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At least 739 records · Page 41

Seasonal Updraft Speeds Change Cloud Droplet Number Concentrations in Low Level Clouds Over the Western North Atlantic

To determine the impact of dynamic and aerosol processes on marine low clouds, we examine the seasonal impact of updraft speed w and cloud condensation nuclei concentration at 0.43 % supersaturation () on the cloud droplet number concentration (N(C)) of low-level clouds over the western North Atlantic Ocean. Aerosol and cloud properties were measured with instruments on board the NASA LaRC Falcon HU-25 during the ACTIVATE (Aerosol Cloud meTeorology Interactions oVer the western ATlantic Experiment) mission in summer (August) and winter (February–March) 2020. The data are grouped into different loadings, and the density functions of NC and w near the cloud bases are compared. For low updrafts (w < 1.3 m s−1), NC in winter is mainly limited by the updraft speed and in summer additionally by aerosols. At larger updrafts (w > 3 m s−1), NC is impacted by the aerosol population, while at clean marine conditions cloud nucleation is aerosol-limited, and for high it is influenced by aerosols and updraft. The aerosol size distribution in winter shows a bimodal distribution in clean marine environments, which transforms to a unimodal distribution in high due to chemical and physical aerosol processes, whereas unimodal distributions prevail in summer, with a significant difference in their aerosol concentration and composition. The increase of is accompanied with an increase of organic aerosol and sulfate compounds in both seasons. We demonstrate that NC can be explained by cloud condensation nuclei activation through upwards processed air masses with varying fractions of activated aerosols. The activation highly depends on w and thus supersaturation between the different seasons, while the aerosol size distribution additionally affects NC within a season. Our results quantify the seasonal influence of w and on NC and can be used to improve the representation of low marine clouds in models.

Simon Kirschler↗

Symposium /International/ on Combustion, 18th, University of Waterloo, Waterloo, Ontario, Canada, August 17-22, 1980, Proceedings

Problems related to combustion generated pollution are explored, taking into account the mechanism of NO formation from nitrogen compounds in hydrogen flames studied by laser fluorescence, the structure and similarity of nitric oxide production in turbulent diffusion flames, the effect of steam addition on NO formation, and the formation of NO2 by laminar flames. Other topics considered are concerned with propellant combustion, fluidized bed combustion, the combustion of droplets and sprays, premixed flame studies, fire studies, and flame stabilization. Attention is also given to coal flammability, chemical kinetics, turbulent combustion, soot, coal combustion, the modeling of combustion processes, combustion diagnostics, detonations and explosions, ignition, internal combustion engines, combustion studies, and furnaces.

Source record↗

Nucleation and condensation in the primitive solar nebula

It is pointed out that the primitive solar nebula may be modeled using the frictionally induced transport theory of Lynden-Bell and Pringle (1974) if the principal frictional mechanism within the nebula is turbulent viscosity. The present investigation is concerned with the construction of a model of a section of the primitive solar nebula as a basis for the study of nucleation and condensation processes within this section. The construction involves a relatively simple application of the Lynden-Bell and Pringle theory subject to steady mass flow conditions. The calculations which are conducted in connection with the investigation indicate that by the time the gas in the primitive solar nebula has become sufficiently supercooled to nucleate condensation centers, several different compounds, including the magnesium silicates forsterite and enstatite (MgSiO3), will probably be able to condense on the growing condensation center.

Cameron, A. G. W.↗

The Latitude Dependence of the Effect of Pinatubo on Stratospheric Ozone

Statistical analysis of TOMS and SBLT total ozone data indicate that the eruption of Pinatubo in 1991 led to a significant decrease in ozone at northern midlatitudes with little or no effect at southern midlatitudes. We argue that this puzzling absence of a southern hemisphere effect may be an artifact of the statistical analysis. We have run a 3D CTM simulation of the past 30 years of stratospheric photochemistry with variable forcing due to chlorine/bromine compounds, solar ultraviolet radiation, and volcanic aerosols. This integration used winds from the FVGCM, which has similar interannual variability to the atmosphere. When this CTM output was examined with a standard time-series analysis, we found an effect of Pinatubo in the southern hemisphere, but not in the northern hemisphere. We then reran the CTM without volcanic aerosols. The subtraction of the two simulations indicated that, as expected, that Pinatubo affected both hemispheres in the model. This means that the northern hemisphere effect was in the model but did not show up in the statistical analysis. We also had an on-line parameterized chemical ozone tracer with seasonally repeating production and loss over the simulation. We used this as a dynamical surrogate to remove interannual variability from the original model output. The residual time series was then analyzed for the Pinatubo effect and we were able to find it in both hemispheres. We suggest that the combination of the two volcanoes, El Chichon and Pinatubo, with the solar cycle and interannual variability led to this problem of analysis in the northern hemisphere of our model. We furthermore suggest that a similar think may be occurring in the southern hemisphere of the data. An analysis of the atmosphere's southern hemisphere with a good dynamical surrogate may solve the mystery of the missing southern hemisphere effect of Pinatubo on ozone.

