, the use of broadband, high-resolution, and time-dependent (microsecond time scale) micro- and mm-wave spectroscopy makes it an ideal tool for characterizing both transient and stable molecules, as well as studying their spectroscopy and dynamics.In this Account, we review recent advances made using the CPUF technique, including studies of photodissociation, radical-radical reaction dynamics, and low temperature kinetics. These studies highlight both the strength of universal and multiplexed detection and the challenges of coupling it to a high-density collisional environment. Product branching and product evolution as a function of time have been measured for astrochemically relevant systems, relying on the detailed characterization of these flow conditions via experiments and fluid dynamics simulations. In the photodissociation of isoxazole, an unusual heterocyclic molecule with a very low-energy conical intersection, we have identified 7 products in 5 reaction channels and determined the product branching, pointing to both direct and indirect pathways. We have also approached the same system from separated NO and C3H3 reactants to explore a broader range of the potential energy surface, demonstrating the power of multichannel branching measurements for complex radical-radical reactions. We determined the product branching in the C3H2 isomers in the photodissociation of the propargyl radical and identified the importance of a hydrogen atom catalyzed isomerization to the lowest energy cyclic form. This then motivated a study of direct D-H exchange reaction in radicals, in which we demonstrate that it is an important and overlooked pathway for deuterium fractionation in astrochemical environments. Recently, we have shown the measurement of low temperature kinetics inside an extended Laval nozzle, after which a shock-free secondary expansion to low temperature and density affords an ideal environment for detection by rotational spectroscopy. These results highlight the power and potential of the CPUF approach, and future prospects will also be discussed in light of these developments.

Dias, Nureshan↗
NASA NTRS2019

CMB-HD: an Ultra-Deep, High-Resolution Millimeter-Wave Survey over Half the Sky

A millimeter-wave survey over half the sky, that spans frequencies in the range of 30 to 350 gigahertz, and that is both an order of magnitude deeper and of higher-resolution than currently funded surveys would yield an enormous gain in understanding of both fundamental physics and astrophysics. By providing such a deep, high-resolution millimeter-wave survey (about 0.5 microK-arcminutes noise and 15 arcseconds resolution at 150 gigahertz), CMB-HD (Cosmic Microwave Background - Henry Draper catalog entry) will enable major advances. It will allow 1) the use of gravitational lensing of the primordial microwave background to map the distribution of matter on small scales (k approximately equal to 10 h per megaparsec), which probes dark matter particle properties. It will also allow 2) measurements of the thermal and kinetic Sunyaev-Zel’dovich effects on small scales to map the gas density and gas pressure profiles of halos over a wide field, which probes galaxy evolution and cluster astrophysics. In addition, CMB-HD would allow us to cross critical thresholds in fundamental physics: 3) ruling out or detecting any new, light (less than 0.1 electronvolts), thermal particles, which could potentially be the dark matter, and 4) testing a wide class of multi-field models that could explain an epoch of inflation in the early Universe. Such a survey would also 5) monitor the transient sky by mapping the full observing region every few days, which opens a new window on gamma-ray bursts, novae, fast radio bursts, and variable active galactic nuclei. Moreover, CMB-HD would 6) provide a census of planets, dwarf planets, and asteroids in the outer Solar System, and 7) enable the detection of exo-Oort clouds around other solar systems, shedding light on planet formation. The combination of CMB-HD with contemporary ground and space-based experiments will also provide powerful synergies. CMB-HD will deliver this survey in 5 years of observing 20,000 square degrees, using two new 30-meter-class off-axis cross-Dragone telescopes to be located at Cerro Toco in the Atacama Desert. The telescopes will field about 2.4 million detectors (600,000 pixels) in total. The CMB-HD survey will be made publicly available, with usability and accessibility a priority.

Sehgal, Neelima↗
NASA NTRS2002

Antarctic Impulsive Transient Antenna (ANITA) instrumentation

We will report on the details of the ANITA instrument. This instrument is fundamentally a broadband antenna, which is arrayed and constructed in such a way as to be optimized for the detection and characterization of high-energy neutrino cascades.

