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Mass mortality and extraterrestrial impacts

The discovery of iridium enrichment at the Cretaceous/Tertiary boundary resulted in formulation of hypothesis of a cometary or asteroid impact as the cause of the biological extinctions at this boundary. Subsequent discoveries of geochemical anomalies at major stratigraphic boundaries like the Precambrian/Cambrian, Permian/Triassic, Middle/Late Jurassic, resulted in the application of similar extraterrestrial impact theories to explain biological changes at these boundaries. Until recently the major physical evidence, as is the location of the impact crater site, to test the impact induced biological extinction was lacking. The diameter of such a crater would be in the range of 60 to 100 km. The recent discovery of the first impact crater in the ocean provide the first opportunity to test the above theory. The crater, named Montagnais and located on the outer shelf off Nova Scotia, Canada, has a minimum diameter of 42 km, with some evidence to a diameter of more than 60 km. At the Montagnais impact site, micropaleontological analysis of the uppermost 80 m of the fall-back breccia represented by a mixture of pre-impact sediments and basement rocks which fills the crater and of the basal 50 m of post-impact marine sediments which overly the impact deposits, revealed presence of diversified foraminiferal and nannoplankton assemblages. The sediments which are intercalated within the uppermost part of the fall-back breccia, had to be deposited before the meteorite impact. The post-impact deposits were laid down almost immediately after the impact as also supported by the micropaleontological data. In conclusion, micropaleontological studies of sediments from the first submarine impact crater site identified in the ocean did not reveal any mass extinction or significant biological changes at the impact site or in the proximal deep ocean basin.

Jansa, L. F.↗

Effect of Impact Damage on the Fatigue Response of TiAl Alloy-ABB-2

The ability of gamma-TiAl to withstand potential foreign or domestic object damage is a technical risk to the implementation of gamma-TiAl in low pressure turbine (LPT) blade applications. In the present study, the impact resistance of TiAl alloy ABB-2 was determined and compared to the impact resistance of Ti(48)Al(2)Nb(2)Cr. Specimens were impacted with four different impact conditions with impact energies ranging from 0.22 to 6.09 J. After impacting, the impact damage was characterized by crack lengths on both the front and backside of the impact. Due to the flat nature of gamma-TiAl's S-N (stress vs. cycles to failure) curve, step fatigue tests were used to determine the fatigue strength after impacting. Impact damage increased with increasing impact energy and led to a reduction in the fatigue strength of the alloy. For similar crack lengths, the fatigue strength of impacted ABB-2 was similar to the fatigue strength of impacted Ti(48)Al(2)Nb(2)Cr, even though the tensile properties of the two alloys are significantly different. Similar to Ti(48)Al(2)Nb(2)Cr, ABB-2 showed a classical mean stress dependence on fatigue strength. The fatigue strength of impacted ABB-2 could be accurately predicted using a threshold analysis.

