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At least 739 records · Page 41

Mobility Hubs: Workforce Landscape Assessment, Development Opportunities, and Local Transportation Planning

Through the U.S. Department of Energy's Energy to Communities (E2C) program, NLR, other national laboratory experts, and select organizations provide Expert Match - free, short-term technical assistance to address near-term energy challenges and questions. Expert Match is for community stakeholders who have decision-making power or influence in their community but need access to additional energy expertise to inform key upcoming decisions. This Expert Match request supported Equticity in Chicago, IL with an analysis workforce development considerations and opportunities and is intended to support decision-making on micromobility initiatives.

33 ADVANCED PROPULSION SYSTEMS↗

Meeting the Challenges of Modern Transit through the Integration of Traditional Transit, On-Demand Micro-Transit Services and Vehicle Automation - A Case Study in Chandler, Arizona

Current technology trends of vehicle automation, electrification and on-demand transit are providing new tools to develop effective public mobility services, yet need to be balanced with traditional modes to serve the spectrum of demand effectively and efficiently. Automated vehicle transportation network company (TNC) services, better known as 'Robotaxis' are beginning to proliferate and scale across the US, with Waymo as the lead commercial entity. Chandler, AZ was the first fully automated deployment of Waymo technology. Chandler was also one of the first municipalities in Arizona to roll out micro-transit service to its citizens in 2022. At present the Chandler Flex micro-transit program is beginning to partner with Waymo to augment micro-transit services during peak demands, another first in the nation. However, the mix of services in Chandler relies not only on new technology, but also on traditional modes including fixed route transit and para-transit services. These are blended and balanced such that both old and new modes are applied within the context in which each excel. This presentation will provide background on the Chandler, AZ public mobility services, and the performance metrics that govern their use and selection within the spectrum of development and population density as well as socio-demographics within Chandler. Additionally, the behavioral response of the use of unmanned, automated vehicles employed to augment micro-transit is novel, the first in the nation - and initial feedback from public transit constituents in Chandler will be shared.

24 POWER TRANSMISSION AND DISTRIBUTION↗

IRIS: A Portable Runtime System Exploiting Multiple Heterogeneous Programming Systems

Across embedded, mobile, enterprise, and HPC systems, computer architectures are becoming more heterogeneous and complex. This complexity is causing a crisis in programming systems and performance portability. Several programming systems are working to address these challenges, but the increasing architectural diversity is forcing software stacks and applications to specialize for each architecture. As we show, all of these approaches critically depend on their runtime system for discovery, execution, scheduling, and data orchestration. To address this challenge, we believe that a more agile and proactive runtime system is essential to increase performance portability and improve user productivity. In this regard, we have designed and implemented IRIS: a portable runtime system exploiting multiple heterogeneous programming systems. IRIS can discover available resources, manage multiple diverse programming systems (e.g., CUDA, Hexagon, HIP, Level Zero, OpenCL, OpenMP) simultaneously in the same execution, respect data dependencies, orchestrate data movement proactively, and provide for user-configurable scheduling. Our evaluation on three architectures, ranging from Qualcomm Snapdragon to a Summit supercomputer node, shows that IRIS improves portability across a wide range of diverse heterogeneous architectures with negligible overhead.

Kim, Jungwon↗

Synthesis and Characterization of Tc(I) Carbonyl Nitrosyl Species Relevant to the Hanford Tank Waste: FY 2016 Status Report

