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Global Properties of the Ejecta Absorptions in the Spectrum of Eta Carinae

Between 2400A to 3160A, we have identified approximately 500 absorption line complexes, each with up to 20 velocity components. Lines of Fe I, Fe II, Ti II, V II, Ni II, Co II, Mn II, Mg I, Mg II and Na I have been identified. Surprisingly, most of the lines originate from energy levels significantly above the ground level. This is indcative of optical pumping from the Central Source. Line widths and population of various levels are non-thermal. The relative column densities change with velocity. For example, Fe 11 column densities for one transition arising from approx. 0.l ev increase with ejecta velocity while Fe 11 column densities for another transition decreases with velocity. This may be due to softening of the ultraviolet radiation that pumps the various ions (neutrals) with velocity. If we assume that the distance of each system scales with distance from the Central Source, only a thirty percent change in distance is noted; yet the ratio of column densities for the Fe I1 examples given above changes by nearly thirty-fold. If the ejecta distance scales with distance from Eta Carinae, then it is likely that this ejecta originated at nearly the same time. The geometry of the Homunculus has been determined to be a double-lobed structure tilted out of the plane of the sky. We interpret the ejecta as being in the wall of the Southwest lobe, and that this wall just happens to be in line of sight from Eta Carinae to the observer. As Eta Carinae enters into the upcoming minimum, we are already seeing some evidence for changes in column densities due to changes in ultraviolet fluxes. This is reinforced by IUE observations that we have recently re-analyzed with respect to the 5.52 year (2020 +/- 10 days) spectroscopic period. Observations were done through STScI and funding was through the STIS GTO resources.

Gull, T. R.↗

Chandra X-Ray Observations of the Spiral Galaxy M81

A Chandra X-Ray Observatory ACIS-S imaging observation is used to study the population of X-ray sources in the nearby Sab galaxy M81 (NGC 3031). A total of 177 sources are detected with 124 located within the D(sub 25) isophote to a limiting X-ray luminosity of approx. 3 x 10(exp 36) ergs/s. Source positions, count rates, luminosities in the 0.3-8.0 keV band, limiting optical magnitudes, and potential counterpart identifications are tabulated. Spectral and timing analysis of the 36 brightest sources are reported including the low luminosity active galactic nucleus, SN 1993J, and the Einstein-discovered ultraluminous X-ray source X6. The nucleus accounts for approx. 86%, or 5 x 10(exp 40) ergs/s, of the total X-ray emission from M81. Its spectrum is well fitted by an absorbed power law with photon index 1.98 +/- 0.08, consistent with previous observations (average index 1.9). SN 1993J has softened and faded since its discovery. At an age of 2594 days, SN 1993J displayed a complex thermal spectrum from a reverse shock rich in Fe L and highly ionized Mg, Si, and S but lacking O. A hard X-ray component, emitted by a forward shock, is also present. X6 is spatially coincident with a stellar object with optical brightness and colors consistent with an O9-B1 main-sequence star. It is also coincident with a weak radio source with a flux density of approx. 95 microJy at lambda = 3.6 cm. The continuum-dominated X-ray spectrum of X6 is most closely reproduced by a blackbody disk model suggesting the X-ray source is an approx. 18 solar mass object accreting at nearly its Eddington limit.

Swartz, Douglas A.↗

Understanding the Long-Term Spectral Variability of Cygnus X-1 with Burst and Transient Source Experiment and All-Sky Monitor Observations

