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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 739 records · Page 41
All sourcesNASA NTRSDOE OSTI
NASA NTRS1980

Absorption and resonance Raman spectra of Pb2, Pb3 and Pb4 in xenon matrices

Lead metal was vaporized and trapped in solid xenon at 12K. Electronic absorption and resonance Raman spectra were recorded of the resulting matrix, which was shown to contain Pb2, Pb3, and possibly Pb4 molecular species. The vibrational frequency for Pb2 is determined to be 108/cm for the ground state, with a dissociation energy of 82000/cm. Ad3h symmetry is indicated for the Pb3 species, with nu sub 1=117/cm and nu sub 2 = 96 /cm. The existence of Pb4 is suggested by a fundamental and overtone of 111/cm spacing.

Stranz, D. D.↗
NASA NTRS1983

Spherical micro-glass particle impingement studies of thermoplastic materials at normal incidence

Light optical and scanning electron microscope studies were conducted to characterize the erosion resistance of polymethyl methacrylate (PMMA), polycarbonate (PC), polytetrafluoroethylene (PTFE) and ultra-high-molecular-weight-polyethylene (UHMWPE). Erosion was caused by a jet of spherical micro-glass beads at normal impact. During the initial stages of damage, the surfaces of these materials were studied using a profilometer. Material buildup above the original surface was observed on PC and PMMA. As erosion progressed, this buildup disappeared as the pit became deeper. Little or no buildup was observed on PTFE and on UHMWPE. UHMWPE and PTFE are the most resistant materials and PMMA the least. Favorable properties for high erosion resistance seem to be high values of ultimate elongation, and strain energy and a low value of the modulus of elasticity. Erosion-rate-versus-time curves of PC and PTFE exhibit incubation, acceleration and steady state periods. A continuously increasing erosion rate period was observed however for PMMA instead of a steady state period. At early stages of damage and at low impact pressure material removal mechanisms appear to be similar to those for metallic materials.

Rao, P. V.↗
NASA NTRS1984

Spherical microglass particle impingement studies of thermoplastic materials at normal incidence

Light optical and scanning electron microscope studies were conducted to characterize the erosion resistance of polymethyl methacrylate (PMMA), polycarbonate (PC), polytetrafluoroethylene (PTFE) and ultra-high-molecular-weight-polyethylene (UHMWPE). Erosion was caused by a jet of spherical micro-glass beads at normal impact. During the initial stages of damage, the surfaces of these materials were studied using a profilometer. Material buildup above the original surface was observed on PC and PMMA. As erosion progressed, this buildup disappeared as the pit became deeper. Little or no buildup was observed on PTFE and on UHMWPE. UHMWPE and PTFE are the most resistant materials and PMMA the least. Favorable properties for high erosion resistance seem to be high values of ultimate elongation, and strain energy and a low value of the modulus of elasticity. Erosion-rate-versus-time curves of PC and PTFE exhibit incubation, acceleration and steady state periods. A continuously increasing erosion rate period was observed however for PMMA instead of a steady state period. At early stages of damage and at low impact pressure material removal mechanisms appear to be similar to those for metallic materials.

Veerabhadra Rao, P.↗
NASA NTRS1985

Angular particle impingement studies of thermoplastic materials at normal incidence

Scanning electron microscope studies were conducted to characterize the erosion resistance of polymethyl methacrylate (PMMA), polycarbonate (PC), polytetrafluorethylene (PTFE), and ultra-high-molecular-weight polyethylene (UHMWPE). Erosion was caused by a jet of angular microparticles of crushed glass at normal incidence. Material built up above the original surface on all of the materials. As erosion progressed, this buildup disappeared. UHMWPE was the most resistant material and PMMA the least. The most favorable properties for high erosion resistance were high values of ultimate elongation, maximum service temperature, and strain energy and a low value of the modulus of elasticity. Erosion-rate-versus-time curves of PC and PTFE exhibited incubation, acceleration, and steady-state periods. PMMA also exhibited a deceleration period, and an incubation period with deposition was observed for UHMWPE.

Rao, P. V.↗
NASA NTRS1987

Organic nonlinear optical materials

Recently, it became clear that organic compounds with delocalized pi electrons show a great nonlinear optical response. Especially, secondary nonlinear optical constants of more than 2 digits were often seen in the molecular level compared to the existing inorganic crystals such as LiNbO3. The crystallization was continuously tried. Organic nonlinear optical crystals have a new future as materials for use in the applied physics such as photomodulation, optical frequency transformation, opto-bistabilization, and phase conjugation optics. Organic nonlinear optical materials, e.g., urea, O2NC6H4NH2, I, II, are reviewed with 50 references.

Umegaki, S.↗
NASA NTRS1989

Ballistic-electron-emission microscopy investigation of Schottky barrier interface formation

Ballistic-electron-emission microscopy (BEEM) has been used to investigate the origin of defects at the Au/GaAs(100) Schottky barrier interface. In addition, molecular beam epitaxy (MBE) and in situ fabrication methods have been employed to control Schottky barrier interface properties. BEEM characterization combined with MBE methods has enabled the development of a near-ideal Schottky barrier interface with drastically reduced defect density.

