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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
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Inertial sensors reviewing ring laser, electrostatic fluid sphere, magnetic resonance, superconductivity gyroscope, relativistic rotating tensor, vortex rate and quantum mechanical effect sensing
Sulfur trioxide production in photolysis of sulfur dioxide at 1849 angstroms, noting oxygen addition effect on quantum yield
Pressure effects on quantum yields of carbon trioxide formation in gas phase ozone photolysis with carbon dioxide
In this paper a completely classical model for laser action is discussed. An active medium consisting of classical anharmonic oscillators interacts with a classical electromagnetic field in a resonant cavity. Comparison with the case of a medium consisting of harmonic oscillators shows the significance of nonlinearities for producing self-sustained oscillations in the radiation field. The results for the classical model are found to be similar to those for a semiclassical model of the ammonia-beam maser. The conclusion is that laser action is not intrinsically a quantum-mechanical effect. The classical-laser theory as given in this paper can also be applied to the case of the electron-cyclotron maser.
Various atomic constant for 23 elements from helium to mercury were computed and are presented in tables. The data given for each element start with the element name, its atomic number, its ionic state, and the designation and series limit for each parent configuration. This is followed by information on the energy level, parent configuration, and designation for each term available to the program. The matrix elements subtables are ordered by the sequence numbers, which represent the initial and final levels of the transitions. Each subtable gives the following: configuration of the core or parent, designation and energy level for the reference state, effective principal quantum number, energy of the series limit, value of the matrix element for the reference state interacting with itself, and sum of all of the dipole matrix elements listed in the subtable. Dipole and quadrupole interaction data are also given.
The indeterminacy inherent to the formal extension of Arrhenius' law to reactions in turbulent flows is shown to be surmountable in the case of a binary exchange reaction with a sufficiently high activation energy. A preliminary calculation predicts that the turbulent reaction rate is invariant in the Arrhenius form except for an equivalently lowered activation energy. This is a reflection of turbulence-augmented molecular vigor, and causes an appreciable increase in the reaction rate. A similarity to the tunnel effect in quantum mechanics is indicated. The anomaly associated with the mild ignition of oxy-hydrogen mixtures is discussed in this light.
The results describing the dc and CO2 laser heterodyne characteristics of a three element photodiode array and single element and four element photodiode arrays are presented. The measured data shows that the n(+)-p configuration is capable of achieving bandwidths of 475 to 725 MHz and noise equivalent powers of 3.2 x 10 to the minus 20th power W/Hz at 77 K and 1.0 x 10 to the minus 19th power W/Hz at 145 K. The n(+)-n(-)-p photodiodes exhibited wide bandwidths (approximately 2.0 GHz) and fairly good effective heterodyne quantum efficiencies (approximately 13-30 percent at 2.0 GHz). Noise equivalent powers ranging from 1.44 x 10 to the minus 19th power W/Hz to 6.23 x 10 to the minus 20th power W/Hz were measured at 2.0 GHz.
Silicon superlattices and their applicability to improved semiconductor devices were studied. The device application potential of the atomic like dimension of III-V semiconductor superlattices fabricated in the form of ultrathin periodically layered heterostructures was examined. Whether this leads to quantum size effects and creates the possibility to alter familiar transport and optical properties over broad physical ranges was studied. Applications to improved semiconductor lasers and electrondevices were achieved. Possible application of silicon sperlattices to faster high speed computing devices was examined. It was found that the silicon lattices show features of smaller fundamental energyband gaps and reduced effective masses. The effects correlate strongly with both the chemical and geometrical nature of the superlattice.
A new L(2) approach for the calculation of the threshold molecular capture width needed for the determination of DR cross sections was developed. The widths are calculated with Fermi's golden rule by substituting Rydberg orbitals for the free electron continuum coulomb orbital. It is shown that the calculated width converges exponentially as the effective principal quantum number of the Rydberg orbital increases. The threshold capture width is then easily obtained. Since atmospheric recombination involves very low energy electrons, the threshold capture widths are essential to the calculation of DR cross sections for the atmospheric species studied here. The approach described makes use of bound state computer codes already in use. A program that collects width matrix elements over CI wavefunctions for the initial and final states is described.
Atomic inner-shell processes have quite different characteristics, in several important aspects, from processes in the optical regime. Energies are large, e.g., the 1s binding energy reaches 100 keV at Z = 87; relativistic and quantum-electrodynamic effects therefore are strong. Radiationless transitions vastly dominate over photon emission in most cases. Isolated inner-shell vacancies have pronounced single-particle character, with correlations generally contributing only approximately 1 eV to the 1s and 2p binding energies; the structure of such systems is thus well tractable by independent-particle self-consistent-field atomic models. For systems containing multiple deep inner-shell vacancies, or for highly stripped ions, the importance of relativistic intermediate coupling and configuration interaction becomes pronounced. Cancellation of the Coulomb interaction can lead to strong manifestations of the Breit interaction in such phenomena as multiplet splitting and hypersatellite X-ray shifts. Unique opportunities arise for the test of theory.
Copper chloride intercalated pitch-based carbon fibers are found to have electrical resistivities as low as 12.9 micro-ohm-cm, and are air- and thermally-stable at and above room temperature. This is therefore a good candidate system for conductor application. In addition, Shubnikov-deHaas quantum oscillatory effects were found, and electronic properties of the intercalated fiber are studied using magnetic fields to 20 tesla.
