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At least 739 records · Page 41

Brentwood Lessons Learned Project Report

The purpose of this report is to document lessons learned in the installation of the hydrogen fueling station at the National Park Service Brentwood site in Washington, D.C., to help further the deployment of hydrogen infrastructure required to support hydrogen and other fuel cell technologies. Hydrogen fueling is the most difficult infrastructure component to build and permit. Hydrogen fueling can include augmenting hydrogen fueling capability to existing conventional fuel fueling stations as well as building brand new hydrogen fueling stations. This report was produced as part of the Brentwood Lessons Learned project. The project consisted of transplanting an existing modular hydrogen fueling station from Connecticut to the National Park Service Brentwood site. This relocation required design and construction at the Brentwood site to accommodate the existing station design as well as installation and validation of the updated station. One of the most important lessons learned was that simply moving an existing modular station to an operating site was not necessarily straight-forward - performing the relocation required significant effort and cost. The station has to function at the selected operating site and this functionality requires a power supply, building supports connecting to an existing alarm system, electrical grounding and lighting, providing nitrogen for purging, and providing deionized water if an electrolyzer is part of the station package. Most importantly, the station has to fit into the existing site both spatially and operationally and not disrupt existing operations at the site. All of this coordination and integration requires logistical planning and project management. The idea that a hydrogen fueling station can be simply dropped onto a site and made immediately operational is generally not realistic. Other important lessons learned include that delineating the boundaries of the multiple jurisdictions that have authority over a project for all parties involved in the project are key to an efficient approval process; and site investigation is necessary when integrating a new station design onto an existing site, particularly an older existing site that may have limited documentation on the site history and operations. The lessons learned for permitting and subcontracting construction work can be applied to other similar sites and to commercial sites.

30 DIRECT ENERGY CONVERSION↗

Pacific Northwest National Laboratory Annual Site Environmental Report for Calendar Year 2022 (Final Report)

Pacific Northwest National Laboratory (PNNL), one of the U.S. Department of Energy (DOE) Office of Science’s 10 national laboratories, provides innovative science and technology development in the areas of energy and the environment, fundamental and computational science, and national security. There are three DOE offices within the Richland area. Two are responsible for the Hanford Site, whereas the Pacific Northwest Site Office (PNSO) oversees PNNL. PNNL prepares this Annual Site Environmental Report to meet the requirements of DOE Order 231.1B, Environmental, Safety and Health Reporting, and DOE Order 458.1, Radiation Protection of the Public and the Environment, assuring that the public is informed of any PNNL-Richland Campus or PNNL-Sequim Campus event that could adversely affect the health and safety of the public, site staff, or the environment. The report provides a synopsis of ongoing environmental management performance and compliance activities for operations that occur on the PNNL-Richland Campus in Richland, Washington, and at the PNNL-Sequim Campus near Sequim, Washington. It describes the location of and background for each facility; addresses compliance with applicable DOE, federal, state, and local regulations, and site-specific permits; documents environmental monitoring efforts and their status; presents potential radiation doses to staff and the public in the surrounding areas; and describes DOE-required data quality assurance methods used for data verification. The ASER summarizes site compliance with federal, state, and local environmental laws, regulations, policies, directives, permits, and Orders, and provides environmental management performance benchmarks and their status to the public, regulatory agencies, community officials, Native American tribes, and public interest groups.

54 ENVIRONMENTAL SCIENCES↗

Data Driven Commercial Building Energy Code Compliance and Technology Inventory for New York City

