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At least 739 records · Page 41

On the physical conditions in the 'high-velocity' cloud near Zeta Ori

The problem of the 'high-velocity' clouds is rediscussed. Recent OAO-C Copernicus observations of lines of four atoms and ions have been used to estimate the density and temperature in both the 'high-velocity' and 'normal' interstellar clouds in the line-of-sight to Zeta Ori. The temperature and densities in the normal cloud are similar to previous results for interstellar clouds, yielding temperatures of the order of 100 K and compositions underabundant relative to the sun by factors of 3 or more. The high-velocity cloud, however, is warmer (at least 1000 K) and appears to have a normal solar abundance.

Drake, J. F.↗

External bulb variable volume maser

A maser functioning as a frequency standard stable to one part in 10 to the 14th power includes a variable volume, constant surface area storage bulb having a fixed volume portion located in a resonant cavity from which the frequency standard is derived. A variable volume portion of the bulb, exterior to the resonant cavity, has a maximum volume on the same order of magnitude as the fixed volume bulb portion. The cavity has a length to radius ratio of at least 3:1 so that the operation is attained without the need for a feedback loop. A baffle plate, between the fixed and variable volume bulb portions, includes apertures for enabling hydrogen atoms to pass between the two bulb portions and is an electromagnetic shield that prevents coupling of the electromagnetic field of the cavity into the variable volume bulb portion.

Reinhardt, V. S.↗

Martin Marietta atomic oxygen Low Earth Orbit (LEO) simulation

An atomic oxygen beam apparatus that produces flux levels and atomic kinetic energy similar to that encountered by spacecraft in low Earth orbit (LEO) is described. The beam apparatus consists of an electric discharge ion source, mass filter, decelerator, and neutralizer. Specific design goals include a 1.3 cm beam diameter, a 5 eV beam energy, and a flux density on the order of 10(15) cm(-2) s(-1). The total fluence will be on the order of 10(19) cm(-2) for an 8 hour test. The neutral oxygen beam will expose various materials contained within a large target chamber. Within the chamber will be a rather complex suite of instrumentation that will allow real-time studies of material mass loss and reactant species spatial distribution. In addition, a UV solar simulator will aid in the understanding of various synergistic effects.

Sjolander, Gary W.↗

Unified analysis of multipole and finite-mass corrections in long-range Coulombic interactions

Simple expressions are derived for all multipole nonadiabatic and finite-nuclear-mass corrections to the long-range effective potential due to two-Coulomb-photon exchange at threshold energy, and also for first-order energy corrections for the scattering between a spinles point charged particle and a spinless Coulombic complex and between two spinless Coulombic complexes. All these corrections are treated on equal footing, and the results are expressed, respectively, in terms of single-center and London-analog two-center atomic-multipole spectral sums.

Au, C. K.↗

Structural and electronic changes in the growth of mercury overlayers on Cu(001) - A helium beam scattering, LEED and ARPES study

We used ABS, LEED and angle-resolved photo-electron spectroscopy (ARPES) to study bilayer films of Hg on Cu(001). In the surface temperature range of 180 to 330 K, the first Hg layer forms two ordered phases, a c(2x2) (with coverage-0.5 of Cu(001)) and a high density (partially commensurate) c(4x4) (coverage-0.62). ARPES data show that there is little or no dispersion of the 5d band of Hg. ABS data show that this layer is not flat, with in-registry Hg atoms lying about 0.15 below the not-in-registry Hg atoms. From ABS we find that the second layer forms a completely registered c(4x4) phase. From ARPES we obtain that the second layer has an electronic structure, particularly the 5d levels, characteristic of bulk mercury. Preliminary results of calculations of the structure of the bilayer are given.

