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At least 739 records · Page 41

Cryogenic spray vaporization in high-velocity helium, argon and nitrogen gasflows

Effects of gas properties on cryogenic liquid-jet atomization in high-velocity helium, nitrogen, and argon gas flows were investigated. Volume median diameter, D(sub v.5e), data were obtained with a scattered-light scanning instrument. By calculating the change in spray drop size, -Delta D(sub v.5)(exp 2), due to droplet vaporization, it was possible to calculate D(sub v.5C). D(sub v.5C) is the unvaporized characteristic drop size formed at the fuel-nozzle orifice. This drop size was normalized with respect to liquid-jet diameter, D(sub O). It was then correlated with several dimensionless groups to give an expression for the volume median diameter of cryogenic LN2 sprays. This expression correlates drop size D(sub v.5c) with aerodynamic and liquid-surface forces so that it can be readily determined in the design of multiphase-flow propellant injectors for rocket combustors.

Ingebo, Robert D.↗

Studies of liquid metal surfaces using Auger spectroscopy

The surface composition of liquid gallium-tin alloys is studied in an Auger electron spectrometer as a function of bulk composition and temperature. The sessile drop samples are cleaned by argon ion bombardment sputtering of the liquid. This technique produces surfaces that are entirely free of impurities within the sensitivity of the spectrometer and remain so for many days. Tin is found to be strongly adsorbed at the liquid-vacuum interface. Surface concentrations based on Auger measurements are found to be in reasonably good agreement with values calculated from surface tension measurements interpreted in terms of a monolayer depth distribution model for the adsorbed tin.

Hardy, S.↗

Space simulation experiments on reaction control system thruster plumes.

A space simulation procedure was developed for studying rocket plume contamination effects using a 5-lb bipropellant reaction control system thrustor. Vacuum chamber pressures of 0.00003 torr (70 miles altitude) were achieved with the thrustor firing in pulse trains consisting of eight pulses - 50 msec on, 100 msec off, and seven minutes between pulse trains. The final vacuum was achieved by cooling all vacuum chamber surfaces to liquid-helium temperature and by introducing a continuous argon leak of 48 std. cc/sec into the test chamber. Fast time response liquid flow rate measurements showed that large variations occurred in the ratio of oxidizer to fuel flow for pulse-on times up to 120 msec. These variations could lead to poor combustion efficiency and the production of contamination.

Cassidy, J. F.↗

Revisiting the pseudo-supercritical path method: An improved formulation for the alchemical calculation of solid–liquid coexistence

Alchemical free energy calculations via molecular dynamics have been applied to obtain thermodynamic properties related to solid–liquid equilibrium conditions, such as melting points. In recent years, the pseudo-supercritical path (PSCP) method has proved to be an important approach to melting point prediction due to its flexibility and applicability. In the present work, we propose improvements to the PSCP alchemical cycle to make it more compact and efficient through a concerted evaluation of different potential energies. The multistate Bennett acceptance ratio (MBAR) estimator was applied at all stages of the new cycle to provide greater accuracy and uniformity, which is essential concerning uncertainty calculations. In particular, for the multistate expansion stage from solid to liquid, we employed the MBAR estimator with a reduced energy function that allows affine transformations of coordinates. Free energy and mean derivative profiles were calculated at different cycle stages for argon, triazole, propenal, and the ionic liquid 1-ethyl-3-methyl-imidazolium hexafluorophosphate. Comparisons showed a better performance of the proposed method than the original PSCP cycle for systems with higher complexity, especially the ionic liquid. Furthermore, a detailed study of the expansion stage revealed that remapping the centers of mass of the molecules or ions is preferable to remapping the coordinates of each atom, yielding better overlap between adjacent states and improving the accuracy of the methodology.

