Reactive scattering of K atoms from oriented CH sub 3 I molecules.
Potassium atom reactive scattering from oriented methyl iodine molecules, determining variation of chemical reactivity over molecular surface
SURFACE INTERACTION↗
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Results for “surface interaction”
Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
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Surface hydroxyl in MgO.
Forces holding hydroxyl ions to surfaces of MgO particles
SURFACE INTERACTION↗
Nucleate boiling on a vibrating surface.
Surface vibration effect on nucleate pool boiling, measuring heat-transfer coefficient and proposing mechanism
STRUCTURAL VIBRATION↗
Interaction of metastable molecules with surfaces
Metastable diatomic N beam scattering from Teflon and Cu surfaces measured for velocity and angular distributions
Donnelly, D. P.↗
Coadsorption of hydrogen and carbon monoxide on /111/ platinum
Hydrogen and carbon monoxide coadsorption on platinum single crystal surface, examining interactions and species formation by thermal flash and electron impact techniques in ultrahigh vacuum
Baldwin, V. H., Jr.↗
Noise from interaction of flow with rigid surfaces: A review of current status of prediction techniques
A brief review of some fundamental aspects of sound arising from turbulent boundary layers, noise due to flow past a single discontinuity (trailing edge), noise from airfoils operating in turbulent flow, and noise due to rigid flow discontinuities (spoilers) immersed in rigid ducts is presented. Emphasis is on dipole-like sound fields associated with turbulent flow past a trailing edge, rigid bodies in turbulence and in-duct spoilers. Representative available data are reviewed and evaluated in terms of theoretical considerations and, where possible, empirical prediction techniques are given in terms of convenient aerodynamic and geometric parameters. Limitations on current knowledge are discussed.
Hayden, R. E.↗
Task 4: Lake Ice Surveillance, 1406
The author has identified the following significant results. Although it is readily recognized that there is a need for ground truth to provide adequate guidance for remote sensing data interpretation, it is noted that, in terms of radar remote sensing, this ground truth is often inadequate. It is necessary to make basic electrical and physical measurements of the surface and to some depth below it. A brief outline is presented of a ground truth scheme which uses measurements of the dielectric constant. Two portable instruments were designed specifically for this purpose; these were: (1) a Q-meter for measurement of dielectric constant and loss tangent; and (2) an instrument to measure electrical properties of the two operating frequencies of the imaging radar. Although extensive data are lacking, several general cases of radar-earth surface and interaction are described; also, examples of radar imagery and some data on ice and snow are presented. It is concluded that the next logical step is to begin to quantify the radar ground truth in preparation for machine interpretation and automatic data processing of the radar imagery.
Porcello, L. J.↗
Application of dielectric constant measurements to radar imagery interpretation
The author has identified the following significant results. Although it is readily recognized that there is a need for ground truth to provide adequate guidance for remote sensing data interpretation, it is noted that, in terms of radar remote sensing, this ground truth is often inadequate. It is necessary to make basic electrical and physical measurements of the surface and to some depth below it. A brief outline is presented of a ground truth scheme which uses measurements of the dielectric constant. Two portable instruments were designed specifically for this purpose; these were: (1) a Q-meter for measurement of dielectric constant and loss tangent; and (2) an instrument to measure electrical properties of the two operating frequencies of the imaging radar. Although extensive data are lacking, several general cases of radar-earth surface and interaction are described; also, examples of radar imagery and some data on ice and snow are presented. It is concluded that the next logical step is to begin to quantify the radar ground truth in preparation for machine interpretation and automatic data processing of the radar imagery.
Bryan, M. L.↗
A Study of Trailing Edge Blowing as a Means of Reducing Noise Generated by the Interaction of Flow with a Surface
A system for reducing the noise generated when a jet impinges against a flap is described. The eddies formed by the alternate zones of positive and negative pressure on the flap surface are identified as the sound source. In the proposed concept, a stream of low velocity secondary air is ejected from a slot near the trailing edge of the flap as a buffer between the flap and the primary air jet to reduce the intensity of the fluctuating surface pressure field near the flap edge and thus reduce the intensity of the aerodynamic noise.
Scharton, T. D.↗
Estimating subsonic aerodynamic characteristics of complex planforms
Vortex-lattice FORTRAN program estimates subsonic aerodynamic characteristics of complex planforms and interacting lifting surfaces with separated flow around sharp edges.
Lamar, J. E.↗
Some factors influencing radiation of sound from flow interaction with edges of finite surfaces
Edges of surfaces which are exposed to unsteady flow cause both strictly acoustic effects and hydrodynamic effects, in the form of generation of new hydrodynamic sources in the immediate vicinity of the edge. An analytical model is presented which develops the explicit sound-generation role of the velocity and Mach number of the eddy convection past the edge, and the importance of relative scale lengths of the turbulence, as well as the relative intensity of pressure fluctuations. The Mach number (velocity) effects show that the important paramater is the convection Mach number of the eddies. The effects of turbulence scale lengths, isotropy, and spatial density (separation) are shown to be important in determining the level and spectrum of edge sound radiated for the edge dipole mechanism. Experimental data is presented which provides support for the dipole edge noise model in terms of Mach number (velocity) scaling, parametric dependence on flow field parameter, directivity, and edge diffraction effects.