Building Performance Standards (BPS) are gaining national traction. A BPS will require new processes in the design, construction, and operation of buildings that take the occupants into account and enable predictive analysis to ensure compliance with current and future GHG emissions caps. In New York City, most buildings over 25,000 square feet will be regulated by a BPS starting in 2024, regardless of whether it is new construction permitted under current energy codes or an existing building. This research is one of the first to begin the evaluation of a long-term series of building policies in the context of an open data ecosystem, in cooperation with city agencies. Existing building policies enacted in NYC have ranged from building energy benchmarking and labeling to energy audits to the regulation of GHG emission in buildings. Through the development of a dataset related to building technologies and energy consumption, this project can help to evaluate if meaningful conclusions can be drawn for the data that has been largely self-reported in compliance with city regulations. This project will also provide lessons learned from a deep dive into these types of datasets to provide best practices for municipalities or states seeking to embark on policies like those enacted in NYC. In addition, a Building Automation System (BAS) Stretch Standard of Care (SSOC) for owners, designers, and building operators will enable the measurement and predictive analysis of energy consumption and GHG emissions at the plant, system, or component level, in anticipation of regulated GHG limits on buildings based on energy use. The SSOC is expected to be suitable for use on a national level. The primary feature of an SSOC is a standardized format for a set of BAS points that can be used to control and to gather data from individual plants, systems, or components that are related to building energy consumption. This project examined how measurements compare to prescriptive or simulation-based energy code targets, finding little correlation between predictive 8760-hour energy modeling and actual energy consumption for a small sample (n=27) of buildings constructed after 2015. Other analysis found that, while large multifamily housing (MFH) buildings showed a general trend similar to predicted reductions in energy use from the implementation of model commercial energy codes, this trend was not evident in the office, K-12 school, and hotel use groups in NYC. No upward or downward trends in energy consumption were found when buildings were grouped by size. Energy audit data were analyzed and it appears that there is bias by audit company on measures recommended to clients. Further research should be performed to cross-analyze this with other attributes, such as building size, vintage, and number of stories. Analysis found that for 281 buildings that were permitted and completed after 2015 and had submitted benchmarking data in 2022, between 81% and 96% (by use group) were found to be in compliance with the 2024 to 2029 NYC BPS emission caps, and between 55% and 89% were in compliance with the 2030-2034 caps. This work is beneficial to the public in helping policymakers and building stakeholders better understand the wide-ranging implications of a BPS.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Mesoscale convective systems in the third pole region: Characteristics, mechanisms and impact on precipitation

The climate system of the Third Pole region, including the (TP) and its surroundings, is highly sensitive to global warming. Mesoscale convective systems (MCSs) are understood to be a vital component of this climate system. Driven by the monsoon circulation, surface heating, and large-scale and local moisture supply, they frequently occur during summer and mostly over the central and eastern TP as well as in the downstream regions. Further, MCSs have been highlighted as important contributors to total precipitation as they are efficient rain producers affecting water availability (seasonal precipitation) and potential flood risk (extreme precipitation) in the densely populated downstream regions. The availability of multi-decadal satellite observations and high-resolution climate model datasets has made it possible to study the role of MCSs in the under-observed TP water balance. However, the usage of different methods for MCS identification and the different focuses on specific subregions currently hamper a systematic and consistent assessment of the role played by MCSs and their impact on precipitation over the TP headwaters and its downstream regions. Here, we review observational and model studies of MCSs in the TP region within a common framework to elucidate their main characteristics, underlying mechanisms, and impact on seasonal and extreme precipitation. We also identify major knowledge gaps and provide suggestions on how these can be addressed using recently published high-resolution model datasets. Three important identified knowledge gaps are 1) the feedback of MCSs to other components of the TP climate system, 2) the impact of the changing climate on future MCS characteristics, and 3) the basin-scale assessment of flood and drought risks associated with changes in MCS frequency and intensity. A particularly promising tool to address these knowledge gaps are convection-permitting climate simulations. Therefore, the systematic evaluation of existing historical convection-permitting climate simulations over the TP is an urgent requirement for reliable future climate change assessments.

54 ENVIRONMENTAL SCIENCES↗

Guideline for Characterizing and Evaluating a Candidate Project Site for Solar Thermal Applications

