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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 739 records · Page 41
All sourcesNASA NTRSDOE OSTI
NASA NTRS1985

The effects of transient rheology on the interpretation of lower mantle viscosity

The role played by transient rheology in the interpretation of mantle viscosity is reexamined. The investigation has been carried out by comparing the amplitude responses with the data of secular variation of J(2), the relative sea-level histories at sites well within the ice margins and at the ice margin like the city of Boston. A linear Burgers body rheology has been assumed in ther lower mantle. The data near the edge of the ice load proves most sensitive to the transient viscosity structure. The non-monotonic behavior of sea-level data near Boston can be explained both by a steady-state lower mantle viscosity of 10 to the 22nd P with a thick lithosphere and by a transient lower mantle rheology but with a thin lithosphere. The long-term viscosity of the lower mantle in this second model has a steady-state value of around 5 x 10 to the 23rd P.

Sabadini, R.↗
NASA NTRS1989

Disk-instability model for soft-X-ray transients containing black holes

Consideration is given to the time-dependent behavior of the accretion disks in low-mass X-ray binaries as a model for soft X-ray transients. The thermal stability and vertical structure properties of the disk are studied in the range between 10 to the 7th and 10 to the 8th cm. An Eulerian time-dependent thin disk model is used to show that, for relevant accretion rates, the disk suffers a thermal instability leading to intermittent accretion onto the central compact object. The disk instability model reproduces the basic features of outbursts of soft X-ray transients. Also, the physical state of quiescence of the binary A0620-00 is examined, focusing on the possible existence of a black hole. It is suggested that the modulation of the accretion flow in the inner disk may be responsible for the bimodal behavior observed in the spectra of black hole candidates such as Cyg X-1, GX 339-4, and A0620-00.

Mineshige, Shin↗
DOE OSTI2024

Transient Nanoscopy of Exciton Dynamics in 2D Transition Metal Dichalcogenides

Abstract The electronic and optical properties of 2D transition metal dichalcogenides are dominated by strong excitonic resonances. Exciton dynamics plays a critical role in the functionality and performance of many miniaturized 2D optoelectronic devices; however, the measurement of nanoscale excitonic behaviors remains challenging. Here, a near‐field transient nanoscopy is reported to probe exciton dynamics beyond the diffraction limit. Exciton recombination and exciton–exciton annihilation processes in monolayer and bilayer MoS 2 are studied as the proof‐of‐concept demonstration. Moreover, with the capability to access local sites, intriguing exciton dynamics near the monolayer‐bilayer interface and at the MoS 2 nano‐wrinkles are resolved. Such nanoscale resolution highlights the potential of this transient nanoscopy for fundamental investigation of exciton physics and further optimization of functional devices.

2D materials↗
DOE OSTI2025

Ultrafast Electron–Dipole Interactions in TeO- Photodetachment

We present direct experimental evidence of ultrafast coupling between ejected electrons and dynamically forming dipole moments in TeO, captured during the photodetachment of TeO?. By combining high-resolution cryogenic photoelectron spectroscopy with velocity-map imaging, we assess previously inaccessible excited states and resolve rich photoelectron angular distributions (PADs) that encode electron–dipole interactions. Systematic comparison of PADs from femtosecond and picosecond lasers reveals striking deviations from free-electron behavior, representing direct evidence of a transient dipole moment evolving on femtosecond timescales. Quantitative analysis pinpoints the dipole buildup time to be within ~60 fs, providing real-time access to the birth of a molecular dipole field. This work establishes a general approach to probing electron-dipole interactions in their formation stages, offering fundamental insights into the ultrafast interplay between departing electrons and transient polar systems — a process that lies at the core of atomic, molecular, and ultrafast physics.