Stolarski, Richard S.↗

Effect of High Temperature Storage on AC Characteristics of Polymer Tantalum Capacitors

Replacement of MnO2 with conductive polymers as cathode materials in chip tantalum capacitors allows for a substantial reduction of the equivalent series resistance (ESR), improvement of frequency characteristics, and elimination of the possibility of ignition during failures. One of the drawbacks of chip polymer tantalum capacitors (CPTCs) is a relatively poor long-term stability at high temperatures. In this work, variations of capacitance, dissipation factor, and ESR in different types of capacitors including automotive grade parts from three manufacturers have been monitored during storage at temperatures from 100 ºC to 175 ºC for up to 18,000 hours. Results show that ESR is the most and capacitance the least sensitive to degradation parameter. Times to parametric failures have been simulated using a Weibull-Arrhenius model that allowed for assessments of activation energies of the degradation and prediction of times to failure at the use temperature. Degradation of CPTCs was explained by thermo-oxidative processes in conductive polymers that result in exponential increasing of the resistivity with time of ageing. This process starts after a certain incubation period that depends on packaging materials and design and corresponds to the time that is necessary to form delamination between the encapsulating molding compound and lead frame. The effectiveness of the existing qualification procedures to assure stable operation of CPTCs is discussed.

Alexander A Teverovsky↗

Effect of High Temperature Storage on AC Characteristics of Polymer Tantalum Capacitors

Replacement of MnO2 with conductive polymers as cathode materials in chip tantalum capacitors allows for a substantial reduction of the equivalent series resistance (ESR), improvement of frequency characteristics, and elimination of the possibility of ignition during failures. One of the drawbacks of chip polymer tantalum capacitors (CPTCs) is a relatively poor long-term stability at high temperatures. In this work, variations of capacitance, dissipation factor, and ESR in different types of capacitors including automotive grade parts from three manufacturers have been monitored during storage at temperatures from 100 ºC to 175 ºC for up to 18,000 hours. Results show that ESR is the most and capacitance the least sensitive to degradation parameter. Times to parametric failures have been simulated using a Weibull-Arrhenius model that allowed for assessments of activation energies of the degradation and prediction of times to failure at the use temperature. Degradation of CPTCs was explained by thermo-oxidative processes in conductive polymers that result in exponential increasing of the resistivity with time of ageing. This process starts after a certain incubation period that depends on packaging materials and design and corresponds to the time that is necessary to form delamination between the encapsulating molding compound and lead frame. The effectiveness of the existing qualification procedures to assure stable operation of CPTCs is discussed.

Aging↗

Effect of High Temperature Storage on AC Characteristics of Polymer Tantalum Capacitors

Replacement of MnO2 with conductive polymers as cathode materials in chip tantalum capacitors allows for a substantial reduction of the equivalent series resistance (ESR), improvement of frequency characteristics, and elimination of the possibility of ignition during failures. One of the drawbacks of chip polymer tantalum capacitors (CPTCs) is a relatively poor long-term stability at high temperatures. In this work, variations of capacitance, dissipation factor, and ESR in different types of capacitors including automotive grade parts from three manufacturers have been monitored during storage at temperatures from 100 ºC to 175 ºC for up to 18,000 hours. Results show that ESR is the most and capacitance the least sensitive to degradation parameter. Times to parametric failures have been simulated using a Weibull-Arrhenius model that allowed for assessments of activation energies of the degradation and prediction of times to failure at the use temperature. Degradation of CPTCs was explained by thermo-oxidative processes in conductive polymers that result in exponential increasing of the resistivity with time of ageing. This process starts after a certain incubation period that depends on packaging materials and design and corresponds to the time that is necessary to form delamination between the encapsulating molding compound and lead frame. The effectiveness of the existing qualification procedures to assure stable operation of CPTCs is discussed.