25 ENERGY STORAGE↗

Space transportation systems, 1980-2000

An overview of projected space transportation systems for the 1980-2000 period is presented. Methods for meeting the requirements in that area are documented through a description of the Space Shuttle and its current upper stages, reusable transfer vehicles, Shuttle uprating, fully reusable and single-stage transports, heavy lift vehicles, and advanced vehicles for orbital transfer and lunar landing. The structure of the liquid oxygen/liquid hydrogen boosters, cryogenic propellants, whose main propulsion system is a derivative of the RL-10 engine used in the Centaur launch, and mixed mode propulsion engine is also described, as is the flyback booster concept and such related issues as propellants and rocket engines, staging velocity, configuration shape, and whether it should be manned or unmanned. Especially noted are proposed propulsion systems going beyond the present Shuttle such as the nuclear and electric propulsion concepts, the resistojet, using liquid hydrogen, ion thruster, using argon, magnetoplasmadynamic thrusters, solar thermal rocket, and solar sail concept where the basic idea is to use a 'sail' of thin reflective material to generate a net force by reflection of solar radiation.

Cohan, C. J.↗

Cryogenic liquid-jet breakup in two-fluid atomizers

A two-fluid atomizer was used to study the breakup of liquid-nitrogen jets in nitrogen, argon, and helium atomizing gas flows. A scattered-light scanner particle sizing instrument previously developed at NASA Lewis Research Center was further developed and used to determine characteristic drop diameters for the cryogenic sprays. In the breakup regime of aerodynamic-stripping, i.e., sonic-velocity conditions, the following correlation of the reciprocal Sauter mean diameter, D(sub 32)exp -1, with the atomizing-gas flowrate, W(g), was obtained: D(sub 32)exp -1 = k(sub c)(W(g)exp 1.33), where k(sub c) is a proportionality constant evaluated for each atomizing gas. Values of k(sub c) = 120, 220, and 1100 were obtained for argon, nitrogen, and helium gasflows, respectively. The reciprocal Sauter mean diameter and gas flowrate have the units of 1/cm and g/sec, respectively. In the regime of capillary-wave breakup, or subsonic conditions, it was found that D(sub 32)exp -1 = k(g)(W(g)exp 0.75), where k = 270, 390, and 880 for argon, nitrogen, and helium gasflows, respectively.

Ingebo, Robert D.↗

Shadowgraphy of transcritical cryogenic fluids

The future of liquid-rocket propulsion depends heavily on continued development of high pressure liquid oxygen/hydrogen systems that operate near or above the propellant critical states; however, current understanding of transcritical/supercritical injection and combustion is yet lacking. The Phillips Laboratory and the United Technologies Research Center are involved in a collaborative effort to develop diagnostics for and make detailed measurements of transcritical droplet vaporization and combustion. The present shadowgraph study of transcritical cryogenic fluids is aimed at providing insight into the behavior of liquid oxygen or cryogenic stimulants as they are injected into a supercritical environment of the same or other fluids. A detailed history of transcritical injection of liquid nitrogen into gaseous nitrogen at reduced pressures of 0.63 (subcritical) to 1.05 (supercritical) is provided. Also, critical point enhancement due to gas phase solubility and mixture effects is investigated by adding helium to the nitrogen system, which causes a distinct liquid phase to re-appear at supercritical nitrogen pressures. Liquid oxygen injection into supercritical argon or nitrogen, however, does not indicate an increase in the effective critical pressure of the system.

Woodward, R. D.↗

Generation of reactive species in water film dielectric barrier discharges sustained in argon, helium, air, oxygen and nitrogen

Activation of liquids with atmospheric pressure plasmas is being investigated for environmental and biomedical applications. When activating the liquid using gas plasma produced species (as opposed to plasmas sustained in the liquid), a rate limiting step is transport of these species into the liquid. To first order, the efficiency of activating the liquid is improved by increasing the ratio of the surface area of the water in contact with the plasma compared to its volume—often called the surface-to-volume ratio (SVR). Maximizing the SVR then motivates the plasma treatment of thin films of liquids. In this paper, results are discussed from a computational investigation using a global model of atmospheric pressure plasma treatment of thin water films by a dielectric barrier discharge (DBD) sustained in different gases (Ar, He, air, N 2 , O 2 ). The densities of reactive species in the plasma activated water (PAW) are evaluated. The residence time of the water in contact with the plasma is increased by recirculating the PAW in plasma reactor. Longer lived species such as H 2 O 2aq and NO 3 - aq accumulate over time (aq denotes an aqueous species). DBDs sustained in Ar and He are the most efficient at producing H 2 O 2aq , DBDs sustained in argon produces the largest density of NO 3 - aq with the lowest pH, and discharges sustained in O 2 and air produce the highest densities of O 3aq . Finally, comparisons to experiments by others show agreement in the trends in densities in PAW including O 3aq , OH aq , H 2 O 2aq and NO 3 - aq , and highlight the importance of controlling desolvation of species from the activated water.