We present a comprehensive analysis of all observations of Cyg X-1 by the Compton Gamma Ray Observatory Burst and Transient Source Experiment (BATSE; 20-300 keV) and by the Rossi X-Ray Timing Explorer all-sky monitor (ASM; 1.5-12 keV) until 2002 June, including approximately 1200 days of simultaneous data. We find a number of correlations between fluxes and hardnesses in different energy bands. In the hard (low) spectral state, there is a negative correlation between the ASM 1.5-12 keV flux and the hardness at any energy. In the soft (high) spectral state, the ASM flux is positively correlated with the ASM hardness but uncorrelated with the BATSE hardness. In both spectral states, the BATSE hardness correlates with the flux above 100 keV, while it shows no correlation with the 20-100 keV flux. At the same time, there is clear correlation between the BATSE fluxes below and above 100 keV. In the hard state, most of the variability can be explained by softening the overall spectrum with a pivot at approximately 50 keV. There is also another, independent variability pattern of lower amplitude where the spectral shape does not change when the luminosity changes. In the soft state, the variability is mostly caused by a variable hard (Comptonized) spectral component of a constant shape superposed on a constant soft blackbody component. These variability patterns are in agreement with the dependencies of the rms variability on the photon energy in the two states. We also study in detail recent soft states from late 2000 until 2002. The last of them has lasted thus far for more than 200 days. Their spectra are generally harder in the 1.5-5 keV band and similar or softer in the 3-12 keV band than the spectra of the 1996 soft state, whereas the rms variability is stronger in all the ASM bands. On the other hand, the 1994 soft state transition observed by BATSE appears very similar to the 1996 one. We interpret the variability patterns in terms of theoretical Comptonization models. In the hard state, the variability appears to be driven mostly by changing flux in seed photons Comptonized in a hot thermal plasma cloud with an approximately constant power supply. In the soft state, the variability is consistent with flares of hybrid, thermal/nonthermal, plasma with variable power above a stable cold disk. The spectral and timing differences between the 1996 and 2000-2002 soft states are explained by a decrease of the color disk temperature. Also, on the basis of broadband pointed observations simultaneous with those of the ASM and BATSE, we find the intrinsic bolometric luminosity increases by a factor of approximately 3-4 from the hard state to the soft one, which supports models of the state transition based on a change of the accretion rate.

Zdziarski, Andrzej A.↗

Search for X-ray Spectral Features in Two BL Lac Objects

This grant covered the analysis and interpretation of astrophysical data obtained with the XMM-Newton satellite mission. BL Lac objects are active galactic nuclei that exhibit unusually strong polarization and variability, and are also missing the usual strong optical/ultraviolet emission lines. They are typically strong X-ray sources, but this is the first survey gathering high-quality spectral data from a significant number of these objects. The observations were successful, and all data (for objects in this proposal as well as that of Dr. Perlman s) were of very good quality, as expected. We find that the X-ray spectra of most of these objects are well described by a power-law after allowing for low-energy absorption that can be attributed to neutral gas in the line of sight, presumably located in our own Galaxy. However, in some cases we see indications of a deviation from power-law behavior in the sense that the spectrum appears to be steepening (softening) to higher energies. We are developing a theoretical model in which the steepening is a result of energy-dependent cooling of the radiating particles.We searched for discrete spectral features that might be intrinsic to the objects or their host galaxies, but we found none at the level of sensitivity provided by these data. These are interestingly strong upper bounds.

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Home Insulation With the Stroke of a Brush