This document presents a structured procedure for characterizing and evaluating candidate project sites for concentrating solar power (CSP) and solar heat for industrial processes (SHIP) applications. The objective is to provide project developers, researchers, and other stakeholders with a consistent, technology-agnostic framework for early-stage site assessment, enabling informed decision-making prior to significant investment in project development. Site selection is a critical factor in project success or failure for both CSP and SHIP projects. Key factors such as solar resource availability, land characteristics, environmental and regulatory constraints, infrastructure availability, and community context are determined by the choice of project site and can materially impact project performance, cost, schedule, and overall viability. This procedure is designed to systematically evaluate these factors, identify potential fatal flaws, and prioritize the most favorable candidate sites for further development. The process begins with rapid screening-level evaluation, using publicly available data to assess solar resource, land availability and suitability, zoning and land-use compatibility, and exclusion zones such as protected lands or sensitive habitats. Sites that meet the minimum screening criteria advance to a more detailed characterization. Subsequent sections of this report provide guidance for a next-level assessment of the most important technical and environmental parameters, including: 1) Solar resource quality, variability, and uncertainty using multiyear datasets and, where appropriate, on-site measurement campaigns; 2) Meteorological conditions such as wind, temperature, extreme weather events, and soiling impacts; 3) Land characteristics including slope, shading, and geotechnical conditions; and 4) Environmental and regulatory considerations, including permitting processes, endangered species, cultural resources, and visual impacts. The procedure also addresses infrastructure and integration considerations, including: 1) Grid interconnection requirements for CSP power generation projects; 2) Electrical and operational integration for SHIP facilities; 3) Water availability, quality, and permitting constraints, which are particularly critical for CSP in arid regions; and 4) Site access, construction logistics, and availability of workforce and supporting services. Recognizing the importance of social and economic context, the procedure includes evaluation of community engagement factors, such as stakeholder sentiment, proximity to sensitive visual receptors, workforce development opportunities, and local economic incentives. The outputs of these assessments are synthesized in a cost and risk evaluation, translating site characteristics into expected impacts on capital cost, operating cost, schedule, and technical risk. This is complemented by screening-level performance modeling, including 8760 simulations and long-term projections, to quantify expected energy or thermal output, assess variability thereof, and support comparison between candidate sites. Finally, the procedure provides high-level guidance on a structured go/no-go decision framework, categorizing sites based on identified risks and constraints, and outlining a clear path forward to feasibility studies and front-end engineering design for viable projects. By standardizing the site characterization process across both CSP and SHIP applications, this guideline aims to: 1) Improve consistency and transparency in early-stage project evaluation; 2) Reduce development risk and avoid investment in nonviable project sites; 3) Support collaboration between developers, researchers, and public agencies; and 4) Accelerate successful deployment of concentrating solar technologies for both power generation and industrial process heat.

14 SOLAR ENERGY↗

Environmental Concerns and Mitigation Associated with Geothermal Resource Confirmation Drilling Activities

In 2017-2018, the Bureau of Land Management's National Renewable Energy Coordination Office, through its Geothermal Program, funded the National Renewable Energy Laboratory (NREL) to analyze technical and environmental considerations related to geothermal resource confirmation drilling. NREL solicited input from a group of technical and environmental experts in the geothermal industry, along with analyzing National Environmental Policy Act of 1969 (NEPA) documentation for previously approved projects. The collected data and analysis will be used by the Bureau of Land Management to examine the possibility of developing a new classification of wells and/or expediting the NEPA compliance process, which could potentially reduce permitting and regulatory compliance timelines when compared to the current process for obtaining a geothermal drilling permit for resource confirmation drilling activities.

15 GEOTHERMAL ENERGY↗

Environmental Concerns and Mitigation Associated with Geothermal Resource Confirmation Drilling Activities

In 2017-2018, the Bureau of Land Management's National Renewable Energy Coordination Office, through its Geothermal Program, funded the National Renewable Energy Laboratory (NREL) to analyze technical and environmental considerations related to geothermal resource confirmation drilling. NREL solicited input from a group of technical and environmental experts in the geothermal industry, along with analyzing National Environmental Policy Act of 1969 (NEPA) documentation for previously approved projects. The collected data and analysis will be used by the Bureau of Land Management to examine the possibility of developing a new classification of wells and/or expediting the NEPA compliance process, which could potentially reduce permitting and regulatory compliance timelines when compared to the current process for obtaining a geothermal drilling permit for resource confirmation drilling activities.