Aging↗

Effect of High Temperature Storage on AC Characteristics of Polymer Tantalum Capacitors

Replacement of MnO2 with conductive polymers as cathode materials in chip tantalum capacitors allows for a substantial reduction of the equivalent series resistance (ESR), improvement of frequency characteristics, and elimination of the possibility of ignition during failures. One of the drawbacks of chip polymer tantalum capacitors (CPTCs) is a relatively poor long-term stability at high temperatures. In this work, variations of capacitance, dissipation factor, and ESR in different types of capacitors including automotive grade parts from three manufacturers have been monitored during storage at temperatures from 100 ºC to 175 ºC for up to 18,000 hours. Results show that ESR is the most and capacitance the least sensitive parameter to degradation. Times to parametric failures have been simulated using a Weibull-Arrhenius model that allowed for assessments of activation energies of the degradation and prediction of times to failure at the use temperature. Degradation of CPTCs was explained by thermo-oxidative processes in conductive polymers that result in exponential increase of the resistivity with time of aging. This process starts after a certain incubation period that depends on packaging materials and design and corresponds to the time that is necessary to form delamination between the encapsulating molding compound and lead frame. The effectiveness of the existing qualification procedures to assure stable operation of CPTCs is discussed.

high temperature storage (HTS)↗

Trioxane-Air Counterflow Diffusion Flames in Normal and Microgravity

Trioxane, a weakly bound polymer of formaldehyde (C3H6O3, m.p. 61 C, b.p. 115 C), is a uniquely suited compound for studying material flammability. Like many of the more commonly used materials for such tests (e.g., delrin, polyethylene, acrylic sheet, wood, and paper), it displays relevant phenomena (internal heat conduction, melting, vaporization, thermal decomposition, and gas phase reaction of the decomposition products). Unlike the other materials, however, it is non-sooting and has simple and well-known chemical kinetic pathways for its combustion. Hence it should prove to be much more useful for numerical modeling of surface combustion than the complex fuels typically used. We have performed the first exploratory tests of trioxane combustion in the counterflow configuration to determine its potential as a surrogate solid fuel which allows detailed modeling. The experiments were performed in the spring and summer of 1998 at the National Institute of Standards and Technology in Gaithersburg, MD, and at NASA-GRC in Cleveland. Using counterflow flames at 1-g, we measured the fuel consumption rate and the extinction conditions with added N2 in the air; at mg conditions, we observed the ignition characteristics and flame shape from video images. We have performed numerical calculations of the flame structure, but these are not described here due to space limitations. This paper summarizes some burning characteristics of trioxane relevant to its use for studying flame spread and fire suppression.

Linteris, Gregory T.↗

Volatile chemical product emissions enhance ozone and modulate urban chemistry

Decades of air quality improvements have substantially reduced the motor vehicle emissions of volatile organic compounds (VOCs). Today, volatile chemical products (VCPs) are responsible for half of the petrochemical VOCs emitted in major urban areas. We show that VCP emissions are ubiquitous in US and European cities and scale with population density. We report significant VCP emissions for New York City (NYC), including a monoterpene flux of 14.7 to 24.4 kg ⋅ d−1 ⋅ km−2 from fragranced VCPs and other anthropogenic sources, which is comparable to that of a summertime forest. Photochemical modeling of an extreme heat event, with ozone well in excess of US standards, illustrates the significant impact of VCPs on air quality. In the most populated regions of NYC, ozone was sensitive to anthropogenic VOCs (AVOCs), even in the presence of biogenic sources. Within this VOC-sensitive regime, AVOCs contributed upwards of ∼20 ppb to maximum 8-h average ozone. VCPs accounted for more than 50% of this total AVOC contribution. Emissions from fragranced VCPs, including personal care and cleaning products, account for at least 50% of the ozone attributed to VCPs. We show that model simulations of ozone depend foremost on the magnitude of VCP emissions and that the addition of oxygenated VCP chemistry impacts simulations of key atmospheric oxidation products. NYC is a case study for developed megacities, and the impacts of VCPs on local ozone are likely similar for other major urban regions across North America or Europe.

