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At least 739 records · Page 41

The past, present, and future of nuclear fuel

Abstract New reactor concepts have motivated study of a variety of nuclear fuel types. Most nuclear fuels have their origins dating back to the very beginnings of nuclear materials. We survey the most prevalent types of nuclear fuels and their properties and give some historical context as to their development. We end with our perspective on what the next 50 years of nuclear fuel research might lead to. In our opinion, while optimized microstructures and chemistries are certainly on the horizon, the biggest developments will be the continued integration of modeling and simulation with experiments to extract the greatest amount of energy possible from existing fuel candidates in a safe and economical way. Graphical abstract

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Fork Experiments in the Hot Cell Using Spent Fuel Rods for International Nuclear Safeguards

This work leveraged the rare availability of 25 full-length pressurized water reactor spent fuel rods and 1 irradiated mixed-oxide rod at an Oak Ridge National Laboratory hot cell. This was done to collect measurement data with two Fork detectors to assess the detectors’ capability of verifying operator declaration data and detecting partial defects in spent fuel, which are the two primary goals of international safeguards on spent nuclear fuel. The data can also be used to benchmark the ORIGEN module, which has been adopted in the International Atomic Energy Agency’s (IAEA’s)/European Atomic Energy Community’s (Euratom’s) Integrated Review and Analysis Program to predict the Fork detector count rates in real time. In this project, the authors first calibrated two Fork detectors—a standard one and a modified one—by using known strong neutron and gamma sources. Then, the authors measured all 26 fuel rods at multiple locations along the length. The fuel rods were then assembled into three arrays—2 × 2, 3 × 3, and 5 × 5—by using specially designed support grids to mimic fuel assemblies and measure the arrays with both detectors. For the 5 × 5 array, 4 and 8 fuel rods of the array were replaced in two separate cases with short stainless-steel rods to mimic two partial defect scenarios, and the arrays were measured before and after the replacements. Polyethylene blocks were used in this experiment to mimic water. The results show that the Fork detectors were able to verify operator declarations and detect partial defects in spent fuel, and the authors were the first to demonstrate this through experiments. A discovery was also made that determined the root cause of the nonlinear response to gamma dose in the ion chambers used in IAEA and Euratom’s Fork detectors. After the experiments, both detectors were retrieved from the hot cell for future use. The data collected in this project will be used in a parallel International Nuclear Safeguards Engagement Program (INSEP) project to enhance the safeguards in the Finnish spent fuel encapsulation plant, and the data will be useful to other projects in the future given the increased safeguards needs due to spent fuel transfer and disposal activities worldwide.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Nuclear Software Validation for 7% Enriched UO 2 Fuel Lattices

This analysis performs validation for the Virtual Environment for Reaction Application’s (VERA’s) neutronics codes MPACT and Shift against measured data from the Seven Percent Critical Experiment (7uPCX) at Sandia National Laboratory. The benchmarking supports the future application of VERA for analysis of high-assay low-enriched uranium (HALEU) fuel in commercial pressurized water reactors (PWRs). VERA demonstrates very good agreement with measured data, and the deterministic code MPACT also agrees very well with higher-fidelity stochastic methods KENO-VI and Shift in both total neutron flux and fission rate distribution comparisons. Despite some significant differences between the 7uPCX and existing commercial PWRs that challenge the neutron cross section data and transport solver methods used by MPACT, all of the results are excellent. The agreement increases the confidence in the applicability and accuracy of VERA for reactor analysis of HALEU fuels in commercial reactors.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Destructive PIE and Safety Testing of Six AGR-2 UO 2 Capsule 3 Compacts