15 GEOTHERMAL ENERGY↗

Hot Springs and Geysers: Exploring Historical and Modern Impacts of Geothermal Energy Production on Associated Natural Surface Systems and Standardizing Management Practices

Surface thermal features, most notably hot springs and geysers are increasingly being recognized for their importance to ecosystems, indigenous cultures, and in some cases agriculture, recreation, and tourism. Geothermal project development poses a potential risk to these natural features but current regulatory requirements for assessing and managing these risks during exploration, permitting and monitoring are somewhat inconsistent and unpredictable across different geothermal fields. This has resulted in uncertainty and increases in exploration risk for geothermal energy developers that have led to costly project delays, cancellations, or hesitation to commit. Varying regulatory requirements may also influence public perception, fostering confusion, distrust and ultimately opposition to geothermal projects, further contributing to project delays or cancellations. At a time when there is an increasing urgency for reliable baseload clean energy, geothermal is a net-zero, renewable solution that additionally provides access to more equitable and environmentally just clean power. Continued integration of geothermal energy into the national energy roadmap can be facilitated through consistent and predictable permitting, providing regulators the framework they need, developers a clear path forward, and transparency that the public deserves. This project, currently in its beginning phases, seeks to address this important issue by providing a technical basis from which to build a preliminary protocol for assessing and managing potential impacts from new or existing geothermal energy projects to surface thermal features and their associated ecosystems. Development of this preliminary protocol will be informed by (1) a literature review of well-documented case studies in the western U.S. and New Zealand to understand the range of conditions that exemplify geothermal-surface thermal systems; (2) development of generic illustrative conceptual-numerical models to quantify, understand, and predict the first-order controls (e.g., pressure and permeability) on surface flows; and (3) additional independent and scientifically rigorous evaluations of geothermal-surface thermal system case studies from the Basin and Range Province that incorporate publicly available data as well as data provided by industry through data-sharing agreements. Learning from the successes of the process used to develop the Induced Seismicity Management Protocol (ISMP), we ultimately aim to use these initial efforts as a springboard for establishing a surface thermal feature management working group that will work collaboratively to finalize the protocol as well as co-create recommended best practices for implementation. We envision that the working group will primarily be composed of representatives from regulatory entities, government agencies, Tribes, academia, national laboratories, and industry, and will include early and regular engagement with community organizations and environmental groups. This will help ensure broad acceptance and implementation of the protocol, which will facilitate a more consistent, predictable, and standardized regulatory process, and help to ensure that geothermal energy continues to provide a reliable source of clean energy, and a pathway to achieving greater energy equity in the U.S.

Best Practices↗

Policy Reforms to Unleash Domestic Critical Minerals Mining and Processing

The United States faces growing strategic and economic risks due to its limited ability to mine, process, and refine the minerals required for national defense, energy systems, advanced manufacturing, and emerging technologies. Although the country possesses significant geological resources, development has been slowed by long and unpredictable permitting timelines, fragmented regulatory responsibilities, limited midstream processing capacity, and a shrinking technical workforce. These structural barriers have created supply chain vulnerabilities that constrain industrial growth and reduce national resilience. This report presents a comprehensive set of reforms intended to modernize the nation’s approach to critical minerals. The recommendations address federal permitting, environmental review processes, the legal framework governing mining activities, interagency coordination, domestic processing and refining capacity, and the education and workforce systems needed to support long term industry development. The analysis emphasizes practical steps to shorten project timelines, improve regulatory clarity, expand processing infrastructure, enable recovery from both conventional and nontraditional sources, and update outdated requirements that hinder the development of essential materials. Taken together, the recommended reforms would strengthen domestic supply chains, improve investment certainty, and reduce dependence on external minerals and processing infrastructure. By aligning policy, regulatory frameworks, and workforce capabilities with national needs, the United States can build a more resilient and secure critical minerals ecosystem that supports long term economic competitiveness and technological leadership.

29 - ENERGY PLANNING, POLICY AND ECONOMY↗

Modifications to WRF's dynamical core to improve the treatment of moisture for large-eddy simulations: WRF DY-CORE MOISTURE TREATMENT

