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At least 739 records · Page 41

A Simulated Drilling Mission to Search for Biomolecular Signatures of Life on Mars Performed in the Atacama Desert (Chile): Demonstrating Drilling, Sample Handling, and Life-Detection Instruments Remotely Operated with Mission-like Protocols

The search for evidence of life on Mars requires accessing materials that are protected from the oxidizing and irradiated conditions at the surface. Mars rovers Curiosity and Perseverance have performed shallow (few cm) drilling to access relevant samples. The upcoming ExoMars mission will acquire samples from up to 2 meters depth. Field experiments in Mars analog sites help prepare for this and other future deep drilling missions. In Sept. 2019 the ARADS (Atacama Rover Astrobiology Drilling Studies project (Glass et al. 2022) conducted a roverbased drilling mission to search for biomolecular evidence of life in a Mars analog site in Atacama, Chile.

Carol R. Stoker↗

Recent Results from Dragonfly Testing/Analysis as we head to PDR

Dragonfly is a relocatable lander mission to Saturn's moon Titan4, which as well as being a target of out-standing astrobiological interest as an organic-rich Ocean World, has the combination of low gravity (1/7 that of Earth) and a thick atmosphere (4x the density of Earth), making it an environment uniquely suitable for flight. Thus, the Dragonfly lander (similar in size to the Curiosity Mars rover) can take off using lift from a set of eight rotors and fly to a new landing site several kilometers away. The ability to perform such flights, lasting approximately 30 minutes, every month or so on Titan brings unprecedented mobility to planetary exploration, on a world known to have a diverse land-scape of dunes, craters and other features. Dragonfly is planned to launch in 2027, and following a nearly seven year interplanetary cruise would arrive at Titan by 2034. Due to the large scale height of the Titan atmosphere, Entry, Descent, and Landing (EDL) will be prolonged affair, taking nearly two hours to reach the surface. The ballistic entry environments that Dragonfly will be subjected to are fairly similar to that experienced by recent Mars missions; peak heating on the aeroshell will be about 300 W/sq.cm and peak deceleration is about 10g’s. Following the five minute entry segment, much of the remaining time is spent descending on the drogue and main para-chutes, which carry the dual role of decelerating the spacecraft and stabilizing the system during the long descent. While on one hand, this leisurely EDL sequence affords a relaxed timeline and plenty of time for event staging, it also provides ample opportunity for small disturbances to grow into potential flight safety risks, adding emphasis to the need for careful modeling, simulation and testing of key dynamic events. About two hours after entering the atmosphere, the nearly one metric ton rotocraft will be lowered approximately one meter out of the backshell (the ‘pose’ maneuver) to expose all eight rotors. The rotors will then be used to arrest any residual spin rate and prepare the system for transition to powered flight. Once despin is complete and the lander reaches a target altitude of 1.2 km above the surface (as verified by on-board lidar), the lander will be released and free fall for approximately one second before beginning controlled free flight. This entire “preparation for powered flight” process takes place over several minutes while the system is subject to the dynamic environment produced by so-called “wrist-mode” oscillations as the lander and backshell swing on the main parachute. Once in free flight, the lander will engage on-board terrain relative navigation to locate and navigate to a safe landing zone in the Shangri-La dune field south of Selk crater. Communication during this sequence will be limited to a series of direct-to-Earth X-band tones signalling key events and providing forensic information. Once on the ground, the lander will begin to send additional information, including data collected during this EDL sequence by the on-board Dragonfly Entry Aerosciences Measurements (DrEAM) instrumentation suite. This presentation will walk through the entry to first landing timeline in more detail, with a focus on recent analysis and testing results that inform system performance, margins and residual risk estimation.

