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At least 739 records · Page 41

Examining infrared thermography based approaches to rapid fatigue characterization of additively manufactured compression molded short fiber thermoplastic composites

A novel additive manufacturing (AM) methodology combined with a compression molding (CM) process has been developed to optimize the microstructure of short fiber thermoplastic composites (SFTs)with higher fiber alignment and lower porosity, yielding superior stiffness, strength, and structural integrity. Here, the current work examines the efficacy of the ‘passive’ infrared thermography (IRT) techniques for rapid fatigue characterization of SFTs that use the surface temperature evolution during cyclic loading due to self-heating as a fatigue indicator. A comparison of fatigue limits obtained from traditional stress-life (SN) (≈53.1%σ uts ) and IRT (≈54.1%σ uts ) shows a close match. However, the SN curve required 18 specimens and two weeks of continuous cyclic testing, while IRT used three specimens with 5 hours of testing. Thus, the IRT approach provides an accelerated testing framework for rapidly estimating the fatigue limit. Additionally, existing phenomenological approaches to IRT fatigue characterization have been examined.

42 ENGINEERING↗

Emerging Potassium Metal Anodes: Perspectives on Control of the Electrochemical Interfaces

Potassium metal acts as the anode in emerging potassium metal batteries (KMBs). It further serves as the counter-electrode for potassium ion battery (KIB) half-cells, with its reliable performance being critical for assessing the working electrode material. This first-of-its-kind critical review focuses on the dual challenge of controlling the potassium metal-substrate and the potassium metal-electrolyte interface so as to prevent dendrites. The discussion begins with a comparison of the physical and chemical properties of K metal anodes versus the much oft studied Li and Na metal anodes. Based on established descriptions for root causes of dendrites, the problem should be less severe for K than for Li or Na, while in fact the opposite is observed. The key reason that the K metal surface rapidly becomes dendritic in common electrolytes is its unstable solid electrolyte interphase (SEI). An unstable SEI layer is defined as being non self-passivating. No SEI is perfectly stable during cycling, and all SEI structures are heterogenous both vertically and horizontally relative to the electrolyte interface. The difference between a "stable" and an "unstable" SEI may be viewed as the relative degree to which during cycling it thickens and becomes further heterogeneous. The unstable SEI on K metal leads to a number of interrelated problems, such as low cycling Coulombic efficiency (CE), a severe impedance rise, large overpotentials, and possibly electrical shorting; all of which have been reported to occur as early as in the first ten plating/stripping cycles. Many of the traditional "interface fixes" employed for Li and Na metal anodes, such as various artificial SEIs, surface membranes, barrier layers, the secondary separators, etc. have not been attempted or optimized for the case of K. This is an important area for further exploration, with an understanding that success may come harder than with Li due to K-based SEI reactivity with both ether and ester solvents. The second critical problem with K metal anodes is that they do not thermally or electrochemically wet a standard (untreated) Cu foil current collector. Published experimental and modeling research directly highlights the weak bonding between the K atoms and a Cu surface. Existing surface treatment approaches that achieve improved K wetting are discussed, along with the general design rules for future studies. Also discussed are geometry-based methods to tune nucleation, as well dual approaches where nucleation and SEI structure are tuned through complementary schemes to achieve extended half-cell and full battery stability. We hypothesize that K metal never achieves a planar wetting morphology even at cycle one making the dendrites "baked-in". We propose that classical thin films growth models, Frank van der Merwe (F-M), Volmer Weber (V-W), and Stranski-Krastanov (S-K) can be employed to describe early stage plating behavior. It is demonstrated that island-like V-W growth is the applicable description for the natural plating behavior of K on pristine Cu. Moving forward, there are three inter-related thrusts to be pursued: First, K salt - based electrolyte formulations have to mature and become further tailored to handle the increased reactivity of a metal rather than an ion anode. Second, the K-based SEI structure needs to be further understood and ultimately tuned to be less reactive. Third, the energetics of the K metal - current collector interface must be controlled to promote planar wetting/dewetting throughout cycling.

25 ENERGY STORAGE↗

Impact of the hydrogen content on the photoluminescence efficiency of amorphous silicon alloys

This paper analyzes the impact of hydrogen on the photoluminescence (PL) efficiency of the three wide gap silicon alloys: silicon carbide (a-SiC{sub x}), silicon nitride (a-SiN{sub x}): silicon oxide (a-SiO{sub x}). All three materials behave similarly. The progression of the PL efficiency over the Si content splits into two regions. With decreasing Si content, the PL efficiency increases until a maximum is reached. With a further decrease of the Si content, the PL efficiency declines again. A comprehensive analysis of the sample structure reveals that the PL efficiency depends on the degree of passivation of Si and Y atoms (Y = C, N, O) with hydrogen. For samples with a high Si content, an effective passivation of incorporated Y atoms gives rise to an increasing PL efficiency. The PL efficiency of samples with a low Si content is limited due to a rising amount of unpassivated Si defect states. We find that a minimum amount of 0.2 H atoms per Si atom is required to maintain effective luminescence.