Among long-lived radioactive constituents in the Hanford tank waste, Tc presents a unique challenge in that it exists predominantly in the liquid phase, generally in the anionic form of pertechnetate, TcO 4 - , which is highly volatile at low-activity waste (LAW) vitrification melter temperatures and mobile in the Hanford site’s subsurface environment. The complex behavior of Tc under storage, treatment, and immobilization conditions significantly affects its management options, which to-date remain uncertain. In strongly alkaline environments, Tc exists as pertechnetate, TcO 4 - (oxidation state +7), and in the reduced forms (oxidation state < +7) collectively known as non-pertechnetate species. Pertechnetate is a well-characterized, anionic Tc species that can be removed from LAW by anion exchange or solvent extraction methods. There is no definitive information on the origin of the non-pertechnetate Tc species, nor is there a comprehensive description of their composition and behavior. It has been recently proposed that the non-pertechnetate species can comprise Tc(I) metal center and carbonyl or mixed carbonyl nitrosyl ligands stabilizing low-valent Tc. Recent work by our group has significantly expanded this previous work, generating a series of Tc(I) carbonyl compounds and demonstrating that they can be generated from reduction of TcO 4 - in the simulated Hanford tank waste in presence of CO at elevated temperature (Levitskaia et al. 2014). These results are consistent with the previous proposal that [Tc(CO) 3 ] + species can be present in the Hanford tank waste and suggest that the low Tc(I) oxidation state is stabilized by the π-accepting ability of the CO ligands. The continuation work has been initiated to develop model Tc carbonyl nitrosyl compounds and investigate their potential presence in the Hanford tank wastes. This report summarizes our to-date results.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Review of Cementitious Materials Development and Applications That Have Supported DOE-EM Missions: Waste Treatment, Conditioning, Containment Structures, Tank Closures, Facility Decommissioning, Environmental Restoration, and Structural Assessments

The Department of Energy (DOE) is tasked with managing the legacy defense wastes that resulted from nuclear materials production and nuclear arms development. Nuclear-waste management encompasses generation, processing (treatment and packaging), storage, transport, and disposal. To date, there are over 100 million gallons of liquid radioactive and chemical mixed wastes within the Department of Energy complex as well as solid waste, debris, and environmental restoration media that require disposal. DOE has been able to meet the challenges involved in dispositioning this waste using unique technical approaches and application-specific data required due to the nature of the constituents to be managed (e.g., long-lived radionuclides and highly mobile radionuclides in the near surface environments). Cementitious materials have played a prominent role historically in the successful disposition of these wastes, in the reduction of risk to the public, and in the closure of decommissioned tanks and facilities across the DOE complex.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Evaluation of Dose- and Risk-Based Groundwater Cleanup Levels for Low Energy Beta Radioisotopes

Low-energy beta-emitting radionuclides that were released historically during reactor operations and plutonium separations activities at some U.S. Department of Energy sites have migrated into the groundwater, forming contaminant plumes that are subject to federally regulated remediation actions. At the Hanford Site, the low-energy beta-emitting radionuclides include iodine-129, technetium-99, chlorine-36, carbon-14, and tritium (H-3). All are highly mobile in the subsurface, and except for tritium, and have very long half-lives—thousands to millions of years. The geochemistry and transport behavior of these contaminants in the subsurface present significant challenges for remediation of groundwater to federal drinking water standards (DWS)—the appropriate or relevant and applicable requirements (ARARs) for cleanup. For some of the low-energy beta-emitter contaminants, particularly iodine-129, cleanup and restoration of groundwater to DWS may not be attainable within a reasonable timeframe using currently available treatment technologies.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Reliability Requirements and Research Strategies for Urban Air Mobility Propulsion

An emerging new mission for aeronautics is Urban Air Mobility (UAM), a concept for air transportation around metropolitan areas with passenger-carrying operations. UAM vehicles must be capable of vertical take-off and landing, and this requirement presents unique technical challenges for electric and hybrid-based vertical take-off and landing (eVTOL). A critical challenge for UAM market growth is to gain public acceptance for being as safe as - or safer than - commercial air travel and automotive transportation. There is a lack of data for propulsion systems, components, and the associated thermal management systems for UAM eVTOL propulsion systems. The new mission, new propulsion system concepts, safety criticality of propulsion component performance during vertical take-off and lift operations, and lack of data presents many research challenges and opportunities. NASA has developed and published UAM vehicle concept studies. For a subset of the said concept vehicles, NASA has contracted for a study to identify failure modes and hazards associated with the propulsion systems of the concept vehicles and to perform functional hazard analyses (FHA) and failure modes and effects criticality analyses (FMECA) for each. From the completed study results, it was recommended for NASA to support research toward developing electric/hybrid-electric propulsion components with improved reliability and to explore powertrain architectures that can take advantage of higher reliability components to achieve inherent air-vehicle safety. NASA has started a research effort for UAM propulsion with a focus toward improving safety and reliability. Recent results and research strategy will be discussed toward the goals by means of: 1) improving individual component reliability through advanced materials and design methods, 2) improving the thermal management system, and 3) designing propulsion system architectures to provide inherent UAM vehicle safety.