Matthew M. Coggon↗

The atmospheres of Titan and the Galilean satellites

The stability of various atmospheres on Titan and the Galilean satellites is examined relative to escape. One method consists of the comparison of exospheric temperature and a blow-off temperature defined for the various constituents. Another method consists of the evaluation of outflow based on a polytropic model. Hydrogen, methane, nitrogen, and neon atmospheres are examined. It is found that the Jovian satellites require heavier gases if they are to have any but very tenuous atmospheres, since all constituents examined are unstable. Nitrogen is stable on Titan, but methane and neon are marginally stable. Hydrogen is extremely unstable as a major constituent. As a minor constituent it is rapidly lost from Titan's thermosphere and must be replenished by outgassing or dissociation of a hydrogen compound, if the presently observed hydrogen content on Titan is not a transient occurrence. The rate of loss may be limited by diffusion, but could be augmented by vertical convection.

Gross, S. H.↗

The design and development of a mixer compound exhaust system for a quiet clean general aviation turbofan

Lower engine fuel consumption has become a dominant factor in turbofan engine design due to rapidly increasing fuel costs. One engine component with a large impact on engine performance is the exhaust system. Previous exhaust system studies have demonstrated the significant exhaust system efficiency gains available through mixing of the core and bypass flows. Typically, a large, costly rig and engine program are required to develop and optimize these gains. The purpose of this paper is to present the results of the low-cost design system used for the quiet, clean general aviation turbofan mixer nozzle design and development. The scale model and full-scale engine test results confirm the predicted 3 to 5% reduction in cruise fuel consumption. This unique design system, which is based on integrating advanced three-dimensional viscous numerical methods with empirical optimization techniques, is summarized and detailed comparisons with test data are presented. The ability to accurately predict relative performance of mixer systems with substantially reduced development time and cost savings is demonstrated.

Blackmore, W. L.↗

Transparent Ada rendezvous in a fault tolerant distributed system

There are many problems associated with distributing an Ada program over a loosely coupled communication network. Some of these problems involve the various aspects of the distributed rendezvous. The problems addressed involve supporting the delay statement in a selective call and supporting the else clause in a selective call. Most of these difficulties are compounded by the need for an efficient communication system. The difficulties are compounded even more by considering the possibility of hardware faults occurring while the program is running. With a hardware fault tolerant computer system, it is possible to design a distribution scheme and communication software which is efficient and allows Ada semantics to be preserved. An Ada design for the communications software of one such system will be presented, including a description of the services provided in the seven layers of an International Standards Organization (ISO) Open System Interconnect (OSI) model communications system. The system capabilities (hardware and software) that allow this communication system will also be described.

Racine, Roger↗

Post-SL9 Sulfur Photochemistry on Jupiter

We have modeled the photochemical evolution of the sulfur containing species that were observed in Jupiter's stratosphere after the Shoemaker Levy 9 (SL9) impacts. We find that most of the sulfur is converted to S8 in the first few days. Other important sulfur reservoirs are CS, whose abundance increases markedly with time, and possibly H2CS, HNCS, and NS, whose abundances depend on kinetic reaction rates that are unknown at the present. We discuss the temporal variation of the major sulfur compounds, make abundance and compositional predictions useful for comparison with observations, and discuss the possible condensation of sulfur containing species.

Moses, Julianne I.↗

Hemispherical Optical Dome for Underwater Communication

For many years, acoustic systems have been used as the primary method for underwater communication; however, the data transfer rate of such systems is low because sound propagates slowly through the water. A higher throughput can be achieved using visible light to transmit data underwater. The first issue with using this approach is that there is generally a large loss of the light signal due to scattering and absorption in water even though there is an optimal wavelength for transmission in the blue or green wavelengths of the visible spectrum. The second issue is that a simple system consisting only of a highly directional source transmitter and small optical detector receiver has a very narrow field of view. The goal of this project is to improve an optical, underwater communication system by increasing the effective field of view of the receiving optics. To this end, we make two changes to the simple system: (1) An optical dome was added near the receiver. An array of lenses is placed radially on the surface of the dome, reminiscent of the compound eye of an insect. The lenses make the source and detector planes conjugate, and each lens adds a new region of the source plane to the instrument's total field of view. (2) The receiver was expanded to include multiple photodiodes. With these two changes, the receiver has much more tolerance to misalignments (in position and angle) of the transmitter.Two versions of the optical dome (with 6 and 8 diameters) were designed using the CREO CAD software and modeled using the CODE V optical design software. A series of these transparent hemispherical domes, with both design diameters, were manufactured using a 5-axis mill. The prototype was then retrofitted with lenses and compared with the computer-generated model to demonstrate the effectiveness of this solution. This work shows the dome design improves the optical field of view of the underwater communication system considerably. Furthermore, with the experimental test results, a geometric optimization model was derived providing insights to the design performance limits.