36 MATERIALS SCIENCE↗

Quantum anomalous Hall insulator phase in asymmetrically functionalized germanene

Here, using first-principles computations, we discuss topological properties of germanene in buckled as well as planar honeycombs with asymmetric passivation via hydrogen and nitrogen (GeHN) atoms. GeHN in the planar structure is found to harbor a quantum anomalous Hall (QAH) insulator phase. Our analysis indicates that the buckled GeHN also possesses a QAH phase under tensile strain. We computed the associated Chern numbers and edge states to confirm the presence of the QAH state. In particular, chiral edge bands connecting conduction and valence bands were found at the edges of a planar zigzag GeHN nanoribbon. By considering a range of buckling distances, we demonstrate how the system undergoes the transition from the trivial to the QAH phase between the buckled and planar structures. Finally, we show CdTe(111) to be a suitable substrate for supporting buckled germanene in the QAH phase. Our results suggest that functionalized germanene could provide a robust QAH-based platform for spintronics applications.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

CdHgTe heterostructures for new-generation IR photodetectors operating at elevated temperatures

The parameters of multilayer Cd{sub x}Hg{sub 1–x}Te heterostructures for photodetectors operating at wavelengths of up to 5 μm, grown by molecular-beam epitaxy (MBE) on silicon substrates, are studied. The passivating properties of thin CdTe layers on the surface of these structures are analyzed by measuring the C–V characteristics. The temperature dependences of the minority carrier lifetime in the photoabsorption layer after growth and thermal annealing are investigated. Samples of p{sup +}–n-type photodiodes are fabricated by the implantation of arsenic ions into n-type layers, doped with In to a concentration of (1–5) × 10{sup 15} cm{sup –3}. The temperature dependences of the reverse currents are measured at several bias voltages; these currents turn out to be almost two orders of magnitude lower than those for n{sup +}–p-type diodes.

36 MATERIALS SCIENCE↗

Analysis of Microseismicity and Reactivated Fault Size to Assess the Potential for Felt Events by CO 2 Injection in the Illinois Basin

The results of monitoring of carbon dioxide (CO 2 ) injection at the Illinois Basin—Decatur Project (IBDP) and the companion Illinois Industrial Carbon Capture and Sequestration Sources (IL-ICCS) project—have shown that reservoir response to fluid pressure changes can vary significantly at different injection locations within the same reservoir. Predrill reservoir characterization is important to identify potentially seismogenic faults. However, interpretations of newly reprocessed 3D seismic reflection data illustrate the challenges related to their identification in a region dominated by faulting with small vertical offsets. Faults interpreted in the 3D seismic volume range from ~300 to 1200 m wide and are in the same size range as faults that could have been the source of historical events up to Mw 2.7 in central Illinois. The array of monitoring sensors that was installed for the IBDP continues to collect data, as injection operates in IL-ICCS, the second injection well. CO 2 injection rates for the IL-ICCS well are on average 1.7 times the rates injected in the IBDP well, but a significantly reduced rate of induced seismicity is observed. This article presents results of passive seismic monitoring for the duration of the project to date, integrating active and passive seismic data to develop a new interpretation of the subsurface structure at the Decatur site that explicitly identifies pathways for fluid flow into the basement leading to induced seismicity, and provides a geological explanation for the sharp reduction of induced seismicity during injection at higher rates into the second well. The use of seismic moment to estimate the length of seismogenic slip planes in the local subsurface suggests that faults large enough to produce felt seismicity are unlikely to be present at or near the Decatur site.

Geochemistry & Geophysics↗

Microwave emission of Arctic Sea ice

The feasibility of carrying microwave radiometers on Nimbus E and F missions for sea ice surveys was studied in the arctic using aircraft. It was found that passive microwave signatures of Arctic Sea ice relate specifically to the structure and type of ice. It is concluded that a new tool for conducting ice surveys from aircraft and satellites with remote sensors was discovered.

Gloersen, P.↗

New developments in blown flap noise technology

The noise technology relating to blown-flap systems is reviewed. There are three general sources of noise: turbomachinery, airframe, and the interaction noise of the jet blowing on the flaps. The latter noise-source area is the most critical and the main subject dicussed. Characteristics of lower surface blown and upper surface blown systems are described, including noise spectra, directivity, jet velocity characteristics, aircraft geometric variation effects, and aircraft forward speed effects. Noise reduction concepts are described, including slowing down the jet flow field by devices and engine cycle modifications, structural geometry and shielding modifications, local flow field modifications of the passive and active type, and the absorption of noise. It is concluded that, while there has been considerable progress in the past several years, low noise characteristics in blown flap aircraft must be largely built in by better application of low noise principles during the design.