ANITA↗
NASA NTRS2008

Using the HHT to Search for Gravitational Waves

Gravitational waves are a consequence of Einstein's theory of general relativity applied to the motion of very dense and massive objects such as black holes and neutron stars. Their detection will reveal a wealth of information about these mysterious objects that cannot be obtained with electromagnetic probes. Two projects are underway to attempt the detection of gravitational waves: NASA's Laser Interferometer Space Antenna (LISA), a space based mission being designed to search for waves from supermassive black holes at the centers of galaxies, and the NSF's Laser Interferometer Gravitational Wave Observatory (LIGO), a ground based facility that is now searching for waves from supernovae. pulsars, and the coalescence of black hole and neutron star systems. Because general relativity is an inherently non-linear theory, many of the predicted source waveforms show strong frequency modulation. In addition, the LIGO and LISA detectors are highly sensitive devices that produce a variety of non-linear transient noise features. Thus the unique capabilities of the HHT. the extraction of intrawave modulation and the characterization of non-linear and non-stationary signals, have a natural application to both signal detection and experimental characterization of the detectors. In this talk I will give an overview of the status of the field. including some of the expected sources of gravitational waves, and I will also describe the LISA and LIGO detectors. Then I will describe some applications of the HHT to waveform detection and detector noise characterization.

Camp, Jordan↗
NASA NTRS1982

Persistent X-ray emission from a gamma-ray burst source

A quiescent X-ray source detected with the Einstein X-ray Observatory in a location consistent with that of an intense gamma ray burst is shown to be also consistent with the location of the 1928 optical transient, the likely optical counterpart of the gamma ray burst source GBS0117-29. The system appears to be underluminous in X-rays by a factor of 10; possible reasons for this are discussed. The observed X-ray flux would require an accretion rate of about 10 to the -14th (d/1 kpc/)-squared solar masses per year, which is probably too low to be consistent with published nuclear flash models for gamma bursts, unless the distance is substantially greater than about 1 kpc or the burst recurrence time is greater than about 50 yrs, or the accretion rate is highly variable. Such a long recurrence time appears to be inconsistent with the detection of the optical burst.

Grindlay, J. E.↗
DOE OSTI2026

Optimizing Optical Searches for Supermassive Black Hole Binaries in Active Galactic Nuclei Light Curves: Fourier versus Bayesian Periodicity Detection

Simulations predict that supermassive black hole binaries (SMBHBs) will exhibit periodic brightness variations that may exceed the stochastic variability intrinsic to active galactic nuclei (AGN). In this paper, we simulate SMBHBs with damped random walk (DRW) AGN variability and an added sinusoidal signal from the orbital motion, and test three methods—a generalized Lomb–Scargle periodogram (GLSP), a nested Bayesian sampler (NBS), and a weighted wavelet z-transform (or WWZ)—to determine which is best at recovering the periodicity. Our simulated light curves follow the properties of the Catalina Real-Time Transient Survey (or CRTS), Legacy Survey of Space and Time (LSST), and Zwicky Transient Facility (ZTF) to best inform current and future SMBHB searches. We map a broad range of parameter space and identify which DRW-only light curves best mimic periodicity and pass each method’s model selection. The NBS performs best at detecting periodicity and filtering out DRW-only light curves. Combined candidate selection with both the NBS and GLSP significantly reduces false-positive rates (FPRs) with marginal impact on true-positive rates (TPRs). With this joint model selection pipeline, we find the lowest FPRs in ZTF-like simulations and the highest detection rates in LSST-like simulations. Using a modified computation of the false-alarm probability with GLSP, we efficiently triage LSST AGN light curves (∼10 7 light curves in ∼10–30 hr) and achieve TPRs and FPRs of ∼40% and ∼0.5%, respectively.