Hy-Tech Thermal Solutions, LLC, of Melbourne, Florida, is producing a very complex blend of ceramic vacuum-filled refractory products designed to minimize the path of hot air transfer through ceilings, walls, and roofs. The insulating ceramic technology blocks the transfer of heat outward when applied to paint on interior walls and ceilings, and prevents the transfer of heat inward when used to paint exterior walls and roofs, effectively providing year-round comfort in the home. As a manufacturer and marketer of thermal solutions for residential, commercial, and industrial applications, Hy-Tech Thermal Solutions attributes its success to the high performance insulating ceramic microsphere originally developed from NASA thermal research at Ames Research Center. Shaped like a hollow ball so small that it looks as if it is a single grain of flour to the naked eye (slightly thicker than a human hair), the microsphere is noncombustible and fairly chemical-resistant, and has a wall thickness about 1/10 of the sphere diameter, a compressive strength of about 4,000 pounds per square inch, and a softening point of about 1,800 C. Hy-Tech Thermal Solutions improved upon these properties by removing all of the gas inside and creating a vacuum. In effect, a 'mini thermos bottle' is produced, acting as a barrier to heat by reflecting it away from the protected surface. When these microspheres are combined with other materials, they enhance the thermal resistance of those materials. In bulk, the tiny ceramic 'beads' have the appearance of a fine talcum powder. Their inert, nontoxic properties allow them to mix easily into any type of paint, coating, adhesive, masonry, or drywall finish. Additionally, their roundness causes them to behave like ball bearings, rolling upon each other, and letting the coatings flow smoothly. When applied like paint to a wall or roof, the microsphere coating shrinks down tight and creates a dense film of the vacuum cells. The resulting ceramic layer improves fire resistance, protects from ultraviolet rays, repels insects such as termites, and shields from the destructive forces of nature.

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XMM-Newton Spectroscopy of the Galactic Microquasar GRS 1758-258 in the Peculiar Off/Soft State

We report on an XMM-Newton Reflection Grating Spectrometer observation of the black hole candidate and Galactic microquasar GRS 1758-258. The source entered a peculiar "off/soft" state in 2001 late February in which the spectrum softened while the X-ray flux-and the inferred mass accretion rate-steadily decreased. We find no clear evidence for emission or absorption lines in the dispersed spectra, indicating that most of the observed soft flux is likely from an accretion disk and not from a cool plasma. The accretion disk strongly dominates the spectrum in this lower luminosity state and is only mildly recessed from the marginally stable orbit. These findings may be di8licult to explain in terms of advection-dominated accretion flow (ADAF) models. We discuss these results within the context of ADAF models, simultaneous two-flow models, and observed correlations between hard X-ray flux and jet production.

Miller, J. M.↗

Lunar and Planetary Science XXXV: Mars Polar Processes: Land and Sky

The titles in this section include: 1) Morphological Evidence for the Large-scale Evolution of Martian North Polar Troughs? 2) New Views of the Martian Polar Regions: The Latest Results from the Mars Odyssey THEMIS Investigation; 3) Observations at the Chasma Australe Re-Entrant, South Polar Region, Mars; 4) Stratigraphic Details of Uppermost Units within South Polar Layered Deposits on Mars; 5) Detailed Geologic Analysis of Part of the South Polar Layered Deposits, Planum Australe, Mars: Part II; 6) SHARAD: Radar Volume Scattering and the Polar Layered Terrains on Mars; 7) Arabia and Memnonia Equatorial Regions with High Content of Water: Data from HEND/Odyssey; 8) Alaskan Permafrost Analogs of Martian Small Valley Networks, Thermokarst, Terrain Softening, Terraces, and Volcanic Craters; 9) Periglacial Processes in the Southern Hemisphere of Mars; 10) Thermal Modeling of Possible Surface Water Ice Deposits in Juventae Chasma; 11) Modeling Depth to Ground Ice on Mars; 12) Ground Ice at the Phoenix Landing Site: A Preflight Assessment; 13) Possible Temperature-related Differences in Slope Angle between the North and South Walls of Coprates Chasma, Mars; 14) Seasonal Variations within Korolev Crater, Mars; 15) South Polar Ar Enhancement as a Tracer for Southern Winter Horizontal Meridional Mixing; 16) An Investigation of the Correlation of Water-Ice and Dust Retrievals via the MGS TES Data Set; 17) Observations of Plasma Waves near Mars and Their Implications for Atmospheric Loss.

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Lunar and Planetary Science XXXV: Mercury, Top to Bottom

The following topics were discussed in this document: Resonant Rotation of the Two-Layer Mercury Model; Chronology of Lobate Scarp Thrust Faults and the Mechanical Structure of Mercury's Lithosphere; Mercury: Determination of Internal Structure and Evolution; Searching for Terrain Softening near Mercury's North Pole; Mercury: First Spectra from 0.7 to 5.5 micron Support Low FeO and Feldspathic Composition.