Yamaguchi and Feingold (2012) note that the cloud fields in their Weather Research and Forecasting (WRF) large-eddy simulations (LESs) of marine stratocumulus exhibit a strong sensitivity to time stepping choices. In this study, we reproduce and analyze this sensitivity issue using two stratocumulus cases, one marine and one continental. Results show that (1) the sensitivity is associated with spurious motions near the moisture jump between the boundary layer and the free atmosphere, and (2) these spurious motions appear to arise from neglecting small variations in water vapor mixing ratio (qv) in the pressure gradient calculation in the acoustic sub­stepping portion of the integration procedure. We show that this issue is remedied in the WRF dynamical core by replacing the prognostic equation for the potential temperature θ with one for the moist potential temperature θm=θ(1+1.61qv), which allows consistent treatment of moisture in the calculation of pressure during the acoustic sub­steps. With this modification, the spurious motions and the sensitivity to the time stepping settings (i.e., the dynamic time step length and number of acoustic sub­steps) are eliminated in both of the example stratocumulus cases. This modification improves the applicability of WRF for LES applications, and possibly other models using similar dynamical core formulations, and also permits the use of longer time steps than in the original code.

Xiao, Heng↗

Sensitivity of U.S. summer precipitation to model resolution and convective parameterizations across gray zone resolutions: Sensitivity Across Gray Zone Resolutions

Simulating summer precipitation is a significant challenge for climate models that rely on cumulus parameterizations to represent moist convection processes. Motivated by recent advances in computing that support very high-resolution modeling, this study aims to systematically evaluate the effects of model resolution and convective parameterizations across the gray zone resolutions. Simulations usingthe Weather Research and Forecasting model were conducted at grid spacings of 36 km, 12 km, and 4 km fortwo summers over the conterminous U.S. The convection-permitting simulations at 4 km grid spacing are most skillful in reproducing the observed precipitation spatial distributions and diurnal variability. Notable differences are found between simulations with the traditional Kain-Fritsch (KF) and the scale-aware Grell-Freitas (GF) convection schemes, with the latter more skillful in capturing the nocturnal timing in the Great Plains and North American monsoon regions. The GF scheme also simulates a smoother transition from convective to large-scale precipitation as resolution increases, resulting in reduced sensitivity to model resolution compared to the KF scheme. Nonhydrostatic dynamics has a positive impact on precipitation over complex terrain even at 12 km and 36 km grid spacings. With nudging of the winds toward observations, we show that the conspicuous warm biases in the Southern Great Plains are related to precipitation biases induced by large-scale circulation biases, which are insensitive to model resolution. Overall, notable improvements in simulating summer rainfall and its diurnal variability through convection-permitting modeling and scale-aware parameterizations suggest promising venues for improving climate simulations of water cycle processes.

54 ENVIRONMENTAL SCIENCES↗

Direct Observation of Bandgap Oscillations Induced by Optical Phonons in Hybrid Lead Iodi.de Perovskites

Hybrid organic-inorganic perovskites such as methylammonium lead iodide have emerged as promising semiconductors for energy-relevant applications. The interactions between charge carriers and lattice vibrations, giving rise to polarons, have been invoked to explain some of their extraordinary optoelectronic properties. Here, time-resolved optical spectroscopy is performed, with off-resonant pumping and electronic probing, to examine several representative lead iodide perovskites. The temporal oscillations of electronic bandgaps induced by coherent lattice vibrations are reported, which is attributed to antiphase octahedral rotations that dominate in the examined 3D and 2D hybrid perovskites. The off-resonant pumping scheme permits a simplified observation of changes in the bandgap owing to the A(g) vibrational mode, which is qualitatively different from vibrational modes of other symmetries and without increased complexity of photogenerated electronic charges. The work demonstrates a strong correlation between the lead-iodide octahedral framework and electronic transitions, and provides further insights into the manipulation of coherent optical phonons and related properties in hybrid perovskites on ultrafast timescales.

coherent optical phonons↗

Designing Light-Activated Charge-Separating Proteins with a Naphthoquinone Amino Acid

The first principles design of manmade redox-protein maquettes is used to clarify the physical/chemical engineering supporting the mechanisms of natural enzymes with a view to recapitulate and surpass natural performance. Herein, we use intein-based protein semisynthesis to pair a synthetic naphthoquinone amino acid (Naq) with histidine-ligated photoactive metal–tetrapyrrole cofactors, creating a 100 μs photochemical charge separation unit akin to photosynthetic reaction centers. By using propargyl groups to protect the redox-active para-quinone during synthesis and assembly while permitting selective activation, we gain the ability to employ the quinone amino acid redox cofactor with the full set of natural amino acids in protein design. Direct anchoring of quinone to the protein backbone permits secure and adaptable control of intraprotein electron-tunneling distances and rates.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Modeling golden eagle‐vehicle collisions to design mitigation strategies

