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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 739 records · Page 41
All sourcesNASA NTRSDOE OSTI
NASA NTRS1986

3s-3p laser gain and X-ray line ratios for the carbon isoelectronic sequence

Calculations have been conducted for the 46 levels belonging to six different configurations in the C I isoatomic sequence, for atomic numbers 18, 22, 26, 30, 34, and 36, with electron densities in the 10 to the 15th to 10 to the 22nd/cu cm range. The 2s2 2p 3p levels' large populations are due to the large electron collisional monopole excitation rates from the ground configuration, as well as to the small radiative decay rates to the ground configuration; this leads to population inversions for transitions of the 3s-3p type. Attention is given to the density-dependence of X-ray line ratios, which represent a promising diagnostic for electron density.

Feldman, U.↗
NASA NTRS1988

Determination of electron density and temperature in non-LTE plasmas from spectral lines of impurity ions

A novel approach for calculating the populations of the excited Li-like ions C IV, N V, O VI, and Ne VIII is presented. The populations of the 2(2P), 3(2S), 3(2P), and 3(2D) electronic levels in these ions in optically thin plasmas with a broad range of electron density, N(e), and temperature, T(e), are determined from the collisional-radiative model by solving the system of rate equations for the production of excited ions; the equations are linear with respect to the excited ion populations, and the N(e) and T(e) are taken as independent variables. These populations are used to determine the ratios of line intensities for dipole allowed transitions between various energy levels. This approach can be applied to impurities other than the lithiumlike ions and is especially useful for diagnostics of systems where nonintrusive spectroscopic techniques must be used.

Kunc, Joseph A.↗
NASA NTRS2014

Investigation of Structure and Transport in Li-Doped Ionic Liquid Electrolytes: [pyr14][TFSI], [pyr13][FSI], [EMIM][BF4]

Ionic liquid electrolytes have been proposed as a means of improving the safety and cycling behavior of advanced lithium batteries; however, the properties of these electrolytes under high lithium doping are poorly understood. Here, we employ both polarizable molecular dynamics simulation and experiment to investigate the structure, thermodynamics and transport of three potential electrolytes, N-methyl-N-butylpyrrolidinium bis(trifluoromethylsufonyl)imide ([pyr14][TFSI]), N- methyl-N-propylpyrrolidinium bis(fluorosufonyl)imide ([pyr13][FSI]), and 1-ethyl-3-- methylimidazolium boron tetrafluoride ([EMIM][BF4]), as a function of Li (-) salt concentration and temperature. Structurally, Li(+) is shown to be solvated by three anion neighbors in [pyr14][TFSI] and four anion neighbors in both [pyr13][FSI] and [EMIM][BF4], and at all levels of xLi we find the presence of lithium aggregates. Furthermore, the computed density, diffusion, viscosity, and ionic conductivity show excellent agreement with experimental data. While the diffusion and viscosity exhibit a systematic decrease and increase, respectively, with increasing xLi, the contribution of Li(+) to ionic conductivity increases until reaching a saturation doping level of xLi 0.10. Comparatively, the Li(+) conductivity of [pyr14][TFSI] is an order of magnitude lower than that of the other liquids, which range between 0.1-0.3 mScm. The differences in Li(+) transport are reflected in the residence times of Li(+) with the anions, which are revealed to be much larger for [pyr14][TFSI] (up to 100 ns at the highest doping levels) than in either [EMIM][BF4] or [pyr13][FSI]. Finally, we comment on the relative kinetics of Li(+) transport in each liquid and we present strong evidence for transport through anion exchange (hopping) as opposed to the net motion of Li(+) with its solvation shell (vehicular).

ionic liquids↗
NASA NTRS2014

Investigation of Structure and Transport in Li-Doped Ionic Liquid Electrolytes: [pyr14][TFSI], [pyr13][FSI], [EMIM][BF4]

