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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 739 records · Page 41

Chiral Recognition: A Spin-Driven Process in Chiral Oligothiophene. A Chiral-Induced Spin Selectivity (CISS) Effect Manifestation

In this paper it is experimentally demonstrated that the electron-spin/molecular-handedness interaction plays a fundamental role in the chiral recognition process. This conclusion is inferred comparing current versus potential (I-V) curves recorded using chiral electrode surfaces, which are obtained via chemisorption of an enantiopure thiophene derivative: 3,3'-bibenzothiophene core functionalized with 2,2'-bithiophene wings (BT 2 T 4 ). The chiral recognition capability of these chiral-electrodes is probed via cyclic voltammetry measurements, where, Ag nanoparticles (AgNPs) capped with enantiopure (BT 2 T 4 ) (BT 2 T 4 )@AgNP) are used as the chiral redox probe. Then, the interface handedness is explored by recording spin-polarized (I-V) curves in spin-dependent electrochemistry (SDE) and magnetic-conductive atomic force microscopy (mc-AFM) experiments. The quality of the interfaces is thoroughly cross-checked using X-ray photoemission spectroscopy, Raman, electrodesorption measurements, which further substantiate the metal(electrode)-sulfur(thiophene) central role in the chemisorption process. Spin-polarization values of about 15% and 30% are obtained in the case of SDE and mc-AFM experiments, respectively.

36 MATERIALS SCIENCE↗

CORC $^{\circledR}$ cable terminations with integrated Hall arrays for quench detection

ReBCO superconducting cables have the potential to enable compact thermonuclear fusion reactors that operate at magnetic fields exceeding 20 T and allow operation at temperatures far exceeding the boiling point of liquid helium, potentially allowing for demountable magnets. Normal zone detection remains a challenge, and while novel quench detection techniques are an active area of research, few are non-invasive, provide real-time quench detection, and have been demonstrated with current ramp rates relevant for fusion reactors. To address this problem, a CORC$^{\circledR}$ cable termination is developed with integrated Hall sensors to monitor current redistribution as a proxy for quench detection. The methodology exploits the current sharing and layered topology in CORC$^{\circledR}$ cables, and allows quench detection using a localized sensor instead of co-wound voltage wires or optical fibers. Furthermore, experiments are presented where current redistribution is measured from induced quenches, and in a 0.2 meter CORC$^{\circledR}$ sample it is found that the Hall sensors detect normal zone transitions with a similar magnitude and temporal resolution as voltage measurements. To emulate the conditions of dynamic poloidal and central solenoidal fields, experiments are repeated with ramp rates up to 10 kA s -1 that demonstrate the potential to detect normal zone development over a range of experimental parameters.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Advances in constraining intrinsic alignment models with hydrodynamic simulations

We use galaxies from the illustristng, massiveblack-ii, and illustris-1 hydrodynamic simulations to investigate the behaviour of large scale galaxy intrinsic alignments. Our analysis spans four redshift slices over the approximate range of contemporary lensing surveys z = 0–1. We construct comparable weighted samples from the three simulations, which we then analyse using an alignment model that includes both linear and quadratic alignment contributions. Our data vector includes galaxy–galaxy, galaxy–shape, and shape–shape projected correlations, with the joint covariance matrix estimated analytically. In all of the simulations, we report non-zero IAs at the level of several σ. For a fixed lower mass threshold, we find a relatively strong redshift dependence in all three simulations, with the linear IA amplitude increasing by a factor of ~2 between redshifts z = 0 and z = 1. We report no significant evidence for non-zero values of the tidal torquing amplitude, A 2 , in TNG, above statistical uncertainties, although MBII favours a moderately negative A 2 ~ –2. Examining the properties of the TATT model as a function of colour, luminosity and galaxy type (satellite or central), our findings are consistent with the most recent measurements on real data. We also outline a novel method for constraining the TATT model parameters directly from the pixelized tidal field, alongside a proof-of-concept exercise using TNG. This technique is shown to be promising, although comparison with previous results obtained via other methods is non-trivial.

