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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 739 records · Page 41
All sourcesNASA NTRSDOE OSTI
DOE OSTI2023

Advanced Mineral Separations with Novel Simulated Moving Beds

Lithium is a critical mineral that is widely used in batteries and energy storage applications, making it increasingly important in the next few decades. To meet the growing demand for lithium and secure domestic supply chains, there is a need to exploit unconventional lithium resources. However, utilizing current lithium extraction processes is challenging due to the high salinity in those resources. Thus, it is essential to develop energy-efficient, and less chemical-intensive separation processes that can exploit high-salinity lithium resources. Accordingly, this project aims to design a novel zwitterionic stationary phase and use it to develop a continuous chromatography process to recover LiCl minerals from traditionally unexploited domestic saline resources. The developed zwitterionic stationary phase allows fractionating minerals based on their different sorbent affinities under water elution. A systematically designed continuous process can separate lithium from other minerals, reducing the risk of material fouling and the overall chemical consumption to produce battery-grade lithium. This approach is expected to significantly enhance the efficiency and sustainability of the lithium extraction process while also reducing the environmental impact associated with traditional processes. At the end of the project, the technology will be demonstrated in continuous mode using a simulated moving bed (SMB) to recover >100 g of LiCl from real resource waters. The U.S.-based resources that this project targets for LiCl recovery are formation water, oil-produced water, and geothermal brines, supplied by Standard Lithium Ltd. and Shell Inc, respectively.

critical minerals↗
NASA NTRS1991

Determining the IV fluids required for a ten day medical emergency on Space Station Freedom - Comparison of packaged vs. on-orbit produced solutions

To aid planning for the storage of supplies onboard Space Station Freedom, an estimate was made of the amount of intravenous (IV) fluid required to support a patient who has suffered a medical emergency for a period of up to 10 days. Six different medical scenarios were evaluated, and the volume of IV fluids required for each scenario was estimated. Up to 220 liters of fluid would be required to support a patient for all of the scenarios. When optimizing the volumes to support any single scenario, a total of 123 liters is required. Use of a water polishing system to produce sterile water for injection from potable supplies and on-station formulation of IV fluids results in a smaller mass and volume requirement for the Fluid Therapy Subsystem than carrying prepackaged bags of fluid.

Creager, Gerald J.↗
DOE OSTI2020

Balancing Water Sustainability and Productivity Objectives in Microalgae Cultivation: Siting Open Ponds by Considering Seasonal Water-Stress Impact Using AWARE-US

Microalgae have great potential as an energy crop. Scaling-up algal biofuel production in the United States (US) should be done with careful attention to water stress. This study evaluates the regional and seasonal water-stress impact of potential algae-pond deployments in the US. Three site-selection strategies focusing on biomass yield, water-use efficiency (WUE), and water-stress impact, respectively, are applied and compared to meet a US algae biomass production target of 30 million metric tons/yr ash-free dry weight, which converts to 20.8 billion L renewable diesel, via hydrothermal liquefaction. Ranking algae ponds based on biomass yield leads to freshwater consumption of 2.66 km3/yr, resulting in the highest water-stress impact (39.1 US equivalent km3). Under the WUE scenario, water consumption is reduced by 81%, but biomass yield is reduced by 12%. In contrast, adding a water-stress constraint to the biomass-yield ranking reduces water consumption by 50% and water-stress impact by 97%, with a small yield reduction (1.7%). Results show that pond location has a significant effect on water stress and that water stress is not proportional to water consumption or yield. Furthermore, capturing seasonal water patterns is critical for planning because sites in water-abundant regions can have short-term but significant water-stress impacts.

algae, Biofuel, water scarcity footprint, hydrothe↗
DOE OSTI2025

Reports from the Frontier: Understanding Voltage Losses in Anion Exchange Membrane Water Electrolyzers

With the growth of renewable energy sources, hydrogen is attracting significant attention worldwide as an effective medium for energy storage. “Green hydrogen” is currently produced primarily by water electrolysis in which water is split into hydrogen and oxygen using power from low-carbon energy sources such as wind, solar, and nuclear. Among the low temperature water electrolysis technologies, anion exchange membrane water electrolyzers (AEMWEs) have recently emerged as a promising competitor to traditional alkaline water electrolyzers (AWEs) and proton exchange membrane electrolyzers (PEMELs) due to their potential stack cost reduction in various cell components. In conclusion, favorable aspects of AEMWEs include the use of PGM-free electrocatalysts as well as low-cost membranes, bipolar plates (BPs), and porous transport layers while offering high voltage efficiency and durability.