Yang, Fan↗
DOE OSTI2025

Controlling Ligand Excimer Formation with Dipole Changes in Emissive Rare-Earth/Phosphonic Acid Complexes

The interactions between substituted arylvinyl phosphonic acid (AVPA) ligands within a Eu-AVPA complex are shown to influence the outcomes of excited state evolution after photoexcitation. Compared with unfunctionalized AVPAs, pairs of ligands functionalized with CF 3 in the para position preassociate in the ground state of complexes with Eu 3+ according to calculated geometry optimizations. The CF 3 -substituted AVPA complexes show evidence of red-shifted optical absorption and undergo more efficient excimer formation, as revealed by transient absorption spectroscopy. We rationalize this behavior through simulations of excited-state geometry optimizations that reveal evolution toward interligand phenyl-phenyl planarity for specific excited states. Emission from complexed Eu 3+ after energy transfer from the ligand is found to be weaker with CF 3 substitution, which we hypothesize is due to intracomplex, interligand aggregates with excimer-promoting geometries. These observations point to the need to consider ground-state geometries as well as dynamic excited-state processes to understand the flow of energy in rare earth coordination complexes.

09 BIOMASS FUELS↗
DOE OSTI2023

Ultrafast transient absorption measurements of photocarrier dynamics in PdSe 2

We investigate the photocarrier dynamics in bulk PdSe 2 , a layered transition metal dichalcogenide with a novel pentagonal structure and unique electronic and optical properties. Using femtosecond transient absorption microscopy, we study the behavior of photocarriers in mechanically exfoliated bulk PdSe 2 flakes at room temperature. By employing a 400 nm ultrafast laser pulse, electron–hole pairs are generated, and their dynamics are probed using an 800 nm detection pulse. Our findings reveal that the lifetime of photocarriers in bulk PdSe 2 is approximately 210 ps. Furthermore, by spatially resolving the differential reflection signal, we determine a photocarrier diffusion coefficient of about 7.3 cm 2 s –1 . Based on these results, we estimate a diffusion length of around 400 nm and a photocarrier mobility of approximately 300 cm 2 V –1 s –1 . Furthermore, these results shed light on the ultrafast optoelectronic properties of PdSe 2 , offer valuable insights into photocarriers in this emerging material, and enable design of high-performance optoelectronic devices based on PdSe 2 .

77 NANOSCIENCE AND NANOTECHNOLOGY↗
DOE OSTI2016

In Situ Methods, Infrastructures, and Applications on High Performance Computing Platforms, a State-of-the-art (STAR) Report

The considerable interest in the high performance computing (HPC) community regarding analyzing and visualization data without first writing to disk, i.e., in situ processing, is due to several factors. First is an I/O cost savings, where data is analyzed /visualized while being generated, without first storing to a filesystem. Second is the potential for increased accuracy, where fine temporal sampling of transient analysis might expose some complex behavior missed in coarse temporal sampling. Third is the ability to use all available resources, CPU’s and accelerators, in the computation of analysis products. This STAR paper brings together researchers, developers and practitioners using in situ methods in extreme-scale HPC with the goal to present existing methods, infrastructures, and a range of computational science and engineering applications using in situ analysis and visualization.

97 MATHEMATICS AND COMPUTING↗
DOE OSTI2016

Behavior of fuel with zirconium alloy cladding in reactivity-initiated accident and loss-of-coolant accident - 2016-0090

Along with our colleagues at the Japan Atomic Energy Research Institute (JAERI) and Japan Atomic Energy Agency (JAEA), we have performed extensive research programs for more than 2 decades and have developed a better understanding of fuel behavior under accident conditions. Data and findings from these research programs have provided the technical basis directly and indirectly for regulatory criteria in Japan and other countries. This paper reviews and summarizes the major outcomes from the research programs performed at JAERI and JAEA facilities and identifies further research needs. The programs aim to generate data and models to (1) evaluate the adequacy of present safety criteria and safety margins; (2) create a database for the future regulation of higher-burnup UO{sub 2} and mixed-oxide (MOX) fuels, new cladding, and pellets; (3) provide adequately mechanistic computer codes for regulatory application; (4) promote a better understanding of phenomena that appear in high-burnup regions and MOX fuels, such as rim effect and an effect of plutonium agglomerates in MOX fuels, and to evaluate those effects on fuel behavior in accident conditions; and (5) to assess fuel behaviors with higher fuel duty, such as plant power uprates, longer operating cycles, and water chemistry changes. The programs comprise reactivity-initiated accident studies, including pulse-irradiation experiments in the Nuclear Safety Research Reactor, cladding mechanical tests, and the development and verification of RANNS; loss-of-coolant accident tests, including integral thermal shock tests, oxidation rate measurements, and cladding mechanical tests; development and verification of a computer code FEMAXI-6 that simulates high-burnup fuel behavior under normal operating and abnormal transient conditions; and studies on phenomena specific to high-burnup regions, including thermal property measurements, experimental and analytical simulation of rim structure formation, cladding mechanical tests on effects of hydrides, etc. (authors)