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Progressive Damage Analyses of Skin/Stringer Debonding

The debonding of skin/stringer constructions is analyzed using a step-by-step simulation of material degradation based on strain softening decohesion elements and a ply degradation procedure. Decohesion elements with mixed-mode capability are placed at the interface between the skin and the flange to simulate the initiation and propagation of the delamination. In addition, the initiation and accumulation of fiber failure and matrix damage is modeled using Hashin-type failure criteria and their corresponding material degradation schedules. The debonding predictions using simplified three-dimensional models correlate well with test results.

Daville, Carlos G.↗

The growing world of expansins

Expansins are cell wall proteins that induce pH-dependent wall extension and stress relaxation in a characteristic and unique manner. Two families of expansins are known, named alpha- and beta-expansins, and they comprise large multigene families whose members show diverse organ-, tissue- and cell-specific expression patterns. Other genes that bear distant sequence similarity to expansins are also represented in the sequence databases, but their biological and biochemical functions have not yet been uncovered. Expansin appears to weaken glucan-glucan binding, but its detailed mechanism of action is not well established. The biological roles of expansins are diverse, but can be related to the action of expansins to loosen cell walls, for example during cell enlargement, fruit softening, pollen tube and root hair growth, and abscission. Expansin-like proteins have also been identified in bacteria and fungi, where they may aid microbial invasion of the plant body.

NASA Discipline Plant Biology↗

Crustal Magnetic Spectra from Correlated Sources on Mars

The spectral method for distinguishing crustal from core-source magnetic fields has been re-examined, modified and applied to both a comprehensive geomagnetic field model and an altitude normalized magnetic map of Mars. These observational spectra are fairly fitted by theoretical forms expected from certain elementary classes of magnetic sources. For Earth we found fields from a core radius 3512 +/- 64 km and a crust represented by a shell of random dipolar sources at radius 6367 +/- 14 km. For Mars we found only a field from a crust represented in the same way, but 46 +/- 10 km below the planetary menu radius. More realistic theoretical spectra, allowing for crustal thickness, oblateness and magnetization by a planet centered dipole, were derived and discussed, as were spectral effects of laterally correlated sources. The main effect of laterally correlated sources is to soften the spectrum at high degrees. We tend to over-estimate source shell depth when this is omitted. To include this effect simply size and magnetization distribution functions for extended sources are recast as a characteristic diameter and mean square magnetization amplitude for an ensemble of vertically magnetized spherical caps on a shell. For small caps, and at moderated degrees, the practical derivatives of the log-theoretical spectrum with respect to amplitude, shell radius, and cap diameter are approximately proportional to l, n, and -n **2, respectively. Separation of diameter from amplitude from layer thickness. Results from applications to observational spectra are discussed, noting that there are now several fine field models for Mars; moreover, the terrestrial magnetic spectrum at high degrees, as revised, updated with high precision Oerstad data, and upgrade with high resolution Champ data, appears softer than before.

Voorhies, Coerte V.↗

An Expanded RXTE Survey of Long-Term X-ray Variability in Seyfert 1 Galaxies

The first seven years of RXTE monitoring of Seyfert 1 active galactic nuclei have been systematically analyzed to yield five homogenous samples of 2-12 keV light curves, probing hard X-ray variability on successively longer durations from approx. 1 day to approx. 3.5 years. 2-10 keV variability on time scales of approx. 1 day, as probed by ASCA, are included. All sources exhibit stronger X-ray variability towards longer time scales, with variability amplitudes saturating at the longest time scales, but the increase is greater for relatively higher luminosity sources. The well-documented anticorrelation between variability amplitude and luminosity is confirmed on all time scales. However, anticorrelations between variability amplitude and black hole mass estimate are evident on only the shortest time scales probed. The data are consistent with the models of power spectral density (PSD) movement described in Markowitz et al. (2003) and McHardy et al. (2004), whereby Seyfert 1 galaxies variability can be described by a single, universal PSD shape whose cutoff frequency scales with black hole mass. The best-fitting scaling relations between variability time scale, black hole mass and X-ray luminosity support an average accretion rate of 2% of the Eddington limit for the sample. Nearly all sources exhibit stronger variability in the relatively soft 2-4 keV band compared to the 7-12 keV band on all time scales. Color-flux diagrams support also Seyfert 1s' softening as they brighten. There are indications that relatively less luminous or less massive sources exhibit a greater degree of spectral variability for a given increase in overall flux.