Ionic liquid electrolytes have been proposed as a means of improving the safety and cycling behavior of advanced lithium batteries; however, the properties of these electrolytes under high lithium doping are poorly understood. Here, we employ both polarizable molecular dynamics simulation and experiment to investigate the structure, thermodynamics and transport of three potential electrolytes, N-methyl-N-butylpyrrolidinium bis(trifluoromethylsufonyl)imide ([pyr14][TFSI]), N- methyl-N-propylpyrrolidinium bis(fluorosufonyl)imide ([pyr13][FSI]), and 1-ethyl-3-- methylimidazolium boron tetrafluoride ([EMIM][BF4]), as a function of Li (-) salt concentration and temperature. Structurally, Li(+) is shown to be solvated by three anion neighbors in [pyr14][TFSI] and four anion neighbors in both [pyr13][FSI] and [EMIM][BF4], and at all levels of xLi we find the presence of lithium aggregates. Furthermore, the computed density, diffusion, viscosity, and ionic conductivity show excellent agreement with experimental data. While the diffusion and viscosity exhibit a systematic decrease and increase, respectively, with increasing xLi, the contribution of Li(+) to ionic conductivity increases until reaching a saturation doping level of xLi 0.10. Comparatively, the Li(+) conductivity of [pyr14][TFSI] is an order of magnitude lower than that of the other liquids, which range between 0.1-0.3 mScm. The differences in Li(+) transport are reflected in the residence times of Li(+) with the anions, which are revealed to be much larger for [pyr14][TFSI] (up to 100 ns at the highest doping levels) than in either [EMIM][BF4] or [pyr13][FSI]. Finally, we comment on the relative kinetics of Li(+) transport in each liquid and we present strong evidence for transport through anion exchange (hopping) as opposed to the net motion of Li(+) with its solvation shell (vehicular).

molecular dynamics↗
NASA NTRS2010

Radiation Testing of PICA at the Solar Power Tower

Sandia National Laboratory's Solar Power Tower was used to irradiate specimens of Phenolic Impregnated Carbon Ablator (PICA), in order to evaluate whether this thermal protection system material responded differently to potential shock layer radiative heating than to convective heating. Tests were run at 50, 100 and 150 Watts per square centimeter levels of concentrated solar radiation. Experimental results are presented both from spectral measurements on 1- 10 mm thick specimens of PICA, as well as from in-depth temperature measurements on instrumented thicker test specimens. Both spectral measurements and measured in-depth temperature profiles showed that, although it is a porous, low-density material, PICA does not exhibit problematic transparency to the tested high levels of NIR radiation, for all pragmatic cm-to-inch scale thicknesses. PICA acted as a surface absorber to efficiently absorb the incident visible and near infrared incident radiation in the top 2 millimeter layer in the Solar Power Tower tests up to 150 Watts per square centimeter.

White, Susan M.↗
NASA NTRS2010

Radiation Testing of PICA at the Solar Power Tower

Sandia National Laboratory's Solar Power Tower was used to irradiate specimens of Phenolic Impregnated Carbon Ablator (PICA), in order to evaluate whether this thermal protection system material responded differently to potential shock layer radiative heating than to convective heating. Tests were run at 50, 100 and 150 Watts per square centimeter levels of concentrated solar radiation. Experimental results are presented both from spectral measurements on 1- 10 mm thick specimens of PICA, as well as from in-depth temperature measurements on instrumented thicker test specimens. Both spectral measurements and measured in-depth temperature profiles showed that, although it is a porous, low-density material, PICA does not exhibit problematic transparency to the tested high levels of NIR radiation, for all pragmatic cm-to-inch scale thicknesses. PICA acted as a surface absorber to efficiently absorb the incident visible and near infrared incident radiation in the top 2 millimeter layer in the Solar Power Tower tests up to 150 Watts per square centimeter.

White, Susan↗
NASA NTRS1975

15 cm cusped magnetic field mercury ion thruster research

The importance of achieving a uniform current density in the exhaust beam of an electrostatic ion thruster is discussed in terms of thrust level and accelerator grid lifetime. A neutral residence time approach is used to propose a magnetic field geometry which should produce a highly uniform beam current density. The discharge chamber length to diameter ratio is shown to be an important optimization parameter and experimental evaluation of the cusped field thruster over a wide range of this parameter is presented. Beam profile measurements 5 cm downstream of the accelerator grid indicate a beam profile flatness parameter which is 25% greater than the SERT II value. Flatness parameters extrapolated to the plane of the accelerator grid are demonstrated to be as high as 0.9.