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗
DOE OSTI2015

Development of a robust modeling tool for radiation-induced segregation in austenitic stainless steels

Irradiation-assisted stress corrosion cracking (IASCC) of austenitic stainless steels in Light Water Reactor (LWR) components has been linked to changes in grain boundary composition due to irradiation induced segregation (RIS). This work developed a robust RIS modeling tool to account for thermodynamics and kinetics of the atom and defect transportation under combined thermal and radiation conditions. The diffusion flux equations were based on the Perks model formulated through the linear theory of the thermodynamics of irreversible processes. Both cross and non-cross phenomenological diffusion coefficients in the flux equations were considered and correlated to tracer diffusion coefficients through Manning’s relation. The preferential atom-vacancy coupling was described by the mobility model, whereas the preferential atom-interstitial coupling was described by the interstitial binding model. The composition dependence of the thermodynamic factor was modeled using the CALPHAD approach. Detailed analysis on the diffusion fluxes near and at grain boundaries of irradiated austenitic stainless steels suggested the dominant diffusion mechanism for chromium and iron is via vacancy, while that for nickel can swing from the vacancy to the interstitial dominant mechanism. The diffusion flux in the vicinity of a grain boundary was found to be greatly influenced by the composition gradient formed from the transient state, leading to the oscillatory behavior of alloy compositions in this region. This work confirms that both vacancy and interstitial diffusion, and segregation itself, have important roles in determining the microchemistry of Fe, Cr, and Ni at irradiated grain boundaries in austenitic stainless steels.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗
NASA NTRS1977

Analysis methods for Kevlar shield response to rotor fragments

Several empirical and analytical approaches to rotor burst shield sizing are compared and principal differences in metal and fabric dynamic behavior are discussed. The application of transient structural response computer programs to predict Kevlar containment limits is described. For preliminary shield sizing, present analytical methods are useful if insufficient test data for empirical modeling are available. To provide other information useful for engineering design, analytical methods require further developments in material characterization, failure criteria, loads definition, and post-impact fragment trajectory prediction.

Gerstle, J. H.↗
NASA NTRS1979

Design, analysis, and tests of a shuttle-type heat-pipe-cooled leading edge

A one-half scale heat-pipe-cooled leading edge model was designed and fabricated to verify feasibility and performance of a full-scale Phase B shuttle orbiter design. Model performance was investigated experimentally by radiant heating and aerothermal tests and analytically by using a simple technique which predicts heat pipe start-up from the frozen state and also predicts transient and steady-state thermal behavior. Analytical results agree well with experimental results for start-up and steady-state heat pipe operation. The results indicate that variations in angle of attack and roll orientation had a negligible effect on heat pipe performance. The heat pipes effectively isothermalized the leading edge, and reduced peak temperatures to levels compatible with the use temperatures of superalloys. Results of these tests demonstrated the durability of the heat-pipe-cooled leading edge in withstanding earth-entry thermal and mechanical loads and indicate that the use of heat pipes in leading edge structures is a reliable concept for fully reusable hypersonic cruise and space transportation systems.

Camarda, C. J.↗
NASA NTRS1987

Effect of axial impact on the static flexure of graphite/epoxy beams

Graphite-epoxy beams were subjected to an eccentric axial impact load in a drop tower test fixture in order to study their large displacement flexural behavior. The time history of the transient axial load exhibited a large magnitude occurring just after impact, which was many times greater than the static failure load. The damage caused by this peak dynamic load was measured by the reduction in energy absorption of the impacted beam relative to a virgin beam in static tests. For the thirty-ply specimens, the amount of damage increased with increasing axial stiffness.

