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At least 739 records · Page 41

Petrology and geochemistry of olivine-normative and quartz-normative basalts from regolith breccia 15498 - New diversity in Apollo 15 mare basalts

Analysis of mare basalt clasts from Apollo 15 shows a greater diversity than previously recognized and provides new constraints on the petrogenesis of these basalts. The quartz-normative basalts (QNB) from 15498 are divided into four groups based on chemical variations: primitive, intermediate/1, intermediate/2, and evolved. The olivine-normative basalts (ONB) are divided into three groups: low-SiO2, high-SiO2, and olivine-pyroxene cumulates. Least-squares mixing calculations show that the high SiO2 ONBs may be parental to the QNB suite. Variations within the low-SiO2 ONBs are explained by olivine factionation. It is suggested that the presence of these basalt types may result from the position of breccia 15498 near the edge of the mare plain where normal ONBs are scarce, and from its presumed origin as ejecta from Dune Crater.

Vetter, Scott K.↗

Evidence from the Semarkona ordinary chondrite for Al-26 heating of small planets

The first observation of radiogenic Mg-26 in nonrefractory meteoritic material, a plagioclase-bearing, olivine-pyroxene clast chondrule in the Semarkona ordinary chondrite, is reported. The inferred initial abundance of Al-26 is sufficient to produce incipient melting in well-insulated bodies of chondritic composition. It is concluded that planetary accretion and diffentiation must have begun on a timescale comparable to the half-life of Al-26 and that, even if widespread melting did not occur, Al-26 heating played a significant role in thermal metamorphism on small planets.

Hutcheon, I. D.↗

Millimeter petrology and kilometer mineralogical exploration of the moon

Coordinated petrologic and spectroscopic analyses were undertaken for a specially prepared 1-cm chip of regolith breccia 60019. The mafic minerals of each large clast were readily identified from spectral reflectance measurements of the same clasts, and mineral abundance was shown to be directly related to absorption strength. Although most clasts of 60019 are noritic in composition, the presence of abundant olivine and/or high-Ca pyroxene in several clasts is easily noted spectroscopically. The origin of an unusual absorption feature near 0.6 micron in an anorthositic clast was determined by petrographic analysis to be due to very fine-grained translucent ilmenite. The 60019 matrix is dark and glassy, and although a variety of clasts occur on all scales, particulate powders of 60019 are all very similar and have spectral properties that indicate a noritic breccia bulk composition.

Pieters, C. M.↗

High alumina (HA) and very high potassium (VHK) basalt clasts from Apollo 14 breccias. I - Mineralogy and Petrology - Evidence of crystallization from evolving magmas

The mineralogy and petrography of very high potassium (VHK) and high alumina (HA) basalts from the Apollo 14 site provide an insight into their magmatic evolution. Generally, their parageneses are similar, with olivine and chromite the early liquidus phases, followed by plagioclase and pyroxene, which crystallized together. Although late-stage ilmenite and FeNi metal occur in both VHK and HA samples, the VHKs also crystallize K-feldspar and Fa-rich olivine. Zoning of constituent minerals is similar for both basalt types, demonstrating that the parental magmas for both HA and VHK basalts became enriched in K, Na, Ca, Fe, and Ti and depleted in Mg and Al as crystallization proceeded. Enrichment of K in the VHK basalts is above that expected from normal fractional crystallization.

Neal, C. R.↗

Chemical and isotopic constraints on the petrogenesis of the large mare basalt clast in breccia 15459

Results are presented that demonstrate that the large mare basalt clast in Apollo 15 breccia 15459 may represent one or more independent magma types. The complex nonequilibrium pyroxene and plagioclase compositions and relatively abundant mesostasis suggest that the 15459 clast is not a slowly cooled crystal cumulate. The addition of about 40 percent olivine to an olivine-normative basalt parental magma is found to be necessary to explain the high MgO abundances of picritic basalts by the accumulation of olivine in the magma. The present clast has a slightly younger age and a slightly higher Sr-87/Sr-86 ratio than most Apollo 15 basalts.

Nyquist, L.↗

Remote sensing and geologic studies of localized dark mantle deposits on the moon

Localized lunar dark mantle deposits (LDMD) are small, smooth low-albedo units of pyroclastic origin commonly found associated with endogenic source craters. Analysis of near-infrared spectra, multispectral images, and radar data obtained for 25 LDMD has led to the identification of three compositional groups of LDMD. Group 1 deposits are composed predominantly of highlands-rich wall rock but also contain a substantial juvenile component, Group 2 deposits are composed largely of mare plug rock material, while Group 3 deposits are rich in a mixture of olivine and pyroxene. Variations in eruption conditions are interpreted to be largely responsible for the varying mineralogy of these three types of deposits.