Banaszak, Sebastian M. [Vanderbilt Univ., Nashvill↗
DOE OSTI2024

MEGASIM: Distribution and Detection of Earth Trojan Asteroids

Abstract Using N -body simulation results from the MEGASIM data set, we present spatial distributions of Earth Trojan Asteroids and assess the detectability of the population in current and next-generation ground-based astronomical surveys. Our high-fidelity Earth Trojan Asteroid (ETA) distribution maps show never-before-seen high-resolution spatial features that evolve over timescales up to 1 Gyr. The simulation was synchronized to start times and timelines of two observational astronomy surveys: (1) the Vera C. Rubin Observatory’s Legacy Survey of Space and Time (LSST) and (2) the Zwicky Transient Facility (ZTF). We calculate upper limits for the number of ETAs potentially observable with both the ZTF and LSST surveys. Due to the Yarkovsky Effect, we find no stable ETAs on billion-year timescales likely to be detected by any ETA survey, as no C-type or S-type ETAs (with H < 22 and H < 24, respectively) are likely to be stable on billion-year timescales, and ETAs large enough to remain stable on billion-year timescales are very rare relative to the rest of the ETA population. We find that a twilight ETA survey will not drastically increase the likelihood of individual ETA detection, but it would provide orders of magnitude more observations of select ETA populations. The null detection to date from ZTF restricts the potential ETA population to hundreds of objects larger than 100 m (at H ≈ 22), while a null detection by LSST will further restrict the ETA population to tens of objects larger than 100 m.

79 ASTRONOMY AND ASTROPHYSICS↗
NASA NTRS1990

Averaging Sampled Sensor Outputs To Detect Failures

Fluctuating signals smoothed by taking consecutive averages. Sampling-and-averaging technique processes noisy or otherwise erratic signals from number of sensors to obtain indications of failures in complicated system containing sensors. Used under both transient and steady-state conditions. Useful in monitoring automotive engines, chemical-processing plants, powerplants, and other systems in which outputs of sensors contain noise or other fluctuations in measured quantities.

Panossian, Hagop V.↗
DOE OSTI2023

Enhancement of operational Flexibility of Power Plants Using IN740

Headers are crucial components within diverse industries, especially in the energy sector, as they enable the efficient transfer of fluids. The selection of materials for headers is determined by their specific applications; for example, Grade 91 and Grade 92 steels are commonly utilized. In our research, we recommend the adoption of INCONEL alloy 740 due to its exceptional robustness and heat-resistant characteristics. One critical parameter in header systems is the heat transfer coefficient, which directly influences the efficiency of heat exchange processes and can thereby impact the structural integrity of the headers. This coefficient is closely linked with factors such as the Nusselt number, which is influenced by fluid flow characteristics and thermal properties. The flow direction within headers, whether unidirectional or multidirectional—significantly affects the overall dynamics of heat transfer. This research focuses on exploring the behavior of headers, a specific pipeline system component, using ANSYS simulation software. The study aims to predict heat transfer and mechanical behavior within headers under various conditions through steady-state and transient simulations (parts 1 and 2 of the report). Key parameters such as heat transfer coefficient, velocity, and temperature are examined with the goal of optimizing header design. Part 3 of the report addresses the critical yet underexplored relationship between pressure drop and heat transfer coefficients in the transient flow regime within headers, specifically focusing on smooth horizontal circular tubes. Limited experimental work has been conducted in this area, prompting the need for comprehensive analysis. By leveraging machine learning techniques, this research aims to establish a correlation between pressure drop and heat transfer across various flow conditions, including laminar, transient, quasi-turbulent, and turbulent regimes. The data utilized for this analysis were meticulously gathered from existing literature, capturing simultaneous measurements of pressure drops and heat transfer. Part 4: In the context of power plants, header pipes are essential components that significantly influence system performance by facilitating the collection and distribution of steam. This report highlights the critical role of header pipes in enhancing reliability, efficiency, and overall power plant performance. A key aspect of this investigation is shape optimization, which aims to maximize performance while minimizing material usage. By focusing on shape optimization, this research contributes to improved efficiency and a reduced environmental footprint for power plant installations. The methodology developed in this study emphasizes optimizing header shapes to decrease reliance on expensive alloy materials and lower maintenance costs. Furthermore, a case study was conducted using a header from an operational power plant to validate the proposed optimization techniques. Finally, part 5 addresses the challenges associated with flexible operations in boiler systems, the study outlines several strategies for enhancing the durability and reliability of steam headers. Key approaches include material selection, which involves utilizing advanced materials with superior high-temperature properties and enhanced fatigue resistance to extend the lifespan of steam headers. Design modifications are also recommended, focusing on implementing changes that mitigate thermal stress and cyclic loading to reduce the likelihood of failures under varying operating conditions. Additionally, the study emphasizes the importance of regular inspection and monitoring by establishing rigorous protocols to detect early signs of damage, allowing for timely maintenance and minimizing the risks of catastrophic failures. Furthermore, operational guidelines are developed to minimize the frequency and severity of thermal transients, ensuring stable and efficient operations. Collectively, these strategies provide a robust framework for overcoming the unique challenges posed by flexible operation in boiler systems, ultimately contributing to improved reliability and performance in power plant operations. Through this comprehensive approach, the study not only enhances the understanding of pressure drop and heat transfer relationships but also promotes advancements in design and operation that will benefit the entire power generation industry.