Dragonfly↗

Filling the Gaps in Understanding Solar Flares

Solar flares provide a laboratory for plasma physics and magnetohydrodynamic processes. While the mechanism of transferring magnetic flux between topological domains via reconnection is accepted in a general sense, some of the finer details remain to be worked out: What elusive thresholds, pertaining to which physical quantities, determine the initiation of flux transfer that cascades into the energy release observed in the impulsive phase of a flare? What role does turbulence play in accelerating or prolonging magnetic reconnection? To what degree do magnetic waves contribute to the transport of energy, or to the acceleration of particles in the impulsive phase? While our innate human curiosity and our instinctive impulse to explore compel us to investigate these intricacies of million-degree magnetized plasmas, the impacts of space weather on our technology-dependent society and economy obligate us to pursue a quantitative understanding, with the ultimate goal being trustworthy predictive capabilities. In this presentation, I will touch upon a few aspects of solar flares where improvements in observational and analytical capabilities can be expected to help us fill gaps in our understanding, as well as some of the recent, current, and near-term developments that are carrying the field forward.

David E. McKenzie↗

Importance of Sulfur for Phosphorus Mobility on the Martian Surface

Sulfur and phosphorus were mobile on the martian surface, and we present evidence that sulfate was likely a control on phosphate mobility. Mobility of the two elements on the martian surface is crucial for the habitability of Mars because their availability for biochemical reactions and biological structures is a major constraint on life. In the sedimentary rocks of Gale crater, the rover Curiosity has discovered evidence of mobile S and P with the alpha particle X-ray spectrometer (APXS). Sulfur-rich fluids are evident in ubiquitous Ca-sulfate veins that crosscut the bedrock. Compelling evidence of P mobility is in nodules, veins, crusts, and haloes with P2O5 enrichments (1.5-7.5 wt%) relative to the median bedrock (0.9-1.2 wt%) and average basaltic crust (~0.9 wt%). We have investigated phosphorus mobility in Hawaiian analogues, where the primary P2O5 (0.2-2.1 wt%) is contained in Ca-apatite. Four relevant processes have emerged: (1) In open-system, circumneutral regolith weathering profiles, we found up to 40% of the P was leached over 10s-100s ka. (2) Natural acid-sulfate alteration at the Maunakea summit resulted in the dissolution of apatite and mobilization of phosphate 10s-1000s µm to rock surfaces where it formed Al-phosphates and substituted into crystalline sulfates (alunite and jarosite). (3) Experimental results indicate that basaltic sediment chemisorbs phosphate (pH < 7). (4) In experimental systems containing water, basaltic sediment, and a starting pH = 2-7, phosphate has higher solubility in chloride-rich fluids, but significantly lower solubility in sulfate-rich fluids. For example, in water doped with phosphate (~100-500 mg/L), ~60-80% of the PO43- was removed from the sulfate-rich fluid, whereas ~20% of the PO43- was removed from the Cl-rich and pure water fluids (likely via adsorption). Gypsum precipitated from the sulfate-rich fluids; the fate of phosphate in the solid residue is unconfirmed. The potential for phosphate incorporation in martian sulfates is reflected in the enrichment of P2O5 in Gale Ca-sulfate veins, based on preliminary analyses of APXS data. Models for the mobility of phosphorus in Gale crater should consider these conflicting P characteristics: (1) P solubility may have been inhibited by sulfate and (2) P¬ is enriched in diagenetic features and was therefore mobile.

Jeff A. Berger↗

Isochemical Characteristics of the Clay-Sulfate Transition in Gale Crater, Mars: APXS Results From Mont Mercou to the Marker Band Valley

During sols 3052-3572 (March 2021 to August 2022), Curiosity traversed a region in Gale crater where orbital observations predicted a vertical stratigraphic transition from a phyllosilicate unit to the overlying layered sulfates of Mt. Sharp [1, 2]. This region was informally named the clay-sulfate transition (CST). The Alpha Particle X-ray Spectrometer (APXS) was systematically deployed to sedimentary bedrock and selected diagenetic features to analyze possible chemical changes with increasing elevation (a proxy for increasing stratigraphic position). The occurrence of Ca- and Mg-sulfate was a particular focus. Here, we present results from the APXS investigation of the CST, as well as results from the first targets of the sulfate unit located in Marker Band Valley (MBV).

