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At least 739 records · Page 41

New class of tritium breeders for fusion applications: Metal-reinforced composite breeders

Commercial fusion reactors operating on a D-T fuel cycle will require a steady supply of tritium to maintain the burning plasma required for continuous power generation. Since tritium has a short half-life, there is negligible natural abundance which necessitates fusion reactors to produce their own source of tritium. Tritium is most easily produced by surrounding a fusion reactor core with lithium (Li), which reacts under the intense neutron flux leaving the reactor core to form tritium and helium. Due to the hazards and technical challenges associated with surrounding a fusion reactor core with many tons of molten Li, other Li-bearing tritium breeder materials have been pursued. Unfortunately, most of the liquid breeders historically examined are exceedingly corrosive to reactor structural materials while many solid breeders in the form of ceramics are forced to make tradeoffs between Li content and mechanical integrity. In this work, to break the historic limit between Li-density and mechanical integrity of traditional solid breeders, a new class of solid tritium breeders is developed: metal-reinforced composite (MERC) breeders. Specifically, the high Li-density of lithium oxide (Li 2 O) is exploited through the addition of a metal reinforcing phase, producing a composite breeder material exhibiting high splitting tensile strength and quasi-ductility with a Li-density greater than other leading solid breeder candidates, including lithium orthosilicate (Li 4 SiO 4 ) and lithium metatitanate (Li 2 TiO 3 ). Mechanical testing, microstructural characterization, and neutronic simulation results are presented and discussed in light of fusion reactor design considerations.

11 - NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Titanium Layer Influence on the Strength of a Hybrid Titanium Composite Laminate

An experimental study was undertaken to investigate the mechanical response of four hybrid titanium composite laminate (HTCL) systems, each prepared using a graphite fiber reinforced thermoplastic polyimide as the adhesive in a unidirectional prepreg. Two of the four HTCL systems were fabricated with the titanium Ti-15-3 alloy, while the other two systems were fabricated with the titanium Timetal Beta-21S alloy. Each HTCL system consisted of either three plies or four plies of the titanium alloy. Systems with only three plies of titanium had plies measuring 10 mils thick, whereas systems consisting of four plies of titanium had plies measuring 5 mils thick. The improvement in mechanical properties achieved by comparing the uniaxial tensile results of static strength at room temperature. Results included stress-strain curves, ultimate strength, strain-to-failure, initial modulus of the HTCL's, and the description of the observed modes of failure.

Veazie, David R.↗

Fiber/matrix debonding evaluation of SiCf/SiC composites using micropillar compression technique

Third-generation silicon carbide (SiC) composites reinforced by SiC fibers (Hi-Nicalon S [HNS] and Tyranno SA3 [SA3]) are attractive for use in next generation reactors owing to their high strength and chemical inertness at high temperatures, as well as enhanced radiation tolerance under neutron irradiation environments. To optimize composite performance, the interfacial mechanical properties of chemical vapor–infiltrated (CVI) SiC f /SiC composites are investigated in this effort by using a slant interface micropillar compression testing procedure. The micropillar test specimens, containing an inclined pyrolytic carbon (PyC) interphase, are prepared using a focused ion beam. The novel microcompression testing successfully quantifies the debond shear strength and internal friction coefficient of micropillar test samples by using the Mohr-Coulomb formulation. Furthermore, according to four types of SiCf/SiC composite microcompression test results, interfacial properties and debond mechanisms are significantly affected by the PyC layer thickness, the local bonding mechanism of the PyC interphase on the SiC fiber surface, and the surface roughness of fibers. Regardless of PyC thicknesses, SA3-reinforced CVI SiC f /SiC composites are found to have much higher debond shear strengths than HNS-reinforced SiC f /SiC CVI composites. By using this micropillar compression technique alongside analytical methods, we uncover new understandings of PyC interface properties. Additionally, the micropillar test results obtained are correlated with macroscopic mechanical properties of neutron-irradiated CVI SiCf/SiC composites.

