Structural and electronic evolution in the Cu 3 SbS 4 –Cu 3 SnS 4 solid solution
Experimental and theoretical studies of the order–disorder transition in the Cu 3 SbS 4 –Cu 3 SnS 4 solid solution reveal evidence for S 2−δ species.
Chen, Kan↗
SEARCH · Engineering Papers
Results for “structural evolution”
Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
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Structural and reactive evolution of oxidatively grafted Pd catalysts on MnO 2 for the low-temperature oxidation of CO
We report Isolated Pd atoms supported on high surface area MnO 2 , prepared by the oxidative grafting of (bis(tricyclohexylphosphine-palladium(0)), catalyze (>50 turnovers, 17 h) the low temperature (≤325 K) oxidation of CO (7.7 kPa O 2 , 2.6 kPa CO) with results of in situ/operando and ex situ spectroscopic characterization signifying a synergistic role of Pd and MnO 2 in facilitating redox turnovers.
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
Evolution of the structural transition in Mo 1–x W x Te 2
The composition dependence of the structural transition between the monoclinic 1T' and orthorhombic Td phases in the Mo 1–x W x Te 2 Weyl semimetal was investigated by elastic neutron scattering on single crystals up to x ≈ 0.54. First observed in MoTe 2 , the transition from T d to 1T' is accompanied by an intermediate pseudo-orthorhombic phase, T d *. Upon doping with W, the T d * phase vanishes by x ≈ 0.34. Above this concentration, a phase coexistence behavior with both T d and 1T' is observed instead. The interlayer in-plane positioning parameter δ, which relates to the 1T' β angle, decreases with temperature as well as with W substitution, likely due to strong anharmonicity in the interlayer interactions. As a result, the temperature width of the phase coexistence remains almost constant up to x ≈ 0.54, in contrast to the broadening reported under pressure.
36 MATERIALS SCIENCE↗
Strain-controlled evolution of electronic structure indicating topological phase transition in the quasi-one-dimensional superconductor TaSe 3
In this work, we report the signature of a strain-controlled topological phase transition in the electronic structure of a quasione-dimensional superconductor TaSe 3 . Using angle-resolved photoemission spectroscopy and first-principles calculation, TaSe 3 is identified to be in a weak topological insulator phase which has topologically nontrivial surface states only at the allowed planes. Under uniaxial tensile strain, a Dirac point and the topological surface state emerge on the originally forbidden ($10\overline{1}$) plane, which demonstrates the transition to a strong topological insulator phase. Our results accomplish the experimental realization of possible topological insulating phases in TaSe 3 and highlight the possibility of coupling the superconductivity with two distinct topological insulating phases in a controllable manner.
75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
Evolution of water structures in metal-organic frameworks for improved atmospheric water harvesting
Designing water uptake Although the locations of water molecules in some porous materials have been determined with diffraction techniques, determining the filling sequence of water sites has been challenging. Hanikel et al . used single-crystal x-ray diffraction to locate all of the water molecules in pores of the metal-organic framework MOF-303 at different water loadings (see the Perspective by Öhrström and Amombo Noa). They used this information on the water molecule adsorption sequence to modify the linkers of this MOF and control the water-harvesting properties from humid air for different temperature regimes. —PDS
Science & Technology - Other Topics↗
In-situ measurements of surface structure and composition evolution during high-flux plasma exposure.
Abstract not provided.
Kolasinski, Robert↗
Replication Data for: Evolution of Metastable Structures at Bimetallic Surfaces from Microscopy and Machine-Learning Molecular Dynamics
The data underlying this published work have been made publicly available in this repository as part of the IMASC Data Management Plan. This work was supported as part of the Integrated Mesoscale Architectures for Sustainable Catalysis (IMASC), an Energy Frontier Research Center funded by the U.S. Department of Energy, Office of Science, Basic Energy Sciences under Award # DE-SC0012573.
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
Using Ghost Fronts Within STEREO Heliospheric Imager Data to Infer the Evolution in Longitudinal Structure of a Coronal Mass Ejection
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C. J. Scott↗
CME Evolution in the Structured Heliosphere and Effects at Earth and Mars During Solar Minimum
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Erika Palmerio↗
Temporal evolution of velocity structures in the solar wind
Generally poor correlations were obtained of solar wind flow speed measurements at one point in the ecliptic plane with measurements at the same point 28 days (one solar rotation) earlier or with measurements at other points in the ecliptic plane separated by 50 deg or more in solar longitude. This is evidence that either the flow speed is a very sensitive function of solar latitude or that temporal processes typically alter the speed of the wind emanating from particular solar regions on a time scale of about 4 days. From a measure of the persistence of the flow speed at the orbit of the earth, it appears that the temporal explanation is more likely to be the correct one.
Gosling, J. T.↗
The topology of large-scale structure. II - Nonlinear evolution of Gaussian models
The evolution of non-Gaussian behavior in the large-scale universe from Gaussian initial conditions is studied. Topology measures developed in previous papers are applied to the smoothed initial, final, and biased matter distributions of cold dark matter, white noise, and massive neutrino simulations. When the smoothing length is approximately twice the mass correlation length or larger, the evolved models look like the initial conditions, suggesting that random phase hypotheses in cosmology can be tested with adequate data sets. When a smaller smoothing length is used, nonlinear effects are recovered, so nonlinear effects on topology can be detected in redshift surveys after smoothing at the mean intergalaxy separation. Hot dark matter models develop manifestly non-Gaussian behavior attributable to phase correlations, with a topology reminiscent of bubble or sheet distributions. Cold dark matter models remain Gaussian, and biasing does not disguise this.