Markowitz, A.↗

The Chandra Large Area Synoptic X-ray Survey (CLASXS) of the Lockman Hole-Northwest: The X-ray Catalog

We present the X-ray catalog and basic results from our Chandra Large Area Synoptic X-ray Survey (CLASXS) of the Lockman Hole-Northwest field. Our 9 ACIS-I fields cover a contiguous solid angle of approx. 0.4 sq deg and reach fluxes of 5 x 10(exp -16) ergs/sq cm/s (0.4-2 keV) and 3 x 10(exp -15) ergs/sq cm/s (2-8 keV). Our survey bridges the gap between ultradeep pencil-beam surveys, such as the Chandra Deep Fields (CDFs), and shallower, large area surveys, allowing a better probe of the X-ray sources that contribute most of the 2-10 keV cosmic X-ray background (CXB). We find a total of 525 X-ray point sources and 4 extended sources. At approx. 10(exp -14)ergs/sq cm/s (2-8 keV), our number counts are significantly higher than those of several non-contiguous, large area surveys. Such a large difference is an indication of clustering in the X-ray sources. On the other hand, the integrated flux from the CLASXS field, combined with ASCA and Chandra ultradeep surveys, is consistent with results from other large area surveys, within the variance of the CXB. We see spectral evolution in the hardening of the sources at fluxes below 10(exp -14) ergs/sq cm/s, which agrees with previous observations from Chandra and XMM-Newton. About 1/3 of the sources in the CLASXS field have multiple observations, allowing variability tests. Above 4 x 10(exp -14) ergs/sq cm/s (0.4-8 keV), approx. 61% of the sources are variable. We also investigated the spectral variability of the variable sources. While most show spectral softening with increasing flux, or no significant spectral change, there are a few sources that show a different trend. Four extended sources in CLASXS is consistent with the previously measured LogN-LogS of galaxy clusters. Using X-ray spectra and optical colors, we argue that 3 of the 4 extended sources are galaxy clusters or galaxy groups. We report the discovery of a gravitational lensing arc associated with one of these sources. Using red sequence and brightest cluster galaxy methods, we find that the redshifts of the extended sources are in the range z approx. 0.5 - 1. The inferred masses within the Einstein radii are consistent with the mass profiles of local groups scaled to the same virial radii.