Draper, S. L.↗

Investigation of MMOD Impact on STS-115 Shuttle Payload Bay Door Radiator

The Orbiter radiator system consists of eight individual 4.6 m x 3.2 m panels located with four on each payload bay door. Forward panels #1 and #2 are 2.3 cm thick while the aft panels #3 and #4 have a smaller overall thickness of 1.3 cm. The honeycomb radiator panels consist of 0.028 cm thick Aluminum 2024-T81 facesheets and Al5056-H39 cores. The face-sheets are topped with 0.005 in. (0.127 mm) silver-Teflon tape. The radiators are located on the inside of the shuttle payload bay doors, which are closed during ascent and reentry, limiting damage to the on-orbit portion of the mission. Post-flight inspections at the Kennedy Space Center (KSC) following the STS-115 mission revealed a large micrometeoroid/orbital debris (MMOD) impact near the hinge line on the #4 starboard payload bay door radiator panel. The features of this impact make it the largest ever recorded on an orbiter payload bay door radiator. The general location of the damage site and the adjacent radiator panels can be seen in Figure 2. Initial measurements of the defect indicated that the hole in the facesheet was 0.108 in. (2.74 mm) in diameter. Figure 3 shows an image of the front side damage. Subsequent observations revealed exit damage on the rear facesheet. Impact damage features on the rear facesheet included a 0.03 in. diameter hole (0.76 mm), a approx.0.05 in. tall bulge (approx.1.3 mm), and a larger approx.0.2 in. tall bulge (approx.5.1 mm) that exhibited a crack over 0.27 in. (6.8 mm) long. A large approx.1 in. (25 mm) diameter region of the honeycomb core was also damaged. Refer to Figure 4 for an image of the backside damage to the panel. No damage was found on thermal blankets or payload bay door structure under the radiator panel. Figure 5 shows the front facesheet with the thermal tape removed. Ultrasound examination indicated a maximum facesheet debond extent of approximately 1 in. (25 mm) from the entry hole. X-ray examinations revealed damage to an estimated 31 honeycomb cells with an extent of 0.85 in. x 1.1 in. (21.6 x 27.9 mm). Pieces of the radiator at and surrounding the impact site were recovered during the repair procedures at KSC. They included the thermal tape, front facesheet, honeycomb core, and rear facesheet. These articles were examined at JSC using a scanning electron microscope (SEM) with an energy dispersive x-ray spectrometer (EDS). Figure 6 shows SEM images of the entry hole in the facesheet. The asymmetric height of the lip may be attributed to projectile shape and impact angle. Numerous instances of a glass-fiber organic matrix composite were observed in the facesheet tape sample. The fibers were approximately 10 micrometers in diameter and variable lengths. EDS analysis indicated a composition of Mg, Ca, Al, Si, and O. Figures 7 and 8 present images of the fiber bundles, which were believed to be circuit board material based on similarity in fiber diameter, orientation, consistency, and composition. A test program was initiated in an attempt to simulate the observed damage to the radiator facesheet and honeycomb. Twelve test shots were performed using projectiles cut from a 1.6 mm thick fiberglass circuit board substrate panel. Results from test HITF07017, shown in figures 9 and 10, correlates with the observed impact features reasonably well. The test was performed at 4.14 km/sec with an impact angle of 45 degrees using a cylindrical projectile with a diameter and length of 1.25 mm. The fiberglass circuit board material had a density of 1.65 g/cu cm, giving a projectile mass of 2.53 mg. An analysis was performed using the Bumper code to estimate the probability of impact to the shuttle from a 1.25 mm diameter particle. Table 1 shows a 1.6% chance (impact odds = 1 in 62) of a 1.25 mm or larger MMOD impact on the radiators of the vehicle during a typical ISS mission. There is a 0.4% chance (impact odds = 1 in 260) that a 1.25 mm or larger MMOD particle would impact the RCC wing leading edge and nose cap during a typical miion. Figure 11 illustrates the vulnerable areas of the wing leading edge reinforced carbon-carbon (RCC), an area of the vehicle that is very sensitive to impact damage. The highlighted red, orange, yellow, and light green areas would be expected to experience critical damage if impacted by an OD particle such as the one that hit the RH4 radiator panel on STS-115.

Hyde, J.↗

Micrometeorite Impact Test of Flex Solar Array Coupon

Spacecraft with solar arrays operate throughout the near earth environment and are increasingly planned for outer planet missions. An often overlooked test condition for solar arrays that is applicable to these missions is micrometeorite impacts and possibly electrostatic discharge (ESD) events resulting from these impacts. The Marshall Space Flight Center (MSFC) is partnering with Space Systems/Loral, LLC (SSL) to examine the results of simulated micrometeorite impacts on the electrical performance of an advanced, lightweight flexible solar array design. The test is performed at NASA MSFC's Microlight Gas Gun Facility. The SSL-provided coupons consist of three strings, each string with two solar cells in series. Five impacts will be induced at various locations on a powered test coupon under different string voltage (0 volts - 150 volts) and string current (1.1 amperes - 1.65 amperes) conditions. The maximum specified test voltage and current represent margins of 1.5 times for both voltage and current. The test parameters are chosen to demonstrate new array design robustness to any ESD event caused by plasma plumes resulting from a simulated micrometeorite impact. A second unpowered coupon will undergo two impacts: one impact on the front side and one impact on the back side. Following the impact testing, the second coupon will be exposed to a thermal cycle test to determine possible damage propagation and further electrical degradation due to thermally-induced stress. The setup, checkout, and results from the impact testing are discussed. The challenges for impact testing include precise coupon alignment to control impact location; pressure management during the impact process; and measurement of the true transient electrical response during impact on the powered coupon. Results from pre- and post-test visual and electrical functional testing are also discussed.

