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At least 739 records · Page 41

Hard X-Ray Lags in GRO J1719-24

We have used the Fourier cross spectra of GRO J1719-24. as obtained with BATSE, to estimate the phase lags between the X-ray flux variations in the 20-,50 and 50-100 keV energy bands as a function of Fourier frequency in the interval 0.002-0.488 Hz. Our analysis covers the entire approximately 80 day X-ray outburst of this black-hole candidate, following the first X-ray detection on 1993 September 25. The X-ray variations in the 50-100 keV band, lag those in the 20-50 keV energy band by an approximately constant phase difference of 0.072 +/- 0.010 rad in the frequency interval 0.02-0.20 Hz. The time lags of GRO J1719-24 decrease with frequency as a power law, with index 1.04 +/- 0.13 for frequencies >/= 0.01 Hz. These results are discussed together with those obtained in recent similar studies of the black-hole candidates Cyg X-1 and GRO J0422+32.

VanderHooft, Frank↗

Hard X-Ray Lags in GRO J1719--24

We have used the Fourier cross spectra of GRO J1719-24, obtained with BATSE, to estimate the phase lags between the X-ray flux variations in the 20 50 and 50-100 keV energy bands as a function of Fourier frequency in the interval 0.002-0.488 Hz. Our analysis covers the entire about 80 day X-ray outburst of this black hole candidate, following the first X-ray detection on 1993 September 25. The X-ray variations in the 50-100 keV band lag those in the 20-50 keV energy band by an approximately constant phase difference of 0.072 + 0.010 rad in the frequency interval 0.02-0.20 Hz. The peak phase lags in the interval 0.02-0.20 Hz are about twice those of Cyg X-1 and GRO J0422+32. These results are consistent with models for Comptonization regions composed of extended nonuniform clouds around the central source.

VanDerHooft, F.↗

Vital phase of space science

Space science began with the indirect phase where the activity in space was inferred from such terrestrial phenomena as geomagnetic storms, ionospheric variations, and fluctuations in the cosmic ray intensity. The direct phase was initiated with spaceflight placing instruments directly in space and permitting the direct observation of UV and X rays, as well as precision observations of solar luminosity variations. The evidence from these many direct studies, together with the historical record of terrestrial conditions, shows that the variations of the luminosity of the Sun affect the terrestrial atmosphere at all levels, with devastating changes in climate tracking the major changes in the activity level and luminosity of the Sun. The quantification and understanding of this vital connection should be the first priority of space science and geophysics, from oceans and atmosphere through the ionosphere, magnetosphere, and all the way to the convective zone of the Sun. It becomes the vital phase of space science, focused on the basic science of the changing habitability of Earth.

Parker, E. N.↗

GraphTango: A Hybrid Representation Format for Efficient Streaming Graph Updates and Analysis

Abstract Streaming graph processing performs batched updates and analytics on a time-evolving graph. The underlying representation format of the graph largely determines the throughputs of these updates and analytics phases. Existing representation formats usually employ variations of hash tables or adjacency lists. However, a recent study showed that the adjacency-list-based approaches perform poorly on heavy-tailed graphs, and the hash table-based approaches suffer on short-tailed graphs. We propose GraphTango, a hybrid representation format that provides excellent update and analytics throughput regardless of the graph’s degree distribution. GraphTango dynamically switches among three different formats based on a vertex’s degree: (i) Low-degree vertices store the edges directly with the neighborhood metadata, confining accesses to a single cache line, (2) Medium-degree vertices use adjacency lists, and (3) High-degree vertices use hash tables as well as adjacency lists. In this case, the adjacency list provides fast traversal during the analytics phase, while the hash table provides constant-time lookups during the update phase. We further optimized the performance by designing an open-addressing-based hash table that fully utilizes every fetched cache line. In addition, we developed a thread-local lock-free memory pool that allows fast growing/shrinking of the adjacency lists and hash tables in a multi-threaded environment. We evaluated GraphTango with the help of the SAGA-Bench framework and compared it with four other representation formats: Stinger, Degree-aware Robin Hood Hashing, and two adjacency list-based formats with different workload balancing scheme. On average, GraphTango provides 4.5x higher insertion throughput, 3.2x higher deletion throughput, and 1.1x higher analytics throughput over the next best format. Furthermore, we integrated GraphTango with the state-of-the-art graph processing frameworks DZiG and RisGraph. Compared to the vanilla DZiG and vanilla RisGraph , [ GraphTango + DZiG ] and [ GraphTango + RisGraph ] reduces the average batch processing time by 2.3x and 1.5x, respectively.