Sensmeier, M. D.↗
NASA NTRS1994

Lox droplet vaporization in a supercritical forced convective environment

A systematic investigation has been conducted to study the effects of ambient flow conditions (i.e. pressure and velocity) on supercritical droplet gasification in a forced-convective environment. The model is based on the time-dependent conservation equations in axisymmetric coordinates, and accommodates thermodynamic nonidealities and transport anomalies. In addition, an efficient scheme for evaluating thermophysical properties over the entire range of fluid thermodynamic states is established. The analysis allows a thorough examination of droplet behavior during its entire lifetime, including transient gasification, dynamic deformation, and shattering. A parametric study of droplet vaporization rate in terms of ambient pressure and Reynolds number is also conducted.

Hsiao, Chia-Chun↗
NASA NTRS2001

Studies of Fundamental Particle Dynamics in Microgravity

This work summarizes theoretical and experimental concepts used to design the flight experiment mission for SHIVA - Spaceflight Holography Investigation in a Virtual Apparatus. SHIVA is a NASA project that exploits a unique, holography-based, diagnostics tool to understand the behavior of small particles subjected to transient accelerations. The flight experiments are designed for testing model equations, measuring g, g-jitter, and other microgravity phenomena. Data collection will also include experiments lying outside of the realm of existing theory. The regime under scrutiny is the low Reynolds number, Stokes regime or creeping flow, which covers particles and bubbles moving at very low velocity. The equations describing this important regime have been under development and investigation for over 100 years and yet a complete analytical solution of the general equation had remained elusive yielding only approximations and numerical solutions. In the course of the ongoing NASA NRA, the first analytical solution of the general equation was produced by members of the investigator team using the mathematics of fractional derivatives. This opened the way to an even more insightful and important investigation of the phenomena in microgravity. Recent results include interacting particles, particle-wall interactions, bubbles, and Reynolds numbers larger than unity. The Space Station provides an ideal environment for SHIVA. Limited ground experiments have already confirmed some aspects of the theory. In general the space environment is required for the overall experiment, especially for cases containing very heavy particles, very light particles, bubbles, collections of particles and for characterization of the space environment and its effect on particle experiments. Lightweight particles and bubbles typically rise too fast in a gravitational field and heavy particles sink too fast. In a microgravity environment, heavy and light particles can be studied side-by-side for long periods of time.

Rangel, Roger↗
NASA NTRS2001

The SHIVA Project: Spaceflight Holography in a Virtual Apparatus

The poster summarizes theoretical and experimental concepts used in the development of the proposed NASA flight experiment SHIVA (Spaceflight Holography in a Virtual Apparatus). SHIVA exploits a unique holography-based, diagnostics tools to understand the behavior of small particles subjected to transient accelerations. Flight experiment protocols and apparatus will test model equations, characterize the acceleration environment and other microgravity phenomena. The primary objective of SHIVA is to enhance the current understanding of complex dynamics of small particles subjected to transient microgravity conditions. Existing theory did not fully describe the movement of particles in fluids in the microgravity environment. Results from recent ground-based experiments and comparison with the model recently developed by Rangel and Coimbra are presented.

Jim Trolinger↗
NASA NTRS2007

Estimation Filter for Alignment of the Spitzer Space Telescope

A document presents a summary of an onboard estimation algorithm now being used to calibrate the alignment of the Spitzer Space Telescope (formerly known as the Space Infrared Telescope Facility). The algorithm, denoted the S2P calibration filter, recursively generates estimates of the alignment angles between a telescope reference frame and a star-tracker reference frame. At several discrete times during the day, the filter accepts, as input, attitude estimates from the star tracker and observations taken by the Pointing Control Reference Sensor (a sensor in the field of view of the telescope). The output of the filter is a calibrated quaternion that represents the best current mean-square estimate of the alignment angles between the telescope and the star tracker. The S2P calibration filter incorporates a Kalman filter that tracks six states - two for each of three orthogonal coordinate axes. Although, in principle, one state per axis is sufficient, the use of two states per axis makes it possible to model both short- and long-term behaviors. Specifically, the filter properly models transient learning, characteristic times and bounds of thermomechanical drift, and long-term steady-state statistics, whether calibration measurements are taken frequently or infrequently. These properties ensure that the S2P filter performance is optimal over a broad range of flight conditions, and can be confidently run autonomously over several years of in-flight operation without human intervention.

Bayard, David↗