Hayden, R. E.↗
Geodynamic problems
The understanding of the solid earth and suggestions of what measurements should be undertaken based on estimates of instrumental feasibilities were reviewed. The observations include: (1) earth evolution and mantle convection; (2) lithosphere-asthenosphere-surface load interaction; (3) glacier-ocean-solid earth interaction; (4) solid earth interactions with the sun, moon, core, oceans, and atmosphere; (5) zones of strain accumulation; and (6) earthquakes.
Kaula, W. M.↗
Three dimensional boundary conditions in supersonic flow
A theoretical analysis of the flow pattern at a solid surface in three dimensional supersonic flow is presented. The additional information necessary to overcome the nonuniqueness associated with the body tangency condition in three dimensions was developed. The analysis is based on the fact that three dimensional waves propagate locally exactly as they do in axisymmetric flow when viewed in the osculating plane to the streamline. The supersonic flow over an infinite swept corner is examined by both the classical solution and the three dimensional solution in the osculating plane and the results are shown to be identical. A simple numerical algorithm is proposed which accounts for the three wave surfaces that interact at a solid boundary.
Rudman, S.↗
Intraband optical conductivity sigma/omega,T/ of Cu, Ag, and Au - Contribution from electron-electron scattering
The frequency and temperature dependence of the intraband optical conductivity of the noble metals Cu, Ag and Au is measured and contributions of electron-electron scattering are assessed. Optical measurements were performed at temperatures of 77, 295 and 425 K to obtain values of the Drude electron scattering rate with a linear dependence on temperature which may be attributed to electron-phonon scattering, and a quadratic dependence on photon energy, which is suggestive of electron-electron scattering but is a factor of two to three times greater than would be expected. Comparison of the optical data with dc electrical and thermal resistivity data which also show behavior attributed to electron-electron scattering reveals discrepancies of up to an order of magnitude. Other possible mechanisms for the frequency dependence, including absorptance, electron-surface plasmon interactions, a two-carrier model, and a structure dependence are considered, and it is concluded that the frequency dependence in the Drude scattering rates of the noble metals is not yet quantitatively understood
Parkins, G. R.↗
Steam reforming of n-hexane on pellet and monolithic catalyst beds. A comparative study on improvements due to heat transfer
Monolithic catalysts with higher available active surface areas and better thermal conductivity than conventional pellets beds, making possible the steam reforming of fuels heavier than naphtha, were examined. Performance comparisons were made between conventional pellet beds and honeycomb monolith catalysts using n-hexane as the fuel. Metal-supported monoliths were examined. These offer higher structural stability and higher thermal conductivity than ceramic supports. Data from two metal monoliths of different nickel catalyst loadings were compared to pellets under the same operating conditions. Improved heat transfer and better conversion efficiencies were obtained with the monolith having higher catalyst loading. Surface-gas interaction was observed throughout the length of the monoliths.
Source record↗
Absence of silicic volcanism on Mars - Implications for crustal composition and volatile abundance
It is believed that explosive basic to ultrabasic eruptions may be responsible for small cinder conelike features on Mars and perhaps for the ancient flank-scoured paterae. Eruptions of this type may have been driven by near-surface water/ice-magma interactions or volatile rich magmas. Noting that the paterae represent a unique style of volcanism that stopped approximately 2 b.y. ago, it is suggested that the volatiles associated with these features were derived from mantle sources and that the cessation of patera formation may coincide with the termination of the period of maximum planetary degassing. Since approximately 2 b.y. ago volcanism has been dominantly effusive, except for such minor explosive ash events as those that blanketed part of the summit of Hecates Tholus. It is proposed that such eruptions were driven by volatiles generated by differentiation of a magma chamber, similar to Icelandic explosive eruptions.
Francis, P. W.↗
Metastability of isoformyl ions in collisions with helium and hydrogen
The stability of HOC(+) ions under conditions in interstellar molecular clouds is considered. In particular, the possibility that collisions with helium or hydrogen will induce isomerization to the stable HCO(+) form is examined theoretically. Portions of the electronic potential energy surfaces for interaction with He and H atoms are obtained from standard quantum mechanical calculations. Collisions with He atoms are found to be totally ineffective for inducing isomerization. Collisions with H atoms are found to be ineffective at low interstellar temperatures owing to a small (about 500 K) barrier in the entrance channel; at higher temperatures where this barrier can be overcome, however, collisions with hydrogen atoms do result in conversion to the stable HCO(+) form. Although detailed calculations are not presented, it is argued that low-energy collisions with H2 molecules are also ineffective in destroying the metastable ion.
Green, S.↗
Solution influence on biomolecular equilibria - Nucleic acid base associations
Various attempts to construct an understanding of the influence of solution environment on biomolecular equilibria at the molecular level using computer simulation are discussed. First, the application of the formal statistical thermodynamic program for investigating biomolecular equilibria in solution is presented, addressing modeling and conceptual simplications such as perturbative methods, long-range interaction approximations, surface thermodynamics, and hydration shell. Then, Monte Carlo calculations on the associations of nucleic acid bases in both polar and nonpolar solvents such as water and carbon tetrachloride are carried out. The solvent contribution to the enthalpy of base association is positive (destabilizing) in both polar and nonpolar solvents while negative enthalpies for stacked complexes are obtained only when the solute-solute in vacuo energy is added to the total energy. The release upon association of solvent molecules from the first hydration layer around a solute to the bulk is accompanied by an increase in solute-solvent energy and decrease in solvent-solvent energy. The techniques presented are expectd to displace less molecular and more heuristic modeling of biomolecular equilibria in solution.
Pohorille, A.↗