Ahmed, Alif↗

Performance analysis and simulation of the SPS reference phase control system

The major elements required in the operation of an SPS which employs retrodirectivity as a means of pointing the beam to Earth include the spacetenna, the rectenna, and the pilot signal transmitter. The phase control system is faced with several problems: (1) path delay variations due to imperfect SPS circular orbits; (2) ionospheric effects; (3) initial phase beam forming; (4) beam pointing; (5) beam safing; (6) high power phase noise effects; and (7) interference. The use of SOLARISM, a computer program to select pilot signal parameters and evaluate SPS performance is described.

Lindsey, W. C.↗

Extraordinarily strong magneto-responsiveness in phase-separated LaFe 2 Si

Materials responding vigorously to minor variations of external stimuli with negligible hysteresis could revolutionize many of the energy technologies, including refrigeration, actuation, and sensing. Here, we report a combined experimental and theoretical study of a two-phase composite, naturally formed at the LaFe 2 Si stoichiometry, which exhibits a nearly anhysteretic, two-step first-order ferromagnetic-to-paramagnetic phase transformation with enhanced sensitivity to an external magnetic field. Other unusual properties include a large plateau-like positive magnetoresistance, magnetic-field-induced temperature and entropy changes occurring over a wide temperature range, and a Griffiths-like phase associated with short-range ferromagnetic clustering in the paramagnetic state. The heat capacity, magnetization, Mössbauer spectroscopy, and electrical resistivity, all exhibit characteristic, unusually sharp, first-order discontinuities even in magnetic fields as high as 100 kOe. We expect that similar phenomena could be designed in other mixed-phase systems, leading to novel functionalities, such as giant caloric effects in many yet undiscovered or/and underperforming intermetallic compounds.

36 MATERIALS SCIENCE↗

Three-dimensional imaging of grain boundaries via quantitative fluorescence X-ray tomography analysis

Abstract Three-dimensional visualization of material composition within multiple grains and across complex networks of grain boundaries at nanoscales can provide new insight into the structure evolution and emerging functional properties of the material for diverse applications. Here, using nanoscale scanning X-ray fluorescence tomography, coupled with an advanced self-absorption correction algorithm developed in this work, we analyze the three-dimensional gain distributions and compositions in a Ce 0.8 Gd 0.2 O 2-δ -CoFe 2 O 4 mixed ionic-electronic conductor system with high accuracy and statistical significance. Our systematic investigation reveals an additional emergent phase and uncovers highly intriguing composition stability ranges for the multiple material phases within this system. The presented visualization of composition variations across complex interfaces, supported by our quantitative composition analysis, discloses mechanistic pathways of the diverse phase transformations occurring in the material synthesis, providing insights for the optimization of transport properties in the mixed ionic-electronic conductor system.

36 MATERIALS SCIENCE↗

Spectral reflectance systematics for mixtures of powdered hypersthene, labradorite, and ilmenite

Spectral reflectance measurements in the range from 0.4- to 2.5 microns were made for synthetic powder mixtures of a single suite of plagioclase, pyroxene, and ilmenite, which are the principal mineral phase types making up virtually all lunar surface materials studied to date. Binary and ternary data plots of the parameters albedo, band depth, and red to blue ratios versus mixture composition show how variation in the concentration of each mineral phase in a mixture affects changes in the overall reflectance spectrum of the mixture. Principal mixing effects noted are (1) the disproportionate darkening effect of opaque ilmenites and (2) the persistence, the wavelength stability, and the depth versus concentration proportionality of the 1-micron band of pyroxene. These results indicate that by comparing the albedo and band depth of an unknown spectrum with calibration data obtained with laboratory standards, it is possible to determine the ratio of crystalline phases in the material producing spectra such as may be obtained telescopically from small areas on lunar and planetary surfaces.