Design↗

Hemispherical Optical Dome for Underwater Communication

For many years, acoustic systems have been used as the primary method for underwater communication; however, the data transfer rate of such systems is low because sound propagates slowly through the water. A higher throughput can be achieved using visible light to transmit data underwater. The first issue with using this approach is that there is generally a large loss of the light signal due to scattering and absorption in water even though there is an optimal wavelength for transmission in the blue or green wavelengths of the visible spectrum. The second issue is that a simple system consisting only of a highly directional source/transmitter and small optical detector/receiver has a very narrow field of view. The goal of this project is to improve an optical, underwater communication system by increasing the effective field of view of the receiving optics. To this end, we make two changes to the simple system: (1) An optical dome was added near the receiver. An array of lenses is placed radially on the surface of the dome, reminiscent of the compound eye of an insect. The lenses make the source and detector planes conjugate, and each lens adds a new region of the source plane to the instrument's total field of view. (2) The receiver was expanded to include multiple photodiodes. With these two changes, the receiver has much more tolerance to misalignments (in position and angle) of the transmitter.Two versions of the optical dome (with 6 and 8 diameters) were designed using the CREO CAD software and modeled using the CODE V optical design software. A series of these transparent hemispherical domes, with both design diameters, were manufactured using a 5-axis mill. The prototype was then retrofitted with lenses and compared with the computer-generated model to demonstrate the effectiveness of this solution. This work shows the dome design improves the optical field of view of the underwater communication system considerably. Furthermore, with the experimental test results, a geometric optimization model was derived providing insights to the design performance limits.

Underwater↗

Advanced Modular Power System Electronics Enclosure Thermal Testing

An analysis was set up to model the temperature of the advanced modular power system (AMPS) power distribution cards when installed within the electronics enclosure case. The analysis was used to determine the steady-state temperature distribution of the cards within the case. To verify the analysis, an experiment was set up and conducted to simulate the operation of the cards within the enclosure. Four tests were conducted. The tests varied the position of the cold plate and evaluated the use of a thermal compound to reduce the contact resistance between the joints within the thermal path between the cards and the cold plate. Three of the four cases examined showed very good agreement between the analysis and the experiment with a less than 1-percent variation in the predicated temperatures determined through the analysis and the experimentally derived temperatures. In the remaining case, the difference between the analysis and experiment was approximately 12 percent. Both the experiment and analysis showed that the modular power conditioning cards can be maintained within their desired maximum operating temperature range of 40 to 45 °C through thermal conduction to a cold plate when operating with their estimated maximum heat output of 16 W per card.

Colozza, Anthony J.↗

Propagation of sound waves in tubes of noncircular cross section

Plane-acoustic-wave propagation in small tubes with a cross section in the shape of a flattened oval is described. Theoretical descriptions of a plane wave propagating in a tube with circular cross section and between a pair of infinite parallel plates, including viscous and thermal damping, are expressed in similar form. For a wide range of useful duct sizes, the propagation constant (whose real and imaginary parts are the amplitude attenuation rate and the wave number, respectively) is very nearly the same function of frequency for both cases if the radius of the circular tube is the same as the distance between the parallel plates. This suggests that either a circular-cross-section model or a flat-plate model can be used to calculate wave propagation in flat-oval tubing, or any other shape tubing, if its size is expressed in terms of an equivalent radius, given by g = 2 x (cross-sectional area)/(length of perimeter). Measurements of the frequency response of two sections of flat-oval tubing agree with calculations based on this idea. Flat-plate formulas are derived, the use of transmission-line matrices for calculations of plane waves in compound systems of ducts is described, and examples of computer programs written to carry out the calculations are shown.

Richards, W. B.↗