Hecht, M. H.↗
NASA NTRS1991

The effects of shock wave precursors ahead of hypersonic entry vehicles

A model has been developed to predict the magnitude and characteristics of the shock wave precursor ahead of a hypervelocity vehicle. This model includes both chemical and thermal nonequilibrium, utilizes detailed mass production rates for the photodissociation and photoionization reactions, and accounts for the effects of radiative absorption and emission on the individual internal energy modes of both atomic and diatomic species. Comparison of the present results with shock tube data indicates that the model is reasonably accurate. A series of test cases representing earth aerocapture return from Mars indicate that there is significant production of atoms, ions and electrons ahead of the shock front due to radiative absorption and that the precursor is characterized by an enhanced electron/electronic temperature and molecular ionization. However, the precursor has a negligible effect on the shock layer flow field.

Stanley, Scott A.↗
NASA NTRS1992

LDEF polymeric materials: 10 months versus 5.8 years of exposure

The chemical characterization of several polymeric materials which received both 10 months and 5.8 years of exposure on a Row 9 experiment (A0134) is reported. Specimens include polysulfone film, polysulfone matrix/graphite-fiber reinforced composites, and coated and uncoated epoxy matrix/graphite fiber reinforced composites. The effect of 10 months of exposure on an experimental silicon-containing polyimide copolymer film is also reported. The results of infrared, thermal, x-ray photoelectron, and scanning electron microscope analyses will be compared for the two exposures. Solution property measurements on the thermoplastic polysulfone resin will also be presented. Molecular level effects attributable to exposure and present in 10-month specimens are not present in 5.8-year specimens. This suggests that increased atomic oxygen fluence toward the end of the mission may have eroded selected environmentally-induced changes in surface chemistry for 5.8-year specimens.

Young, Philip R.↗
NASA NTRS1994

First measurement of helium on Mars: Implications for the problem of radiogenic gases on the terrestrial planets

108 +/- 11 photons of the martian He 584-A airglow detected by the Extreme Ultraviolet Explorer (EUVE) satellite during a 2-day exposure (January 22-23, 1993) correspond to the effective disk average intensity of 43 +/- 10 Rayleigh (Ra). Radiative transfer calculations, using a model atmosphere appropriate to the conditions of the observation and having an exospheric temperature of 210 +/- 20 K, result in a He mixing ratio of 1.1 +/- 0.4 ppm in the lower atmosphere. Nonthermal escape of helium is due to electron impact ionization and pickup of He(+) by the solar wind, to collisions with hot oxygen atoms, and to charge exchange with molecular species with corresponding column loss rates of 1.4 x 10(exp 5), 3 x 10(exp 4), and 7 x 10(exp 3)/sq cm/s, respectively. The lifetime of helium on Mars is 5 x 10(exp 4) years. the He outgassing rate, coupled with the Ar-40 atmospheric abundance and with the K:U:Th ratio measured in the surface rocks, is used as input to a single two-reservoir degassing model which is applied to Mars and then to Venus. A similar model with known abundances if K, U, and Th is applied to Earth. The models for Earth and Mars presume loss of all argon accumulated in the atmospheres during the first billion years by large-scale meteorite and planetesimal impacts. The models show that the degassing coefficients for all three planets may be approximated by function delta = delta(sub 0) x (t(sub 0)/t)(exp 1/2) with delta(sub 0) = 0.1, 0.04, and 0.0125 Byr for Earth, Venus, and Mars, respectively. After a R(exp 2) correction this means that outgassing processes on Venus and Mars are weaker than on Earth by factors of 3 and 30, respectively. Mass ratios of U and Th are almost the same for all three planets, while potassiumis depleted by a factor of 2 in Venus and Mars. Mass ratio of helium and argon are close to 5 x 10(exp -9) and 2 x 10(exp -8) g/g in the interiors of all three planets. The implications of these results are discussed.

Krasnopolsky, V. A.↗
NASA NTRS1998

Fullerene Machines

Fullerenes possess remarkable properties and many investigators have examined the mechanical, electronic and other characteristics of carbon SP2 systems in some detail. In addition, C-60 can be functionalized with many classes of molecular fragments and we may expect the caps of carbon nanotubes to have a similar chemistry. Finally, carbon nanotubes have been attached to t he end of scanning probe microscope (Spill) tips. Spills can be manipulated with sub-angstrom accuracy. Together, these investigations suggest that complex molecular machines made of fullerenes may someday be created and manipulated with very high accuracy. We have studied some such systems computationally (primarily functionalized carbon nanotube gears and computer components). If such machines can be combined appropriately, a class of materials may be created that can sense their environment, calculate a response, and act. The implications of such hypothetical materials are substantial.

Globus, Al↗
NASA NTRS2011

A Diagnostic Test for Determining the Location of the GeV Emission in Powerful Blazars

An issue currently under debate in the literature is how far from the black hole is the Fermi-observed GeV emission of powerful blazars emitted. Here we present a clear diagnostic tool for testing whether the Ge V emission site is located within the sub-pc broad emission line (BLR) region or further out in the few pc scale molecular torus (MT) environment. Within the BLR the scatteri~ takes place at the onset of the Klein-Nishina regime, causing the electron cooling time to become almost energy independent and as a result, the variation of high-energy emission is expected to be achromatic. Contrarily, if the emission site is located outside the BLR, the expected GeY variability is energy-dependent and with amplitude increasing with energy. We demonstrate this using time-dependent numerical simulations of blazar variability.