79 ASTRONOMY AND ASTROPHYSICS↗

The MaNGA firefly Value-Added-Catalogue: resolved stellar populations of 10,010 nearby galaxies

We present the Mapping Nearby Galaxies at Apache Point Observatory survey (MaNGA) FIREFLY Value Added Catalogue (VAC) – a catalogue of ~3.7 million spatially resolved stellar population properties across 10 010 nearby galaxies from the final data release of the MaNGA survey. The full spectral fitting code FIREFLY is employed to derive parameters such as stellar ages, metallicities, stellar and remnant masses, star formation histories, star formation rates, and dust attenuation. In addition to Voronoi-binned measurements, our VAC also provides global properties, such as central values and radial gradients. Two variants of the VAC are available: presenting the results from fits using the M11-MILES and the novel MaStar stellar population models. MaStar allows to constrain the fit over the whole MaNGA wavelength range, extends the age-metallicity parameter space, and uses empirical spectra from the same instrument as MaNGA. The fits employing MaStar models find, on average, slightly younger ages, higher mass-weighted metallicities, and smaller colour excesses. These differences are reduced when matching the wavelength range and converging template grids. We further report that FIREFLY stellar masses are systematically lower by ~0.3 dex than masses from the MaNGA PCA and Pipe3D VACs, but match masses from the NSA best with only ~0.1-dex difference. Finally, we show that FIREFLY stellar ages correlate with spectral index age indicators H δ A and D n (4000), though with a clear additional metallicity dependence.

79 ASTRONOMY AND ASTROPHYSICS↗

Gravitational Test beyond the First Post-Newtonian Order with the Shadow of the M87 Black Hole

In this study, the 2017 Event Horizon Telescope (EHT) observations of the central source in M87 have led to the first measurement of the size of a black-hole shadow. This observation offers a new and clean gravitational test of the black-hole metric in the strong-field regime. We show analytically that spacetimes that deviate from the Kerr metric but satisfy weak-field tests can lead to large deviations in the predicted black-hole shadows that are inconsistent with even the current EHT measurements. We use numerical calculations of regular, parametric, non-Kerr metrics to identify the common characteristic among these different parametrizations that control the predicted shadow size. We show that the shadow-size measurements place significant constraints on deviation parameters that control the second post-Newtonian and higher orders of each metric and are, therefore, inaccessible to weak-field tests. The new constraints are complementary to those imposed by observations of gravitational waves from stellar-mass sources.

79 ASTRONOMY AND ASTROPHYSICS↗

Dual Context: Leveraging Structured Application Context for Code Generation and Runtime Feature Activation via Chat Interfaces

Integrating artificial intelligence (AI) capabilities into software applications typically involves two common paths. For developers, AI assists in generating and documenting source code and other related software engineering efforts. For users, AI assists them through question-and-answer exchanges via chatbots. Both approaches have their value, but neither effectively leverages the modularity of component-based architectures that modern web application frameworks offer. We implement a proof of concept within a centralized suite of applications used for the Atmospheric Radiation Measurement (ARM) Data Center Operational Tools, where we introduce a third integration path through the ARM Context Engine (ACE). ACE is a context driven system that uses structured contextual specifications to enable Large Language Models (LLMs) to render interactive and feature-rich user interface (UI) components directly within chat responses, alongside or in place of conventional text outputs. These specifications serve two important purposes across what we call code context and UI context. Code context provides AI-assisted development tools with structured application knowledge beyond raw code, including component relationships, architectural patterns and schematic information, enabling the generation of consistent, well-structured code. UI context defines the rules for enabling and rendering component features at runtime based on the user's natural language input, allowing end users to activate capabilities such as data export, filtering, and pagination within chat responses, without requiring code changes or redeployment. We demonstrate, through a comparative evaluation against general-purpose AI chatbots, that context-driven component rendering provides interactive capabilities that text-based responses cannot replicate, including deterministic component behavior, application-consistent design language, and on-demand feature activation. A development effort comparison further shows that features that traditionally require multi-step development cycles can be activated with a single naturallanguage request. In this ongoing work, we present ACE as an emerging approach to AI integration that positions modular, well-documented software architecture as the foundation for AI-ready applications. ACE treats context as a shared resource across both development and user-facing AI, bringing cohesion to conventionally disconnected efforts, bridging developer tooling and end-user capabilities within a single framework.