Gibson, J. S.↗

Definition of ground test for Large Space Structure (LSS) control verification, appendix G

A Large Space Structure (LSS) ground test facility was developed to help verify LSS passive and active control theories. The facility also perform: (1) subsystem and component testing; (2) remote sensing and control; (3) parameter estimation and model verification; and (4) evolutionary modeling and control. The program is examined as is and looks at the first experiment to be performed in the laboratory.

Source record↗

Active vibrations and noise control for turboprop application research program activities

The objectives of this work include the following: (1) development of active noise control techniques to alleviate inefficiencies and drawbacks of passive noise control approach especially at low frequencies; (2) reduction of structurally radiated noise applying external forces to the vibrating structure by means of force actuators made of piezoelectric material; and (3) reduction of fuselage vibration levels in propeller driven aircraft by means of distributed piezoelectric actuators that are actively controlled.

Paonessa, A.↗

Behavior of an inversion-based precipitation retrieval algorithm with high-resolution AMPR measurements including a low-frequency 10.7-GHz channel

A microwave-based, profile-type precipitation retrieval algorithm has been used to analyze high-resolution passsive microwave measurements over an ocean background, obtained by the Advanced Microwave Precipitation Radiometer (AMPR) flown on a NASA ER-2 aircraft. The analysis is designed to first determine the improvements that can be gained by adding brightness temperature information from the AMPR low-frequency channel (10.7 GHz) to a multispectral retrieval algorithm nominally run with satellite information at 19, 37, and 85 GHz. The impact of spatial resolution degradation of the high-resolution brightness temperature information on the retrieved rain/cloud liquid water contents and ice water contents is then quantified in order to assess the possible biases inherent to satellite-based retrieval. Careful inspection of the high-resolution aircraft dataset reveals five distinctive brightness temperature features associated with cloud structure and scattering effects that are not generally detectable in current passive microwave satellite measurements. Results suggest that the inclusion of 10.7-GHz information overcomes two basic problems associated with three-channel retrieval. Intercomparisons of retrievals carried out at high-resolution and then averaged to a characteristic satellite scale to the corresponding retrievals in which the brightness temperatures are first convolved down to the satellite scale suggest that with the addition of the 10.7-GHz channel, the rain liquid water contents will not be negatively impacted by special resolution degradation. That is not the case with the ice water contents as they appear ti be quite sensitive to the imposed scale, the implication being that as spatial resolution is reduced, ice water contents will become increasingly underestimated.

Smith, E. A.↗

Displacement based multilevel structural optimization

Multidisciplinary design optimization (MDO) is expected to play a major role in the competitive transportation industries of tomorrow, i.e., in the design of aircraft and spacecraft, of high speed trains, boats, and automobiles. All of these vehicles require maximum performance at minimum weight to keep fuel consumption low and conserve resources. Here, MDO can deliver mathematically based design tools to create systems with optimum performance subject to the constraints of disciplines such as structures, aerodynamics, controls, etc. Although some applications of MDO are beginning to surface, the key to a widespread use of this technology lies in the improvement of its efficiency. This aspect is investigated here for the MDO subset of structural optimization, i.e., for the weight minimization of a given structure under size, strength, and displacement constraints. Specifically, finite element based multilevel optimization of structures (here, statically indeterminate trusses and beams for proof of concept) is performed. In the system level optimization, the design variables are the coefficients of assumed displacement functions, and the load unbalance resulting from the solution of the stiffness equations is minimized. Constraints are placed on the deflection amplitudes and the weight of the structure. In the subsystems level optimizations, the weight of each element is minimized under the action of stress constraints, with the cross sectional dimensions as design variables. This approach is expected to prove very efficient, especially for complex structures, since the design task is broken down into a large number of small and efficiently handled subtasks, each with only a small number of variables. This partitioning will also allow for the use of parallel computing, first, by sending the system and subsystems level computations to two different processors, ultimately, by performing all subsystems level optimizations in a massively parallel manner on separate processors. It is expected that the subsystems level optimizations can be further improved through the use of controlled growth, a method which reduces an optimization to a more efficient analysis with only a slight degradation in accuracy. The efficiency of all proposed techniques is being evaluated relative to the performance of the standard single level optimization approach where the complete structure is weight minimized under the action of all given constraints by one processor and to the performance of simultaneous analysis and design which combines analysis and optimization into a single step. It is expected that the present approach can be expanded to include additional structural constraints (buckling, free and forced vibration, etc.) or other disciplines (passive and active controls, aerodynamics, etc.) for true MDO.