The Advanced Gas Reactor (AGR) Fuel Development and Qualification Program’s second irradiation experiment (AGR-2) was irradiated in the Advanced Test Reactor (ATR) at Idaho National Laboratory (INL) from June 2010 to October 2013 (Collin 2014). The fuel compacts in this experiment held either tristructural isotropic (TRISO)-coated spherical kernels of uranium oxide (UO2) or TRISO-coated kernels containing both uranium carbide and uranium oxide phases (UCO). There were six separately monitored and controlled capsules in the AGR-2 test train. Capsule 3 held twelve compacts containing UO2-TRISO particles fabricated by BWX Technologies Nuclear Operations Group. The AGR-2 TRISO particles were fabricated in a pilot-scale fluidized-bed chemical vapor deposition (FB-CVD) furnace with a coating chamber inner diameter of 150 mm (Phillips, Barnes, and Hunn 2010), which was a change from the first irradiation experiment (AGR-1) particles that had been coated in a lab-scale FB-CVD coating system with a chamber inner diameter of 50 mm (Lowden 2006). The TRISO particles were overcoated with resinated graphite flake at Oak Ridge National Laboratory (ORNL), and the overcoated particles were pressed into one-inch-long, half-inch-diameter cylinders (Hunn, Montgomery, and Pappano 2010). Each cylindrical compact held an average of 1,543 TRISO particles with 9.6% enriched UO2 kernels that had a nominal diameter of 500 μm (Hunn, Savage, and Silva 2012). Capsule 3 compacts were irradiated to average calculated burnups of 9.01–10.69% fissions per initial metal atom (FIMA), and the average calculated fluences of fast neutrons with energies E n > 0.18 MeV were 3.05–3.53×10 25 n/m 2 (Sterbentz 2014). The calculated time-average, volume-average Capsule 3 compact temperatures were 996–1,062°C. However, Capsule 3 compact temperatures varied several hundred degrees across each compact, and the timeaverage minimum (TA min ) and time-average maximum (TA max ) temperatures were between 889–999°C and 1,072–1,105°C, respectively (Hawkes 2014). After irradiation, the AGR-2 test train was transferred from ATR to the INL Materials and Fuels Complex for inspection and disassembly (Ploger, Demkowicz, and Harp 2015). The initial inspection included dimensional metrology of the compacts and graphite fuel holders. Like all the AGR-2 compacts, the compacts in Capsule 3 shrank slightly during irradiation, as expected, with an average length reduction of 1.07–1.24% and an average diameter reduction of 0.13–0.41%. Post-irradiation examination (PIE) of the capsule components was completed to measure select fission products ( 90 Sr, 110m Ag, 134 Cs, 137 Cs, 144 Ce, and 154 Eu) outside the compacts (Stempien and Demkowicz 2020). This involved gamma counting of the graphite and graphoil spacers at the top and bottom of each capsule, acid leaching for radiochemical analysis of fission products on the metallic capsule components, and burn-leach analysis of the graphite holders. The total amount of 110mAg measured on the Capsule 3 components was 13% of the calculated capsule inventory. This was significantly lower than the amount of 110m Ag measured on the three UCO capsule components, which ranged from 32–70%. The lower 110m Ag release in Capsule 3 was likely due to lower peak temperatures compared with the UCO fuel capsules (Hawkes 2014). Measured inventories of the other select fission products were also lower in Capsule 3.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

TRU BISON Simulation Overview [Slides]

The BISON fuel performance code has been used to model minor actinide (MA) bearing metallic ternary fuel. This presentation gives an overview on the progress made so far on this effort, focusing on the modeling of EBR-II experiment X501-G591. Comparisons with PIE have also been made.

11 - NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Nuclide inventory validation: radiochemical assay data quality and modeling challenges in benchmark models development

Oak Ridge National Laboratory is conducting radiochemical assay experiments, using high-precision analytical protocols validated with a comprehensive quality assurance plan, to expand the nuclide inventory validation basis for high burnup spent nuclear fuel. Preliminary measurement data for key actinides and fission products in two pressurized water reactor spent fuel samples are being used to investigate the impact of measurement data uncertainty on the sample burnup estimation. These measurement data are also being used to examine the impact of assumptions applied when developing best-estimate computational models to simulate fuel irradiation history. The simulations are being performed using depletion capabilities in the SCALE code system. Comparison of calculated and measured nuclide concentrations shows good agreement for the considered nuclides. (authors)

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Reactivity-initiated accidents in two pressurized water reactor high burnup core designs