Yang, Y.↗

Simultaneous Multiwavelength Monitoring of 3C66A

The radio-selected BL Lac object 3C66A was the target of an intensive multiwavelength campaign from Sept. 2003 through Feb. 2004. It was monitored by the Whole Earth Blazar Telescope (WEBT) collaboration, in tandem with 20 X-ray monitoring observations by the Rossi X-Ray Timing Explorer (RXTE), VHE gamma-ray observations by STACEE and VERITAS, and long-term monitoring at radio frequencies. In addition. 9 observations using the VLBA are being carried out during the campaign and throughout the year 2004 to follow possible structural changes of the source. 21 pointings with RXTE during the period Sept. 15 - Dec. 27, 2003. All collected data have been fully analyzed, and first results have already been published at the 8th HEAD Meeting in New Orleans, LA, in Sept. 2004, and will also be presented at the 205th AAS Meeting in San Diego, CA, in Jan. 2005. A first Journal paper, to be submitted to the Astrophysical Journal, is currently in preparation, and we plan to have it ready for submission in January 2005. A gradual brightening of the source over the course of the campaign was observed at all optical frequencies, culminating in a very bright flare at the end of January 2004. Optical light curves indicate intraday microvariability on time scales down to about 1.3 hours. No significant color-magnitude correlation for the entire data set was evident, but there is a slight indication of a gradual spectral softening in the optical over the entire duration of multi-day outbursts (in both the rising and decaying phase). The X-ray spectrum is consistent with a power-law with a photon spectral index of approx. 2.1, indicating that the RXTE energy band might be located right at the intersection of the synchrotron and the high-energy emission components. No significant flux or spectral variability at X-ray energies was detected, though there seems to be a trend of very modest brightening in tandem with the optical flux. The first 4 VLBA epochs indicate a rather smooth jet with only very moderate internal structure. After decomposition in Gaussian components, evidence for superluminal motion (11.0+/-4.7/h c) was found in only one out of 6 jet components. The radial radio brightness profile suggests a magnetic field decay infinity/r and, thus, a predominantly perpendicular magnetic field orientation.

Boettcher, M.↗

Downscattering due to Wind Outflows in Compact X-ray Sources: Theory and Interpretation

A number of recent lines of evidence point towards the presence of hot, outflowing plasma from the central regions of compact Galactic and extragalactic X-ray sources. Additionally, it has long been noted that many of these sources exhibit an "excess" continuum component, above approx. 10 keV, usually attributed to Compton Reflection from a static medium. Motivated by these facts, as well as by recent observational constraints on the Compton reflection models - specifically apparently discrepant variability timescales for line and continuum components in some cases - we consider possible of effects of out-flowing plasma on the high-energy continuum spectra of accretion powered compact objects. We present a general formulation for photon downscattering diffusion which includes recoil and Comptonization effects due to divergence of the flow. We then develop an analytical theory for the spectral formation in such systems that allows us to derive formulae for the emergent spectrum. Finally we perform the analytical model fitting on several Galactic X-ray binaries. Objects which have been modeled with high-covering-fraction Compton reflectors, such as GS1353-64 are included in our analysis. In addition, Cyg X-3, is which is widely believed to be characterized by dense circumstellar winds with temperature of order 10(exp 6) K, provides an interesting test case. Data from INTEGRAL and RXTE covering the approx. 3 - 300 keV range are used in our analysis. We further consider the possibility that the widely noted distortion of the power-law continuum above 10 keV may in some cases be explained by these spectral softening effects.

Titarchuk, Lev↗

Effects of Control Mode and R-Ratio on the Fatigue Behavior of a Metal Matrix Composite