Vidali, G.↗

Investigation of the Effect of Etch Pits on the Material Properties of Carbon Fiber Structures

It is well known that etch pits are formed on carbon surfaces during their consumption in reactive gas environments such as during ablation of carbon-based thermal protection system (TPS) materials. These pits start out from atomic defects on the carbon surface, grow in size and then ultimately lead to the complete removal of the solid carbon material. However, the effect of such etch pits on the material properties of carbon ablators such as FiberForm are poorly understood, as the maximum size of pits are on the order of microns in size, which makes them hard to observe experimentally. Hence, we have developed a module within the Porous Microstructure Analysis code PuMA that can generate etch pits on an arbitrary material surface, with a prescribed distribution of pit size and density. We use this newly developed module to calculate material properties of FiberForm, which is the base material for one of the most commonly used TPS materials - Phenolic Impregnated Carbon Ablator (PICA). The detailed microstructure of FiberForm in PuMA will either be generated synthetically or obtained from X-ray microtomography. Our simulations show that material properties such as the thermal conductivity and tortuosity decrease with increasing degree of pitting. This will be helpful to more accurately predict the degradation of carbon-based TPS during ablation, and furthermore may allow us to identify previously unknown TPS failure modes due to pitting.

PuMA↗

Optical Time Transfer for Bistatic SAR Spacecraft

A spacecraft-to-spacecraft optical time-transfer simulation has been developed as a tool for informing NASA’s Surface Deformation and Change (SDC) mission architecture. The SDC mission will combine radar images from multiple spacecraft to improve understanding of the Earth’s sea-level and landscape changes. Spacecraft must be precisely synchronized in order to create sharp radar images. Simulation of multiple spacecraft time-synchronizing via laser communication can inform technology choices of a mission by providing a picosecond-precision level estimate of clock error. This timing and ranging simulation has been combined with a radar system performance analysis pipeline. The simulated timing errors are used to predict performance of bistatic SAR systems in the presence of oscillator noise and time synchronization in accuracy. This analysis includes both analytic approximation equations from existing literature, and a numerical radar simulation to extract key system performance parameters like phase error and signal-to-noise ratio (SNR)degradation. Precision time-transfer techniques facilitate the accurate synchronization of clocks between any combination of terminals. Most time-transfer technology for comparing two clocks at different terminals use radio frequencies (RF) to measure the time delay between the sending and receiving of signals. Laser technology offers the capability to transmit high data rates with systems that are of smaller size and lower power than comparable RF systems. The clocks on independent spacecraft will have some phase and frequency errors between them that result in clock drift. The two clock models that are included in this bi-directional MATLAB simulation are a cesium-based Chip-Scale Atomic Clock (CSAC) and a rubidium-based Miniature Atomic Clock (MAC). The CSAC has flown as hardware for small satellite missions such as the University of Florida’s CHOMPTT mission. A study of example orbits, including that of NASA NASA-ISRO Synthetic Aperture Radar Mission (NISAR) mission, and lasing rates demonstrate the impact of flight configuration parameters on the synchronization error between two spacecraft. The MATLAB timing simulation uses a Runge-Kutta 4th-order method to propagate spacecraft orbits and computes the light-travel time estimate between them. The simulation outputs the estimated range and estimated clock error based on a user-defined spacecraft cluster configuration. The radar simulation and analytic approximations are applied to evaluate a potential future NASA bistatic SAR constellation architecture. In the proposed architecture, satellites follow each other in the same orbit at 800 km altitude, with a 210 km baseline. We also baseline the CSAC as an ultra stable oscillator, and use NASA’s NISAR for baseline radar system parameters to compute a clock-system introduced phase error of 5.6 degrees without synchronization by frequent time transfer. We build on this base case with a sensitivity analysis of radar performance over a proposed range of constellation and radar system parameters. With this analysis pipeline, we comment on which radar parameters should or should not be changed to minimize synchronization requirements. This analysis technique could be extended or modified to evaluate the timing requirements of other geometries for other future multistatic SAR missions, or other interferometric satellite missions.

Surface Deformation and Change↗

Effect of velocity-changing collisions on the output of a gas laser.

A theoretical model for the pressure dependence of the intensity of a gas laser is presented in which only velocity-changing collisions with foreign-gas atoms are included. This is a special case where the phase shifts are the same for the two atomic-laser levels or are so small that deflections are the dominant effect of collisions. A collision model for hard-sphere repulsive interactions is derived and the collision parameters, persistence of velocity and collision frequency, are assumed to be independent of velocity. The collision theory is applied to a third-order expansion of the polarization in powers of the cavity electric field (weak-signal theory). The resulting expression for the intensity shows strong pressure dependence. The collisions reduce the amount of saturation and the laser intensity increases with pressure in a characteristic fashion.