Tadimeti, Vijay [ORNL]↗

Local adaptation of switchgrass drives trait relations to yield and differential responses to climate and soil environments

Abstract Switchgrass, a potential biofuel crop, is a genetically diverse species with phenotypic plasticity enabling it to grow in a range of environments. Two primary divergent ecotypes, uplands and lowlands, exhibit trait combinations representative of acquisitive and conservative growth allocation strategies, respectively. Whether these ecotypes respond differently to various types of environmental drivers remains unclear but is crucial to understanding how switchgrass varieties will respond to climate change. We grew two upland, two lowland, and two intermediate/hybrid cultivars of switchgrass at three sites along a latitudinal gradient in the central United States. Over a 4‐year period, we measured plant functional traits and biomass yields and evaluated genotype‐by‐environment (G × E) interaction effects by analyzing switchgrass responses to soil and climate variables. We found substantial evidence of G × E interactions on biomass yield, primarily due to deviations in the response of the southern lowland cultivar Alamo, which produced more biomass in hotter and drier environments relative to other cultivars. While lowland cultivars had the highest potential for yield, their yields were more variable year‐to‐year compared to other cultivars, suggesting greater sensitivity to environmental perturbations. Models comparing soil and climate principal components as explanatory variables revealed soil properties, especially nutrients, to be most effective at predicting switchgrass biomass yield. Also, positive correlations between biomass yield and conservative plant traits, such as high stem mass and tiller height, became stronger at lower latitudes where the climate is hotter and drier, regardless of ecotype. Lowland cultivars, however, showed a greater predisposition to exhibit these conservative traits. These results suggest switchgrass trait allocation trade‐offs that prioritize aboveground biomass production are more tightly associated in hot, dry environments and that lowland cultivars may exhibit a more specialized strategy relative to other cultivars. Altogether, this research provides essential knowledge for improving the viability of switchgrass as a biofuel crop.

09 BIOMASS FUELS↗

Data for Stetten et al. (2025), "Biogeochemical controls on iron speciation and cycling across upland to shoreline gradients in freshwater and estuarine coastal soils (Lake Erie and Chesapeake Bay, United States)"

Coastal environments are dynamic interfaces that mediate carbon and nutrient exchanges between terrestrial landscapes and open waters, but it is unclear how biogeochemical reactions, in particular iron (Fe) redox transformations, affect the understanding and prediction of coastal ecosystem functions. This dataset includes measurements from two freshwater sites in the Western and Central basins of Lake Erie (Ohio, United States) and two estuarine sites in the Chesapeake Bay (Maryland, United States); the analytical results were reported by Stetten et al. (2025) in Science of the Total Environment. It was produced as part of the COMPASS-FME project, which seeks to advance a scalable, predictive understanding of the fundamental biogeochemical processes, ecological structure, and ecosystem dynamics that distinguish coastal terrestrial-aquatic interfaces from the purely terrestrial or aquatic systems to which they are coupled. The sites were sampled in November 2022 (CRC), December 2022 (MSM), February 2023 (GCW), and March 2023 (OWC); site codes follow those used by Pennington et al. (2025).The dataset consists of the following soil data:- Solid data (Fe concentration, etc.)- Porewater data (sulfate, sulfide, etc.)- Linear combination fitting results of X-ray absorption near edge structure (XANES) spectra; i.e., quantitative results of the oxidation state of Fe, indicated as a proportion of pure Fe(III) and Fe(II) model compounds- Linear combination fitting results of EXAFS (extended X-ray absorption fine structure) spectra, indicated as proportion of of Fe-model compounds (illite, smectite, etc.)Each data type has a single file in comma-separated value (CSV) format. No special software is required to read it.

54 ENVIRONMENTAL SCIENCES↗

Impact of Shifts in Vegetation Phenology on the Carbon Balance of a Semiarid Sagebrush Ecosystem

Dryland ecosystems are critical in regulating the interannual variability of the global terrestrial carbon cycle. The responses of such ecosystems to weather and environmental conditions remain important factors that limit the accurate projections of carbon balance under future climate change. Here, we investigated how shifts in vegetation phenology resulting from changes in weather and environmental conditions influenced ecosystem carbon cycling in one semiarid ecosystem in the Hanford area of central Washington, United States. We examined two years of measurements of the phenology camera, eddy covariance, and soil chamber from an upland semiarid sagebrush ecosystem. Both years had contrasting diel and seasonal patterns of CO 2 fluxes, primarily driven by differences in vegetation phenology. The net ecosystem exchange of CO 2 (NEE) and evapotranspiration (ET) in 2019 were enlarged by shifted vegetation phenology, as a cold and snow-covered winter and warm and dry winter in 2020 resulted in constrained magnitudes of NEE and ET during the summer months. The annual gross primary productivity (GPP) was much higher in 2019 than in 2020 (-211 vs. -112 gC m -2 ), whereas ecosystem respiration was comparable in these two years (164 vs. 144 gC m -2 ). Thus, the annual NEE in 2019 was negative (-47 gC m -2 ) with the sagebrush ecosystem functioning as a carbon sink, while the positive annual NEE in 2020 indicated that the sagebrush ecosystem functioned as a carbon source. Our results demonstrate that winter snowpack can be a critical driver of annual carbon uptake in semiarid sagebrush ecosystems.