Striz, Alfred G.↗

Cloud Radiative Forcing at the ARM Climate Research Facility: Technique, Validation, and Comparison to Satellite-derived Diagnostic Quantities - Part 1

It has been hypothesized that continuous ground-based remote sensing measurements from active and passive remote sensors combined with regular soundings of the atmospheric thermodynamic structure can be combined to describe the effects of clouds on the clear sky radiation fluxes. We critically test that hypothesis in this paper and a companion paper (Part II). Using data collected at the Southern Great Plains (SGP) Atmospheric Radiation Measurement (ARM) site sponsored by the U.S. Department of Energy, we explore an analysis methodology that results in the characterization of the physical state of the atmospheric profile at time resolutions of five minutes and vertical resolutions of 90 m. The description includes thermodynamics and water vapor profile information derived by merging radiosonde soundings with ground-based data, and continues through specification of the cloud layer occurrence and microphysical and radiative properties derived from retrieval algorithms and parameterizations. The description of the atmospheric physical state includes a calculation of the infrared and clear and cloudy sky solar flux profiles. Validation of the methodology is provided by comparing the calculated fluxes with top of atmosphere (TOA) and surface flux measurements and by comparing the total column optical depths to independently derived estimates. We find over a 1-year period of comparison in overcast uniform skies, that the calculations are strongly correlated to measurements with biases in the flux quantities at the surface and TOA of less than 10% and median fractional errors ranging from 20% to as low as 2%. In the optical depth comparison for uniform overcast skies during the year 2000 where the optical depth varies over 3 orders of magnitude we find a mean positive bias of 46% with a median bias of less than 10% and a 0.89 correlation coefficient. The slope of the linear regression line for the optical depth comparison is 0.86 with a normal deviation of 20% about this line. In addition to a case study where we examine the cloud radiative effects at the TOA, surface and atmosphere by a middle latitude synoptic-scale cyclone, we examine the cloud top pressure and optical depth retrievals of ISCCP and LBTM over a period of 1 year. Using overcast period from the year 2000, we find that the satellite algorithms tend to bias cloud tops into the middle troposphere and underestimate optical depth in high optical depth events (greater than 100) by as much as a factor of 2.

Mace, Gerald G.↗

Wide-Band Heterodyne Submillimetre Wave Spectrometer for Planetary Atmospheres

We present calculations and measurements on a passive submillimetre wave spectroscopic sounder to gather data on the thermal structure, dynamics and composition of the upper atmosphere of a planet, e.g. the stratosphere of Jupiter, or the entire thickness of the atmosphere of Mars. The instrument will be capable of measuring wind speeds, temperature, pressure, and key constituent concentrations in the stratosphere of the target planet. This instrument consists of a Schottky diode based front end and a digital back-end spectrometer. It differs from previous space-based spectrometers in its combination of wide tunability (520-590 GHz), and rapid frequency switching between widely spaced lines within that range. This will enable near simultaneous observation of multiple lines, which is critical to the reconstruction of atmospheric pressure and density versus altitude profiles. At the same time frequency accuracy must be high to enable wind speeds to be determined directly by measurement of the line's Doppler shift.

Submillimeter↗

Coherence Effects in L-Band Active and Passive Remote Sensing of Quasi-Periodic Corn Canopies

Due to their highly random nature, vegetation canopies can be modeled using the incoherent transport theory for active and passive remote sensing applications. Agricultural vegetation canopies however are generally more structured than natural vegetation. The inherent row structure in agricultural canopies induces coherence effects disregarded by the transport theory. The objective of this study is to demonstrate, via Monte-Carlo simulations, these coherence effects on L-band scattering and thermal emission from corn canopies consisting of only stalks.

Utku, Cuneyt↗

Heat pipe augmented passive solar heating system

A heat pipe augmented passive solar space heating system modulates the temperature inside a building structure, particular during heating seasons when the ambient temperature is below levels customarily associated with adequate room comfort, and in some embodiments comprises a solar absorber, a heat pipe surrounding wholly or partially by insulation, the heat pipe having three main sections which are an evaporator at one end proximal to the solar absorber, a condenser at the other end proximal to an interior room being heated, and a rubber adiabatic section between those. Additional aspects such as a mechanical valve in the adiabatic section are disclosed to limit unwanted thermal gains when cooling is needed because the ambient temperatures already exceed room comfort.

14 SOLAR ENERGY↗

MRS: Surveillance Test Article Development

The presentation covers work performed in FY23 on surveillance test article development. Surveillance test articles have been used of integrity assessment in light water reactor plants, this work seeks to develop a specimen that is passively loaded and could be used in advanced nuclear reactors for structural material health monitoring.

36 MATERIALS SCIENCE↗