Borenstein, M.↗

Nonstoichiometric defects in GaAs and the EL2 bandwagon

In the present paper, an attempt is made to formulate a common framework for a discussion of nonstoichiometric defects, especially EL2 and dislocations. An outline is provided of the most important settled and unsettled issues, taking into account not only fundamental interests, but also urgent needs in advancing IC technology. Attention is given to stoichiometry-controlled compensation, the expected role of melt stoichiometry in electrical conductivity for the basic atomic disorders, defect equilibria-dislocations and EL2, and current issues pertaining to the identification of EL2. It is concluded that nonstoichiometric defects play a critical role in the electronic properties of GaAs and its electronic applications. Very significant progress has been recently made in learning how to adjust melt stoichiometry in order to maximize its beneficial effects and minimize its detrimental ones.

Lagowski, J.↗

Laser velocimetry in turbulent flow fields - Particle response

Measurements of the particle response in a decelerating flow and a highly turbulent two-phase flow were obtained. Simultaneous measurements of the particle size and velocity served to quantify the particle response to the prevailing flow field. In the case of a flow incident upon a cylinder, the particle lag for a range of size classes was recorded. Results were also obtained in the flow generated by an atomizer operating on the leeward side of a flat disk bluff body in a coflowing air stream. Measurements of the mean axial, mean radial, and rms velocities and angles of trajectories were obtained for representative particle size classes. The air velocity and turbulence intensity were inferred from the seed particles on the order of one micrometer in diameter. Particles 9 micrometers and larger showed significant differences with respect to the gas phase mean velocity and turbulence intensity even at low velocities. In two-phase flows, reliable measurements of the continuous phase velocity and turbulence parameters requires the simultaneous measurement of particle size as a means for rejecting readings from large particles from the velocity pdf's.

Bachalo, W. D.↗

Energetic neutral atom image of a storm-time ring current

Energetic neutral atom (ENA) images of a storm-time ring current produced from direct measurements and model simulations are presented and analyzed. An ENA image of the storm-time ring current was obtained with the Medium Energy Particles Instrument (MEPI) mounted on ISEE 1 on September 29, 1978, and a zero-order model of the ring current ion was employed to simulate the ENA image. The simulated instrument response is compared with actual ENA measurements. It is observed that the spatial distribution of singly charged ions detected from the ENA images displays equatorial midnight/noon asymmetry in differential ion intensity with a midnight/noon ratio of greater than or equal to 20:1; peak ion fluxs, H(+) and O(+), in the midnight sector are greater than 10 to the 6th/(sq cm s sr keV); and ENA fluxes from the brighter areas of the image exceed greater than 1000/(sq cm s sr keV). It is noted that the ENA image from MEPI data correlates with the morphology of the simulated response of MEPI calculated from the model.

Roelof, Edmond C.↗

Multilayer relaxation and surface structure of ordered alloys

Using BFS, a new semiempirical method for alloys, we study the surface structure of fcc ordered binary alloys in the Ll(sub 2) structure (Ni3Al and Cu3Au). We show that the surface energy is lowest for the mixed composition truncation of the low-index faces of such systems. Also, we present results for the interlayer relaxations for planes close to the surface, revealing different relaxations for atoms of different species producing a rippled surface layer.

Kobistek, Robert J.↗

Structural evolution, electrochemical kinetic properties, and stability of A-site doped perovskite Sr(1-x)Yb(x)CoO(3-δ)