Composite Because of their high specific stiffness and strength at elevated temperatures, continuously reinforced metal matrix composites (MMC's) are under consideration for a future generation of aeropropulsion systems. Since components in aeropropulsion systems experience substantial cyclic thermal and mechanical loads, the fatigue behavior of MMC's is of great interest. Almost without exception, previous investigations of the fatigue behavior of MMC's have been conducted in a tension-tension, load-controlled mode. This has been due to the fact that available material is typically less than 2.5-mm thick and, therefore, unable to withstand high compressive loads without buckling. Since one possible use of MMC's is in aircraft skins, this type of testing mode may be appropriate. However, unlike aircraft skins, most engine components are thick. In addition, the transient thermal gradients experienced in an aircraft engine will impose tension-compression loading on engine components, requiring designers to understand how the MMC will behave under fully reversed loading conditions. The increased thickness of the MMC may also affect the fatigue life. Traditionally, low-cycle fatigue (LCF) tests on MMC's have been performed in load control. For monolithic alloys, low-cycle fatigue tests are more typically performed in strain control. Two reasons justify this choice: (1) the critical volume from which cracks initiate and grow is generally small and elastically constrained by the larger surrounding volume of material, and (2) load-controlled, low-cycle fatigue tests of monolithics invariably lead to unconstrained ratcheting and localized necking--an undesired material response because the failure mechanism is far more severe than, and unrelated to, the fatigue mechanism being studied. It is unknown if this is the proper approach to composite testing. However, there is a lack of strain-controlled data on which to base any decisions. Consequently, this study addresses the isothermal, LCF behavior of a [0]_32 MMC tested under strain- and load-controlled conditions for both zero-tension and tension-compression loading conditions. These tests were run at 427 C on thick specimens of SiC-reinforced Ti-15-3. For the fully-reversed tests, no difference was observed in the lives between the load- and strain-controlled tests. However, for the zero-tension tests, the strain-controlled tests had longer lives by a factor of 3 in comparison to the load-controlled tests. This was due to the fact that under strain-control the specimens cyclically softened, reducing the cracking potential. In contrast, the load-controlled tests ratcheted toward larger tensile strains leading to an eventual overload of the fibers. Fatigue tests revealed that specimens tested under fully-reversed conditions had lives approximately an order of magnitude longer than for those specimens tested under zero tension. When examined on a strain-range basis, the fully reversed specimens had similar, but still shorter lives than those of the unreinforced matrix material. However, the composite had a strain limitation at short lives because of the limited strain capacity of the brittle ceramic fiber. The composite also suffered at very high lives because of the lack of an apparent fatigue limit in comparison to the unreinforced matrix. The value of adding fibers to the matrix is apparent when the fatigue lives are plotted as a function of stress range. Here, the composite is far superior to the unreinforced matrix because of the additional load-carrying capacity of the fibers.

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Layered Deposits and Pitted Terrain in the Circum Hellas Region

Much of the southern highlands has been mantled since the Noachian, including a general blanket of possibly airfall-derived sediment that softens the landscape, the Electris mantle including knobby chaos in several basins, and a variety of deposits that are the subject of this study that share the common characteristics of being generally confined to basins and crater floors and that manifest irregular interior depressions. Many of these features occur in a zone surrounding Hellas. These deposits share the general characteristics of having fairly smooth, nearly planar surfaces and abrupt scarps bordering interior and marginal depressions. Despite these common characteristics, a wide range of morphologies occurs. Several end-members are discussed below. Additional information is included in the original extended abstract.

Moore, J. M.↗

Characterization of Ternary NiTiPt High-Temperature Shape Memory Alloys

Pt additions substituted for Ni in NiTi alloys are known to increase the transformation temperature of the alloy but only at fairly high Pt levels. However, until now only ternary compositions with a very specific stoichiometry, Ni50-xPtxTi50, have been investigated and then only to very limited extent. In order to learn about this potential high-temperature shape memory alloy system, a series of over twenty alloys along and on either side of a line of constant stoichiometry between NiTi and TiPt were arc melted, homogenized, and characterized in terms of their microstructure, transformation temperatures, and hardness. The resulting microstructures were examined by scanning electron microscopy and the phase compositions quantified by energy dispersive spectroscopy."Stoichiometric" compositions along a line of constant stoichiometry between NiTi to TiPt were essentially single phase but by any deviations from a stoichiometry of (Ni,Pt)50Ti50 resulted in the presence of at least two different intermetallic phases, depending on the overall composition of the alloy. Essentially all alloys, whether single or two-phase, still under went a martensitic transformation. It was found that the transformation temperatures were depressed with initial Pt additions but at levels greater than 10 at.% the transformation temperature increased linearly with Pt content. Also, the transformation temperatures were relatively insensitive to alloy stoichiometry within the range of alloys examined. Finally, the dependence of hardness on Pt content for a series of Ni50-xPtxTi50 alloys showed solution softening at low Pt levels, while hardening was observed in ternary alloys containing more than about 10 at.% Pt. On either side of these "stoichiometric" compositions, hardness was also found to increase significantly.

Rios, Orlando↗