08 HYDROGEN↗
NASA NTRSDate not supplied

Cloud Condensation Nuclei in the Early Martian Atmosphere

Explanations for how early Mars supported warmer and wetter conditions 3.5 to 4 billion years ago have long been debated. A water cloud greenhouse has been proposed as a mechanism of warming early Mars, but modeling studies of these environments produce mixed results. Studies show that both H 2 O and CO 2 clouds are capable of influencing atmospheric and surface temperatures, but the amount of warming induced is very sensitive to the cloud physics assumptions made. Producing a strong water cloud greenhouse effect is dependent on forming clouds as high in the atmosphere as possible to maximize warming. However, the majority of studies of H 2 O and CO 2 clouds on early Mars assume that a constant number of seed nuclei are available at all altitudes for clouds to condense onto. Here we test the validity of this assumption in massive CO 2 atmospheres. Explaining how dust is lofted into the middle atmosphere to serve as seed nuclei for cloud formation is a challenge even for present day Mars. This problem may change in an early Mars environment where having a more massive atmosphere could result in differences in the general circulation, vertical transport, and settling time scales of dust. Here, we begin a first-ever study of the early Mars dust cycle and how it might couple to the water cycle. We present early Mars simulations in which dust is injected at the surface and can be transported throughout the atmosphere. We explore the resulting vertical and horizontal distributions of dust particles and their sizes with an emphasis on the maximum height of the dust. We aim to investigate what the distribution of cloud condensation nuclei may have been on early Mars and how this might impact cloud formation.

Kathryn Steakley↗
NASA NTRS2010

Field Scale Testing of RESOLVE at 2010 ISRU Analog Test

When mankind returns to the moon, there will be one aspect of the architecture that will totally change how we explore the solar system. For the first time in space exploration, we will take the initial steps towards breaking our reliance on Earth-supplied consumables by extracting resources from planetary bodies. Our first efforts in this area, known as In Situ Resource Utilization (ISRU), will be directed at extracting some of the abundant oxygen found in the lunar regolith. But the "holy grail" of lunar ISRU will be finding an exploitable source of lunar hydrogen. If we can find a source of hydrogen that can be reasonably extracted from the regolith, it would provide a foundation for true independence from Earth consumables. With in-situ hydrogen and oxygen (and/or water) we can produce many of the major consumables needed to travel to and operate on a sustainable lunar outpost. We would have water to drink, oxygen to breath, and rocket propellants and fuel cell reagents to enable extended access and operations across the moon. NASA initiated development of an experiment package named RESOLVE (Regolith & Environment Science and Oxygen & Lunar Volatile Extraction) that could be flown to the rim or into a permanently shadowed crater to answer the questions surrounding elevated hydrogen at the lunar poles.

Captain, Janine E.↗
NASA NTRS1998

Requirements for Planetary Outpost Life-Support Systems and the Possible Use of In Situ Resources

If humans are ever to live and work on the Moon or Mars for extended periods of time, the operation of regenerative life-support systems at the planetary outposts will be a critical requirement. The substantial amount of materials consumed by humans and the inevitable waste products make open-loop life-support systems and resupply missions (as used in Space Shuttle and Mir operations) impractical and expensive. Natural resources found on the Moon and Mars could be used in conjunction with regenerative life support systems to further reduce the amount of material that would need to be delivered from Earth. There have been numerous studies and experiments conducted on the production of O from regolith materials on the Moon and from the atmosphere of Mars. One or several of these processes could undoubtedly be used to produce the O required by the crews at planetary outposts. Water is required in the greatest quantities, primarily for tasks such as personal hygiene and clothes washing, and it will be the most precious consumable. Again, several process have been described to produce water on the Moon using solar-wind implanted H and O, and if water ice can be found and mined at the lunar poles, another source of water may be available.

Gruener, John E.↗
NASA NTRS1961

Landing Characteristics of a Lenticular-Shaped Reentry Vehicle

An experimental investigation was made of the landing characteristics of a 1/9-scale dynamic model of a lenticular-shaped reentry vehicle having extendible tail panels for control after reentry and for landing control (flare-out). The landing tests were made by catapulting a free model onto a hard-surface runway and onto water. A "belly-landing" technique in which the vehicle was caused to skid and rock on its curved undersurface (heat shield), converting sinking speed into angular energy, was investigated on a hard-surface runway. Landings were made in calm water and in waves both with and without auxiliary landing devices. Landing motions and acceleration data were obtained over a range of landing attitudes and initial sinking speeds during hard-surface landings and for several wave conditions during water landings. A few vertical landings (parachute letdown) were made in calm water. The hard-surface landing characteristics were good. Maximum landing accelerations on a hard surface were 5g and 18 radians per sq second over a range of landing conditions. Horizontal landings on water resulted in large violent rebounds and some diving in waves. Extreme attitude changes during rebound at initial impact made the attitude of subsequent impact random. Maximum accelerations for water landings were approximately 21g and 145 radians per sq second in waves 7 feet high. Various auxiliary water-landing devices produced no practical improvement in behavior. Reduction of horizontal speed and positive control of impact attitude did improve performance in calm water. During vertical landings in calm water maximum accelerations of 15g and 110 radians per sq second were measured for a contact attitude of -45 deg and a vertical velocity of 70 feet per second.