Mixed ionic and electronic conducting (MIEC) perovskite SrCoO(3-δ) is a widely studied (electro)catalyst for the oxygen reduction reaction (ORR) and possesses different crystal structures at different temperatures. These temperature dependent phase transitions significantly impact the ordering of oxygen vacancies and electrochemical kinetic properties as well as the reliability of the related devices. Some of the crystal structures formed, e.g. hexagonal phases, turn out to be almost impermeable to oxygen gas. Therefore, it is important to stabilize the crystal structure of SrCoO(3-δ) that favors the ORR over a wide temperature range. Herein, the partial substitution of the A-site Sr with Yb is systematically studied, including synthesis, characterization and analysis of structural evolution, electrochemical kinetic properties, thermal stability, and stability in a CO2-containing atmosphere. The results indicate that Sr(0.90)Yb(0.10)CoO(3-δ) is able to stabilize the tetragonal crystal structure with less ordered oxygen vacancies, leading to polarization resistances of 0.051, 0.115 and 0.272 U sq.cm at 750, 700 and 650 °C, respectively, on symmetrical cells. Sr(0.90)Yb(0.10)CoO(3-δ) demonstrates a very stable surface oxygen vacancy distribution and electronic structure near oxygen vacancies but dissociation of adsorbed oxygen molecules into atomic oxygen is affected by surface Sr segregation, and polarization resistance degradation is mainly induced by surface Sr segregation. Furthermore, Sr(0.90)Yb(0.10)CoO(3-δ) exhibits excellent thermal stability as well as excellent recovery stability and improved polarization performance after a few pure air/CO2-containing air treatment cycles at 700 °C. However, a hysteresis behavior of polarization performance is observed at 650 °C during gas cycling treatment, which may cause long-term degradation of the Sr(0.90)Yb(0.10)CoO(3-δ) electrode. The different polarization behaviors during gas cycling treatment are induced by different sensitivities of the formed surface strontium carbonate and chemisorbed surface oxo-carbonaceous species to different operating temperatures.

electrochemical kinetic↗

The identification of excited species in arc jet flow

Spectrographic work done at the Atmospheric Reentry Material and Structures Facility (arc jet) located at the Johnson Space Center has led to the identification of several excited molecular and atomic states. The excited molecular states identified are: first positive nitrogen system, second positive nitrogen system, the first negative nitrogen system, the gamma system for nitric oxide, and the 306.4 nm system of OH. Excited atoms identified were nitrogen, oxygen, hydrogen, silicon, copper, sodium, barium, potassium, and calcium. The latter five are considered contaminants. Excited molecular states of oxygen were not seen, suggesting full dissociation of oxygen molecules to oxygen atoms within the arc column and nozzle. Further, evidence exists that O(-) may be present since a background continuum is seen, and because of the existence of positive species (first negative system of N2(+)). Interpretation of spectrographic plates was enhanced by the use of a microdensitometer, and by the application of a second order least squares routine which determined wavelength as a function of plate location. Results of this work will ultimately improve models used in the calculation of heat transfer rates to the space shuttle and the aerobraking orbit transfer vehicles.

Willey, Ronald J.↗

Near-midnight observations of nitric oxide delta- and gamma-band chemiluminescence

Chemiluminescent nightglow emission of the nitric oxide delta and gamma bands was measured from a sounding rocket launched on April 27, 1981, near local midnight. The integrated band emission rates for this near zenith observation above 205 km were less than 10 Rayleighs. The solar zenith angle was 127 deg. The branching ratio from the C2Pi state to the A2Sigma(+) state of NO was determined from comparison of the total emission rate of the delta band system to that of the gamma band system and found to be 0.30 + or - 0.06. The branching ratios within each of the band systems were found to be consistent with previous theoretical and experimental determinations. The vertical atomic nitrogen distribution, derived with the use of a model atmosphere, was found to have a peak density of 2.0 x 10 to the 7th atoms/cu cm at an altitude of 205 km. The analysis of these data indicate the presence of residual NO emission above 270 km at local midnight on the order of 1 Rayleigh of total band emission.

Tennyson, P. D.↗

Relating the Hadamard Variance to MCS Kalman Filter Clock Estimation

The Global Positioning System (GPS) Master Control Station (MCS) currently makes significant use of the Allan Variance. This two-sample variance equation has proven excellent as a handy, understandable tool, both for time domain analysis of GPS cesium frequency standards, and for fine tuning the MCS's state estimation of these atomic clocks. The Allan Variance does not explicitly converge for the nose types of alpha less than or equal to minus 3 and can be greatly affected by frequency drift. Because GPS rubidium frequency standards exhibit non-trivial aging and aging noise characteristics, the basic Allan Variance analysis must be augmented in order to (a) compensate for a dynamic frequency drift, and (b) characterize two additional noise types, specifically alpha = minus 3, and alpha = minus 4. As the GPS program progresses, we will utilize a larger percentage of rubidium frequency standards than ever before. Hence, GPS rubidium clock characterization will require more attention than ever before. The three sample variance, commonly referred to as a renormalized Hadamard Variance, is unaffected by linear frequency drift, converges for alpha is greater than minus 5, and thus has utility for modeling noise in GPS rubidium frequency standards. This paper demonstrates the potential of Hadamard Variance analysis in GPS operations, and presents an equation that relates the Hadamard Variance to the MCS's Kalman filter process noises.