Krantz, Timothy↗

Electroactive polymers as artificial muscles - reality and challenges

For many years, electroactive polymers (EAP) received reIatively little attention due to the small number of available materials and their limited actuation capability. The recent emergence of EAP materials with large displacement response changed the potential capability and paradigms of these materials. The main attractive characteristic of EAP is their operational similarity to biological muscles, particularly their resilience and ability to induce large actuation strains. Even though the actuation force of existing EAP materials and their robustness require further improvement, there has already been a series of reported successes. The successful applications that were demonstrated include catheter steering element, miniature manipulator, dust-wiper, miniature robotic arm, and grippers. Some of the currently considered applications may be difficult to accomplish and it is important to scope the requirements to the level that current materials can address. Using EAP to replace existing actuators may be a difficult challenge and therefore it is highly desirable to identify a niche application where it would not need to compete with existing capabilities. The application of these materials as actuators to drive various manipulation, mobility and robotic devices involves multidiscipline including materials, chemistry, electro-mechanics, computers, electronics, etc. This paper reviews the current efforts and the expectations for the future.

Bar-Cohen, Yoseph↗

Dual in-aquifer and near surface processes drive arsenic mobilization in Cambodian groundwaters

Millions of people globally, and particularly in South and Southeast Asia, face chronic exposure to arsenic from reducing groundwaters in which. Arsenic release to is widely attributed largely to reductive dissolution of arsenic-bearing iron minerals, driven by metal reducing bacteria using bioavailable organic matter as an electron donor. However, the nature of the organic matter implicated in arsenic mobilization, and the location within the subsurface where these processes occur, remains debated. In a high resolution study of a largely pristine, shallow aquifer in Kandal Province, Cambodia, we have used a complementary suite of geochemical tracers (including 14 C, 3 H, 3 He, 4 He, Ne, δ 18 O, δD, CFCs and SF 6 ) to study the evolution in arsenic-prone shallow reducing groundwaters along dominant flow paths. The observation of widespread apparent 3 H- 3 He ages of <55years fundamentally challenges some previous models which concluded that groundwater residence times were on the order of hundreds of years. Surface-derived organic matter is transported to depths of >30m, and the relationships between age-related tracers and arsenic suggest that this surface-derived organic matter is likely to contribute to in-aquifer arsenic mobilization. A strong relationship between 3 H- 3 He age and depth suggests the dominance of a vertical hydrological control with an overall vertical flow velocity of ~0.4±0.1m·yr-1 across the field area. A calculated overall groundwater arsenic accumulation rate of ~0.08±0.03μM·yr -1 is broadly comparable to previous estimates from other researchers for similar reducing aquifers in Bangladesh. Although apparent arsenic groundwater accumulation rates varied significantly with site (e.g. between sand versus clay dominated sequences), rates are generally highest near the surface, perhaps reflecting the proximity to the redox cline and/or depth-dependent characteristics of the OM pool, and confounded by localized processes such as continued in-aquifer mobilization, sorption/desorption, and methanogenesis.

54 ENVIRONMENTAL SCIENCES↗

Accelerance Decoupling: Removing the Influence of the Mobile Launcher from the Space Launch System Integrated Modal Test

Main objective for launch vehicle (LV) modal testing is to quantify the LV’s modal properties in the free-free state (i.e., post pad separation). Given the size of most LVs, free-free testing is a challenge and often not feasible. A test stand, typically the launch pad itself, is utilized as the means to support the LV an Integrated Modal Test (IMT). This shifts the challenge to developing robust numerical methods for removing the influence of the launch pad from the IMT. Preferably fully test driven (method’s that operate based on measured data only). The Accelerance Decoupling (AD) approach, developed and verified by NASA and ASD, is a method with the capability to “subtract out” the influence of the test stand from the IMT using measured data only