Blanchard, Ulysse J.↗
NASA NTRS1974

Microwave profiling of snowpack free-water content

A microwave system is proposed to measure the amount of liquid-phase water in a snowpack operating in the range of 1 to 10 GHz. Attenuation of the beam between source and receivers is produced by the water in the snow. The relationships of frequency, distance, and volume percent of water are calculated for an assumed detector sensitivity, together with the estimated cost of a representative system. A laboratory test is described that shows the attenuation for snow at maximum wetness at 9.35 GHz. A configuration is proposed that involves a vertical tube containing microwave and radioactive sources and another vertical tube containing microwave and gamma-ray detectors, so that density and wetness profiles are obtained simultaneously over essentially the same path.

Linlor, W. I.↗
NASA NTRS1977

Variability of wetland reflectance and its effect on automatic categorization of satellite imagery

The author has identified the following significant results. Land cover categorization of data from the same overpass in four test wetland areas was carried out using a four category classification system. The tests indicate that training data based on in situ reflectance measurements and atmospheric correction of LANDSAT data can produce comparable accuracy of categorization to that achieved using more than four wetlands cover categories (salt marsh cordgrass, salt hay, unvegetated, and water tidal flat) produced overall classification accuracies of 85% by conventional and relative radiance training and 81% by use of in situ measurements. Overall mapping accuracies were 76% and 72% respectively.

Klemas, V.↗
DOE OSTI2026

Designing the Platinum Catalyst Layer for Improved Performance and Durability in Anion Exchange Membrane Water Electrolysis

To lower the cost of hydrogen produced by anion exchange membrane water electrolysis (AEMWE), it is critical to reduce the use of platinum group metal (PGM) catalysts within the device. While iridium has been successfully replaced with PGM-free catalysts at the anode, platinum-based (Pt) cathode catalysts are still required to meet the activity and durability targets. This study investigates the impact of commercial Pt/C catalyst loading, ionomer type and content, and electrode fabrication method on the cathode catalyst layer properties and AEMWE performance with the aim of determining the feasibility of reduced Pt loadings. While increased Pt loading is found to improve beginning-of-life performance, the effects are minimal above 0.6 mg/cm 2 . Ink characterization shows that ionomer type and content affect the ink stability, particle size, and percent of unbound ionomer, which further impact the homogeneity of the sprayed catalyst layers. The 5% PiperION cathode exhibited the highest performance, which may be attributed to a balance between the small particle size and the low proportion of unbound ionomer, minimizing kinetic and transport losses. Theoretical calculations show that the ionomers interact differently with the Pt surface, causing different surface charges and water adsorption strength and activating different mechanisms for hydrogen evolution. Pt-PiperION lowered the enthalpy of water-splitting by 0.1 eV compared to Pt alone and allowed for equal site access between adsorbed H* and OH* (both adsorbed at circa −2.2 eV). Although catalyst-coated membrane (CCM) fabrication techniques are desirable for scale-up, no performance enhancement is observed compared with the catalyst-coated substrate approach. Durability, as measured by degradation rates, Pt loss, and catalyst layer restructuring, was found to improve with increased Pt loadings, higher ionomer content, and CCM architectures. These findings provide important insight into the significant role of the cathode in AEMWE and strategies for maintaining the performance with low Pt loading or PGM-free catalysts.

08 HYDROGEN↗
DOE OSTI2021

The FLOod Probability Interpolation Tool (FLOPIT): A Simple Tool to Improve Spatial Flood Probability Quantification and Communication

Understanding flood probabilities is essential to making sound decisions about flood-risk management. Many people rely on flood probability maps to inform decisions about purchasing flood insurance, buying or selling real-estate, flood-proofing a house, or managing floodplain development. Current flood probability maps typically use flood zones (for example the 1 in 100 or 1 in 500-year flood zones) to communicate flooding probabilities. However, this choice of communication format can miss important details and lead to biased risk assessments. Here we develop, test, and demonstrate the FLOod Probability Interpolation Tool (FLOPIT). FLOPIT interpolates flood probabilities between water surface elevation to produce continuous flood-probability maps. FLOPIT uses water surface elevation inundation maps for at least two return periods and creates Annual Exceedance Probability (AEP) as well as inundation maps for new return levels. Potential advantages of FLOPIT include being open-source, relatively easy to implement, capable of creating inundation maps from agencies other than FEMA, and applicable to locations where FEMA published flood inundation maps but not flood probability. Using publicly available data from the Federal Emergency Management Agency (FEMA) flood risk databases as well as state and national datasets, we produce continuous flood-probability maps at three example locations in the United States: Houston (TX), Muncy (PA), and Selinsgrove (PA). We find that the discrete flood zones generally communicate substantially lower flood probabilities than the continuous estimates.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS1983