Hutsell, Steven T.↗

Advanced Curation of Current and Future Extraterrestrial Samples

Curation of extraterrestrial samples is the critical interface between sample return missions and the international research community. Curation includes documentation, preservation, preparation, and distribution of samples. The current collections of extraterrestrial samples include: Lunar rocks / soils collected by the Apollo astronauts Meteorites, including samples of asteroids, the Moon, and Mars "Cosmic dust" (asteroid and comet particles) collected by high-altitude aircraft Solar wind atoms collected by the Genesis spacecraft Comet particles collected by the Stardust spacecraft Interstellar dust collected by the Stardust spacecraft Asteroid particles collected by the Hayabusa spacecraft These samples were formed in environments strikingly different from that on Earth. Terrestrial contamination can destroy much of the scientific significance of many extraterrestrial materials. In order to preserve the research value of these precious samples, contamination must be minimized, understood, and documented. In addition the samples must be preserved - as far as possible - from physical and chemical alteration. In 2011 NASA selected the OSIRIS-REx mission, designed to return samples from the primitive asteroid 1999 RQ36 (Bennu). JAXA will sample C-class asteroid 1999 JU3 with the Hayabusa-2 mission. ESA is considering the near-Earth asteroid sample return mission Marco Polo-R. The Decadal Survey listed the first lander in a Mars sample return campaign as its highest priority flagship-class mission, with sample return from the South Pole-Aitken basin and the surface of a comet among additional top priorities. The latest NASA budget proposal includes a mission to capture a 5-10 m asteroid and return it to the vicinity of the Moon as a target for future sampling. Samples, tools, containers, and contamination witness materials from any of these missions carry unique requirements for acquisition and curation. Some of these requirements represent significant advances over methods currently used. New analytical and screening techniques will increase the value of current sample collections. Improved web-based tools will make information on all samples more accessible to researchers and the public. Advanced curation of current and future extraterrestrial samples includes: Contamination Control - inorganic / organic Temperature of preservation - subfreezing / cryogenic Non-destructive preliminary examination - X-ray tomography / XRF mapping / Raman mapping Microscopic samples - handling / sectioning / transport Special samples - unopened lunar cores Informatics - online catalogs / community-based characterization.

Allen, Carlton C.↗

Investigation of the effect of etch pits on the material properties of carbon fiber structures

It is well known that etch pits are formed on carbon surfaces during their consumption in reactive gas environments such as during ablation of carbon-based thermal protection system (TPS) materials. These pits start out from atomic defects on the carbon surface, grow in size and then ultimately lead to the complete removal of the solid carbon material [1, 2]. However, the effect of such etch pits on the material properties of carbon ablators such as FiberForm are poorly understood, as the maximum size of pits are on the order of microns in size, which makes them hard to observe experimentally. Hence, we have developed a module within the Porous Microstructure Analysis code PuMA [3] that can generate etch pits on an arbitrary material surface, with a prescribed distribution of pit size and density. Figure 1 shows a FiberForm sample with artificially generated pits of varying radii and pit density. We use this newly developed module to calculate material properties of FiberForm, which is the base material for one of the most commonly used TPS materials - Phenolic Impregnated Carbon Ablator (PICA). The detailed microstructure of FiberForm in PuMA will either be generated synthetically or obtained from X-ray microtomography [4]. Our simulations show that material properties such as the thermal conductivity and tortuosity decrease with increasing degree of pitting. This will be helpful to more accurately predict the degradation of carbon-based TPS during ablation, and furthermore may allow us to identify previously unknown TPS failure modes due to pitting.

PuMA↗