Analytical formulae are fitted to observational data on physical processes occurring in strong magnetic fields surrounding accreting neutron stars. The propagation of normal modes in the presence of a quantizing magnetic field is discussed in terms of a wave equation in Fourier space, quantum electrodynamic effects, polarization and mode ellipticity. The results are applied to calculating the Thomson scattering, bremsstrahlung and Compton scattering cross-sections, which are a function of the frequency, angle and polarization of the magnetic field. Numerical procedures are explored for solving the radiative transfer equations. When applied to modeling X ray pulsars, a problem arises in the necessity to couple the magnetic angle and frequency dependence of the cross-sections with the hydrodynamic equations. The use of time-dependent averaging and approximation techniques is indicated.
An optical field produced by intracavity four-wave mixing is shown to exhibit the following nonclassical features: photon antibunching, squeezing, and violation of Cauchy-Schwarz and Bell's inequalities. These intrinsic quantum mechanical effects are shown to be associated with the nonexistence of a positive normalizable Glauber-Sudarshan P function.
The factors affecting optical communication link performance differ substantially from those at microwave frequencies, due to the drastically differing technologies, modulation formats, and effects of quantum noise in optical communications. In addition detailed design control table calculations for optical systems are less well developed than corresponding microwave system techniques, reflecting the relatively less mature state of development of optical communications. Described below are detailed calculations of received optical signal and background power in optical communication systems, with emphasis on analytic models for accurately predicting transmitter and receiver system losses.
The distribution of dust-scattered intensity in Halley's inner coma is measured with the Vega three-channel spectrometer at three selected wavelengths: 377, 482, and 607 nm. The variation along a cometo-centric radius may be described by a p(sup -s) law where p is the distance between nucleus and optical axis and s is an exponent which is equal to 1 except in an intermediate 3000 less than p less than 7000 km region where s = 1.5. The shape of the radial distribution may be explained with a model including solar radiation pressure effect and quantum scattering efficiencies calculated from Mie theory. Monochromatic images inside an angular sector having its apex at the nucleus show evidence of two dust jets which extend to 40,000 Km. The pixel-to-pixel ratio of two images of dust intensity at 377 and 482 nm shows that the scattered intensity presents an excess of blue coloration in a zone located around the jets between 10,000 and 25,000 km. This coloration is interpreted as being due to a population of sub-micronic grains which result of the fragmentation of dust particles transported in the jets. It is suggested that the diffuse source where an additional quantity of CO was detected might be connected with the presence of a dust jet. In the present scheme, grain particles with a size of several micron or 10 micron would be transported inside a dust jet to distances of several 10,000 km where they would suffer fragmentation and produce sub-micronic particles and a release of gas which would be at the origin of the diffuse source.
Quantum mechanical methods have been used to compute potential energy surfaces for chemical reactions. The reactions studied were among those believed to be important to the NASP and HSR programs and included the recombination of two H atoms with several different third bodies; the reactions in the thermal Zeldovich mechanism; the reactions of H atom with O2, N2, and NO; reactions involved in the thermal De-NO(x) process; and the reaction of CH(squared Pi) with N2 (leading to 'prompt NO'). These potential energy surfaces have been used to compute reaction rate constants and rates of unimolecular decomposition. An additional application was the calculation of transport properties of gases using a semiclassical approximation (and in the case of interactions involving hydrogen inclusion of quantum mechanical effects).
The Far Ultraviolet Wideband Imaging Camera (WIC) complements the magnetospheric images taken by the IMAGE satellite instruments with simultaneous global maps of the terrestrial aurora. Thus, a primary requirement of WIC is to image the total intensity of the aurora in wavelength regions most representative of the aurora] source and least contaminated by dayglow, have sufficient field of view to cover the entire polar region from spacecraft apogee and have resolution that is Sufficient to resolve auroras on a scale of 1 to 2 latitude degrees, The instrument is sensitive in the spectral region from 140- 190 nm. The WIC is mounted on the rotating, IMAGE spacecraft viewing radially outward and has a field of view of 17 deg in the direction parallel to the spacecraft spin axis. Its field of view is 30 deg in the direction perpendicular to the spin axis, although only a 17 deg x 17 deg image of the Earth is recorded. The optics was an all-reflective, inverted Cassegrain Burch camera using concentric optics with a small convex primary and a large concave secondary mirror. The mirrors were coated by a special multi-layer coating, which has low reflectivity in the visible and near UV region, The detector consists of a MCP-Intensified CCD. The MCP is curved to accommodate the focal surface of the concentric optics. Tile phosphor of the image intensifier is deposited on a concave fiberoptic window, which is then Coupled to the CCD with a fiberoptic taper. The camera head operates in a fast frame transfer mode with the CCD being read approximately 30 full frames (512 by 256 pixel) per second with an exposure time of 0.033 s. The image motion (file to the satellite spin is minimal during such a short exposure. Each image is electronically distortion corrected using the look up table scheme. An offset is added to each memory address that is proportional to the image shift due to satellite rotation, and the charge signal is digitally summed in memory. On orbit, approximately 300 frames will be added to produce one WIC image in memory. The advantage of the electronic motion compensation and distortion correction is that it is extremely flexible, permitting several kinds of corrections including motions parallel and perpendicular to the predicted axis of rotation. File instrument was calibrated by applying ultraviolet light through a vacuum monochromator and measuring the absolute responsivity of the instrument. To obtain the data for the distortion look up table the camera was turned through various angles and the input angles corresponding to a pixel matrix were recorded. It was found that the spectral response peaked at 150 nm and fell off in either direction. The equivalent aperture of the camera, including mirror reflectivities and effective photocathode quantum efficiency, is about 0.04 sq cm. Thus, a 100 Rayleigh LBH aurora is expected to produce 23 equivalent counts per pixel per 10 s exposure at the peak of instrument response.
A thermoelectric device formed of nanowires on the nm scale. The nanowires are preferably of a size that causes quantum confinement effects within the wires. The wires are connected together into a bundle to increase the power density.