42 ENGINEERING↗

3D Printing of High Viscosity Reinforced Silicone Elastomers

Recent advances in additive manufacturing, specifically direct ink writing (DIW) and ink-jetting, have enabled the production of elastomeric silicone parts with deterministic control over the structure, shape, and mechanical properties. These new technologies offer rapid prototyping advantages and find applications in various fields, including biomedical devices, prosthetics, metamaterials, and soft robotics. Stereolithography (SLA) is a complementary approach with the ability to print with finer features and potentially higher throughput. However, all high-performance silicone elastomers are composites of polysiloxane networks reinforced with particulate filler, and consequently, silicone resins tend to have high viscosities (gel- or paste-like), which complicates or completely inhibits the layer-by-layer recoating process central to most SLA technologies. Herein, the design and build of a digital light projection SLA printer suitable for handling high-viscosity resins is demonstrated. Further, a series of UV-curable silicone resins with thiol-ene crosslinking and reinforced by a combination of fumed silica and MQ resins are also described. The resulting silicone elastomers are shown to have tunable mechanical properties, with 100–350% elongation and ultimate tensile strength from 1 to 2.5 MPa. Three-dimensional printed features of 0.4 mm were achieved, and complexity is demonstrated by octet-truss lattices that display negative stiffness.

36 MATERIALS SCIENCE↗

Processing and Characterization of Basalt Fiber Reinforced Ceramic Composites for High Temperature Applications Using Polymer Precursors

The development of high temperature structural composite materials has been very limited due to the high cost of the materials and the processing needed. Polymer Derived Ceramics (PDCs) begin as a polymer matrix, which allows a shape to be formed prior to the cure, and is then pyrolized in order to obtain a ceramic with the associated thermal and mechanical properties. The two PDCs used in this development are polysiloxane and polycarbosilane. Basalt fibers are used for the reinforcement in the composite system. The use of basalt in structural and high temperature applications has been under development for over 50 years, yet there has been little published research on the incorporation of basalt fibers as a reinforcement in composites. Continuous basalt fiber reinforced PDCs have been fabricated and tested for the applicability of this composite system as a high temperature structural composite material.

High Temperature Composites↗

Preparation of Highly Crystalline Silk Nanofibrils and Their Use in the Improvement of the Mechanical Properties of Silk Films

Due to their commendable biocompatibility, regenerated silk fibroin (RSF) films have attracted considerable research interest. However, the poor mechanical properties of RSF films have limited their use in various biomedical applications. In this study, a novel, highly crystalline silk fibril was successfully extracted from silk by combining degumming with ultrasonication. Ultrasonication accelerated the development of silk nanofibrils measuring 130–200 nm on the surface of the over-degummed silk fibers, which was confirmed via scanning electron microscopy. Additionally, the crystallinity index of silk fibril was found to be significantly higher (~68%) than that of conventionally degummed silk (~54%), as confirmed by the Fourier-transform infrared (FTIR) spectroscopy results. Furthermore, the breaking strength and elongation of the RSF film were increased 1.6 fold and 3.4 fold, respectively, following the addition of 15% silk nanofibrils. Thus, the mechanical properties of the RSF film were remarkably improved by the addition of the silk nanofibrils, implying that it can be used as an excellent reinforcing material for RSF films.

36 MATERIALS SCIENCE↗

Melt State Reinforcement of Polyisoprene by Silica Nanoparticles Grafted with Polyisoprene

Here, we systematically vary the nanoparticle (NP) dispersion state in composites formed by mixing polyisoprene homopolymers with polyisoprene grafted silica particles, and demonstrate how creep measurements allow us to overcome the limitations of small amplitude oscillatory shear (SAOS) experiments. This allows us to access nearly 13 orders in time in the mechanical response of the resulting composites. We find that a specific NP morphology, a percolating particle network achieved at intermediate graft densities, significantly reinforces the system and has a lower NP percolation loading threshold relative to other morphologies. These important effects of morphology only become apparent when we combine creep measurements with SAOS re-emphasizing the role of synergistically combining methods to access the mechanical properties of polymer nanocomposites over broad frequency ranges.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Mechanical Properties of Triaxial Braided Carbon/Epoxy Composites