Here, this paper presents a safety analysis of two proposed core loadings for 24-month Pressurized Water Reactor (PWR) fuel cycles. This analysis focuses on reactivity-initiated accidents (RIAs) and evaluates core safety performance impacts of rod-averaged burnup limits up to 75 GWD/MTU and less than 7 % enriched UO 2 . The capabilities of Polaris, PARCS, and RELAP5-3D are leveraged to evaluate the core neutronic and thermal–hydraulic behavior for normal-operation, uncontrolled control rod withdrawal (CRW) transients, and control rod ejection (CRE) accidents. The two core designs are compared to identify features of realistic high burnup/extended enrichment core design approaches which have significant safety impact, identify experimental data needs for high-fidelity predictive modeling, and provide recommendations for future high burnup core designs. The first core design evaluated in this study was developed by Southern Nuclear Company and used an ZrB 2 Integral Fuel Burnable Absorber (IFBA) and B 4 C Wet-Annular Burnable Absorber (WABA)-based burnable poison strategy. The second core design assessed in this work used a Gd 2 O 3 -doped UO 2 burnable poison, similar to that used in boiling water reactors or French PWRs. Results indicate that fuel thermal limits are maintained for limiting CRW and hot full power (HFP) CRE transients. Cladding failure is predicted for the highest energy deposition rods in each core during limiting hot zero power (HZP) CRE accidents (where maximum radially averaged enthalpy exceeds 120 cal/g), though licensing may be permissible with a limited number of failed rods. While concerns exist regarding high critical boron concentration during steady state for the IFBA core and large plenum pressures for the gadolinia core design, the analysis demonstrates adequate safety performance during limiting RIA accident scenarios for two representative high burnup core designs. Design changes limiting plenum pressures and implementation of accident tolerant fuel (ATF) cladding features which minimize hydriding and susceptibility to pellet-cladding mechanical interaction (PCMI) are recommended for future high burnup fuel concepts. To support the technical basis for burnup limit increases, high-fidelity fuel performance models are needed to address physical effects not considered in this analysis, and high burnup irradiated fuel tests are required to extend applicability of the fuel failure limits and validate existing and future models.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Modeling Molten Salt Reactor Fission Product Removal with SCALE

Liquid-fuel Molten Salt Reactors (MSRs) allow for continuous online fuel treatment and processing using a variety of subsystems. Among these subsystems, the off-gas system (OGS) continuously removes fission products from the primary fuel salt through a helium sparging process. Accurately modeling fission product behavior is paramount for the development of MSRs; while there are a variety of depletion modeling and simulation tools that allow for removal of material from a defined system, most of them work in a semicontinuous, batch-wise manner. The new tools implemented into TRITON, in the SCALE suite for reactor analysis and design, aim to address this issue by implementing truly continuous material feeds and removals. In addition, material accountancy is enhanced in these tools, which enable tracking of removed material in user-specified mixtures. These continuous depletion tools provide a way to model material transport throughout systems more efficiently and accurately. This report validates the new SCALE MSR modeling capabilities using data from the Molten Salt Reactor Experiment (MSRE). After a framework was established for deriving realistic removal rates based on design specifications, these rates were used by TRITON to continuously remove specific elements while performing burnup calculations. Results were compared to those obtained in MSRE, with a focus on the 135 Xe poison fraction. After these capabilities were validated, the learned concepts and best practices were applied to model the Molten Salt Breeder Reactor (MSBR) and the Molten Salt Demonstration Reactor (MSDR) to study the effects of continuous fission product removal in fuel salt reactivity, as well as the lifetime effects.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

Preliminary Benchmark Uncertainties for Deimos, a HALEU-Fueled and Graphite-Moderated Advanced Reactor Testbed