01 COAL, LIGNITE, AND PEAT↗
DOE OSTI2022

Visible-Light-Driven, Iridium-Catalyzed Hydrogen Atom Transfer: Mechanistic Studies, Identification of Intermediates, and Catalyst Improvements

The harvesting of visible light is a powerful strategy for the synthesis of weak chemical bonds involving hydrogen that are below the thermodynamic threshold for spontaneous H 2 evolution. Piano-stool iridium hydride complexes are effective for the bluelight- driven hydrogenation of organic substrates and contrathermodynamic dearomative isomerization. In this work, a combination of spectroscopic measurements, isotopic labeling, structure–reactivity relationships, and computational studies has been used to explore the mechanism of these stoichiometric and catalytic reactions. Photophysical measurements on the iridium hydride catalysts demonstrated the generation of long-lived excited states with principally metal-to-ligand charge transfer (MLCT) character. Transient absorption spectroscopic studies with a representative substrate, anthracene revealed a diffusion-controlled dynamic quenching of the MLCT state. The triplet state of anthracene was detected immediately after the quenching events, suggesting that triplet–triplet energy transfer initiated the photocatalytic process. The key role of triplet anthracene on the post-energy transfer step was further demonstrated by employing photocatalytic hydrogenation with a triplet photosensitizer and a HAT agent, hydroquinone. DFT calculations support a concerted hydrogen atom transfer mechanism in lieu of stepwise electron/proton or proton/electron transfer pathways. Kinetic monitoring of the deactivation channel established an inverse kinetic isotope effect, supporting reversible C(sp 2 )–H reductive coupling followed by rate-limiting ligand dissociation. Mechanistic insights enabled design of a piano-stool iridium hydride catalyst with a rationally modified supporting ligand that exhibited improved photostability under blue light irradiation. The complex also provided improved catalytic performance toward photoinduced hydrogenation with H 2 and contra-thermodynamic isomerization.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2023

Evidence of Polaron Formation in Halide Perovskites via Carrier Effective Mass Measurements

Carrier effective mass is a central parameter in solid-state physics. It is a measure of the strength of the coupling between a carrier and excitations arising from its surrounding medium, and features prominently in transport and optical calculations. Experimental techniques employed to determine it are steady-state ones, and so are unable to detect any change in the effective mass after a strong perturbation to the system, e.g., strong optical excitation. By combining time-resolved terahertz spectroscopy and transient absorption spectroscopy, on a mixed-cation mixed-halide perovskite thin film, we observe a large and long-lived photoinduced enhancement of the carrier effective mass, and from it deduce a twofold increase of the carrier-phonon coupling constant, giving evidence of polaron formation. Our work demonstrates a new approach to track the strength and ultrafast lifetimes of photoinduced carrier-boson interactions down to picosecond timescales that can be applied to a wide range of solid-state systems.

36 MATERIALS SCIENCE↗