In an on-going effort to increase the safety and efficiency of turbine engines, the National Aeronautics and Space Administration is exploring lightweight alternatives to the metal containment structures that currently encase commercial jet engines. Epoxy reinforced with braided carbon fibers is a candidate structural material which may be suitable for an engine case. This paper reports flat-coupon mechanical-property experiments performed to compliment previously reported subcomponent impact testing and analytical simulation of containment structures. Triaxial-braid T700/5208 epoxy and triaxial-braid T700h436 toughened epoxy composites were evaluated. Also, two triaxial-braid architectures (0 degrees plus or minus 60 degrees, and 0 degrees plus or minus 45 degrees) with the M36 resin were evaluated through tension, compression, and shear testing. Tensile behavior was compared between standard straight-sided specimens (ASTM D3039) and bow-tie specimens. Both double-notch shear (ASTM D3846) and Iosepescu (ASTM D5379) tests were performed as well. The M36/O degrees plus or minus 45 degrees configuration yield the best response when measurements were made parallel to the axial tows. Conversely, the M36/0 degrees plus or minus 60 degrees configuration was best when measurements were made perpendicular to the axial tows. The results were used to identify critical properties and to augment the analysis of impact experiments.

Bowman, C. L.↗

Mechanical Properties of Triaxial Braided Carbon/Epoxy Composites

In an on-going effort to increase the safety and efficiency of turbine engines, the National Aeronautics and Space Administration is exploring lightweight alternatives to the metal containment structures that currently encase commercial jet engines. Epoxy reinforced with braided carbon fibers is a candidate structural material which may be suitable for an engine case. This paper reports flat-coupon mechanical-property experiments performed to compliment previously reported subcomponent impact testing and analytical simulation of containment structures. Triaxial-braid T700/5208 epoxy and triaxial-braid T700/M36 toughened epoxy composites were evaluated. Also, two triaxial-braid architectures (0 +/- 60 deg., 0 +/- 45 deg.) with the M36 resin were evaluated through tension, compression, and shear testing. Tensile behavior was compared between standard straight-sided specimens (ASTM D3039) and bowtie specimens. Both double-notch shear (ASTM D3846) and Iosepescu (ASTM D5379) tests were performed as well. The M36/0 +/- 45 deg. configuration yield the best response when measurements were made parallel to the axial tows. Conversely, the M36/0 +/- 60 deg. configuration was best when measurements were made perpendicular to the axial tows. The results were used to identify critical properties and to augment the analysis of impact experiments.

Bowman, C. L.↗

Microstructure and mechanical properties of a single crystal NiAl alloy with Zr or Hf rich G-phase precipitates

The possibility of producing NiAl reinforced with the G-phase (Ni16X6Si7), where X is Zr or Hf, has been investigated. The microstructure of these NiAl alloys have been characterized in the as-cast and annealed conditions. The G-phases are present as fine cuboidal precipitates (10 to 40 nm) and have lattice parameters almost four times that of NiAl. They are coherent with the matrix and fairly resistant to coarsening during annealing heat treatments. Segregation and nonuniform precipitate distribution observed in as-cast materials were eliminated by homogenization at temperatures near 1600 K. Slow cooling from these temperatures resulted in large plate shaped precipitates, denuded zones, and a loss of coherency in some of the large particles. Faster cooling produced a homogeneous fine distribution of cuboidal G-phase particles in the matrix. Preliminary mechanical properties for the Zr-doped alloy are presented and compared to binary single crystal NiAl. The presence of these precipitates appears to have an important strengthening effect at temperatures not less than 1000 K compared to binary NiAl single crystals.

Locci, I. E.↗

Sharp decline of dust events induces regional wetting over arid and semi-arid Northwest China in the NCAR Community atmosphere model

Abstract Multiple lines of observational evidence have indicated a significant wetting over the arid and semi-arid Northwest China (NWC) during recent decades, coinciding with a simultaneous sharp decline of dust events. Although recent studies have attributed NWC wetting to different anthropogenic and natural forcings, the mechanisms are not definitive and the regional wetting has been greatly underestimated in the Coupled Model Intercomparison Project historical simulations. Based on sensitivity experiments with different dust emission amounts using the NCAR Community Atmospheric Model version 5 (CAM5), here we find that decreasing dusts exert significant impacts on mixed-phase clouds through reducing the concentration of ice nucleating particles, increase the NWC precipitation and thus induce regional wetting through enhancing convection precipitation. A possible convection invigoration mechanism whereby the atmospheric vertical temperature gradient and convective instability are strengthened by reduced dusts, leading to convection invigoration and increased precipitation. These results are reinforced by simulations over the dust region in North Africa where mixed-phase and ice clouds are rare and reduced dusts do not increase precipitation. This study highlights the possible mechanism of dust-ice cloud interactions in recent NWC wetting and future regional climate change.