J.A. Berger↗

High Resolution Imaging and Analysis of Terrestrial Impact Glass: Amorphous Materials, Phyllosilicates and Everything in Between

Introduction: Impact cratering is one of the most ubiquitous geologic processes shaping the surface of all solid bodies in our solar system. Impacts are also a major source of clay minerals, poorly crystalline clay-like phases and amorphous (i.e., lacking long-range atomic order) materials on Earth and Mars. Phyllosilicates and amorphous materials have consistently formed a major component (~20-70 wt%) of every single drilled rock and soil sample in Gale Crater on Mars, as determined by the CheMin instrument on Curiosity. The origin of the amorphous component is speculative, but could be primary impact or volcanic-produced glass(es) deposited via aeolian or fluvial processes, secondary aqueous alteration products or chemical precipitates; it is likely to be a combination of all three possibilities. Efforts to determine the composition of these materials across the rover’s traverse through Gale Crater are ongoing. Naturally occurring amorphous phases are found in a variety of environments on Earth, and terrestrial analogue studies may help shed light on how they may have formed on Mars. Primary and altered impact glass are likely widespread on Mars and may have contributed to the amorphous component found throughout Gale Crater. In its pristine, unaltered state, impact glass (i.e., melt glass) is considered amorphous. However, truly unaltered glass is rarely preserved in crater fill impactites as it quickly alters in the post-impact environ-ment, commonly forming a mixture of hydrated aluminosilicate phases whose structures are not always discernable at the microscale (i.e., they may be amorphous or contain short-range order). These phases are part of an incredibly complex group of materials; differences in their composition and crystalline structure (or lack thereof) and genetic relationship to the more well-crystalline clay minerals are often only discernable at the nanoscale, beyond the resolution of traditional X-ray diffractometers (XRD) and scanning electron microscopes/microprobes (SEM/EPMA) alone. In this contribution, we summarize recent results from ongoing characterization of clay minerals, poorly crystalline clay-like phases, and amorphous materials preserved in altered terrestrial impact glass from the Chicxulub (~66 Ma) and Ries (~15 Ma) impact structures. This work has been performed using a combination of high-resolution transmission electron microscopy (HR-TEM), SEM, microprobe/EPMA, Raman spectroscopy and XRD.

Impact crater↗

Magma-Sediment Interaction Induced Alteration Mineralogy on Mars: Detectability and Analytical Method Comparison Using the Curtis Sandstone as A Terrestrial Analog

Basaltic magmatism is a ubiquitous feature of the Martian crust, and would have interacted with sediments and fluids through the geologic history of Mars to potentially produce higher temperature hydrothermal systems , and contact metamorphic rocks. On Earth, comparable hydrothermal systems represent habitable environments, which can be used as an analog for Mars. Nevertheless, evidence of aforementioned hydrothermal systems on Mars has remained elusive, despite the efforts of both orbital and in-situ analyses. Limited low grade metamorphic minerals typically indicative of hydrothermal systems (prehnite, zeolites, serpentine) have been detected in the Martian crust, though the detections are typically isolated occurrences, and do not necessarily indicate an in-place metamorphic sequence. It is possible that orbital spectroscopy alone is not capable of detecting such an alteration front, with higher resolution in-situ analyses being required to detect the changes in mineralogy and species of alteration minerals associated with magma-sediment interaction. To constrain this, we have investigated a terrestrial analog on the Colorado Plateau, USA, where a mafic dike intrudes a quartz areinite of the Jurassic Curtis Sandstone. The investigation was carried out using Mars relevant instruments: Visible to Near-Infrared (VNIR) spectroscopy analogous to orbital spectroscopy, and X-ray Diffraction (XRD) analogous to CheMin on Mars Sample Laboratory Curiosity. While quartz sandstones have not been, and are unlikely to be, detected on Mars, the relatively mineralogically uniform Curtis Sandstone serves as analog here as it avoids complications of multiple mineral systems or significant element exchange with the surrounding area.