Wright, K. H.↗

Apollo Sample 64455: Petrologic and Geochemical Characterization of a Glass-Coated Impact Melt Rock

Introduction and Background: Impact melts are a key product of the impact cratering process. Impact melts can turbulently entrain pre-existing rock fragments, and melt part of those entrained materials until thermal equilibrium is achieved [1–3]. Lunar impact melt rocks are valuable for determining the precise ages of basin-forming and cratering events, which anchor the cratering chronology and dynamics of the entire solar system [4, and references therein]. Additionally, entrained clasts can inform on the petrology and age of crustal materials that predate the melt-forming impact. In lithologies where no pristine samples are available, entrained materials may hold the record of endogenous lunar volatiles, provided we can untangle their impact histories as high temperature impact melt can heat the clasts and may alter their native volatiles or isotopic signatures [5–6]. Here, we characterize an Apollo 16 sample, 64455,70B, in an effort to understand the physical, microstructural, and geochemical consequences of impact melt contact metamorphism. We acquired optical light and x-ray maps of the sample, as well as quantitative analyses via electron probe microanalysis (EPMA). These tasks allow us to better understand the interaction between impact melts and entrained clasts, ultimately closing knowledge gaps in high-temperature impact processing on planetary surfaces. Sample Description: Sample 64455 is an oblong crystalline rock encased in glass to form an egg-like shape [7–8]. The impact melt coating has altered the outer (1 to 2 mm) rind of the crystalline rock and has preserved schlieren. The interior crystalline rock is likely a crystalline impact melt rock based on its bulk Ir content of 2.25 parts per billion [9]. The composition of the impact melt glass rind cannot be solely derived from the crystalline interior, the glassy rind is more aluminous and less magnesian [10]. Neither the crystalline interior nor the glassy rind were radiometrically age dated, although several studies investigated its cosmogenic isotopes and exposure ages, which reveal the sample was exposed on the lunar surface for ~1–2 Ma [11–13]. Preliminary Results: The interior crystalline rock consists primarily of plagioclase with interstitial pyroxene and olivine. Plagioclase grains are zoned and compositions range from An97–89, while pyroxene compositions generally range from En68Fs19Wo13 to En82Fs15Wo3 and olivine are Fo77 to Fo85. Minor phases include Fe-Ni metal, Ca-phosphates, a K- and Si-rich phase, sulfides, and Fe-phosphides. The glass rind contains approximately 44 wt.% SiO2, 25 wt.% Al2O3, 6 wt.% FeO, 8 wt.% MgO, and 14 wt.% CaO, with other oxides at <1 wt.% each, although the composition of the glass becomes more variable closest to the crystalline rock. The rind consists of rounded plagioclase, pyroxene, and olivine crystals with interstitial melt. In some locations, the rounded crystals are surrounded by closely-packed, blade-like crystals, <5 µm in width. These results indicate that the crystalline interior has partially melted where in contact with the high-temperature impact melt and while further investigation is needed, pyroxene may have preferentially melted relative to olivine and plagioclase. Future Work: We plan to conduct electron backscatter diffraction (EBSD) mapping in order to determine crystallinity and crystal orientation. Next using transmission electron microscopy (TEM) data in conjunction with EBSD and EPMA information, we will model the diffusion of moderately volatile elements between the melt and remnant crystals.

A C Stadermann↗

Large Impact Features on Ganymede and Callisto as Revealed By Geological Mapping and Morphometry

The icy Galilean satellites are host to a broad range of impact feature morphologies. Hypotheses seeking to explain the diversity of these impact features consider the effects of impact melt, the physical state of the subsurface at the time of impact, and the impactor characteristics. As part of a larger effort to assess the role of these factors in the formation and evolution of these impact features, we have performed topographic and geological mapping of 19 large impact features on Ganymede and Callisto. These are divided into two main morphological groups: craters (subdivided into pit, dome, and anomalous dome craters), and penepalimpsests/palimpsests. The transitions from pit, dome, to anomalous dome craters appear to be size-dependent up to diameters of ∼170 km. The morphologies of pit and dome craters appear to be independent of their age or geologic context. The impacts that formed them only affected a cold, rigid ice layer, with the development of pits and raised annuli on their floors possibly stemming from the evolution of a pocket of impact melt. The subdued rims and floors of anomalous dome craters indicate the increasing effect of a weak, warm ice layer on impact feature morphology with increasing size, but their prominent annuli and pits indicate that mobilization of impact melt is also a factor. The very low topographic relief of older penepalimpsests and palimpsests indicates that their impacts penetrated the ice shell to mobilize very large volumes of pre-existing liquid from a subsurface layer, with little contribution to the final feature morphology from impact melt. Penepalimpsests are distinguished from palimpsests by the higher frequency of concentric ridges within their interiors, indicating a generally more robust state of the subsurface that could better support the rotation and uplift of solid material during impact, even if a crater-like depression could not be supported. A few impact features seem to be transitional between anomalous dome craters and penepalimpsests, and the overlap of anomalous dome craters, penepalimpsests, and palimpsests in terms of diameter as well as age indicates that impactor size and subsurface properties over time are major factors in determining which of these morphologies emerges.