Nash, D. B.↗

Geophysical Impacts and Spectroscopic Identification of a Hydrous Iron Sulfate on Icy Worlds

Over geologic time-scales, large volumes of exogenic sulfur ions from Io's plasma torus have been supplied to the surface of Europa and Ganymede, which, combined with recent interpretations of orbiter images, dynamical modeling, and surface-subsurface exchange, suggests further sulfur transport into the interior of the icy worlds. These observations motivate mixed-phase spectral modeling for interpreting orbiter spectroscopy data and determination of hydration states of candidate surface materials including hydrous sulfates. In this work, we present a combined experimental and theoretical study of the low temperature and high pressure vibrational spectral signature of the iron-sulfate monohydrate endmember, szomolnokite (FeSO 4 ·H 2 O). By employing synchrotron Fourier-transform infrared spectroscopy (FTIR) in the diamond anvil cell up to 23 GPa and down to 20 K, we explore the extreme range of pressure-temperature domains relevant to icy environments throughout our solar system and beyond. Combined with our density-functional theory quantum-mechanics molecular dynamics results, we demonstrate that experimentally observed infrared features in the O-H stretching region commonly associated with nH 2 O (n > 1) hydration states can be attributed to a pure monohydrate without the need for pressure-induced exsolved ice, other coexisting hydrous iron sulfates, or strong overtone and combination modes. We further discuss the possibility of lateral variations in density and shear properties on icy worlds associated with temperature variations and the high-pressure phases of kieserite group monohydrated sulfates.

Geosciences↗

Highly Siderophile Element Abundances in Martian Meteorites

Critical evaluation of new and literature data for highly siderophile elements (HSE) in Martian (SNC) meteorites allows several first order conclusions to be drawn. (i) Re concentrations in SNC meteorites are nearly constant (within a factor of two) and do not correlate with rock type. Exceptions to this rule are Chassigny and Dar al Gani (DaG) 476, both of which are inferred to have experienced terrestrial Re contamination. (ii) Fractionations between Rh and Pd are small. Excluding Shergotty, the Rh/Pd ratio of the SNC suite is 0.22\pm0.05. (iii) Os and Ir contents vary by about four orders of magnitude; and positive correlations with MgO, Cr, and Ni suggest that these variations are not controlled by sulfide fractionation. A possible exception is the orthopyroxenite ALH84001, whose HSE's (including Ni, which is compatible in opx) are very low. (iv) Zagami, Shergotty, and Nakhla have nearly identical HSE signatures. Shergotty and Zagami have experienced assimilation-fractional crystallization (AFC) and have "crustal" Sr and Nd isotopic signatures. Conversely, the Nakhla parent was a small degree partial melt of a depleted mantle that interacted little with the Martian crust. These observations suggest that "evolved" HSE signatures can be produced by either fractional crystallization or small degrees of partial melting. (v) Chassigny and other mafic SNC's have HSE signatures that are very distinct from those of Nakhla-Zagami-Shergotty. The HSE elemental ratios of mafic SNC's approach chondritic, implying that the Martian mantle has nearly chondritic relative abundances of the HSE's. (vi) This chondritic HSE signature is observed in SNC's of various ages, suggesting that this is an ancient feature that has not evolved over time. (vii) No correlation is observed between HSE's and signatures of crustal contamination (e.g., Sr isotopes), indicating that the HSE signatures of the SNC suite are not derived from the crust. (vii) The Ru/Pd for the SNC suite ratio is about 0.5 chondritic. We attribute this depletion of Ru to the presence of spinel in the SNC source regions. (viii) Assignment of this depletion of Ru to spinel seems to also imply that spinel is not the cause of Os and Ir fractionations, requiring some other mafic phase to account for the observed variations. -----.