59 BASIC BIOLOGICAL SCIENCES↗

Photometric Objects around Cosmic Webs (PAC) Delineated in a Spectroscopic Survey. I. Methods

We provide a method for estimating the projected density distribution ${\bar{n}}_{2}{w}_{p}({r}_{p})$ of photometric objects around spectroscopic objects in a spectroscopic survey. This quantity describes the distribution of photometric sources with certain physical properties (e.g., luminosity, mass, and color) around cosmic webs (PAC) traced by the spectroscopic objects. The method can make full use of current and future deep and wide photometric surveys to explore the formation of galaxies up to medium redshift (z s < 2) 3 with the aid of cosmological spectroscopic surveys that sample only a fairly limited species of objects (e.g., emission line galaxies). As an example, we apply the PAC method to the CMASS spectroscopic and HSC-SSP PDR2 photometric samples to explore the distribution of galaxies for a wide range of stellar masses from 10 9.0 to 10 12.0 M ⊙ around massive galaxies at z s ≈ 0.6. Using the abundance-matching method, we model ${\bar{n}}_{2}{w}_{p}({r}_{p})$ in N-body simulation using Markov chain Monte Carlo sampling, and we accurately measure the stellar–halo mass relation and stellar mass function for the whole mass range. We can also measure the conditional stellar mass function of satellites for central galaxies of different mass. The PAC method has many potential applications for studying the evolution of galaxies.

79 ASTRONOMY AND ASTROPHYSICS↗

Moderate spectral resolution solar irradiance measurements, aerosol optical depth, and solar transmission, from 360 to 1070 nm, using the refurbished rotating shadow band spectroradiometer (RSS)

Abstract. This paper reports on a third-generation rotating shadow band spectroradiometer (RSS) used to measure global and diffuse horizontal plus direct normal irradiances and transmissions at 1002 wavelengths between 360 and 1070 nm. The prism-dispersed spectral data are from the Atmospheric Radiation Measurement (ARM) Southern Great Plains site in north-central Oklahoma (36.605∘ N, 97.486∘ W) and cover dates between August 2009 and February 2014. The refurbished RSS isolates the detector in a vacuum chamber with pressures near 10−7 torr. This prevents the deposition of outgassed vapors from the interior of the spectrometer shell on the cooled detector that affected the operation of the first commercial RSS. Methods for (1) ensuring the correct wavelength registration of the data and (2) deriving extraterrestrial responses over the entire spectrum, including throughout strong water vapor and oxygen bands, are described. The resulting data produced are archived as ARM data records and include cloud-screened aerosol optical depths, spectral irradiances and direct normal solar transmission, as well as normalized diffuse and global irradiances.

54 ENVIRONMENTAL SCIENCES↗

Bone mineral changes - The second manned Skylab mission

The mineral content of the central os calcis, and distal radius and ulna was measured by the monoenergetic photon absorptiometric technique pre- and postflight on the SL-3 crewmen. No significant changes were observed in the radius and ulna. Only the SPT showed a loss in calcaneal mineral which slowly returned to preflight levels by the 87th postflight day.

Vogel, J. M.↗

Occultation studies of planets and satellites: The occultation of epsilon Geminorum by Mars

The occultation of epsilon Geminorum by Mars on 1976 April 8 was observed at three wavelengths and 4 ms time resolution with the 91 cm telescope. Temperature, pressure, and number density profiles of the Martian atmosphere were obtained for both the immersion and emersion events. Within the altitude range of 50 to 80 km above the mean surface, the mean temperature is 145 K, and the profiles exhibit wavelike structures with a peak to peak amplitude of 35 K and a vertical scale of about 20 km. The ratio of the refractivity of the atmosphere at 4500 A and 7500 A, determined from the time shift of the light curves for these wavelengths, is consistent with the atmospheric composition measured by Viking 1, 15 weeks later. From the central flash - a bright feature in the light curve midway between immersion and emersion - an optical depth is found at 4500 A of 3.3 plus or minus 1.7 per km atm (about 0.23 per equivalent Martian air mass) for the atmosphere about 25 km above the mean surface, near the south polar region. This large value and its weak wavelength dependence rule out Rayleigh scattering as the principal cause of the observed extinction.