Oliver L White↗

Environmental impact assessment by means of a procedure based on fuzzy logic: A practical application

This study shows the practical application of the EIA method based on fuzzy logic proposed by the authors (Peche and Rodriguez, 2009) to a simplified case of study-the activity of a petrol station throughout its exploitation. The intensity (p{sub 1}), the extent (p{sub 2}) and the persistence (p{sub 3}) were the properties selected to describe the impacts and their respective assessment functions v-bar{sub i}=f(p-bar{sub i}) were determined. The main actions (A) and potentially affected environmental factors (F) were selected. Every impact was identified by a pair A-F and the values of the three impact properties were estimated for each of them by means of triangular fuzzy numbers. Subsequently, the fuzzy estimation of every impact was carried out, the estimation of the impact A{sub 1}-F{sub 2} (V-bar{sub 1}) being explained in detail. Every impact was simultaneously represented by its corresponding generalised confidence interval and membership function. Since the membership functions of all impacts were similar to triangular fuzzy numbers, a triangular approach (TA) was used to describe every impact. A triangular approach coefficient (TAC) was introduced to quantify the similarity of each fuzzy number and its corresponding triangular approach, where TAC (V-bar) element of (0, 1] and TAC being 1 when the fuzzy number is triangular. The TACs-ranging from 0.96 to 0.99-proved that TAs were valid in all cases. Next, the total positive and negative impacts-TV-bar{sup +} and TV-bar{sup -} were calculated and later, the fuzzy value of the total environmental impact TV-bar was determined from them. Finally, the defuzzification of TV-bar led to the punctual impact estimator TV{sup (1)} = -88.50 and its corresponding uncertainty interval [{delta}{sub l}(TV-bar),{delta}{sub r}(TV-bar)]=[6.52,6.96], which represent the total value of the EI. In conclusion, the EIA method enabled the integration of heterogeneous impacts, which exerted influence on environmental factors of a very diverse nature in very different ways, into a global impact indicator.

54 ENVIRONMENTAL SCIENCES↗

A method proposal for cumulative environmental impact assessment based on the landscape vulnerability evaluation

Cumulative environmental impact assessment deals with the occasional use in practical application of environmental impact assessment process. The main reasons are the difficulty of cumulative impact identification caused by lack of data, inability to measure the intensity and spatial effect of all types of impacts and the uncertainty of their future evolution. This work presents a method proposal to predict cumulative impacts on the basis of landscape vulnerability evaluation. For this purpose, qualitative assessment of landscape ecological stability is conducted and major vulnerability indicators of environmental and socio-economic receptors are specified and valuated. Potential cumulative impacts and the overall impact significance are predicted quantitatively in modified Argonne multiple matrixes while considering the vulnerability of affected landscape receptors and the significance of impacts identified individually. The method was employed in the concrete environmental impact assessment process conducted in Slovakia. The results obtained in this case study reflect that this methodology is simple to apply, valid for all types of impacts and projects, inexpensive and not time-consuming. The objectivity of the partial methods used in this procedure is improved by quantitative landscape ecological stability evaluation, assignment of weights to vulnerability indicators based on the detailed characteristics of affected factors, and grading impact significance. - Highlights: • This paper suggests a method proposal for cumulative impact prediction. • The method includes landscape vulnerability evaluation. • The vulnerability of affected receptors is determined by their sensitivity. • This method can increase the objectivity of impact prediction in the EIA process.