Many advanced reactor concepts will make use of various uranium fuels with levels of enrichment higher than previously seen in current light water reactors. In particular, High-Assay Low Enriched Uranium (HALEU), that is uranium enriched to 235 U ≈ 20 w/o%, is planned to be used in over ten new reactor concepts. HALEU is attractive for advanced reactors as it enables longer intervals between refueling. Unfortunately, little to no experience with HALEU is available in experimental literature raising concerns for not only licensing advanced re actors but also fabrication and transportation of HALEU fuels. This is where Deimos, a Los Alamos National Laboratory internal project, comes in. Deimos is a new critical experiment scheduled for FY24 at the National Criticality Experiments Research Center (NCERC). Deimos is a graphite moderated, graphite and beryllium reflected critical experiment making use of HALEU TRi-structural ISOtropic (TRISO) fuel from the Compact Nuclear Power System (CNPS). This transaction entails a brief description of efforts to benchmark Deimos for inclusion into the International Criticality Safety

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

High-burnup Experiments in Reactivity Initiated Accidents (HERA)

High-burnup Experiments in Reactivity-initiated Accidents (HERA) is a joint experimental program (JEEP) operating within the United States (U.S.) Nuclear Energy Agency’s (NEA’s) framework for irradiation experiments (FIDES). HERA is dedicated to the understanding of light water reactor (LWR) fuel performance at high burnup under reactivity-initiated accidents (RIA). In-pile RIA experiments have been performed on high-burnup fuels (e.g., above 60 gigawatt days per metric ton of uranium [GWd/MTU]) in the CABRI reactor at the Cadarache site in southern France, and the Nuclear Safety Research Reactor (NSRR) in Japan. However, most of these experiments have taken place with heavily corroded Zircaloy claddings with pulse widths that are narrower (e.g., 5 ms – 30 ms full-width-half-max [FWHM]) than what would be likely in a commercial LWR (e.g., 30 ms – 80 ms FWHM). A few tests were performed in the CABRI facility with FWHM up to 76 ms, though only one “blistered” rod experienced cladding failure. Heavy waterside corrosion and narrow pulse widths are both known to increase the vulnerability of LWR fuel to pellet cladding mechanical interaction (PCMI). The HERA proposal is designed to: (1) quantify the impact of pulse width on fuel performance, offering new insight into the applicability of existing data; (2) generate new data on high burnup fuel under pulse conditions prototypic of LWRs; (3) quantify the additional margin provided by modern cladding alloys to PCMI failure limits; and (4) offer improved data for modelers using specially designed tests that eliminate key uncertainties in high-burnup fuel tests.

(HERA)↗

Reduction of Ultrafine Hematite for a Spouting Bed Chemical Looping Process - Presentation

Chemical looping combustion research has been a topic of great interest since the mid-1990s, although the concept can be traced much further back. It is a combustion technology for fuel utilization that uses a two-reactor system to produce a carbon free effluent stream from the air reactor and a carbon dioxide rich stream from the fuel reactor with oxygen shuttled between the reactors with an oxygen carrier. Chemical looping combustion has been studied extensively because of this inherent separation of the carbon dioxide combustion product from the atmospheric nitrogen over that past 25 years with hundreds of research papers and tens of books. The oxygen carrier is, in general, a solid such as naturally occurring hematite or an engineered carrier like a copper and iron oxide supported on alumina. System technical and economic research activities conducted at the National Energy Technology Laboratory have shown that the costs associated with the carrier, initial and replacement, are a significant factor in the economic viability of the technology. To overcome this economic challenge, the work reported on in this paper investigates the use of a waste iron oxide as the chemical looping oxygen carrier. This waste material is quite unique as it has a particle size of 0.7 um. Given the particle size, the reactions are quite fast. However, the development of a contactor reactor to mix the fuel with the carrier is a fluidization challenge as the material is a Geldart group C material and highly cohesive. Normally, Geldart group C materials are fluidized with either a vibrating bed. This technique is acceptable for low temperature pharmaceuticals production but does not lend itself to much larger reactors used for power production or operation at temperatures in the order of 1100 to 1200 C. Therefore, a hydrodynamic solution was needed to break up the cohesive structures to replace the vibration. In this instance, it was hypothesized that a spouting bed of large Geldart group B or Geldart group D particles could provide the necessary energy to break up the cohesive structures of the Geldart group C material. This paper presents the reduction performance for this novel carrier material in a laboratory spouting bed reactor.