Joel Sills↗

Preparing For Advanced Air Mobility: A System-Level Framework For Infrastructure, Investment, and Deployment

Advanced air mobility (AAM) is moving from demonstration toward early deployment, supported by a growing national strategy that outlines how these systems may evolve across airspace, infrastructure, and operations. As this transition takes shape, a more practical question comes into focus: what does it mean to be ready? This paper introduces a Capability Maturity Model (CMM) as a structured way to think about that challenge. Rather than treating readiness as a fixed condition, it frames it as a progression - one that develops across multiple, interdependent domains over time.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Regional Modeling and Simulation for Vertiport Location Assessment

There is increasing interest in the Urban Air Mobility concept and the realization of electric Vertical Take-Off and Landing (e-VTOL) vehicles flying in the National Airspace System. NASA, FAA, and the industry are investigating various aspects of this new mode of transportation for cargo and humans. There are significant challenges in making this mode a reality, including feasibility, safety, infrastructure, traffic management, public acceptance, and scalability. From the infrastructure perspective, one of the aspects that needs to be addressed is the location of vertiports (named similar to heliports, for vertical take-off and landing vehicles). There is significant on-going research for selecting location of vertiports. However, the locations are largely based on demand models. Also, these efforts are focused in specific local regions, San Francisco/Bay Area, Chicago, Tampa, etc. This talk presents an approach to determine the location of vertiports in regional areas (across the United States), incorporating the desire to have certain attributes closer to or further from the location using a regional modeling tool. The feasibility of flying e-VTOL vehicles between various vertiport locations is also presented using a mobility operations simulation tool.

Air Mobility↗

Energetics and Escape of Interchain-Delocalized Ion Pairs in Nonpolar Media

The electron acceptor F4TCNQ p-dopes aggregates “nanowires” of poly(3-hexylthiophene) in nonpolar solvents but does not dope unaggregated chains. The standard free energy change for the charge transfer to form an ion pair is ΔG° et = -0.21 eV. The dissociation constant to produce free ions in toluene by DC conductivity is K° d = 1 × 10 -8 ± 50% (ΔG° d = 0.48 ± 0.05 eV). This remarkably large K°d, for ions in such a low polarity medium, may reflect interchain delocalization of the hole. The particular characteristics of this material system enables determination of both ΔG° et and ΔG° d , to find the overall free energy change from the two neutral species to completely separated ions in nonpolar media. It is endergonic by +0.27 ± 0.05 eV in contrast to -0.6 eV estimated from reported HOMO LUMO differences, illustrating the challenges that persist in determining such energetics. Steady state microwave conductivity experiments on doped aggregates confirm that holes in the aggregates cannot easily escape their dopant counterion, but at higher dopant concentrations, holes become mobile. These results provide insight into the mechanisms of charge separation involving intermolecularly delocalized charges in nonpolar media, an integral process in organic photovoltaic devices and doped molecular films.

36 MATERIALS SCIENCE↗

Generating multiple benefits from forests by producing value-added products: Lessons from the Pacific Northwestern US

This paper asks what conditions are needed to counteract a declining forest industry. The mobilization of supply chains for new value-added forest products and services can be supported by programs designed to simultaneously achieve multiple goals related to health, climate, and rural economic development. But several challenges are identified that underscore the need to stack benefits and incentives to achieve muti-sectoral goals. Based on a case study in Washington state, we find opportunities and constraints for sourcing forest products are determined by the local and regional conditions such as availability of working forests and their residues, socioeconomic conditions, workforce availability, transportation options, and perceptions about social license of the new industry. Key recommendations are the need for (1) a consistent demand and resilient supply chain for the new product; (2) a stable, supportive policy and assessment framework; (3) timely, transparent, and trusted monitoring and reporting of benefits and costs; (4) fostering engagement and buy-in from stakeholders; (5) a context-specific evaluation of opportunities and constraints; and (6) agreement on the goals of sustainable forestry. A diversity of products and markets builds a more resilient forest-based economy by mitigating impacts of disruptions in any individual market, adding value to biomass, increasing employment, and reducing forest risks to fire, insects, and disease.