54 ENVIRONMENTAL SCIENCES↗

On the attribution of the impacts of extreme weather events to anthropogenic climate change

Investigations into the role of anthropogenic climate change in extreme weather events are now starting to extend into analysis of anthropogenic impacts on non-climate (e.g. socio-economic) systems. However, care needs to be taken when making this extension, because methodological choices regarding extreme weather attribution can become crucial when considering the events’ impacts. The fraction of attributable risk (FAR) method, useful in extreme weather attribution research, has a very specific interpretation concerning a class of events, and there is potential to misinterpret results from weather event analyses as being applicable to specific events and their impact outcomes. Using two case studies of meteorological extremes and their impacts, we argue that FAR is not generally appropriate when estimating the magnitude of the anthropogenic signal behind a specific impact. Attribution assessments on impacts should always be carried out in addition to assessment of the associated meteorological event, since it cannot be assumed that the anthropogenic signal behind the weather is equivalent to the signal behind the impact because of lags and nonlinearities in the processes through which the impact system reacts to weather. Whilst there are situations where employing FAR to understand the climate change signal behind a class of impacts is useful (e.g. ‘system breaking’ events), more useful results will generally be produced if attribution questions on specific impacts are reframed to focus on changes in the impact return value and magnitude across large samples of factual and counterfactual climate model and impact simulations. We advocate for constant interdisciplinary collaboration as essential for effective and robust impact attribution assessments.

54 ENVIRONMENTAL SCIENCES↗

Zircon (U-Th)/He Impact Crater Thermochronometry and the Effects of Shock Microstructures on Helium Diffusion Kinetics

Absolute age determination of impact cratering events remains difficult and often controversial; a challenge that has resulted in < 50% of known impact craters regarded as accurately and precisely dated. Besides conventional 40Ar/39Ar and U-Pb methods, zircon (U-Th)/He (ZHe) dating of impactites has been applied to large- to medium-sized impact structures. ZHe dates can be fully reset in minutes at 1000°C, which is commonly reached in central sections of the melt sheet, whereas resetting of ZHe at <300°C, which might be encountered near the crater margins or persist in post-impact hydrothermal systems, may take >103-6 years. There is a critical need to quantify the effects of shock-induced microstructures and impact metamorphism on helium diffusion kinetics in well-characterized, variably shocked zircon to further establish the reliability of (U-Th)/He for dating impacts. For this purpose, we investigated suevite and impact melt samples from two impact structures, the Chicxulub multi-ring basin and the Ries complex crater, which enables us to compare zircon helium diffusion kinetics from impact structures with differing sizes, ages, and hydrothermal system longevities. Shock microstructures were characterized by backscattered-electron (BSE) imaging prior to diffusion step-heating fractional release experiments using light-bulb furnace with prograde and retrograde incremental 10°C steps from 250°C to 600°C. Afterward, we characterize the diffusion domain sizes and their interconnectivity within the shocked zircon grains using electron backscatter diffraction (EBSD). We find that zircon with few shock microstructures exhibit no significant deviation from helium diffusion kinetics of undamaged zircon. In contrast, zircon grains with planar deformation features (PDFs) and granular textures classified by BSE and EBSD are characterized by a dramatic decrease in helium retentivity, similar to radiation damaged grains, due to a reduction in the effective domain size and the introduction of interconnected fast diffusion pathways created by shock microstructures. A subset of grains were dated by ZHe after the external morphology of the grains was determined by BSE imaging. The euhedral grains yielded a weighted mean age within the uncertainty of the accepted impact ages, whereas the grains with PDFs or granular textures exhibited younger ages. Thus, these diffusion experiments and ZHe dates suggest that the dramatic decrease in domain size likely renders shocked grains more susceptible to impact-induced hydrothermal resetting and subsequent overprinting. Hence, characterization of shock microstructures is critical for determining accurate impact ages using ZHe methods especially when applied to previously unconstrained craters. The thermochronometer also offers the opportunity to determine the magnitude and duration of post-impact hydrothermal circulation.

zircon↗

Exploration Medical Capability IMPACT Medical Database – Medical Item Database (MedID) Content Development Methods

The Informing Mission Planning via Analysis of Complex Tradespaces (IMPACT) project encompasses a suite of computational tools that are used to inform systematic trade study evaluations and research prioritizations regarding the optimization of spaceflight medical systems, including the provision of risk assessment metrics, for a given design reference mission (DRM). The IMPACT Medical Database (IMPACT-MD) is the component that virtually houses the clinical and engineering data for medical conditions, capabilities, and resources used to support these analyses. In addition, IMPACT-MD also provides data to the associated SysML model to support the Level 2, Level 3, and Level 4 requirements development needed for IMPACT. IMPACT-MD contains an internal Evidence Library (EL) sub-component that hosts the clinical evidence, treatment and outcome metric data, and incidence data for each medical condition identified for exploration-class missions. Furthermore, a separate Medical Item Database (MedID) sub-component hosts the engineering data and physical attributes (e.g., mass, volume, power, etc.) associated with each medical resource item identified to address the requisite medical conditions. The IMPACT project is conducted under the Exploration Medical Capability (ExMC) element of the Human Research Program (HRP) within NASA's Space Operations Mission Directorate (SOMD). The reader is referred to the documents in Appendix A for a more complete overview of the IMPACT tool suite and functionality as well as further detail on any associated aspects of the project. The primary purpose of this document is to describe the methods utilized in the collection and verification of engineering data content during the project development phase for the MedID sub-component of the IMPACT-MD project. Engineering content data (both existing and new/future) will be stored in IMPACT-MD for use by the IMPACT project. This document will detail the content development and data credibility for the engineering data housed within the MedID subcomponent of IMPACT-MD, which is used to inform the IMPACT 1.0 project deliverables.