Jones, J. H.↗

Origin of the Central Constant Emission Component of Eta Carinae

The X-ray campaign observation of the wind-wind colliding (WWC) binary system, Eta Carinae, targeted at its periastron passage in 2003, presented a detailed view of the flux and spectral variations of the X-ray minimum phase. One of the discoveries in this campaign was a central constant emission (CCE) component very near the central WWC source (Hamaguchi et al. 2007, ApJ, 663, 522). The CCE component was noticed between 1-3 keY during the X-ray minima and showed no variation on either short timescales within any observation or long timescales of up to ~ 10 years. Hamaguchi et al. (2007) discussed possible origins as collisionally heated shocks from the fast polar winds from Eta Car or the fast moving outflow from the WWC with the ambient gas, or shocked gas that is intrinsic to the wind of Eta Car. During the 2009 periastron passage, we launched another focussed observing campaign of Eta Carinae with the Chandra, XMM-Newton and Suzaku observatories, concentrating on the X-ray faintest phase named the deep X-ray minimum. Thanks to multiple observations during the deep X-ray minimum, we found that the CCE spectrum extended up to 10 keV, indicating presence of hot plasma of kT approx.4-6 keV. This result excludes two possible origins that assume relatively slow winds (v approx. 1000 km/s) and only leaves the possibility that the CCE plasma is wind blown bubble at the WWC downstream. The CCE spectrum in 2009 showed a factor of 2 higher soft band flux as the CCE spectrum in 2003, while the hard band flux was almost unchanged. This variation suggests decrease in absorption column along the line of sight. We compare this result with recent increase in V-band magnitude of Eta Carinae and discuss location of the CCE plasma.

Hamaguchi, Kenji↗

Seasonal Variations in Triton's Atmospheric Mass and Composition

Condensed phases of gases which make up the bulk of Triton's atmosphere are likely to exist on Triton's surface in the form of solid or liquid polar caps which extend as far as 55 deg from the poles. The mass of Triton's atmosphere is governed by the energy balance between the sunlight these caps absorb and the heat they radiate to space. The polar cap temperatures should be approximately equal and uniform over their surfaces. Because of the rapid precession of Triton's orbit about Neptune's pole, the insolation and, therefore, the temperature of the polar caps must vary in a complex fashion. The variations in the temperature of the polar caps will also cause seasonal variations in the mixing ratio of the volatile atmospheric gases owing to the different behaviors of their saturation vapor pressures with temperature. Triton's visible hemisphere is approaching a major southern summer with solstices. If the polar caps are not too thin a dramatic increase in the CH4 column abundance would occur.

Trafton, L. M.↗

Crystallization behavior of a melt-spun Fe-Ni based steel

Whether Fe-Ni-based alloys solidify with a bcc or fcc structure has been observed by many investigators to be a stronger function of kinetics and undercooling than strictly free-energy minimization. Such behavior has been observed in an Fe(52.8)Ni(28.7)Al(3.4)Ti(6.1)B(9.0) alloy. The alloy was cast as ribbons about 45 microns thick using a dual free-jet variation of chillbock melt spinning against a Cu wheel. Optical, X-ray, and electron analyses of the as-cast and annealed ribbons were performed. A microstructure of at least four layers containing combinations of ecc, bcc, and amorphous phases in differing proportions was observed in the as-cast ribbon. The midthickness layer had the most unusual features, containing fcc grains about 75 nm in size encompassing spherulitic regions as large as 15 microns comprised of fcc grains about 25 nm in size. The crystallization sequence responsible for the as-cast microstructure is discussed in terms of the competition between the formation of bcc and fcc phases as influenced by undercooling, recalescence, and variations in cooling rate experienced by the as-cast ribbon.

Michal, G. M.↗

In Situ X-ray Diffraction Investigation of Hydrogen Effects on Deformation-Induced Phase Transformation in Forged and Additively Manufactured 304L Stainless Steels

Here, this study utilized high energy synchrotron x-ray diffraction to probe microstructural evolution during uniaxial deformation of conventionally manufactured and additively manufactured (AM) 304L stainless steel with and without internal hydrogen. The objective of this effort is to highlight the effect of hydrogen on deformation-induced martensite phase transformations in austenitic stainless steels. Solute hydrogen depresses the required applied strain to initiate austenite transformation to ε-martensite and α'-martensite in both forged and AM stainless steel. Similarly, the total fraction of transformation product is larger when the microstructure is saturated with hydrogen. Deformation induced phase transformations also lead to a variation in strain partitioning behavior, which is linked to the chemical composition and stacking fault energy of the starting and hydrogen-charged materials.