Hawke, B. R.↗

An alternate hypothesis for the origin of Angra dos Reis - Porphyry, not cumulate

The Angra dos Reis achondrite is a unique meteorite of potentially great importance for understanding the origins of the solar system and of the terrestrial planets. It is proposed that the meteorite, which consists of megacrysts of Al-Ti augite (fassaite) in skeletal or cellular shapes, olivine, and possibly whitlockite in a fine-grained groundmass of the same materials plus spinel, is a porphyritic igneous rock modified by metamorphism. In this interpretation, the megacrysts represent cellular-textured phenocrysts, and the fine-grain groundmass represents crystallized or devitrified magma. Phase equilibria suggest that Angra dos Reis-like compositions could grow phenocrysts of fassaite pyroxene, olivine, and whitlockite. These same compositions could crystallize, without crystal sorting or accumulation, to an almost monomineralic fassaite pyroxenite.

Treiman, A. H.↗

Allan Hills 84025 - The second brachinite, far more differentiated than brachina, and an ultramafic achondritic clast from L chondrite Yamato 75097

New bulk-compositional and petrographic data tend to confirm that dunitic-wehrlitic meteorite ALH84025 is a second brachinite. It is suggested here that ALH84025 originated as an olivine heteradcumulate, whereas Brachina, or ALH84025, originated as an olivine orthocumulate. The tendency for pyroxenes among brachinites to be high-Ca may be a consequence of a relatively low MgO/FeO ratio, and/or high Na/Ca and K/Ca ratios in the bulk parent body. New data for a 2.5-cm dunite-melatroctolite clast from L6 chondrite Y75097 are reported. This clast has experience depletion of middle REE, except for a large (+) Eu anomaly. The clast as a whole is enriched in phosphates, but almost exclusively in its least-metamorphosed 'core' portion, whereas the analyzed samples represent phosphate-poor portions. It is suggested that this bizarre assemblage probably originated as an achondrite containing cumulus olivine, plagioclase, and phosphate, not necessarily all from a single igneous source rock.

Warren, P. H.↗

The spectral properties of collected interplanetary dust particles

The observed spectral and mineralogical properties of interplanetary dust particles (IDP) allows the conclusion that: (1) the majority of IDP infrared spectra are dominated by olivine, pyroxene, or layer lattice silicate minerals, (2) to the first order the emission spectra of comets Halley and Kohoutek can be matched by mixtures of these IDP infrared types, implying that comets contain mixtures of these different crystalline silicates and may vary from comet to comet and perhaps even within a single comet, (3) do not expect to observe a single 20 micron feature in cometary spectra, (4) carbonaceous materials dominate the visible spectra properties of the IDPs even though the mass in these particles consists primarily of silicates, and (5) the particle characteristics summarized need to be properly accounted for in future cometary emission models.

Sandford, S. A.↗

Neon isotope studies of Fayetteville and Kapoeta meteorites and clues to ancient solar activity

Under the assumption that the solar-flare bombardment of the irradiated grains of gas-rich meteorites occurred about 4.5 b.y. ago on the parent body regoliths at 3 A.U., an estimate of the solar cosmic ray-produced Ne-21 is made by studying etched pyroxene minera separates from both light and dark portions of the gas-rich meteorites Fayetteville and Kapoeta. Excesses of solar cosmic ray Ne-21 were observed in dark portions of these meteorites, after accounting for their galactic cosmic ray Ne-21 production and solar flare Ne-21. In order to produce the estimated solar cosmic ray Ne-21 in the present samples, highly enhanced solar cosmic ray proton fluxes from the ancient sun are required.

Padia, J. T.↗

Chemical, isotopic and mineralogical evidence for the origin of matrix in ordinary chondrites

Results are presented of a combined chemical, isotopic, and mineralogical study of fine-grained opaque matrix material from a type-3 ordinary chondrite Allan Hills A77299. It was found that the matrix of this chondrite (in contrast to chondrules) shows no siderophile element depletions and is remarkably unfractionated relative to CI chondrites. It was also found that the matrix lump has a unique oxygen isotopic composition which lies below the terrestrial fractionation line and differs markedly from the composition of fine-grained matrix lumps and chondrule rims from Semarkona chondrules (Grossman and Wasson, 1987; Grossman et al., 1987); the mineralogy and textures of the matrix lump (which consists of rare angular grains of pyroxene and olivine embedded within a ground-mass of rounded fine-grained olivines), as well as its major element composition, are typical of matrix material of other type-3 chondrites studied. It is concluded that the matrix lump in these chondrites consists largely of material that formed by annealing of amorphous presolar dust or nebular condensates.

Brearley, Adrian J.↗

Electron beam analysis of particulate cometary material

Electron microscopy will be useful for characterization of inorganic dust grains in returned comet nucleus samples. The choice of instrument(s) will depend primarily on the nature of the samples, but ultimately a variety of electron-beam methods could be employed. Scanning and analytical (transmission) electron microscopy are the logical choise for morphological, mineralogical, and bulk chemical analyses of dust grains removed from ices. It may also be possible to examine unmelted ice/dust mixtures using an environmental scanning electron microscope equipped with a cryo-transfer unit and a cold stage. Electron microscopic observations of comet nuclei might include: (1) porosities of dust grains; (2) morphologies and microstructures of individual mineral grains; (3) relative abundances of olivine, pyroxene, and glass; and (4) the presence of phases that might have resulted from aqueous alteration (layer silicates, carbonates, sulfates).