Beattie, J. R.↗
NASA NTRS2004

Web-Based Toxic Gas Dispersion Model for Shuttle Launch Operations

During the launch of the Space Shuttle vehicle, the burning of liquid hydrogen fuel with liquid oxygen at extreme high temperatures inside the three space shuttle main engines, and the burning of the solid propellant mixture of ammonium perchlorate oxidizer, aluminum fuel, iron oxide catalyst, polymer binder, and epoxy curing agent in the two solid rocket boosters result in the formation of a large cloud of hot, buoyant toxic exhaust gases near the ground level which subsequently rises and entrains into ambient air until the temperature and density of the cloud reaches an approximate equilibrium with ambient conditions. In this paper, toxic gas dispersion for various gases are simulated over the web for varying environmental conditions which is provided by rawinsonde data. The model simulates chemical concentration at ground level up to 10 miles (1 KM grids) in downrange up to an hour after launch. The ambient concentration of the gas dispersion and the deposition of toxic particles are used as inputs for a human health risk assessment model. The advantage of the present model is the accessibility and dissemination of model results to other NASA centers over the web. The model can be remotely operated and various scenarios can be analyzed.

Bardina, Jorge↗
NASA NTRS2021

Physics-Based SNOWPACK Model Improves Representation of Near-Surface Antarctic Snow and Firn Density

Estimates of snow and firn density are required for satellite-altimetry-based retrievals of ice sheet mass balance that rely on volume-to-mass conversions. Therefore, biases and errors in presently used density models confound assessments of ice sheet mass balance and by extension ice sheet contribution to sea level rise. Despite this importance, most contemporary firn densification models rely on simplified semi-empirical methods, which are partially reflected by significant modeled density errors when compared to observations. In this study, we present a new drifting-snow compaction scheme that we have implemented into SNOWPACK, a physics-based land surface snow model. We show that our new scheme improves existing versions of SNOWPACK by increasing simulated near-surface (defined as the top 10 m) density to be more in line with observations (near-surface bias reduction from −44.9 to −5.4 kg m−3). Furthermore, we demonstrate high-quality simulation of near-surface Antarctic snow and firn density at 122 observed density profiles across the Antarctic ice sheet, as indicated by reduced model biases throughout most of the near-surface firn column when compared to two semi-empirical firn densification models (SNOWPACK mean bias=−9.7 kg m−3, IMAU-FDM mean bias=−32.5 kg m−3, GSFC-FDM mean bias=15.5 kg m−3). Notably, our analysis is restricted to the near surface where firn density is most variable due to accumulation and compaction variability driven by synoptic weather and seasonal climate variability. Additionally, the GSFC-FDM exhibits lower mean density bias from 7–10 m (SNOWPACK bias=−22.5 kg m−3, GSFC-FDM bias=10.6 kg m−3) and throughout the entire near surface at high-accumulation sites (SNOWPACK bias=−31.4 kg m−3, GSFC-FDM bias=−4.7 kg m−3). However, we found that the performance of SNOWPACK did not degrade when applied to sites that were not included in the calibration of semi-empirical models. This suggests that SNOWPACK may possibly better represent firn properties in locations without extensive observations and under future climate scenarios, when firn properties are expected to diverge from their present state.

Eric Keenan↗
NASA NTRS1976

Some factors influencing radiation of sound from flow interaction with edges of finite surfaces

Edges of surfaces which are exposed to unsteady flow cause both strictly acoustic effects and hydrodynamic effects, in the form of generation of new hydrodynamic sources in the immediate vicinity of the edge. An analytical model is presented which develops the explicit sound-generation role of the velocity and Mach number of the eddy convection past the edge, and the importance of relative scale lengths of the turbulence, as well as the relative intensity of pressure fluctuations. The Mach number (velocity) effects show that the important paramater is the convection Mach number of the eddies. The effects of turbulence scale lengths, isotropy, and spatial density (separation) are shown to be important in determining the level and spectrum of edge sound radiated for the edge dipole mechanism. Experimental data is presented which provides support for the dipole edge noise model in terms of Mach number (velocity) scaling, parametric dependence on flow field parameter, directivity, and edge diffraction effects.