J R Crandall↗

Artificial Intelligence Enhancements to Imagery for Space Operations

Philosophy classes still ponder the question asked by Dr. George Berkely, an Anglican Bishop and philosopher in the 1600’s-- “If a tree falls in a forest and no one is around to hear it, does it make a sound?” With that in mind, I ask the following—If a still image or motion imagery from a space mission cannot be found during a search, does it exist? Since the beginning of spaceflight, imagery has been a key form of data collected. Whether for mere curiosity (what does Earth look like from Space?), or for operational reasons (did the solar panel deploy?), or for engineering purposes (what was that object that floated away from the spacecraft?), imagery has been included in space missions. To be useful, though, the image or motion imagery must be accessible and accessed when needed. During the analog era, that typically meant captions and numbers associated with the physical media. With “born digital” imagery, it is possible to add metadata to the image data file. This metadata might include the date and time of capture, mission, camera, exposure data, and similar data fields. Many modern cameras embed some basic metadata into the image file at the moment of capture. The reality, though, is even with today’s born-digital enhancements with embedded metadata at the time of capture, reviewing and cataloging still and motion imagery is very labor intensive. Humans review the imagery for sensitive content (privacy concerns, imagery containing proprietary data/subject matter), and to identify imagery containing crew members or imagery that should be reviewed for engineering or scientific reasons. All this review and manual data entry is very time-consuming. Many improvements in Artificial Intelligence (AI), Machine Learning, and processing power now make it possible to identify persons, objects, motion, color, audio with sensitive content, and other details after or while the imagery is captured.

Rodney Grubbs↗

Investigating Physical and Chemical Weathering of Fluvial and Aeolian Sediments in Mars-Analog Environments Using Close-Up Image Analysis

Results from the NASA Curiosity rover show that the ancient (>3 Ga) sedimentary rocks in Gale crater formed by fluvial and lacustrine processes, with aeolian processes dominating the geological record after the river-lake system ended in the Hesperian. The sedimentary system in Gale crater contains a mineralogy dominated by basaltic materials, not the quartzofeldspathic minerals that derive most sedimentary rocks on the Earth. There remains a knowledge gap for understanding how basaltic materials are physically and chemically weathered in fluvial and aeolian environments. This research aims to under-stand how the physical and chemical characteristics of basaltic sediments change as they are transported from source-to-sink in Mars-analog environments utilizing close-up images and X-Ray Diffraction (XRD) analysis. These data were collected as part of the SAND-E mission.

F D Garcia Ledezma↗

Carbon Limited Soils of Iceland: Analogs for Identifying Carbon-Mineral Interactions in Gale Crater, Mars Surface Materials

The Mars Science Laboratory’s Curiosity rover mission to Gale Crater, Mars has a goal to search for organic carbon and corresponding evidence of ancient microbiology preserved in clay mineral-rich sedimentary deposits [1]. No clear correlation of clay mineral (smectite) abundances with the Sample Analysis at Mars (SAM) carbon detections (up to 2000 ppm C) [2] has been established, suggesting other phases may preserve organic C in martian sediments. Terrestrial volcanic glass soils can accumulate C due to the C-complexing abilities of poorly crystalline Al- and Fe-oxyhydroxides [3]. The Xray amorphous component (20 to 73 wt. %) in Gale Crater materials [4,5] has received little consideration regarding organic C preservation in Gale Crater. The objectives of this work are to 1) Evaluate C content and level of soil development of basaltic glass-bearing Icelandic soils to determine the role that poorly crystalline phases have in complexing organic C in carbon limited soils and 2) Determine if evolved gas analysis (EGA) of well-characterized Mars analog basaltic materials from Iceland can be used to interpret SAM data to understand the nature of organic-C mineral/geochemical associations in Gale materials.