Classification and area estimation of land covers in Kansas using ground-gathered and LANDSAT digital data

Ground-gathered data and LANDSAT multispectral scanner (MSS) digital data from 1981 were analyzed to produce a classification of Kansas land areas into specific types called land covers. The land covers included rangeland, forest, residential, commercial/industrial, and various types of water. The analysis produced two outputs: acreage estimates with measures of precision, and map-type or photo products of the classification which can be overlaid on maps at specific scales. State-level acreage estimates were obtained and substate-level land cover classification overlays and estimates were generated for selected geographical areas. These products were found to be of potential use in managing land and water resources.

May, G. A.↗
DOE OSTI2022

Effects of plasma on physical properties of water: nanocrystalline-to-amorphous phase transition and improving produce washing

Recently is was discovered in various applications that many physical and chemical properties of water change their temperature dependence between about 35 and 60 degrees Celsius. In particular, heat conductance, light absorption, and surface tension all change their temperature dependence. These drastic changes were associated with water gradually changing its mesoscopic structure: while at the higher temperatures water is a uniform media (amorphous state), at the temperatures below transition it consists of many nano-to-micro-scale clusters (crystalline state). This transition is similar to the second order phase transition. In the present paper we show that treating water with non-thermal plasma (adding plasma-created active compounds) can lower the temperature of the transition and thus cause a significant change in such physical quantities as surface tension, viscosity, freezing rate, and wettability and washability. We present analytical estimates of the transition temperature shift based on the Debye-Hückel theory. We discuss the produce-washing experiments that illustrate the predicted effects.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
NASA NTRS2012

Optimization of a Nafion Membrane-Based System for Removal of Chloride and Fluoride from Lunar Regolith-Derived Water

A long-term human presence in space will require self-sustaining systems capable of producing oxygen and potable water from extraterrestrial sources. Oxygen can be extracted from lunar regolith, and water contaminated with hydrochloric and hydrofluoric acids is produced as an intermediate in this process. We investigated the ability of Nafion proton exchange membranes to remove hydrochloric and hydrofluoric acids from water. The effect of membrane thickness, product stream flow rate, and acid solution temperature and concentration on water flux, acid rejection, and water and acid activity were studied. The conditions that maximized water transport and acid rejection while minimizing resource usage were determined by calculating a figure of merit. Water permeation is highest at high solution temperature and product stream flow rate across thin membranes, while chloride and fluoride permeation are lowest at low acid solution temperature and concentration across thin membranes. The figure of merit varies depending on the starting acid concentration; at low concentration, the figure of merit is highest across a thin membrane, while at high concentration, the figure of merit is highest at low solution temperature. In all cases, the figure of merit increases with increasing product stream flow rate.

Anthony, Stephen M.↗
NASA NTRS1982

Hydrodynamic and aerodynamic breakup of liquid sheets

The effect of hydrodynamic, aerodynamic and liquid surface forces on the mean drop diameter of water sprays that are produced by the breakup of nonswirling and swirling water sheets in quiescent air and in airflows similar to those encountered in gas turbine combustors is investigated. The mean drop diameter is used to characterize fuel sprays and it is a very important factor in determining the performance and exhaust emissions of gas turbine combustors.

Ingebo, R.↗
NASA NTRS1995

Far-Infrared Water Line Emissions from Circumstellar Outflows

We have modeled the far-infrared water line emission expected from circumstellar outflows from oxygen-rich late-type stars, as a function of the mass-loss rate and the terminal outflow velocity. For each mass-loss rate and terminal outflow velocity considered, we computed self-consistently the gas density, temperature, outflow velocity, and water abundance as a function of distance from the star. We then used an escape probability method to solve for the equilibrium level populations of 80 rotational states of water and thereby obtained predictions for the luminosity of a large number of far-infrared rotational transitions of water. In common with previous models, our model predicts that water will be copiously produced in the warm circumstellar gas and that water rotational emission will dominate the radiative cooling. However, our use of a realistic radiative cooling function for water leads to a lower gas temperature than that predicted in previous models. Our predictions for the far-infrared water line luminosities are consequently significantly smaller than those obtained in previous studies. Observations to be carried out by the Infrared Space Observatory will provide a crucial test of the models presented here.

Chen, Wesley↗