Breault, Ronald↗

Multiphysics analysis of fuel fragmentation, relocation, and dispersal susceptibility–Part 3: Thermal hydraulic evaluation of large break LOCA under high-burnup conditions

Increasing the peak rod average burnup of pressurized water reactor (PWR) fuel beyond 62 GWd/tU may increase fuel fragmentation, relocation, and dispersal (FFRD) susceptibility during a large break loss of coolant accident (LBLOCA). TRACE thermal hydraulic (TH) LBLOCA analyses were performed for a realistic 24-month high-burnup PWR equilibrium cycle, to inform subsequent transient BISON high-burnup FFRD susceptibility evaluations. Realistic LBLOCA systems behavior was first established by configuring to and comparing with the BEMUSE OECD LBLOCA benchmark. Fuel and operating conditions were then applied from high-burnup VERA depletion calculations. LBLOCA simulations were performed for 281 selected high-burnup rods, for which transient TH boundary conditions were collected for later use in BISON. The TRACE results indicated that rod linear heat rate (rather than burnup) is the main predictor of peak cladding temperature (PCT) during the event. PCT typically occurred at a local burnup lower than the rod-average burnup, especially for twice-burned fuel.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Advanced Microscopy Report on UCO Fuel Kernels from Selected AGR-1 and AGR-2 Experiments

A variety of neutron irradiation experiments were completed at Idaho National Laboratory (INL) on tristructural isotropic (TRISO) coated particles contained in a graphitic matrix as part of the Advanced Gas Reactor (AGR) fuel development and qualification program. Although the initial advanced microscopy and microanalysis studies on AGR-1 particles focused predominantly on the SiC layer?s role as the main fission-product containment, studies were further expanded to evaluate UCO kernels of selected AGR-1 and AGR-2 coated particles. Fuel kernels tested in the AGR-1 and AGR-2 experiments is composed of a mixture of UO2 and UC, with a nominal as-fabricated stoichiometry of UO1.37 C0.35 and UO1.43 C0.39, respectively. These as-fabricated kernel-stoichiometry values are determined at the completion of kernel fabrication and do not account for any changes that will occur during the subsequent coating and compacting processes.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Credible Criticality Safety Margin in the 30B Package with LEU+ UF 6 and Hypothetical Water Ingress

The commercial nuclear industry is pursuing advancements in fuel and reactor design that increase the uranium enrichment above 5 wt. % 235 U. These advancements will necessitate the ability to transport bulk quantities of UF 6 at increased enrichments. Currently, the 30B cylinder is the primary container used by the industry for UF6 storage and transportation and has a long history of successful shipments. This container can transport up to 2,277 kg of UF 6 at a maximum enrichment of 5 wt. % 235 U. Previous evaluations have assessed the potential impact of criticality safety for 30B transport at higher enrichments but assumed moderator intrusion would not require evaluation. Although current regulations allow for the exception of moderator intrusion for UF6 packages through the design and quality control of the package content, this exception is limited to enrichments up to 5 wt. % 235 U. Thus, an investigation of moderator intrusion into a 30B cylinder should be performed.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Critical and Subcritical Californium Source Driven Noise Analysis Experiments with Fresh PWR Fuels Pins