B. Sutter↗

Hematite Formation and Growth in Gale Crater Seen Through MSL Chemin X-Ray Diffraction Data

For more than 10 Earth years, the Mars Science Laboratory (MSL) Curiosity rover has been studying modern sediments and ancient sedimentary rocks deposited by lacustrine, fluvial, deltaic, and eolian processes in Gale crater. The mineral and X-ray amorphous abundances in rocks and sediments have been quantified via X-ray diffraction (XRD) data from the CheMin instrument. The received data demonstrate significant mineralogical variations within the stratigraphy, including changes in the type and abundances of Fe-oxides/oxyhydroxides silica polymorphs, phyllosilicates, and sulfate minerals. Characterizing Fe-oxides/oxyhydroxide minerals in Gale crater is especially important for constraining past aqueous environments because their formation depends on a variety of conditions, including pH, Eh, temperature, and salinity. Hematite, magnetite, goethite, and akaganeite have been identified by CheMin in different portions of the stratigraphic section. Hematite is the most prevalent Fe-bearing oxide mineral and has been detected (>1 wt.%) in 34 of the studied 36 drill targets. Variations in hematite crystallite size were reported in association with Vera Rubin ridge, which has a strong hematite signature in orbital reflectance spectroscopy. Here, we calculate hematite crystallite sizes and shapes for the entire stratigraphic section to date, to characterize trends and evaluate the processes by which hematite formed and transformed in Gale crater.

M. Szczerba↗

Testing Destruction of Clay Minerals By Silica-Poor Brines in Gale Crater, Mars Using Laboratory and Field Experiments

The Mars Science Laboratory (MSL) Curiosity rover landed in Gale crater to investigate the cause for mineralogical changes seen from orbit, including the clay-sulfate mineral transition observed on its central mound, Aeolis Mons. The lower strata show spectral signatures of clay minerals, hematite, and hydrated Mg sulfates, and the upper strata are dominated by hydrated Mg sulfate signatures. This significant transition has been observed in other locations on Mars, and therefore processes related to the clay mineral-sulfate transition are likely important broadly across Mars. The bulk mineralogy of ~3.7 Ga sedimentary rocks in Gale crater is a product of variations in sediment sources and depositional processes, with overprinting by episodes of early and late diagenetic alteration. Sedimentary analyses of the smectite clay minerals observed in the Glen Torridon (GT) region of Mount Sharp suggest formation in a lacustrine aqueous environment. Examination of the Vera Rubin ridge (VRR) strata indicate that it was formed at the same time as GT and later altered by extensive diagenesis. Recent work suggests that the observed mineral transition from smectites and talc-serpentinites in GT to iron oxides and oxyhydroxides and VRR may have resulted from extensive diagenetic alteration by density driven, silica-poor brines sourced from the overlying sulfur-bearing unit on Mount Sharp. This process of alteration by silica-poor brines is observed in limited locations on Earth. We are therefore working to demonstrate the impacts of silica poor brines on clay mineral alteration in laboratory column and terrestrial analog burial experiments. Column experiments allow the investigation of dissolution and precipitation under conditions that represent a closer analog to natural environments, while burial experiments allow examination of weathering reactions of a known starting material after a specific period of time in a natural field environment. Both methods are valuable for interpreting the water-rock interactions between clay minerals and brines. In preparation for these longer-term column and burial experiments, we are performing preliminary batch dissolution experiments on materials relevant to Glen Torridon: nontronite and serpentinite. We are using magnesium sulfate brine solutions relevant to those proposed on Mars. The results of this study can provide constraints on the characteristics of the diagenetic fluids that formed the altered minerals in Gale crater. They can also provide insights into the role of brine density-driven diagenesis in past aqueous environments on Mars, which have been proposed to be widespread.

