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At least 739 records · Page 41

Natural gas liquefaction employing independent refrigerant path

A method of liquefying natural gas. The method comprises cooling a gaseous natural gas process stream with a refrigerant flowing in a path isolated from the natural gas process stream. The refrigerant may differ in composition from a composition of the natural gas process stream, and the refrigerant composition may be selected to enhance efficiency of the refrigerant path with regard to a specific composition of the natural gas process stream. The refrigeration path may be operated at pressures, temperatures and flow rates differing from those of the natural gas process stream. Other methods of liquefying natural gas are described. A natural gas liquefaction plant is also described.

03 NATURAL GAS↗

Methods and systems for performing chemical separations

The present disclosure provides a method for generating higher hydrocarbon(s) from a stream comprising compounds with two or more carbon atoms (C 2+ ), comprising introducing methane and an oxidant (e.g., O 2 ) into an oxidative coupling of methane (OCM) reactor. The OCM reactor reacts the methane with the oxidant to generate a first product stream comprising the C 2+ compounds. The first product stream can then be directed to a separations unit that recovers at least a portion of the C 2+ compounds from the first product stream to yield a second product stream comprising the at least the portion of the C 2+ compounds.

Jonnavittula, Divya↗

Method of separating components of a gas

A method is disclosed for separating components of a gas. A feed gas stream is passed into a vessel. The feed gas stream includes methane, carbon dioxide, and water. The feed gas stream is cooled in the vessel such that a portion of the methane and a portion of the carbon dioxide condense and a portion of the water desublimates, resulting in a product stream and a depleted gas stream exiting the vessel.

Baxter, Larry↗

Separation methods and systems for oxidative coupling of methane

The present disclosure provides a method for generating higher hydrocarbon(s) from a stream comprising compounds with two or more carbon atoms (C2+), comprising introducing methane and an oxidant (e.g., O2) into an oxidative coupling of methane (OCM) reactor. The OCM reactor reacts the methane with the oxidant to generate a first product stream comprising the C2+ compounds. The first product stream can then be directed to a separations unit that recovers at least a portion of the C2+ compounds from the first product stream to yield a second product stream comprising the at least the portion of the C2+ compounds.

Duggal, Suchia↗

Fuel cell system having enhanced CO2 capture

A carbon dioxide capture system for removing carbon dioxide from a flue gas produced by a combustion power plant. The system includes an electrolyzer cell configured to receive a flue gas comprising carbon dioxide and output a first exhaust stream comprising an enriched flue gas comprising carbon dioxide. The system further includes a fuel cell configured to receive the first exhaust stream and output a second exhaust stream comprising carbon dioxide. The second exhaust stream contains a higher concentration of carbon dioxide than the first exhaust stream.

Jahnke, Fred C.↗

Hydrothermal liquefaction system

A hydrothermal liquefaction (HTL) system can comprise a biomass slurry source, a first pump in fluid communication with the slurry source and configured to pressurize a biomass slurry stream from the slurry source to a first pressure, a first heat exchanger in fluid communication with the first pump and configured to heat a slurry stream received from the first pump to a first temperature, a second pump in fluid communication with the first heat exchanger and configured to pressurize a slurry stream received from the first heat exchanger to a second pressure higher than the first pressure, a second heat exchanger in fluid communication with the second pump and configured to heat a slurry stream received from the second pump to a second temperature higher than the first temperature, and a HTL reactor configured to produce biocrude from a slurry stream received from the second heat exchanger.

Thorson, Michael R.↗

Process of producing ethylene

A process of producing ethylene involving steam cracking ethane to produce a steam cracker product stream containing ethylene; cooling and drying the steam cracker product stream; contacting the cooled and dried steam cracker product stream with a MOF sorbent capable of adsorbing ethylene from the product stream, and desorbing the ethylene from the MOF sorbent using an ethylene sweep gas. The process replaces complex and energy intensive fractionation steps of the prior art with a selective adsorption step for separating ethylene from the steam cracker product stream. An energy efficient ethylene sorbent regeneration method and related apparatus systems are also disclosed.

Weissman, Jeffrey G.↗

Catalytic hot-gas filtration of biomass pyrolysis vapors

The present disclosure relates to a device that includes a filter element and a catalyst, where the filter element is configured to remove particulate from a stream that includes at least one of a gas and/or a vapor to form a filtered stream of the gas and/or the vapor, the catalyst is configured to receive the filtered stream and react a compound in the filtered stream to form an upgraded stream of the gas and/or the vapor, further including an upgraded compound, and both the filter element and the catalyst are configured to be substantially stable at temperatures up to about 500° C.

