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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
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Reducing Solvent Consumption in Reductive Catalytic Fractionation through Lignin Oil Recycling
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Implementing a Doping Approach for Poly(methyl methacrylate) Recycling in a Circular Economy
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Reduction of CO to Methanol with Recyclable Organic Hydrides
We report the reaction steps for the selective conversion of a transition metal carbonyl complex to a hydroxymethyl complex that releases methanol upon irradiation with visible light have been successfully quantified in acetonitrile solution with dihydrobenzimidazole organic hydride reductants. Dihydrobenzimidazole reductants have been shown to be inactive toward H 2 generation in the presence of a wide range of proton sources and have been regenerated electrochemically or photochemically. Specifically, the reaction of cis-[Ru(bpy) 2 (CO) 2 ] 2+ (bpy = 2,2'-bipyridine) with one equivalent of a dihydrobenzimidazole quantitatively yields a formyl complex, cis-[Ru(bpy) 2 (CO)(CHO)] + , and the corresponding benzimidazolium on a seconds time scale. Kinetic experiments revealed a first-order dependence on the benzimidazole hydride concentration and an unusually large kinetic isotope effect, inconsistent with direct hydride transfer and more likely to occur by an electron transfer-proton-coupled electron transfer (EΤ-PCET) or related mechanism. Further reduction/protonation of cis-[Ru(bpy) 2 (CO)(CHO)] + with two equivalents of the organic hydride yields the hydroxymethyl complex cis-[Ru(bpy) 2 (CO)(CH 2 OH)] + . Visible light excitation of cis-[Ru(bpy) 2 (CO)(CH 2 OH)] + in the presence of excess organic hydride was shown to yield free methanol. Identification and quantification of methanol as the sole CO reduction product was confirmed by 1 H NMR spectroscopy and gas chromatography. The high selectivity and mild reaction conditions suggest a viable approach for methanol production from CO, and from CO 2 through cascade catalysis, with renewable organic hydrides that bear similarities to Nature's NADPH/NADP + .
Toward Circular Recycling of Polyurethanes: Depolymerization and Recovery of Isocyanates
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Amazonian Moisture Recycling Revisited Using WRF With Water Vapor Tracers
Previous studies have estimated that 25%–35% of Amazonian precipitation comes from evapotranspiration (ET) within the basin. However, due to simplifying assumptions of traditional models, these studies primarily focus on large spatial and temporal scales. This study is the first to analyze the moisture of Amazonian origin at the annual to daily timescale in four different subregions of the Amazon. We analyze the sources, sinks and stores of moisture that originates as Amazonian ET. To do this, we use the Weather Research and Forecast (WRF) regional meteorological model with the added capability of water vapor tracers to track this moisture. Moisture of Amazonian origin shows strong annual and semi-annual signals, with contrasting behavior between the northern and southern parts of the basin. The tracers reveal a strong diurnal cycle of Amazonian water vapor which had not been previously reported. This signal is related to the diurnal cycle of ET, convective precipitation and advected moisture. ET's contribution to atmospheric moisture increases from early morning into the afternoon. Some of this moisture is rained out through convective storms in the early evening. Later in the night and following morning, strong winds associated with the South American Low Level Jet advect moisture downwind. Overall, the beating pattern becomes apparent when visualizing the Amazonian water vapor as an animation.
Cost-effective urine recycling enabled by a synthetic osteoyeast platform for production of hydroxyapatite
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Fire-extinguishing, recyclable liquefied gas electrolytes for temperature-resilient lithium-metal batteries
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Chemical recycling of a lignin-based non-isocyanate polyurethane foam
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High chemical recyclability of vinyl lactone acrylic bioplastics
Biomass-derived vinyl lactone acrylic bioplastics not only exhibit higher thermostability but also depolymerize more selectively to monomers with higher yield and purity compared to their petroleum-based vinyl ester acrylic counterpart.