These experiments were performed in 1983 between August 1 and September 16 and used 35 operational days of critical facility time at the Babcock & Wilcox critical facility in Lynchburg, Va. These measurements were to assess the capability of the Cf source driven noise analysis method to measure the subcriticality of light water reactor fresh fuel configurations. This report documents the experiments of 1983 that were not reported at that time. These measurement with 2.459 wt. % 235 U enriched uranium oxide fresh fuel pins started at the delayed critical configuration of the fully assembled pressurized water reactor (PWR) core configuration with 1511 parts per million (ppm) natural boron (19.8 wt. % 10 B) in the water. This was a cylindrical configuration of 4961 fuel pins. After the initial measurements at delayed criticality, subcritical measurements by the Cf source driven noise analysis method were performed in which the number of detectors and Cf source locations were varied. Additional boron was added to the water moderator and reflector to reduce the neutron multiplication factor, with resulting boron concentrations of 1561, 1613, 1765, 1880, 2104, 2384, 2975, 3606, and 4303 ppm. After the completion of these measurements the increased, the boron concentration was returned to that at delayed critical (1511 ppm) and the reactivity was decreased by reducing the number of fuel pins in steps to 3713, 2553, 1281, 749, and 333 fuel pins and then to that (289) of a s ingle square 17 x 17 pin array, corresponding to a single PW fuel element. For all measurement that started at delayed criticality and then reduced the neutron multiplication factor to various subcritical states, inverse kinetics rod drop measurements at the higher reactivities were also performed but not reported here. At all subcritical states the break frequency noise analysis data was fitted to obtain the prompt neutron decay constant. Some data presented in this report are from notes not in the logbook. The purpose of this report is to document the experimental information for the measurements performed so that a later date someone could perform the required uncertainty and calculational analyses and documentation to use these data for an International Nuclear Criticality Safety Benchmark Program (INCSBEP) or Nuclear Energy Agency (NEA) benchmark. The data from these measurements is available from the Laboratory Records Department of Oak Ridge National Laboratory and the logbook is available from INCSBEP at Idaho National Laboratory.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Comparative analysis of temperature dependent properties of commercial nuclear fuel pellet and surrogates undergoing cracking: A review

A variety of normal and accident scenarios can generate thermal stresses enough to cause cracking in light water reactor (LWR) fuel. To better understand this behavior, cracking experiments have been carried out to induce thermal gradients in fuel pellets via induction heating and direct resistance heating. In this study, Ceria (CeO 2 ) and yttria stabilized zirconia (YSZ) pellets were chosen as a surrogate fuel material for uranium dioxide (UO 2 ). Induction heating was done using copper coils and molybdenum susceptors which heated the surrogates to a threshold temperature that is sufficiently high for the fuel material to conduct current. Thereafter, direct resistance heating was achieved by passing current through the specimen using a DC power supply to introduce volumetric heating to replicate reactor operating conditions. Simultaneous real-time dual imaging of the ceria pellet surface has been designed using optical and infra-red camera system to capture images of cracks and full-field temperature gradients on pellet. It was observed that YSZ pellets need a much higher voltage-current for volumetric heating and do not exhibit the cracking pattern as ceria and UO 2 , hence YSZ was ruled out for further consideration. Ceria was found to be an appropriate surrogate for UO 2 . Furthermore, the experimental set up and test conditions demand the need to primarily understand the thermo-physical, mechanical and optical properties of UO 2 and the surrogates. Thus, it is essential to have an in-depth knowledge about the various temperature dependent properties of UO 2 and CeO 2 for establishing a comparative analysis between the surrogate and UO 2 for conducting experiments.

36 MATERIALS SCIENCE↗

Radial Deconsolidation and Leach-Burn-Leach of AGR-3/4 Compact 1-4 and 10-4

The Advanced Gas Reactor (AGR) Fuel Development and Qualification Program third and fourth irradiation experiments (AGR-3/4), originally planned as separate tests, were combined in one test train for irradiation in the Advanced Test Reactor at Idaho National Laboratory (INL). The irradiation test began on December 14, 2011 and ended on April 12, 2014 (Collin 2016). The originally planned AGR-3 and AGR-4 irradiation experiments were both focused on obtaining data on fission product transport to support the improvement of modeling. The AGR-3 experimental plan was focused on gaseous and metallic fission product release from the kernels and diffusion in the coatings during irradiation and postirradiation safety testing. The AGR-4 experimental plan was focused on diffusivities and sorptivities in the compact matrix and reactor graphite (Petti et al. 2005). These two goals were combined in the AGR-3/4 irradiation, which consisted of twelve independently monitored capsules that each contained four AGR-3/4 compacts in a single stack surrounded by an inner ring of matrix or graphite and an outer ring of graphite. There were two capsule types: a standard capsule and a “fuel body”, in which the outer graphite ring included a floor and cap that fully enclosed the fuel (Stempien et al. 2018a). The fuel body design supported post-irradiation safety testing of the intact fuel and ring assembly to provide data on fission product transport and release from matrix and graphite at accident temperatures (Demkowicz 2017).

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