Magrini, Kimberly A.↗

Hydrothermal liquefaction system

A hydrothermal liquefaction (HTL) system can comprise a biomass slurry source, a first pump in fluid communication with the slurry source and configured to pressurize a biomass slurry stream from the slurry source to a first pressure, a first heat exchanger in fluid communication with the first pump and configured to heat a slurry stream received from the first pump to a first temperature, a second pump in fluid communication with the first heat exchanger and configured to pressurize a slurry stream received from the first heat exchanger to a second pressure higher than the first pressure, a second heat exchanger in fluid communication with the second pump and configured to heat a slurry stream received from the second pump to a second temperature higher than the first temperature, and a HTL reactor configured to produce biocrude from a slurry stream received from the second heat exchanger.

Thorson, Michael R.↗

An empirical study of I/O separation for burst buffers in HPC systems

To meet the exascale I/O requirements for the High-Performance Computing (HPC), a new I/O subsystem, Burst Buffer, based on solid state drives (SSD), has been developed. However, the diverse HPC workloads and the bursty I/O pattern cause severe data fragmentation that requires costly garbage collection (GC) and increases the number of bytes written to the SSD. To address this data fragmentation challenge, a new multi-stream feature has been developed for SSDs. In this work, we develop an I/O Separation scheme called BIOS to leverage this multi-stream feature to group the I/O streams based on the user IDs. We propose a stream-aware scheduling policy based on burst buffer pools in the workload manager, and integrate the BIOS with the workload manager to optimize the I/O separation scheme in burst buffer. We evaluate the proposed framework with a burst buffer I/O traces from Cori Supercomputer including a diverse set of applications. Experimental results show that the BIOS could improve the performance by 1.44x on average and reduce the Write Amplification Factor (WAF) by up to 1.20x. Finally, these demonstrate the potential benefits of the I/O separation scheme for solid state storage systems.

97 MATHEMATICS AND COMPUTING↗

Advancing a Watershed Hydro-Biogeochemical Theory: Linking Water Travel Time and Reaction Rates Under Changing Climate

The major goal of the project is to answer the question how and to what degree does a warming climate alter hydrological functioning and (biogeochemical and chemical weathering) reaction rates at the watershed scale? In particular, how does hydrological functioning (water storage, flow paths, and travel time) change responding to a warming climate? What are the corresponding alterations in biogeochemical and chemical weathering rates at the watershed scale? What is the general watershed-scale reaction rate law that causally links reaction rates to metrics of hydrological functioning that are determined by external hydroclimatic conditions and internal watershed structure characteristics? To answer these questions, we have used field measurements and reactive transport modeling. We have found that: 1) stream chemistry has altered tremendously in warmer years; 2) In this water-limited environment, hydrology is the dominant driver for soil respiration and carbon lateral export at the watershed scale; 3) deeper carbon respiration plays an essential role in regulating the patterns of stream carbon in low and high flow conditions, and deeper groundwater will become increasingly important as warming intensifies. This indicates in mountain streams, a warming climate will modify not only the timing and magnitude of streamflow as expected, but also the chemistry and quality of stream water.

54 ENVIRONMENTAL SCIENCES↗

Long-term hydrological, biogeochemical, and climatological data from Walker Branch Watershed, East Tennessee, USA

In 1967, the original Walker Branch Watershed (WBW) project was established to study elemental cycling and mass balances in a relatively unimpacted watershed. Over the next 50+ years, findings from additional experimental studies and long-term observations on WBW advanced understanding of catchment hydrology, biogeochemistry, and ecology and established WBW as a seminal site for catchment science. The 97.5-ha WBW is located in East Tennessee, USA, on the U.S. Department of Energy's Oak Ridge Reservation. Vegetation on the watershed is characteristic of an eastern deciduous, second-growth forest. The watershed is divided into two subcatchments: the West Fork (38.4 ha) and the East Fork (59.1 ha). Headwater streams draining these subcatchments are fed by multiple springs, and thus flow is perennial. Stream water is high in base cations due to weathering of dolomite bedrock and nutrient concentrations are low. Long-term observations of climate, hydrology, and biogeochemistry include daily (1969–2014) and 15-min (1994–2014) stream discharge and annual runoff (1969–2014); hourly, daily, and annual rainfall (1969–2012); daily climate and soil temperature (1993–2010); and weekly stream water chemistry (1989–2013). These long-term datasets are publicly available on the WBW website (https://walkerbranch.ornl.gov/long-term-data/). While collection of these data has ceased, related long-term measurements continue through the National Ecological Observatory Network (NEON), where WBW is the core terrestrial and aquatic site in the Appalachian and Cumberland Plateau region (NEON's Domain 7) of the United States. These long-term datasets have been and will continue to be important in evaluating the influence of climatic and environmental drivers on catchment processes.