Exploration Medical Capability↗

Practitioners, professional cultures, and perceptions of impact assessment

The very nature of impact assessment (IA) means that it often involves practitioners from a very wide range of disciplinary and professional backgrounds, which open the possibility that how IA is perceived and practised may vary according to the professional background of the practitioner. The purpose of this study is to investigate the extent to which a practitioner's professional background influences their perceptions of the adequacy of impact assessment in New Zealand under the Resource Management Act (RMA). Information gathered concerned professional affiliations, training, understanding of impact assessment practise, and perceptions of adequacy in relation to impact assessment. The results showed a dominance of a legalistic, operational perspective of impact assessment under the Resource Management Act, across all the main professions represented in the study. However, among preparers of impact assessments there was clear evidence of differences between the four main professional groups - surveyors, planners, engineers and natural scientists - in the way they see the nature and purpose of impact assessment, the practical steps involved, and what constitutes adequacy. Similarly, impact assessment reviewers - predominantly planners and lawyers - showed variations in their expectations of impact assessment depending on their respective professional affiliation. Although in many cases the differences seem to be more of a matter of emphasis, rather than major disputes on what constitutes a good process, even those differences can add up to rather distinct professional cultures of impact assessment. The following factors are seen as leading to the emergence of such professional cultures: different professions often contribute in different ways to an impact assessment, affecting their perception of the nature and purpose of the process; impact assessment training will usually be a secondary concern, compared with the core professional training, which will be reflected in the depth and length of such training; and any impact assessment training provided within a profession will often have the 'cultural' imprint of that profession.

54 ENVIRONMENTAL SCIENCES↗

Determination of the impact of glycolate on arp and mcu operations

Savannah River Remediation (SRR) is evaluating an alternate flowsheet for the Defense Waste Processing Facility (DWPF) using glycolic acid as a reductant. An important aspect of the development of the glycolic acid flowsheet is determining if glycolate has any detrimental downstream impacts. Testing was performed to determine if there is any impact to the strontium and actinide sorption by monosodium titanate (MST) and modified monosodium titanate (mMST) or if there is an impact to the cesium removal at the Modular Caustic-Side Solvent Extraction Processing Unit (MCU). Sorption testing was performed using both MST and modified MST (mMST) in the presence of 5,000 and 10,000 ppm (mass basis) glycolate. 10,000 ppm is the estimated bounding concentration expected in the DWPF recycle stream based on DWPF melter flammable gas model results. The presence of glycolate was found to slow the removal of Sr and Pu by MST, while increasing the removal rate of Np. Results indicate that the impact is a kinetic effect, and the overall capacity of the material is not affected. There was no measurable effect on U removal at either glycolate concentration. The slower removal rates for Sr and Pu at 5,000 and 10,000 ppm glycolate could result in lower DF values for these sorbates in ARP based on the current (12 hours) and proposed (8 hours) contact times. For the highest glycolate concentration used in this study, the percentage of Sr removed at 6 hours of contact decreased by 1% and the percentage of Pu removed decreased by nearly 7%. The impact may prove insignificant if the concentration of glycolate that is returned to the tank farm is well below the concentrations tested in this study. The presence of glycolate also decreased the removal rates for all three sorbates (Sr, Pu, and Np) by mMST. Similarly to MST, the results for mMST indicate that the impact is a kinetic effect, and the overall capacity of the material is not affected. The presence of glycolate did not change the lack of affinity of mMST for U. Pre-contacting the MST or mMST with glycolate did not have a significant effect on the performance of the materials when compared to tests having the same concentration of glycolate present in the simulant. These findings suggest that the glycolate is likely influencing removal by sorbate complexation and not by depositing onto or forming a film on the surface of the MST solids. Since the DF values are salt batch dependent, it is not possible to a priori quantify the impacts of glycolate on future processing campaigns. However, we recommend that the impacts of glycolate be evaluated during each salt batch qualification when a final processing concentration is defined, and recommendations can then be made on how to mitigate negative impacts, if needed. Impacts to the performance of the MST or mMST could be mitigated by increasing contact time or increasing sorbent concentrations. In addition to the MST and mMST testing, testing was performed to determine if there is an impact to the cesium removal at Modular Caustic-Side Solvent Extraction Processing Unit (MCU). An Extraction-Scrub-Strip (ESS) test routine was used to simulate cesium removal at the MCU. For this, SRNL performed three ESS tests, using the same basic aqueous waste simulant and solvent. For one test, SRNL added 5,000 ppm (mass basis) of glycolate and added 10,000 ppm of glycolate to a second test. A control test contained no glycolate. The results of all three tests were virtually identical for all the extraction, scrub and strip tests. (A single data point in the 5,000 ppm test is physically impossible and SRNL is currently resolving this obvious error.) At this time, SRNL concludes that the presence of up to 10,000 ppm of glycolate does not affect cesium removal by the current solvent system used in the MCU. Although not tested, the impact of glycolate for the Next Generation Solvent - that replaces BOBCalixC6 with MaxCalix - is expected to be very similar to that for the baseline solvent. Testing is needed to confirm. Additional testing is recommended to both further examine the nature of the interaction of glycolate with MST and mMST and also to help address some postulated risks on ARP/MCU operations with implementation of the glycolate flowsheet. The additional testing includes FTIR and Raman spectroscopy to examine the surface of the MST and mMST particles, iodometric titrations to determine the peroxide content in the mMST before and after exposure to glycolate, particle size measurements of the MST and mMST from the experiments performed with glycolate, and measurements of soluble Ti in the supernate from these glycolate experiments. With regards to MCU impacts, the following tests are also recommended based on the premortem risk assessment.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Effects of Impact and Target Parameters on the Results of a Kinetic Impactor: Predictions for the Double Asteroid Redirection Test (DART) Mission