42 ENGINEERING↗

Characterization of spurious-electron signals in the double-phase argon TPC of the DarkSide-50 experiment

Spurious-electron signals in dual-phase noble-liquid time projection chambers have been observed in both xenon and argon Time Projection Chambers (TPCs). This paper presents the first comprehensive study of spurious electrons in argon, using data collected by the DarkSide-50 experiment at the INFN Laboratori Nazionali del Gran Sasso (LNGS). Understanding these events is a key factor in improving the sensitivity of low-mass dark matter searches exploiting ionization signals in dual-phase noble liquid TPCs. We find that a significant fraction of spurious-electron events, ranging from 30 to 70% across the experiment's lifetime, are caused by electrons captured from impurities and later released with delays of order 5-50 ms. The rate of spurious-electron events is found to correlate with the operational condition of the purification system and the total event rate in the detector. Finally, we present evidence that multi-electron spurious electron events may originate from photo-ionization of the steel grid used to define the electric fields. These observations indicate the possibility of reduction of the background in future experiments and hint at possible spurious electron production mechanisms.

Agnes, P. [GSSI, Aquila; Gran Sasso]↗

Two systems developed for purifying inert atmospheres

Two systems, one for helium and one for argon, are used for purifying inert atmospheres. The helium system uses an activated charcoal bed at liquid nitrogen temperature to remove oxygen and nitrogen. The argon system uses heated titanium sponge to remove nitrogen and copper wool beds to remove oxygen. Both use molecular sieves to remove water vapor.

Foster, M. S.↗

Suppression of Marangoni Convection in Float Zones

The basic purpose of this program is to demonstrate by means of an Earth-based 1-g experiment that the undesirable Marangoni (surface tension) convection can be suppressed or significantly reduced by means of gas jets directed tangentially to the free surface of the liquid in a float zone. These jets will establish the tangential shear stress field over the surface which must be adjusted to equal the counter-stress resultant of the Marangoni shear stress which causes the convection. For proposed materials processing in space (o-g), particularly of important, highly reactive semiconductor materials, e.g., silicon, microgravity will virtually eliminate the unwanted thermal-buoyancy convection in the liquid silicon, but will have no effect in reducing the Marangoni convection. Unless this can be sufficiently suppressed by other means, there may be no significant advantages to the proposed space processing of reactive semiconductors. Although some inert gas such as argon must be used for the corrosive liquid silicon, the Earth-based experiment uses air jets and various transparent oils, since the basic principle involved is the same. The first float zone is enclosed in a very small rectangular box with a quasi-planar free surface. Stable Marangoni convection has been achieved and velocities measured photographically. The air jet system with variable velocity and temperature is under construction. Three independent parameters must be optimized to attain maximum suppression: the gas velocity, angle of attack, and gas temperature.

Dressler, R. F.↗

Cryogenic and Simulated Fuel Jet Breakup in Argon, Helium and Nitrogen Gas Flows

Two-phase flow atomization of liquid nitrogen jets was experimentally investigated. They were co-axially injected into high-velocity gas flows of helium, nitrogen and argon, respectively, and atomized internally inside a two-fluid fuel nozzle. Cryogenic sprays with relatively high specific surface areas were produced, i.e., ratios of surface area to volume were fairly high. This was indicated by values of reciprocal Sauter mean diameters, RSMD's, as measured with a scattered- light scanning instrument developed at NASA Lewis Research Center. Correlating expressions were derived for the three atomizing gases over a gas temperature range of 111 to 422 K. Also, the correlation was extended to include waterjet breakup data that had been previously obtained in simulating fuel jet breakup in sonic velocity gas flow. The final correlating expression included a new dimensionless molecular-scale acceleration group. It was needed to correlate RSMD data, for LN2 and H2O sprays, with the fluid properties of the liquid jets and atomizing gases used in this investigation.