Bradley, John↗

An olivine-microchondrule-bearing clast in the Krymka meteorite

A small (150 x 200-micron-size) clast consisting of 20 vol pct olivine microchondrules (with barred and granular textures) and 80 vol pct recrystallized silicate matrix material occurs in Krymka (LL3.1). This is the fourth microchondrule-bearing clast to be described. The chondrules are zoned in FeO with concentrations increasing toward the surface. The clast most closely resembles a previously described radial-pyroxene-microchondrule-bearing clast in Piancaldoli (LL3.4).

Rubin, Alan E.↗

Interplanetary dust particles collected in the stratosphere - Observations of atmospheric heating and constraints on their interrelationships and sources

TEM and IR spectroscopy investigations of the interplanetary dust particles (IDPs) collected in the stratosphere have shown the majority of IDPs in the layer-lattice silicate and pyroxene classes to not have been heated to temperatures above 600 C during atmospheric entry. This implies that they arrive at the upper atmosphere with low geocentric encounter velocities, and limits the possible encounter trajectories for these particles to relatively circular prograde orbits. On this basis, it is judged unlikely that these IDPs are from earth-crossing comets or asteroids; collected IDPs dominated by olivine include a larger portion of above-600 C-heated particles, suggesting their capture from more eccentric orbits.

Sandford, Scott A.↗

Molten (Mg0.88Fe0.12)2SiO4 at lower mantle conditions - Melting products and structure of quenched glasses

Infrared spectra of quenched magnesium silicate glasses synthesized by fusing olivine at pressures in excess of 50 GPa and temperatures greater than 2500 K demonstrate that silicon is dominantly present in four-fold coordination with respect to oxygen within these quenched glasses. This low coordination is attributed, by analogy with the structural behavior of glasses compressed at 300 K, to the instability of higher coordinations in glasses of these compositions on decompression. Spectra of glasses formed in a hydrous environment document that water is extensively soluble in melts at these high pressures and temperatures. Also, these results are consistent with the melting of (Mg0.88Fe0.12)2SiO4 compositions to liquids near pyroxene in stoichiometry under these conditions, with iron-rich magnesiowuestite being the liquidus phase.

Williams, Quentin↗

Petrogenesis of mesosiderites. I - Origin of mafic lithologies and comparison with basaltic achondrites

New petrologic and trace element data on basaltic and gabbroic clasts in mesosiderites and basaltic achondrites, combined with existing petrologic and trace element data, have served as a basis for interpretation of the petrogenesis of mesosiderite clasts. Compared with the basaltic achondrites, the mesosiderite basaltic and gabbroic clasts contain more abundant modal tridymite and merrilite, and more commonly contain augite as a late magmatic phase. Their pyroxenes tend to be more MgO-rich, and have lower Fe/Mn ratios which are positively correlated with the Fe/Mg ratio. Some of the mesosiderite basaltic and gabbroic clasts contain xenocrystic plagioclase. The basaltic clasts commonly show superchondritic Eu/Sm ratios and slight LREE depletions. The cumulate gabbro clasts are extremely depleted in LIL, have very high Eu/Sm ratios and high Lu/Sm ratios. All of these features can be explained by a model in which the mafic lithologies of mesosiderites were formed by remelting of a mixed basalt-cumulate gabbro-metal source region near the parent body surface.

Mittlefehldt, David W.↗

Mineralogical comparison of the Y86032-type lunar meteorites to feldspathic fragmental breccia 67016

Mineralogical characteristics of lunar meteorites Y82193 and Y86032 were compared to those of Apollo-16 fieldspathic fragmental breccia 67016, using results from electron microprobe analysis and TEM. It was found that the pyroxene mineralogy and chemistry of granulitic clasts in 67016 breccia and the Y86032-type lunar meteorites were much alike, suggesting that the formation processes of the fieldspathic fragmental breccias are also important in the genesis of lunar meteorites. There were differences in matrix microtextures, however, implying that 67016 and Y86032-type breccia formation temperatures were different.

Takeda, H.↗

Shock-induced temperatures of CaMgSi2O6

Results are presented from experiments on CaMgSi2O6 (diopside) single crystal, an end-member pyroxene relevant to studies of the composition of the earth's mantle. Also, experiments were conducted on diopside glass with a density 86 percent that of the diopside crystal. The shock-induced radiation from diopside is used to constrain the temperature of its shock-compressed (Hugoniot) states. The results are combined with other data to place constraints on the high-pressure phase relations in the CaMgSi2O6 system. These constraints are compared with existing models for the earth's mantle. The results imply that the temperature of the D-double prime region must be less than 3000 K.

Svendsen, Bob↗