36 MATERIALS SCIENCE↗

X-ray-diffraction and electrical-transport imaging of superconducting superhydride (La,Y)H 10

Understanding how microscopic structural domains govern macroscopic electronic properties is central to advancing hydride superconductors, yet such correlations remain poorly resolved under pressure. We report the synthesis and characterization of (La 0.9 Y 0.1 )H 10 superhydrides exhibiting coexisting cubic $Fm\bar{3}m$ and $P6_3/mmc$ hexagonal clathrate phases observed over the pressure range from 168 GPa down to 136 GPa. Using synchrotron-based X-ray diffraction imaging at the upgraded Advanced Photon Source, we spatially resolved μm-scale distributions of these phases, revealing structural inhomogeneity across the sample. Four-probe resistance measurements confirmed superconductivity with two distinct transitions: an onset at 244 K associated with the cubic phase and a second near 220 K linked to the hexagonal phase. Notably, resistance profiles collected from multiple current and voltage permutations showed variations in transition width and onset temperature that correlated with the spatial phase distribution. These findings demonstrate a direct connection between local structural domains and superconducting behavior.

Materials science↗

Anti-site defect-induced disorder in compensated topological magnet MnBi2-xSbxTe4

Abstract The gapped Dirac-like surface states of compensated magnetic topological insulator MnBi 2-x Sb x Te 4 (MBST) are a promising host for exotic quantum phenomena such as the quantum anomalous Hall effect and axion insulating state. However, it has become clear that atomic defects undermine the stabilization of such quantum phases as they lead to spatial variations in the surface state gap and doping levels. The large number of possible defect configurations in MBST make studying the influence of individual defects virtually impossible. Here, we present a statistical analysis of the nanoscale effect of defects in MBST with x =0.64, by scanning tunnelling microscopy/spectroscopy. We identify (Bi,Sb) Mn anti-site defects to be the main source of the observed doping fluctuations, leading towards the formation of nanoscale charge puddles and effectively closing the transport gap. Our findings will guide further optimization of this material system via defect engineering, to enable exploitation of its promising properties.

36 MATERIALS SCIENCE↗

Understanding copper diffusion in CuInSe 2 with first-principles based atomistic and continuum models

We investigate the diffusion of copper in CuInSe 2 using thermodynamic and kinetic models based on density functional theory calculations, attempting to reconcile large differences in reported experimental diffusivities. We find that observations of rapid chemical diffusion can be explained by large thermodynamic factors, which we calculate using a compositionally constrained model of intrinsic point defect formation. We further characterize how copper diffusion coefficients depend on material synthesis conditions and exhibit their variation across the CuInSe 2 secondary phase diagram. In doing so, we identify stable off-stoichiometries that are dominated by either vacancy- or interstitial-mediated diffusion mechanisms. These results are employed in the development of a continuum reaction–diffusion model, which we use to simulate experimental depth profiles.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Observations of phase changes in monoolein during high viscous injection

Serial crystallography of membrane proteins often employs high-viscosity injectors (HVIs) to deliver micrometre-sized crystals to the X-ray beam. Typically, the carrier medium is a lipidic cubic phase (LCP) media, which can also be used to nucleate and grow the crystals. However, despite the fact that the LCP is widely used with HVIs, the potential impact of the injection process on the LCP structure has not been reported and hence is not yet well understood. The self-assembled structure of the LCP can be affected by pressure, dehydration and temperature changes, all of which occur during continuous flow injection. These changes to the LCP structure may in turn impact the results of X-ray diffraction measurements from membrane protein crystals. To investigate the influence of HVIs on the structure of the LCP we conducted a study of the phase changes in monoolein/water and monoolein/buffer mixtures during continuous flow injection, at both atmospheric pressure and under vacuum. The reservoir pressure in the HVI was tracked to determine if there is any correlation with the phase behaviour of the LCP. The results indicated that, even though the reservoir pressure underwent (at times) significant variation, this did not appear to correlate with observed phase changes in the sample stream or correspond to shifts in the LCP lattice parameter. During vacuum injection, there was a three-way coexistence of the gyroid cubic phase, diamond cubic phase and lamellar phase. During injection at atmospheric pressure, the coexistence of a cubic phase and lamellar phase in the monoolein/water mixtures was also observed. The degree to which the lamellar phase is formed was found to be strongly dependent on the co-flowing gas conditions used to stabilize the LCP stream. A combination of laboratory-based optical polarization microscopy and simulation studies was used to investigate these observations.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