Bioenergy↗

Dysprosium-doped cadmium oxide as a gateway material for mid-infrared plasmonics

The interest in plasmonic technologies surrounds many emergent optoelectronic applications, such as plasmon lasers, transistors, sensors and information storage. Although plasmonic materials for ultraviolet–visible and near-infrared wavelengths have been found, the mid-infrared range remains a challenge to address: few known systems can achieve subwavelength optical confinement with low loss in this range. With a combination of experiments and ab initio modelling, here we demonstrate an extreme peak of electron mobility in Dy-doped CdO that is achieved through accurate ‘defect equilibrium engineering’. In so doing, we create a tunable plasmon host that satisfies the criteria for mid-infrared spectrum plasmonics, and overcomes the losses seen in conventional plasmonic materials. In particular, extrinsic doping pins the CdO Fermi level above the conduction band minimum and it increases the formation energy of native oxygen vacancies, thus reducing their populations by several orders of magnitude. The substitutional lattice strain induced by Dy doping is sufficiently small, allowing mobility values around 500 cm 2 V –1 s –1 for carrier densities above 10 20 cm –3 . As a result, our work shows that CdO:Dy is a model system for intrinsic and extrinsic manipulation of defects affecting electrical, optical and thermal properties, that oxide conductors are ideal candidates for plasmonic devices and that the defect engineering approach for property optimization is generally applicable to other conducting metal oxides.

36 MATERIALS SCIENCE↗

Fast self-diffusion of ions in CH 3 NH 3 PbI 3 : the interstiticaly mechanism versus vacancy-assisted mechanism

The stability of organic-inorganic halide perovskites is a major challenge for their applications and has been extensively studied. Among the possible underlying reasons, ion self-diffusion has been inferred to play important roles. While theoretical studies congruously support that iodine is more mobile, experimental studies only observe the direct diffusion of the MA ion and possible diffusion of iodine. The discrepancy may result from the incomplete understanding of ion diffusion mechanisms. With the help of first-principles calculations, we studied ion diffusion in CH3NH3PbI3 (MAPbI3) through not only the vacancy-assisted mechanisms presumed in previous theoretical studies, but also the neglected interstiticaly mechanisms. We found that compared to the diffusion through the vacancy-assisted mechanism, MA ion diffusion through the interstiticaly mechanism has a much smaller barrier which could explain experimental observations. For iodine diffusion, both mechanisms can yield relatively small barriers. Depending on the growth conditions, defect densities of vacancies and interstitials can vary and so do the diffusion species as well as diffusion mechanisms. Our work thus supports that both MA and iodine ion diffusion could contribute to the performance instability of MAPbI3. While being congruous with experimental results, our work fills the research gap by providing a full understanding of ion diffusion in halide perovskites.

14 SOLAR ENERGY↗

Radioactive source localization in urban environments with sensor networks and the Internet of Things

The use of radiation detectors as an element in the so-called “Internet of Things” has recently become viable with the available of low-cost, mobile radiation sensors capable of streaming geo-referenced data. New methods for fusing the data from multiple sensors on such a network is presented. The traditional simple and ordinary Kriging methods present a challenge for such a network since the assumption of a constant mean is not valid in this application. In conclusion, a variety of Kalman filters are introduced in an attempt to solve the problem associated with this variable and unknown mean. Results are presented on a deployed sensor network.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Nuclear power technology requirements for NASA exploration missions

It is pointed out that future exploration of the moon and Mars will mandate developments in many areas of technology. In particular, major advances will be required in planet surface power systems. Critical nuclear technology challenges that can enable strategic self-sufficiency, acceptable operational costs, and cost-effective space transportation goals for NASA exploration missions have been identified. Critical technologies for surface power systems include stationary and mobile nuclear reactor and radioisotope heat sources coupled to static and dynamic power conversion devices. These technologies can provide dramatic reductions in mass, leading to operational and transportation cost savings. Critical technologies for space transportation systems include nuclear thermal rocket and nuclear electric propulsion options, which present compelling concepts for significantly reducing mass, cost, or travel time required for Earth-Mars transport.

Bloomfield, Harvey S.↗