Hayden, R. E.↗
NASA NTRS1977

Critical velocity phenomena and the LTP

When the relative velocity between magnetized plasma and neutral gas exceeds a critical value, the gas-plasma interaction is dominated by collective phenomena which rapidly excite and ionize the neutrals. The interaction of the solar wind with a large cloud (between 10 to the 24th and 10 to the 28th power neutrals) vented from the moon should be of this type. Line radiation from such an interaction can yield an apparent lunar surface brightness rivaling reflected sunlight levels over small areas, if the kinetic-energy flow density of the gas is sufficiently high. The aberrated solar-wind flow past the moon would enhance the visibility of such interactions near the lunar sunrise terminator, supporting the statistical studies which indicate that the 'Lunar Transient Phenomena' (anomalous optical phenomena on the moon) are significantly correlated with the position of the terminator on the lunar surface.

Srnka, L. J.↗
NASA NTRS1976

120 MB/S and 240 MB/S bit synchronizer-signal conditioners for NASA high data rate applications

Two bit synchronizer-signal conditioners (BSSC) developed for NASA high data rate applications such as earth resources monitoring are described. One BSSC is centered at 120 MB/s and the other at 240 Mb/s. These subsystems are featured out of the total hardware developed because the BSSC is such a key subsystem in determining overall system statistical performance. These units represent an evolution of high data rate BSSC's available at low data rates. Numerous inputs/outputs, control functions, indicators, plus the ability to minimize the effects of various signal perturbations are provided. Examples of allowed perturbations are input level variations, bit rate variance static and dynamic, baseline, transition density, bandlimiting, etc., as well as noise. Emphasis in the past has been primarily concerned only with noise.

Gray, J. S.↗
NASA NTRS1978

Spontaneous emission near the electron plasma frequency in a plasma with a runaway electron tail

Spontaneous emission of radiation with frequencies near the electron plasma frequency is studied for a plasma which consists of both thermal and runaway electrons. It is found that a substantial enhancement of the spontaneous radiation intensity can occur in this frequency regime via a Cherenkov resonance with the runaway electrons. Numerical analysis indicates that, for reasonable estimates of densities and energies, the plasma-frequency radiation can attain levels greater than the peak thermal emission at the second gyroharmonic.

Freund, H. P.↗
NASA NTRS1979

High-resolution spectra of Jupiter in the 744-980 inverse centimeter spectral range

Spectra of the central 5 in region of Jupiter in the 744 to 980 kayser spectral range are presented at 0.05 and 0.28 kayser resolution. The gases (N-14)H3, (N-15)H3, and PH3 are observed in absorption, and C2H2 and C2H6 observed in emission. A synthetic spectrum which included the opacity from the H2, (N-14)H3, (N-15)H3, and PH3 is compared with observations. It is concluded that: (1) the (N-14)H3 line profiles are best fitted with a NH3 density in the troposphere which is 0.5 times the saturated vapor pressure density and an opaque cloud at the 0.56 bar pressure level, (2) the best fit (N-15)H3/(N-14)H3 ratio is 0.006, (3) the PH3/H2 abundance ratios of NH3 and PH3 must be highly subsaturated above the tropopause or the temperature inversion is cooler than model predictions.

Tokunaga, A. T.↗
NASA NTRS1980

A search for interstellar scandium

The resonance line of Sc II at 3642.785 A has been sought in the interstellar spectrum of Zeta Oph, resulting in an upper limit N(Sc II) not greater than 8.6 billion/sq cm and a depletion of this element at least by a factor of 200, if Sc III contributes a negligible column density. The present upper limit may be somewhat below the level expected under the grain-formation model for interstellar depletions, and is consistent with the abundance expected if the depletions are due to gas-grain collisions. The new limit on this element helps to support the hypothesis that species within a specific range of ionization potential are preferentially depleted.

Snow, T. P., Jr.↗
NASA NTRS1981

Electron reflection and secondary emission characteristics of sputter-textured pyrolytic graphite surfaces

Low secondary and reflected primary electron emission from the collector electrode surfaces is important for optimum collector efficiency and hence for high overall efficiency of microwave amplifier tubes used in communication satellites and in military systems. Ion sputter texturing of the surface effectively suppresses electron emission from pyrolytic graphite, which is a promising collector electrode material. Secondary and reflected primary electron emission characteristics of sputter textured pyrolytic graphite surfaces with microstructures of various sizes and densities are presented. The microstructure with the lowest electron emission levels, less than those of soot, consists of a dense array of tall, thin spires.

Wintucky, E. G.↗