Abstract The Double Asteroid Redirection Test (DART) spacecraft will impact into the asteroid Dimorphos on 2022 September 26 as a test of the kinetic impactor technique for planetary defense. The efficiency of the deflection following a kinetic impactor can be represented using the momentum enhancement factor, β , which is dependent on factors such as impact geometry and the specific target material properties. Currently, very little is known about Dimorphos and its material properties, which introduces uncertainty in the results of the deflection efficiency observables, including crater formation, ejecta distribution, and β . The DART Impact Modeling Working Group (IWG) is responsible for using impact simulations to better understand the results of the DART impact. Pre-impact simulation studies also provide considerable insight into how different properties and impact scenarios affect momentum enhancement following a kinetic impact. This insight provides a basis for predicting the effects of the DART impact and the first understanding of how to interpret results following the encounter. Following the DART impact, the knowledge gained from these studies will inform the initial simulations that will recreate the impact conditions, including providing estimates for potential material properties of Dimorphos and β resulting from DART’s impact. This paper summarizes, at a high level, what has been learned from the IWG simulations and experiments in preparation for the DART impact. While unknown, estimates for reasonable potential material properties of Dimorphos provide predictions for β of 1–5, depending on end-member cases in the strength regime.

58 GEOSCIENCES↗

Flight design system level C requirements. Solid rocket booster and external tank impact prediction processors

The prediction of the SRB and ET impact areas requires six separate processors. The SRB impact prediction processor computes the impact areas and related trajectory data for each SRB element. Output from this processor is stored on a secure file accessible by the SRB impact plot processor which generates the required plots. Similarly the ET RTLS impact prediction processor and the ET RTLS impact plot processor generates the ET impact footprints for return-to-launch-site (RTLS) profiles. The ET nominal/AOA/ATO impact prediction processor and the ET nominal/AOA/ATO impact plot processor generate the ET impact footprints for non-RTLS profiles. The SRB and ET impact processors compute the size and shape of the impact footprints by tabular lookup in a stored footprint dispersion data base. The location of each footprint is determined by simulating a reference trajectory and computing the reference impact point location. To insure consistency among all flight design system (FDS) users, much input required by these processors will be obtained from the FDS master data base.