J E Valdueza↗

The Non-Destructive Separation of Diverse Astrobiologically Relevant Organic Molecules By Customizable Capillary Zone Electrophoresis and Monolithic Capillary Electrochromatography

The in situ detection of organic molecules in space is key to understanding the variety and the distribution of the building blocks of life, and possibly the detection of extraterrestrial life itself. Gas chromatography mass spectrometry (GC-MS) has been the most sensitive analytical instrument for organic analyses in flight, and was used on missions from NASA’s Viking, Phoenix, Curiosity missions to ESA’s Rosetta space probe. While pyrolysis GC-MS revealed the first organics on Mars, this step alters or degrades certain fragile molecules that are excellent biosignatures including polypeptides, oligonucleotides and polysaccharides, rendering the intact precursors undetectable. We have identified a solution tailored to the detection of biopolymers and other biomarkers by the use of liquid-based capillary electrophoresis and electrochromatography. In this study, we show that a capillary electrochromatography (CEC) approach using monolithic stationary phases with tailor-made surface chemistry can separate and identify various polycyclic aromatic hydrocarbons (PAHs), nucleobases and aromatic acids that could be formed under astrophysically relevant conditions. In order to simulate flyby organic sample capture, we conducted hypervelocity impact experiments which consisted of accelerating peptide-soaked montmorillonite particles to a speed of 5.6 km/sec, and capturing them in an amorphous silica aerogel of 10 and 30 mg/cc bulk density. Bulk peptide extraction from aerogel followed by capillary zone electrophoresis led to the detection of only two stereoisomeric peptide peaks. The recovery rates of each step of the extraction procedure after the hypervelocity impact suggest that major peptide loss occurred during the impact. Our study provides initial exploration of feasibility of this approach for capturing intact peptides, and subsequently detecting candidate biomolecules during flight missions that would be missed by GC-MS alone. As the monolith-based electrochromatography technology could be customized to detect specific classes of compounds as well as miniaturized, these results demonstrate the potential of the instrumentation for future astrobiology-related spaceflight missions.

Flyby sample return↗

X-Ray Amorphous Sulfur-Bearing Phases in Sedimentary Rocks of Gale Crater, Mars

The Curiosity rover in Gale crater is investigating a mineral transition observed from orbit—an older “clay unit” to a younger “sulfate unit”—hypothesized to reflect the aridification of Mars' climate. Below this transition, the rover detected crystalline Ca-sulfates with minor Fe-sulfates but also found that some fraction of a rock's bulk SO 3 is often in the poorly constrained X-ray amorphous component. Here, we characterize the abundances and compositions of the X-ray amorphous sulfur-bearing phases in 19 drilled samples using a mass balance approach, and in a subset of 5 samples using evolved SO 2 gas measured using the SAM instrument. We find that ∼20–90 wt% of a sample's bulk SO 3 is in the X-ray amorphous state and that X-ray amorphous sulfur-bearing phase compositions are consistent with mixtures of Mg-S, Fe-S, and possibly Ca-S phases, likely sulfates or sulfites. These phases reside in the bedrock, perhaps as cementing agents deposited with detrital sediments or during early diagenesis, and in diagenetic alteration halos deposited after lithification during late diagenesis. The likely presence of highly soluble Mg-sulfates in the rocks suggests negligible fluid flow through the bedrock post-Mg-sulfate deposition. The X-ray amorphous sulfur-bearing phases probably became amorphous through dehydration in the current Martian atmosphere or inside the CheMin instrument. X-ray amorphous sulfur-bearing materials likely contribute to orbital spectral detections of sulfates, and so our results help form multiple hypotheses to be tested in the sulfate unit and are important for understanding the evolution of the Martian surface environment at Gale crater.