Dotson, Amanda↗
NASA NTRS1982

The great galactic centre mystery

Gamma-ray observations of the center of the Galaxy show a varying positron-electron annihilation radiation emission, while at radio wavelengths a non-thermal compact source surrounded by ionized gas moving at high velocities can be seen. Line emission maps for atomic and ionized hydrogen and molecular gas suggest gas expulsion and a massive collapsed object. IR observations show that ionized gas in the central few parsecs of the Galactic center is concentrated in at least 14 small clouds. Charge-coupled device images show a pair of faint, very red sources within a few arc seconds of IRS 16 and the compact non-thermal radio source. The positron-electron annihilation line emission implies an annihilation rate of 10 to the 43rd per sec, compared with an observed luminosity at IR wavelengths of 10 to the 40 erg per sec. Some models are briefly discussed.

Riegler, G. R.↗
NASA NTRS1979

Electron impact study of potassium hydroxide

An attempt is made to measure the sum of the elastic, rotational and vibrational scattering of electrons by KOH at low impact energies (5 to 20 eV) at angles from 10 to 120 deg. Energy loss spectra taken in the 0 to 18 eV range using an electron impact spectrometer are used to identify the species contributing to electric scattering. At temperatures between 300 and 500 C, only inelastic spectral features belonging to water are detected, while at temperatures from 500 to 800 C strong atomic K lines, indicative of molecular dissociation, and H2 energy loss features become prominent. No features attributable to KOH, the KOH dimer, O2 or potassium oxides were observed, due to the effects of the dissociation products, and it is concluded that another technique will have to be developed in order to measure electron scattering by KOH.

Vuskovic, L.↗
NASA NTRS1972

Thermodynamic properties of hydrogen-helium plasmas.

Calculation of the thermodynamic properties of an atomic hydrogen-helium plasma for postulated conditions present in a stagnation shock layer of a spacecraft entering the atmosphere of Jupiter. These properties can be used to evaluate transport properties, to calculate convective heating, and to investigate nonequilibrium behavior. The calculations have been made for temperatures from 10,000 to 100,000 K, densities of 10 to the minus 7th and .00001 g cu cm, and three plasma compositions: pure hydrogen, 50% hydrogen/50% helium, and pure helium. The shock layer plasma consists of electrons, protons, atomic hydrogen, atomic helium, singly ionized helium, and doubly atomized helium. The thermodynamic properties which have been investigated are: pressure, average molecular weight, internal energy, enthalpy, entropy, specific heat, and isentropic speed of sound. A consistent model was used for the reduction of the ionization potential in the calculation of the partition functions.

Nelson, H. F.↗
NASA NTRS1977

Mechanical properties and the electronic structure of transition of metal alloys

This interdiscipline research program was undertaken in an effort to investigate the relationship between the mechanical strength of Mo based alloys with their electronic structure. Electronic properties of these alloys were examined through optical studies, and the classical solid solution strengthening mechanisms were considered, based on size and molecular differences to determine if these mechanisms could explain the hardness data.

Arsenault, R. J.↗
NASA NTRS1981

Studies of the role of metastables and doubly ionized species in the chemical and thermal structure of the Venusian and Martian ionospheres

Models of the upper atmospheres of Mars and Venus were constructed using Viking and Pioneer Venus data. The neutral densities, with the exception of NO, N(4S), N(2D) and N(2P) were taken from the measured values, along with the neutral, ion, and electron temperatures. Using solar fluxes and relevant cross sections, the production rates of ions and neutral fragments by photo and electron impact processes were computed. These production rates were combined with chemical production rates and loss along with one dimensional transport eddy diffusion, molecular and ambi polar diffusion, and thermal diffusion, to determine the densities of ions and odd nitrogen species. Preliminary calculations show that the chemistry of metastables and doubly ionized species is important in the ionospheres of Mars and Venus. Production of N(+) in metastable reactions is particularly important, and it explains the discrepancy between the measurements of earlier models. Production of CO(+) is also affected. Reactions of O(++) and O(+)(2D) with N2 have important consequences for the escape rate of atomic nitrogen from the Martian atmosphere.

Fox, J. L.↗
NASA NTRS1988

Theoretical studies of solar-pumped lasers

The investigation of stimulated emission causing transitions from the B(1) pi sub u state of sodium to the overlapping 2(1) sigma(+) sub g electronic state has been continued. A new method of estimating the Franck-Condon factors has been developed which instead of fitting the molecular potential curves with Morse functions, estimates the V(r) dependence by interpolation from given potential curves. The results for the sum of the rates from one vibrational level in the upper state to all the levels in the lower state show good agreement with the previous method, implying that curve crossing by stimulated emission due to photons from the oven is an important mechanism in sodium.

Harries, Wynford L.↗