ABSTRACT The incidental take of golden eagles ( Aquila chrysaetos ) as a result of wind energy development requires some form of compensatory mitigation. Although several options have been proposed, only one has been formerly accepted and implemented, and the lack of options can limit the permit process for wind facilities. We developed a model to estimate numbers of golden eagles that die when struck by vehicles when eagles scavenge road kill to evaluate removal of road‐killed carcasses as an additional mitigation option. Our model estimates vehicle collision rates as a function of eagle densities, road traffic volume, and animal carcass abundance at the scale of a Wyoming, USA, county during fall‐winter, and quantifies the effects of different mitigation strategies, including estimates of uncertainty. We evaluated the plausibility of our model estimates by predicting mortality rates for each county in Wyoming and comparing overall state mortality to current estimates of mortality using derived estimates from expert judgment. We also developed a context‐dependent analysis of potential mitigation credits controlling for carcass number, traffic volume, and background carcass removals. We found that mitigation credit should be highest in areas with greatest number of carcasses. Collision mitigation is a potentially useful addition to the mitigation toolbox for wind energy development or other activities that need to offset predicted golden eagle mortality and satisfy incidental take permit requirements. © 2018 The Authors. Journal of Wildlife Management Published by Wiley Periodicals, Inc.

Lonsdorf, Eric↗

Proteomic analysis of hair shafts from monozygotic twins: Expression profiles and genetically variant peptides

Forensic association of hair shaft evidence with individuals is currently assessed by comparing mitochondrial DNA haplotypes of reference and casework samples, primarily for exclusionary purposes. Present work tests and validates more recent proteomic approaches to extract quantitative transcriptional and genetic information from hair samples of monozygotic twin pairs, which would be predicted to partition away from unrelated individuals if the datasets contain identifying information. Protein expression profiles and polymorphic, genetically variant hair peptides were generated from ten pairs of monozygotic twins. Profiling using the protein tryptic digests revealed that samples from identical twins had typically an order of magnitude fewer protein expression differences than unrelated individuals. The data did not indicate that the degree of difference within twin pairs increased with age. In parallel, data from the digests were used to detect genetically variant peptides that result from common nonsynonymous single nucleotide polymorphisms in genes expressed in the hair follicle. Compilation of the variants permitted sorting of the samples by hierarchical clustering, permitting accurate matching of twin pairs. The results demonstrate that genetic differences are detectable by proteomic methods and provide a framework for developing quantitative statistical estimates of personal identification that increase the value of hair shaft evidence.

59 BASIC BIOLOGICAL SCIENCES↗

Validation of the first LiDAR wind resource assessment buoy system offshore the Northeast United States

The US offshore wind industry is maturing with several projects in various stages of development. These projects require site wind and environmental data before and during operation. Conventional techniques such as fixed-bottom meteorological towers present economical and permitting challenges for the US. Floating Light Detection and Ranging (LiDAR) buoys offer significant advantages including reduced costs, less permitting, and reusability. This paper presents the validation of the first floating LiDAR buoy in Northeast US waters. The buoy, named DeepCLiDAR, includes a LiDAR, ecological monitoring sensors, and metocean sensors. A three-phase LiDAR validation plan was executed, and its results are presented. The objective of the validation plan was to verify the accuracy of measurements made by the LiDAR buoy in wave environments against an unmoving reference wind measurement. Due to a lack of reference met masts, the use of a LiDAR on land as a baseline reference was implemented for validation. Comparison to a reference LiDAR instead of a traditional meteorological tower was a unique approach required in the Northeast US waters due to the absence of a reference fixed-bottom meteorological tower in the region at the time of this study. The testing included a comparison of wind speed measurements made by the buoy deployed 15 km offshore from the mainland and a land-based reference LiDAR located on a nearby island. This paper presents the methodology and results of this program, which indicate favorable agreement. This was the first such validation program in the Northeast USA which is now seeing rapid development of offshore wind.

17 WIND ENERGY↗