Elliot, J. L.↗

Lunar mare ridge orientation - Implications for lunar tectonic models

Four circular mare basins were selected for ridge orientation analysis: Crisium, Imbrium, Serenitatis and Tranquillitatis. In each basin a central area was identified in which ridges were neither concentric with basin edges nor seemed to be extensions of significant highland structural trends. Ridge orientations in these central areas and in the remaining marginal areas were measured separately and rose diagrams plotted for each. Rose diagrams of ridge orientations in the four circular mare basins show a narrow dispersion with a statistical average nearly north. Trends of basin margin ridges have a high deviation and are polymodal with maxima in the northwest, north and northeast directions. Mare ridges which display a preferred northern trend result from an east-west compressive stress field.

Fagin, S. W.↗

Far-infrared observations of galactic nuclei

Measurements of far-infrared continuum emission from the central regions of 30 late-type galaxies, 24 of which were previously unreported, are given. Photometry covering wavelengths from 40 to 160 microns has been obtained, yielding information on luminosities, temperatures, and dust masses for most. Good correlations of the far-infrared luminosity with blue colors, reddening, and molecular line radiation are found, supporting the identification of the sources with the molecular cloud component in these galaxies, and strengthening the identification of the energy sources as the young massive stars formed from those clouds. Comparisons with 10-micron data indicate that such data are useful for statistical studies, but have too much scatter to use directly in the analysis of individual sources. Strong correlation with nonthermal radio continuum emission and radio-to-optical flux ratios suggest that massive star formation underlies a wide range of galactic activity.

Rickard, L. J.↗

Microwave remote sensing of sea ice

The long term objectives are: (1) to understand the physics of the multispectral microwave radiative characteristics of sea ice as it goes through different phases; (2) to improve characterization of sea ice cover using satellite microwave sensors; and (3) to study ice/ocean physical and biological processes associated with polynya formations and variability of the marginal sea ice region. Two field experiments were conducted to pursue these objectives. One involved measurements of radiative and physical characteristics of sea ice from a ship during a 3-month long cruise through the Weddell Sea ice pack during the Austral winter of 1986. The other involved similar measurements from two aircrafts and a submarine over the Central Arctic and Greenland Sea region. Preliminary results have already led to an enhanced understanding of the microwave signatures of pancake ice, nilas, first year ice, multiyear ice and effects of snow cover. Coastal and deep ocean polynyas and their role in bottom water formation and ocean circulation were studied using a time series of ice images from SMMR. An unsupervised cluster analysis of Arctic sea ice using SMMR and THIR emissivity and brightness temperature data was implemented. The analysis indicates the existence of several unique and persistent clusters in the Central Arctic region during winter and that the sum of the area of these clusters excluding those of first year ice is about 20 percent less than minimum ice cover area inferred from a previous summer data. This result is consistent with saline surface for some multiyear ice floes as observed during MIZEZ and suggests that a significant fraction of multiyear ice floes in the Arctic have first year ice signatures.

Comiso, J. C.↗

Ultraviolet extinction differences within NGC 6530

Ultraviolet extinction curves are presented for 14 stars in the very young cluster NGC 6530. The variation of the short-wavelength extinction is consistent with that expected based on random errors alone, although the weakest extinction is found only toward the cluster center. Variations significantly larger than the measurement uncertainty are found in the area, width, and central peak position of the 2200 A extinction bump. These parameters are largest in the cluster center and decrease systematically outwards. Physical processes capable of modifying the grains in the H II region containing the cluster are discussed.

Boggs, Don↗

Small-scale experiments in STOVL ground effects

A series of tests was completed in which suckdown and fountain forces and pressures were measured on circular plates and twin-tandem-jet generic STOVL (short takeoff and vertical landing) configurations. The tests were conducted using a small-scale hover rig, for jet pressure ratios up to 6 and jet temperatures up to 700 F. The measured suckdown force on a circular plate with a central jet was greater than that found with a commonly used empirical prediction method. The present data showed better agreement with other sets of data. The tests of the generic STOVL configurations were conducted to provide force and pressure data with a parametric variation of parameters so that an empirical prediction method could be developed. The effects of jet pressure ratio and temperature were found to be small. Lift improvement devices were shown to substantially reduce the net suckdown forces.

Corsiglia, Victor R.↗