Ingebo, Robert D.↗

Space simulation experiments on reaction control system thruster plumes

A space simulation procedure was developed for studying rocket plume contamination effects using a 5-pound bipropellant reaction control system thruster. Vacuum chamber pressures of 3 x 10 to the minus 5 torr (70 miles altitude) were achieved with the thruster firing in pulse trains consisting of eight pulses (50 msec on, 100 msec off, and seven minutes between pulse trains). The final vacuum was achieved by cooling all vacuum chamber surfaces to liquid helium temperature and by introducing a continuous argon leak of 48 std. cc/sec into the test chamber. An effort was made to simulate propellant system flow dynamics corresponding to actual spacecraft mission use. Fast time response liquid flow rate measurements showed that large variations occurred in the ratio of oxidizer to fuel flow for pulse-on times up to 120 msec. These variations could lead to poor combustion efficiency and the production of contamination.

Cassidy, J. F.↗

Scintillating Bubble Chambers for Rare Event Searches

The Scintillating Bubble Chamber (SBC) collaboration is developing liquid-noble bubble chambers for the detection of sub-keV nuclear recoils. These detectors benefit from the electron recoil rejection inherent in moderately-superheated bubble chambers with the addition of energy reconstruction provided from the scintillation signal. The ability to measure low-energy nuclear recoils allows the search for GeV-scale dark matter and the measurement of coherent elastic neutrino-nucleus scattering on argon from MeV-scale reactor antineutrinos. The first physics-scale detector, SBC-LAr10, is in the commissioning phase at Fermilab, where extensive engineering and calibration studies will be performed. In parallel, a functionally identical low-background version, SBC-SNOLAB, is being built for a dark matter search underground at SNOLAB. SBC-SNOLAB, with a 10 kg-yr exposure, will have sensitivity to a dark matter–nucleon cross section of 2×10 –42 cm 2 at 1 GeV/c 2 dark matter mass, and future detectors could reach the boundary of the argon neutrino fog with a tonne-yr exposure. In addition, the deployment of an SBC detector at a nuclear reactor could enable neutrino physics investigations including measurements of the weak mixing angle and searches for sterile neutrinos, the neutrino magnetic moment, and the light Z’ gauge boson.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Conceptual design and analysis of orbital cryogenic liquid storage and supply systems

A wide variety of orbital cryogenic liquid storage and supply systems are defined in NASA and DOD long-range plans. These systems include small cooling applications, large chemical and electrical orbit transfer vehicles and supply tankers. All have the common requirements of low-g fluid management to accomplish gas-free liquid expulsion and efficient thermal control to manage heat leak and tank pressure. A preliminary design study was performed to evaluate tanks ranging from 0.6 to 37.4 cu m (22 to 1320 cu ft). Liquids of interest were hydrogen, oxygen, methane, argon and helium. Conceptual designs were generated for each tank system and fluid dynamic, thermal and structural analyses were performed for Shuttle compatible operations. Design trades considered the paradox of conservative support structure and minimum thermal input. Orbital performance and weight data were developed, and a technology evaluation was completed.

Eberhardt, R. N.↗

Short Shot Tower for Silicon

Drop length necessary to convert molten silicon to shot reduced by proposed new process. Conversion of silicon from powder or chunks to shot often simplifies processing. Shot is more easily handled in most processing equipment. Drops of liquid silicon fall through protective cloud of argon, then through rapidly cooling bath of methanol, where they quickly turn into solid shot.

Bates, H. E.↗

Keyhole and weld shapes for plasma arc welding under normal and zero gravity

A first order study of the interfacial (keyhole) shape between a penetrating argon plasma arc jet and a stationary liquid metal weld pool is presented. The interface is determined using the Young-Laplace equation by assuming that the plasma jet behaves as a one-dimensional ideal gas flow and by neglecting flow within the weld pool. The solution for the keyhole shape allows an approximate determination of the liquid-solid metal phase boundary location based on the assumption that the liquid melt is a stagnant thermal boundary layer. Parametric studies examine the effect of plasma mass flow rate, initial plasma enthalpy, liquid metal surface tension, and jet shear on weldment shape under both normal and zero gravity. Among the more important findings of this study is that keyhole and weld geometries are minimally affected by gravity, suggesting that data gathered under gravity can be used in planning in-space welding.

Keanini, R. G.↗