54 ENVIRONMENTAL SCIENCES↗

Buyers Collusion in Incentivized Forwarding Networks: A Multi-Agent Reinforcement Learning Study

We present the issue of monetarily incentivized forwarding in a multi-hop mesh network architecture from an economic perspective. It is anticipated that credit-incentivized forwarding and relaying will be a simple method of exchanging transmission power and spectrum for connectivity. However, gateways and forwarding nodes, like any other free market, may create an oligopolistic market for the users they serve. In this study, a coalition scheme between buyers aims to address price control by gateways or nodes closer to gateways. In a Stackelberg competition game, buyer agents (users) and sellers (gateways) make decisions using reinforcement learning (RL), with decentralized Deep Q-Networks to buy and sell forwarding resources. We allow communication links between the buyers with a limited messaging space, without defining a collusion mechanism. The idea is to demonstrate that through messaging, and RL tacit collusion can emerge between agents in a decentralized setup. The multi-agent reinforcement learning (MARL) system is presented and analyzed from a machine-learning perspective. Moreover, MARL dynamics are discussed via mean field analysis to better understand divergence causes and make implementation recommendations for such systems. Finally, the simulation results show the results of coordination among the users.

42 ENGINEERING↗

Learning Sequential Distribution System Restoration via Graph-Reinforcement Learning

We report a distribution service restoration algorithm as a fundamental resilient paradigm for system operators provides an optimally coordinated, resilient solution to enhance the restoration performance. The restoration problem is formulated to coordinate distribution generators and controllable switches optimally. A model-based control scheme is usually designed to solve this problem, relying on a precise model and resulting in low scalability. To tackle these limitations, this work proposes a graph-reinforcement learning framework for the restoration problem. We link the power system topology with a graph convolutional network, which captures the complex mechanism of network restoration in power networks and understands the mutual interactions among controllable devices. Latent features over graphical power networks produced by graph convolutional layers are exploited to learn the control policy for network restoration using deep reinforcement learning. The solution scalability is guaranteed by modeling distributed generators as agents in a multi-agent environment and a proper pre-training paradigm. Comparative studies on IEEE 123-node and 8500-node test systems demonstrate the performance of the proposed solution.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Biogenic Straw Aerogel Thermal Insulation Materials

Biogenic wheat straw is a carbon-storing building insulation material. However, the enzymatic hydrolysis ratio of its cellulose is relatively low due to the presence of hemicellulose and lignin hindering its thermal insulation performance. In this work, we report aerogel and straw composites with thermal conductivity of 35 mW m –1 K –1 , while high cellulose fiber conversion in straw is obtained by using a hybrid mechanical and chemical process. Furthermore, we show that the in-situ cellulose-reinforced silica aerogel nanocomposites exhibit an optimal thermal conductivity of 32 mW m –1 K –1 by using 50 wt% of aerogel. Moreover, the hydrophobic aerogel-cellulose composites show a low density, high porosity (90 %), high compression modulus (1.9 MPa), superhydrophobicity, and superior reusability. This work provides a cost-effective and facile method to manufacture biogenic composites from agriculture waste materials, promising for carbon-sequestration building insulation applications.

36 MATERIALS SCIENCE↗

Influence of Fiber Orientation on Deformation of Additive Manufactured Composites

Anisotropy caused by flow-induced fiber orientation of discontinuous fibers within the extrudate in the Extrusion Deposition Additive Manufacturing (EDAM) process gives rise to anisotropic shrinkage in printed parts and thereby, final part deformations. Three fiber orientation states, described by the second-order orientation tensor, were investigated to determine their influence upon final geometry. Two material systems were investigated including a short glass fiber-reinforced polyamide and a short carbon fiber-reinforced polyamide. A curvilinear geometry was modeled and printed virtually in the thermo-mechanical simulation, ADDITIVE3D©. The scale of the printed geometry was in the range of 300–400 mm and contained three semicircular geometry regions connected to linear regions, thereby inducing significant magnification of the spring-in deformation. The predicted deformation of the printed geometry for the three fiber orientation states and two material systems were compared. The deformation predicted for glass fiber-filled polyamide and carbon fiber-filled polyamide of the same fiber orientation states showed comparable deformations. In conclusion, the largest residual deformation was shown to correspond to the orientation tensor with the greatest degree of anisotropy.