R. J. Smith↗

Mineralogical, Elemental, and Tomographic Reconnaissance Investigation for CLPS (METRIC)

METRIC is a robotic science laboratory that can determine the mineralogy, elemental chemistry, micromorphology, and thermophysical properties of planetary regolith. The METRIC suite comprises METRIC XRD/F, an X-ray diffraction/X-ray fluorescence instrument that can determine the mineralogy and elemental chemistry of regolith samples; METRIC XCT, a micro X-ray computed tomography instrument that can be used to evaluate grain/crystallite sizes and textures; METRIC IRS, an imaging spectrometer mounted on a rover that can determine mineralogy and thermophysical properties at the landing site; and a pneumatic sample collection, processing, distribution system developed by Honeybee Robotics. The payload elements could be deployed on a static lander or a rover. Data returned from the METRIC payload would inform origin, formation, and evolution of rocky planetary bodies. METRIC XRD/F draws on heritage from the CheMin instrument on the Mars Science Laboratory (MSL) Curiosity rover [1], with a few important improvements. Like CheMin, METRIC XRD/F operates in transmission geometry and uses piezoelectric actuators on sample cells in a tuning fork geometry to induce convective grain motion of the regolith to create a randomly oriented powder. MSL CheMin uses an energy-sensitive CCD to collect XRD patterns and XRF spectra simultaneously from the same sample cell, resulting in qualitative XRF data. METRIC XRD/F uses two different sample cells, one optimized for XRD and one optimized for XRF, and a silicon drift detector to detect fluoresced X-rays. This improvement to the XRF capabilities provides quantitative geochemical data of major elements down to Z = 11 and allows for the detection of minor and trace elements that are critical for evaluating geologic evolution of the Moon (e.g., P and Th). Modest improvements to the XRD geometry and hardware allow for better angular resolution and the ability to distinguish between members of the pyroxene group. METRIC XCT uses the same geometry and much of the same hardware as METRIC XRD/F, where a CCD would capture images of a regolith sample in a 3 mm diameter sample tube that is rotated 360° in steps <1°. Image brightness can be used to infer compositional data, where brighter materials indicate a higher Z, much like scanning electron microscopy. Data from METRIC XCT complement those from METRIC XRD/F. Particle size, shape, and texture can provide petrologic and provenance information, whereas vesicle size and morphology in volcanic or impact melt lithologies can inform cooling rates. METRIC IRS is a hyperspectral thermal imager that can be mounted to a lander or rover to provide mineralogical data from the broader landing site and help determine whether the samples analyzed by METRIC XRD/F and XCT are representative. The METRIC IRS spectral range (8–14 μm) and resolution (10.8 cm-1) allow for quantitative mineralogy from modelling Reststrahlen bands of major rock-forming minerals (e.g., silicates, phosphates). Radiance cubes can be processed and modelled with an onboard high-performance computer to determine mineral abundances of plagioclase, high-Ca pyroxene, pigeonite, orthopyroxene, olivine, and glass. Regolith samples can be acquired, processed, and delivered to the X-ray instruments via multiple sample handling systems, but the pneumatic sampling systems developed by Honeybee Robotics [e.g., 2] are best suited for relatively low-cost missions that are being competed for the Moon (e.g., NASA’s Payloads and Research Investigations for the Surface of the Moon program). There are pneumatic sampling systems that collect surface material and other systems that pneumatically drill up to ~1 m below the surface, providing material that has not been space weathered and has not been affected by the lander’s exhaust. [1] Blake, D. F., Vaniman, D., Achilles, C., Anderson, R., Bish, D., et al. (2012). Space Sci. Rev. 170, 341-478. https://doi.org/10.1007/s11214-012-9905-1. [2] Zacny, K., Betts, B., Hedlund, M., Long, P., Gramlich, M., Tura, K., Chu, P., Jacob, A., Garcia, A. (2014). IEEE Aerospace Conference, 3-7 March 2014, Big Sky, MT, U.S.A.