Melott, Adrian L.↗
Solid earth science in the 1990s. Volume 2: Panel reports
This is the second volume of a three-volume report. Volume 2, Panel Reports, outlines a plan for solid Earth science research for the next decade. The science panels addressed the following fields: plate motion and deformation, lithospheric structure and evolution, volcanology, Earth structure and dynamics, Earth rotation and reference frames, and geopotential fields.
Source record↗
Deformation mechanisms of NiAl cyclicly deformed near the brittle-to-ductile transition temperature
The intermetallic compound NiAl is one of many advanced materials which is being scrutinized for possible use in high temperature, structural applications. Stoichiometric NiAl has a high melting temperature, excellent oxidation resistance, and good thermal conductivity. Past research has concentrated on improving monotonic properties. The encouraging results obtained on binary and micro-alloyed NiAl over the past ten years have led to the broadening of NiAl experimental programs. The purpose of this research project was to determine the low cycle fatigue properties and dislocation mechanisms of stoichiometric NiAl at temperatures near the monotonic brittle-to-ductile transition. The fatigue properties were found to change only slightly in the temperature range of 600 to 700 K; a temperature range over which monotonic ductility and fracture strength increase markedly. The shape of the cyclic hardening curves coincided with the changes observed in the dislocation structures. The evolution of dislocation structures did not appear to change with temperature.
Cullers, Cheryl L.↗
Experimental validation of optimization-based integrated controls-structures design methodology for flexible space structures
An optimization-based integrated design approach for flexible space structures is experimentally validated using three types of dissipative controllers, including static, dynamic, and LQG dissipative controllers. The nominal phase-0 of the controls structure interaction evolutional model (CEM) structure is redesigned to minimize the average control power required to maintain specified root-mean-square line-of-sight pointing error under persistent disturbances. The redesign structure, phase-1 CEM, was assembled and tested against phase-0 CEM. It is analytically and experimentally demonstrated that integrated controls-structures design is substantially superior to that obtained through the traditional sequential approach. The capability of a software design tool based on an automated design procedure in a unified environment for structural and control designs is demonstrated.
Maghami, Peiman G.↗
Spatial Distribution of Ionospheric Plasma and Field Structures in the High-Latitude F Region
Ion density and velocity measurements from the Dynamics Explorer 2 (DE 2) spacecraft are used to obtain the average magnetic local time versus invariant latitude distribution of irregularities in the high-latitude F region ionosphere. To study the small-scale structure and its relationship to background conditions in the ionosphere, we have formed a reduced database using 2-s (approx. = 16 km) segments of the ion density and velocity data. The background gradients associated with each 2-s segment and the spectral characteristics, such as power at 6 Hz (approx. = 1.3 km) and spectral index, are among the reduced parameters used in this study. The relationship between the observed plasma structure and its motion is complex and dependent on the externally applied fields as well as locally generated plasma structure. The evolution of plasma structures also depends critically on the conductivity of the underlying ionosphere. Observations indicate an enhancement of irregularity amplitudes in two spatially isolated regions in both the ion density and the velocity. Convective properties seem to play a more important role in winter hemisphere where smaller-scale structures are maintained outside the source regions. (Delta)V irregularity amplitudes are enhanced in the cusp and the polar cap during northward interplanetary magnetic field regardless of season. The power in (Delta)V is usually higher than that associated with local polarization electric fields, suggesting that the observed structure in (Delta)N/N is strongly influenced by (Delta)V structure applied to large density gradients.
Kivanc, O.↗
Structure, Motion, and Evolution of Star-Forming Dense Cores
Under this grant in the past year we have pursued spectral-line observations of star-forming regions over size scales from 0.01 pc to 0.5 pc. Our main goal has been to measure the systematic and turbulent motions of condensing and collapsing gas. The following summary is excerpted from our recent application for a new three-year grant, submitted in June, 2002.
Myers, Philip C.↗
Structure, Motion, and Evolution of Star-Forming Dense Cores
We have pursued spectral-line observations of star-forming regions over size scales from 0.01 pc to 0.5 pc. Our main goal has been to measure the systematic and turbulent motions of condensing and collapsing gas.
Myers, Philip C.↗
Far-IR/Submillimeter Interferometry Missions in NASA's Roadmap: SPIRIT and SPECS
Information vital to the attainment of the major scientific objectives of NASA's Origins and Structure and Evolution of the Universe themes is uniquely available in the far-IR and submillimeter (FIR/SMM). NASA is studying concepts and investing in technologies for FIR/SMM observatories that could fly in the period 2010 - 2025 and provide enormous increases in measurement capabilities to extend the legacy of the next-generation missions SIRTF and Herschel. Future FIR/SMM space observatories will have the sensitivity needed to reach back in time to the formation epoch of the first luminous objects, the angular resolution needed to image proto-planetary systems and distinguish the emissions of individual galaxies, and the spectral resolution needed to probe the physical conditions and measure the flows of interstellar gas in young galaxies, nascent stars, and the dust-enshrouded nuclei of galaxies that harbor massive black holes. NASA's roadmap includes the JWST-class Single Aperture Far-IR (SAFIR) telescope and 1 km maximum-baseline FIR/SMM interferometer. This talk will focus on the niche for FIR/SMM interferometry and describe two missions: SPECS, the Submillimeter Probe of the Evolution of Cosmic Structure, and the pathfinder mission SPIRIT, the Space Infrared interferometric Telescope. I will give the scientific motivation for these missions, describe mission concepts and telescope measurement capabilities, and compare these capabilities with those of the next-generation IR telescopes, and with the complementary JWST and ALMA.
Leisawitz, David T.↗