36 MATERIALS SCIENCE↗

In Vitro and in Vivo Analyses of the Effects of Source, Length, and Charge on the Cytotoxicity and Immunocompatibility of Cellulose Nanocrystals

Cellulose nanocrystals (CNCs) are an emergent, sustainable nanomaterial which are bio-sourced, abundant, and biodegradable. On account of their high aspect ratio, low density, and mechanical rigidity, they have been employed in numerous areas of biomedical research including as reinforcing materials for bone or tissue scaffolds or as carriers in drug delivery systems. Given the promise of these materials for such use, characterizing and understanding their interactions with biological systems is an important step to prevent toxicity or inflammation. Reported herein are studies aimed at exploring the in-vitro and in-vivo effects that source, length, and charge of the CNCs have on cytotoxicity and immune response. In this study, CNCs from four different biosources (cotton, wood, Miscanthus x. Giganteus, and sea tunicate) were prepared and functionalized with positive or negative charges to obtain a small library of CNCs with a range of dimensions and surface charge. A method to remove endotoxic or other impurities on the CNC surface leftover from the isolation process was developed, and the biocompatibility of the CNCs was subsequently assayed in-vitro and in-vivo. After subcutaneous injection, it was found that unfunctionalized (uncharged) CNCs form aggregates at the site of injection, inducing splenomegaly and neutrophil infiltration, while charged CNCs having surface carboxylates, sulfate half-esters, or primary amines were biologically inert. No effect of particle source or length was observed in the in-vitro and in-vivo studies conducted. The lack of in-vitro or in-vivo immune response toward charged CNCs in these experiments supports their use in future biological studies.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Layered patterns of active scalar fields in a two-dimensional magnetohydrodynamic system

Here, we observe the formation of staircase patterns in the magnetic potential (𝐴) in a weakly magnetized two-dimensional magnetohydrodynamic system driven by a forced, fluctuating vortex array. Layering occurs due to inhomogeneous mixing of 𝐴 by vortex cells. Magnetic Reynolds number (𝑅 𝑚 )–dependent quenching of the turbulent diffusion of 𝐴 by weak magnetic fields increases the disparity between the (short) cell circulation time and the (long) time for intercell transport of magnetic potential. Thus, magnetic fields strengthen transport barriers between cells and reinforce the staircase, relative to its passive scalar counterpart. The analysis reveals a feedback mechanism, which promotes staircase formation. Magnetic staircases persist in both the flux expulsion (𝑅 𝑚 ⁢𝑣$^2_𝐴$/𝑈$^2_0$<1) and vortex disruption (𝑅 𝑚 ⁢𝑣$^2_𝐴$/𝑈$^2_0$≥1) limits. In the latter case, residual vortex cells homogenize 𝐴. Global layering morphology is shown to be well characterized by staircase curvature. Stochastic forcing of magnetic potential can support magnetic staircases against resistive decay.

magnetohydrodynamics↗

Decentralized Voltage Control of Large-Scale Distribution System with PVs Based on MADRL

This paper proposes a model-free decentralized control framework for the voltage regulation of large-scale distribution systems through the coordinated control of PV inverters. This is achieved by developing a novel interaction mechanism between the surrogate model and the centralized training and decentralized execution multiagent deep reinforcement learning framework. Specifically, the sparse Gaussian processes regression method is first utilized to develop the surrogate model of the original distribution system for reward calculation during the training stage, where each agent represents a sub-region in the centralized fashion for coordination strategy learning. After that, the learned control rules are used to inform controllers within each sub-region for real-time decisions with only local measurements. Comparative tests among various methods on the EPRI Ckt5 test system demonstrate the effectiveness of the proposed method.

distribution system↗