X-ray diffraction↗

A Primordial Atmospheric Origin of Hydrospheric Deuterium Enrichment on Mars

The deuterium-to-hydrogen (D/H or 2H/1H) ratio of Martian atmospheric water (~6× standard mean ocean water, SMOW) is higher than that of known sources, requiring planetary enrichment. A recent measurement by NASA’s Mars Science Laboratory rover Curiosity of Hesperian-era (>3 Ga) clays yields a D/H ratio ~3×SMOW, demonstrating that most of the enrichment occurs early in Mars’s history, reinforcing the conclusions of Martian meteorite studies. As on Venus, Mars’s D/H enrichment is widely thought to reflect preferential loss to space of 1H (protium) relative to 2H (deuterium), but both the cause and the global environmental context of large and early hydrogen losses remain to be determined. Here, we apply a recent model of primordial atmosphere evolution to Mars, link the magma ocean of the accretion epoch with a subsequent water-ocean epoch, and calculate the behavior of deuterium for comparison with the observed record. In contrast to earlier works that consider Martian D/H fractionation in atmospheres in which hydrogen reservoirs are present exclusively as H2O or H2, here we consider 2-component (H2O-H2) outgassed atmospheres in which both condensed (H2O) and escaping (H2) components – and their interaction – are explicitly calculated. We find that a a ≈2-3× hydrospheric deuterium-enrichment is produced rapidly if the Martian magma ocean is chemically reducing at last equilibration with the primordial atmosphere, making H2 and CO the initially dominant species, with minor abundances of H2O and CO2. Reducing gases – in particular H2 – can cause substantial greenhouse warming and prevent a water ocean from freezing immediately after the magma ocean epoch. We find that greenhouse warming due to plausible H2 inventories (pH2=1-102 bars) yields surface temperatures high enough (Ts=290-560 K) to stabilize a water ocean and produce an early hydrological cycle through which surface water can be circulated. Moreover, the pressure-temperature conditions are high enough to produce ocean-atmosphere H2O-H2 isotopic equilibrium through gas-phase deuterium exchange such that surface H2O strongly concentrates deuterium relative to H2, which preferentially takes up protium and escapes from the primordial atmosphere. The efficient physical separation of deuterium-rich (H2O) and deuterium-poor (H2) species via condensation permits equilibrium isotopic partitioning and early atmospheric escape to be recorded in modern crustal reservoirs. The proposed scenario of primordial H2-CO-rich outgassing and escape suggests significant durations (>Myr) of chemical conditions on the Martian surface conducive to prebiotic chemistry immediately following magma ocean crystallization.

Mars↗

Mars 2020 Perseverance Entry Descent and Landing Simulation Statistical Analysis and Operations

On February 18, 2021, the Perseverance rover and Ingenuity helicopter demonstra- tion landed at Jezero Crater. The Entry, Descent, and Landing (EDL) architecture, largely the same used to land Curiosity at Gale Crater on August 6, 2012, required high-fidelity flight dynamics simulation with two independent tools to verify per- formance. The process for creating the EDL simulation using the Dynamics Sim- ulator for Entry, Descent and Surface landing (DSENDS) tool will be discussed, along with its use for for independent verification of the EDL statistical analy- sis results and reference trajectory simulation. Analysis and usage details both in development and cruise, along with post-landing assessment of the prediction performance of the simulation, will also be discussed.

"O'Farrell, Clara"↗

The Mars 2020 Perseverance Navigation Filter

The Mars 2020 (M2020) Entry Descent and Landing (EDL) system delivered a rover named “Perseverance” at Jezero crater (Mars) on February 18th, 2021. M2020 EDL used a Guidance Navigation and Control (GN&C) system to achieve its landing target objectives. The navigation filter (NavFilter) integrated Descent Inertial Measurement Unit (DIMU) measurements to estimate position and attitude. The NavFilter also used the Terminal Descent Sensor (TDS) to es-timate surface-relative position and velocity corrections. The NavFilter provided all of the dynamic state information to the entry controller, entry guidance, Lander Vision System (LVS) and powered descent guidance and control algo-rithms. The NavFilter for Perseverance is based on Curiosity’s NavFilter with a couple of modifications.

Casoliva, Jordi↗