54 ENVIRONMENTAL SCIENCES↗

Natural attenuation of uranium in a fluvial Wetland: Importance of hydrology and speciation

A nuclear fuel fabrication facility released 43,500 kg of uranium into a riparian wetland located on the Savannah River Site between 1955 and 1988. Studies were undertaken to evaluate hydrological and geochemical processes influencing uranium accumulation in the wetland. Gamma-radiation-mapping surveys were conducted by systematically walking over the contaminated wetland with backpacks equipped with global positioning systems and NaI gamma detectors. Based on maps compiled from >700,000 gamma spectra and eight sediment uranium depth profiles, it was determined that 94% of the released uranium remained in the wetland. The uranium in the wetland is concentrated in five multi-hectare areas along the stream, accounting for ~11% of the land area adjacent to the stream. While land type (upland or wetland) and topography provided a reasonable first approximation of where much of the uranium was deposited, hydrological watershed modeling revealed that the stream velocity was especially slow through many of the hot spots. Here, using autoradiography combined with SEM/EDX measurements of contaminated sediments, surprisingly few hot particles were detected. Instead, uranium was evenly distributed throughout the sampled sediment, suggesting that dissolved uranium had bound to sediment particles that became suspended and later deposited in low energy (low flow velocity) portions of the stream. EXAFS suggested that U atoms were present as individual ions in disordered complexes within the sediment. Furthermore, linear combination analyses suggested that the predominant component of the U(VI) was adsorbed to sediment minerals (~70%) and a minor component (~30%) was associated with organic matter phases. Furthermore, these studies show that wetlands can be extraordinarily effective at binding and retaining uranium, thereby providing a natural barrier to the transport of uranium out of a watershed. However, significant anthropogenic or climatic changes to wetlands, such as those associated with flooding, forest fires, or land use, may disrupt the complex hydrological and biogeochemical balance necessary to maintain long-term immobilization of uranium.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Decadal Variability of Southeast US Rainfall in an Eddying Global Coupled Model

Abstract Ocean variability is a dominant source of remote rainfall predictability, but in many cases the physical mechanisms driving this predictability are not fully understood. This study examines how ocean mesoscales (i.e., the Gulf Stream SST front) affect decadal Southeast US (SEUS) rainfall, arguing that the local imprint of large‐scale teleconnections is sensitive to resolved mesoscale features. Based on global coupled model experiments with eddying and eddy‐parameterizing ocean, we find that a resolved Gulf Stream improves localized rainfall and remote circulation response in the SEUS. The eddying model generally improves the air‐sea interactions in the Gulf Stream and the North Atlantic Subtropical High that modulate SEUS rainfall over decadal timescales. The eddy‐parameterizing simulation fails to capture the sharp SST gradient associated with the Gulf Stream and overestimates the role of tropical Pacific SST anomalies in the SEUS rainfall.

54 ENVIRONMENTAL SCIENCES↗

Geoelectric Characterization of Hyporheic Exchange Flow in the Bedrock‐Lined Streambed of East Fork Poplar Creek, Oak Ridge, Tennessee

Abstract A multimethod geoelectric survey was implemented between January and March 2022 along a 220‐m long reach of the bedrock‐lined streambed of East Fork Poplar Creek in Oak Ridge, Tennessee to identify locations of surface‐water and groundwater exchange and characterize the subsurface flow paths that convey water between the stream and flood plain. A waterborne self‐potential (WaSP) survey was completed in January 2022 to measure the electric streaming‐potential field in the stream. Electric resistivity tomography (ERT) was performed in March 2022 on the flood plain adjacent to the WaSP survey reach to map the electric resistivity distribution and characterize the hydrogeology and subsurface flow paths that facilitate surface‐water and groundwater exchange in the bedrock‐lined stream. The combination of WaSP and ERT data support the qualitative interpretation that surface‐water and groundwater exchange likely occurs along fractures in outcropping bedrock and along two fault lines that intersect the limestone creek bed.