Seale, R. H.↗

Temporal Evolution of SL-9 Impact Sites on Jupiter and Global Maps of Jupiter from Multi-Observatory Visible and Infrared Images

The objective of this research was to investigate the temporal behavior of the impact features on Jupiter created by the fragments of the Shoemaker Levy-9 comet that collided with the planet in July 1994. The primary observations used in the study were ground based images of Jupiter acquired from the Swedish Solar Vacuum Tube on the island of La Palma in the Canary Islands. The measurement of position of the impact features in images acquired immediately after the impact over a period of a few days revealed that the apparent drift rates were too high and that a repetitive pattern could be seen in the longitude position on successive rotations. This could be explained only by the fact that the measured longitudes of the impact sites were being affected by parallax due to a significant elevation of the impact debris above the nominal cloud top altitude value used for image navigation. Once the apparent positions are analyzed as a function of the meridian angle, the parallax equation can be used to infer the height of the impact features above the cloud deck, once the true impact position (longitude) for the feature is known. Due to their inherent high spatial resolution, the HST measurements of the impact site locations have been accepted widely. However, these suffer from the parallax themselves since few of them were obtained at central meridian. Ground based imaging have the potential to improve this knowledge as they do observe most of the impact sites on either side of the central meridian, except for the degraded resolution. Measurements over a large number of images enables us to minimize the position error through regression and thus estimate both the actual impact site location devoid of parallax bias, and also of the altitude level of the impact debris above the cloud deck. With rapid imaging there is the potential to examine the time evolution of the altitude level. Several hundred ground based images were processed, navigated and subjected to the impact site location measurements. HST images were also acquired and used to calibrate the results and to improve the sample. The resources available enabled an in-depth study only of impact site A, however, many more images have since become available through the global network observations through Lowell Observatory.

Limaye, Sanjay S.↗

Oceanic Impact: Mechanisms and Environmental Perturbations

The contents include the following: Oceanic impacts-a growing field of fundamental geoscience. Shock metamorphism on the ocean floor (numerical simulations). Numerical modeling of impact-induced modifications of the deep-sea floor. Computer modelling of the water resurge at a marine impact: the Lockne crater, Sweden. Experimental investigation of the role of water in impact vaporization chemistry. Calcareous plankton stratigraphy around the Pliocene Eltanin asteroid impact area (SE Pacific): documentation and application for geological and paleoceanographic reconstruction. Composition of impact melt debris from the Eltanin impact strewn field, Bellingshausen Sea. Iridium concentrations and abundances of meteoritic ejecta from the Eltanin impact in sediment cores from Polarstern expedition ANT XII/4. Unmelted meteoritic debris collected from Eltanin ejecta in Polarstern cores from expedition ANT XII/4. Impact tsunami-Eltanin. Ancient impact structures on modern continental shelves: The Chesapeake Bay, Montagnais, and Toms Canyon craters, Atlantic margin of North America. The Mjolnir marine impact crater porosity anomaly. Kardla (Hiiu-maa Island, Estonia) - the buried and well-preserved Ordovician marine impact structure. Long-term effect of the Kardla crater (Hiiu-maa, Estonia) on Late Ordovician carbonate sedimentation. The middle Devonian Kaluga impact crater (Russia): new interpretation of marine setting.

Gersonde, Rainer↗

An Impact Genesis for Loki Patera?

What happens when a large impact event takes place on a satellite with a thin crust and lithosphere? In the early Solar System impact cratering and volcanism were the dominate processes shaping the surfaces of the terrestrial planets. Impact events may have triggered additional volcanism by uplifting partially molten mantle material to the surface, where it melts due to pressure release. Subsequently, the shattered crust may have provided pathways for magma to reach the surface creating a longer term hot spot. As the crusts of the terrestrial planets thickened, the ability of impacts to trigger volcanism diminished [1]. However, the highly-volcanic jovian satellite Io is located in a "high-impact" area of the Solar System [2], a victim of material attracted by Jupiter s gravitational field. In 1994 huge impacts were observed when fragments of comet Shoemaker- Levy 9 impacted Jupiter. The large icy satellites of Jupiter (Europa, Ganymede and Callisto) are pockmarked with many impact craters. Yet no impact features have been found on Io [3]. This is because of rapid resurfacing of Io due to volcanism, estimated at approx.1 cm/year [4] which over short geological time erases evidence of impacts. Io, however, has a lithosphere over a molten or partially-molten mantle [e.g., 5], and the effects of a sufficiently large impact may extend far beyond the evolution of the impact crater alone. At least one example of impact-triggered volcanism may exist in the Solar System today: the Loki Patera complex on Io.

Thorsos, I. E.↗