54 ENVIRONMENTAL SCIENCES↗

Timely Reporting of Heavy Hitters Using External Memory

Given an input stream S of size N, a Φ-heavy hitter is an item that occurs at least ΦN times in S. The problem of finding heavy-hitters is extensively studied in the database literature. In this work, we study a real-time heavy-hitters variant in which an element must be reported shortly after we see its T = Φ N-th occurrence (and hence it becomes a heavy hitter). We call this the Timely Event Detection (TED) Problem. The TED problem models the needs of many real-world monitoring systems, which demand accurate (i.e., no false negatives) and timely reporting of all events from large, high-speed streams with a low reporting threshold (high sensitivity). Like the classic heavy-hitters problem, solving the TED problem without false-positives requires large space (Ω (N) words). Thus in-RAM heavy-hitters algorithms typically sacrifice accuracy (i.e., allow false positives), sensitivity, or timeliness (i.e., use multiple passes). We show how to adapt heavy-hitters algorithms to external memory to solve the TED problem on large high-speed streams while guaranteeing accuracy, sensitivity, and timeliness. Our data structures are limited only by I/O-bandwidth (not latency) and support a tunable tradeoff between reporting delay and I/O overhead. With a small bounded reporting delay, our algorithms incur only a logarithmic I/O overhead. We implement and validate our data structures empirically using the Firehose streaming benchmark. Multi-threaded versions of our structures can scale to process 11M observations per second before becoming CPU bound. In comparison, a naive adaptation of the standard heavy-hitters algorithm to external memory would be limited by the storage device’s random I/O throughput, i.e., ≈100K observations per second.

97 MATHEMATICS AND COMPUTING↗

Data and script associated with “Shifts in Rain-Snow Partitioning Drive Faster Water Transit Times in the US Pacific Northwest”

This data package contains the data and code to use and run the Water Tracer enabled version of the Weather Research and Forecasting Hydrologic model (WT-WRF-Hydro) with the Sequential Precipitation Input Tagging (SPIT) framework. It is associated with the publication “Shifts in Rain-Snow Partitioning Drive Faster Water Transit Times in the US Pacific Northwest” published in Scientific Reports (Butler et al., 2026; https://doi.org/10.1038/s41598-026-46539-1). We use the Continental U.S. (CONUSII; Rasmussen et al., 2021) dataset to force the model with an historical climate (2006–2013) and a future climate (2086–2093) with a representative carbon pathway (RCP) 8.5 scenario. We use the model to calculate water transit times in five headwater catchments within the U.S. Pacific Northwest. We also show key hydrologic and environmental variables that affect water transit times and changes in the future. Finally, we use observed data to validate the model such as stream water isotopes, snowpack characteristics, and stream discharge. For details on how to navigate data packages generated by this project, see https://data.ess-dive.lbl.gov/portals/PNNLRiverCorridorSFA/About. In addition to a readme, this data package also includes a file-level metadata (FLMD) file that describes each file and a data dictionary (DD) that describes all column/row headers and variable definitions. The data package consists of 11 folders: (1) "Figures" contains the exported figures used in the manuscript; (2) "Model_Isotope_Date" contains the WT-WRF-Hydro isotope date used in model validation; (3) “Model_Outputs_Future” contains the WT-WRF-Hydro future climate outputs; (4) “Model_Outputs_Historical” contains the WT-WRF-Hydro historical climate outputs; (5) “Model_Outputs_Weights_Areas” contains the WT-WRF-Hydro weights per catchment used to calculate water transit times and isotopes in stream water; (6) “MODIS_data_scripts” contains data used to validate snow conditions in the study area; (7) “Observed_Flow_Data” contains the observed streamflow data used in model validation; (8) “Observed_Isotope_Data” contains the observed stream water isotope data used in model validation; (9) “Scripts” contains the Python scripts used to general results and the figures; (10) “Statistic_Outputs” contains the water transit time statistical outputs reported in this manuscript; (11) “Validation_SNOTEL” contains the SNOTEL data used in model validation. The files in this data package have the following file extensions: .tif, .txt, .csv, .pdf, .py, .jpg, and .png.

American River↗

Discovery of Extended Tidal Tails around the Globular Cluster Palomar 13

We use photometry from the DECam Legacy Survey to detect candidate tidal tails extending ~5° on either side of the Palomar 13 globular cluster. The tails are aligned with the proper motion of Palomar 13 and are consistent with its old, metal-poor stellar population. We identify three RR Lyrae stars (RRLs) that are plausibly associated with the tails, in addition to four previously known in the cluster. From these RRLs, we find that the mean distance to the cluster and tails is 23.6 ± 0.2 kpc and estimate the total (initial) luminosity of the cluster to be , consistent with previous claims that its initial luminosity was higher than its current luminosity. Combined with previously determined proper motion and radial velocity measurements of the cluster, we find that Palomar 13 is on a highly eccentric orbit (e ~ 0.8) with a pericenter of ~9 kpc and an apocenter of ~69 kpc, and a recent pericentric passage of the cluster ~75 Myr ago. We note a prominent linear structure in the interstellar dust map that runs parallel to the candidate tidal features, but conclude that reddening due to dust is unlikely to account for the structure that we observe. If confirmed, the Palomar 13 stellar stream would be one of very few streams with a known progenitor system, making it uniquely powerful for studying the disruption of globular clusters, the formation of the stellar halo, and the distribution of matter within our Galaxy.

79 ASTRONOMY AND ASTROPHYSICS↗