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At least 739 records · Page 41

Color Changing Material for Hydrogen Leak Detection

Kennedy Space Center scientists developed a hydrogen leak sensor utilizing a combination of chemochromic pigment and polymer that can be molded or fiber spun into rigid or flexible shapes such as tape. The sensor turns a dark color when exposed to hydrogen gas. This sensor has proven to be very effective for pinpointing the exact location of leaks in hydrogen gas lines and fittings at launch pads. Kennedy Space Center exclusively licensed this technology to the University of Central Florida (UCF), who also holds patents that are complimentary to KSC's. UCF has bundled the patents and exclusively licensed the portfolio to HySense Technology LLC, a startup company founded by a UCF professor who supports the UCF Florida Solar Energy Center (FSEC). HySense has fully developed its product (known as Intellipigment"TM"), and currently has five commercial customers. The company recently won the $100,000 first-place award at the CAT5 innovation competition at the Innovation Concourse of the Southeast: Safety & Manufacturing event in Orlando, FL. Commercial production and sales of this technology by HySense Technology will make this leak sensor widely available for use by NASA, DoD, and industries that utilize hydrogen gas.

Material for Hyrogen↗

Color Evolution from z=0 to z=1

Rest frame Stromgren photometry is presented for 509 galaxies in 17 rich clusters between z=0 and z=1 as a test of color evolution.

galaxies↗

Development and Validation of an Empirical Ocean Color Algorithm with Uncertainties: A Case Study with the Particulate Backscattering Coefficient

We explored how algorithm (model) and in situ measurement (observation) uncertainties can effectively be incorporated into empirical ocean color model development and assessment. In this study we focused on methods for deriving the particulate backscattering coefficient at 555 nm, b(bp)(555)/(m). We developed a simple empirical algorithm for deriving b(bp)(555) as a function of a remote sensing reflectance line height (LH) metric. Model training was performed using a high-quality bio-optical dataset that contains coincident in situ measurements of the spectral remote sensing reflectances, R(rs)(λ)/(sr), and the spectral particulate backscattering coefficients, b(bp)(λ). The LH metric used is defined as the magnitude of Rrs(555) relative to a linear baseline drawn between R(rs)(490) and R(rs)(670). Using an independent validation dataset, we compared the skill of the LH-based model with two other models. We used contemporary validation metrics, including bias and mean absolute error (MAE), that were corrected for model and observation uncertainties. The results demonstrated that measurement uncertainties do indeed impact contemporary validation metrics such as mean bias and MAE. Zeta-scores and z-tests for overlapping confidence intervals were also explored as potential methods for assessing model skill.

ocean color↗

Adaptive Data Screening for Multi-Angle Polarimetric Aerosol and Ocean Color Remote Sensing Accelerated by Automatic Differentiation

Remote sensing measurements from multi-angle polarimeters (MAPs) contain rich aerosol microphysical property information, and these sensors have been used to perform retrievals in optically complex atmosphere and ocean systems. Previous studies have concluded that, generally, five moderately separated viewing angles in each spectral band provide sufficient accuracy for aerosol property retrievals, with performance gradually saturating as angles are added above that threshold. The Hyper-Angular Rainbow Polarimeter (HARP) instruments provide high angular sampling with a total of 90-120 unique angles across four bands, a capability developed mainly for liquid cloud retrievals. In practice, not all view angles are optimal for aerosol retrievals due to impacts of clouds, sun glint, and other impediments. The many viewing angles of HARP can provide resilience to these effects, if the impacted views are screened from the dataset, as the remaining views may be sufficient for successful analysis. In this study, we discuss how the number of available viewing angles impacts aerosol and ocean color retrieval uncertainties, as applied to two versions of the HARP instrument. AirHARP is an airborne prototype that was deployed in the ACEPOL field campaign, while HARP2 is an instrument in development for the upcoming NASA Plankton, Aerosol, Cloud, ocean Ecosystem (PACE) mission. Based on synthetic data, we find that a total of 20-30 angles across all bands (i.e. five to eight viewing angles per band) are sufficient to achieve good retrieval performance. Following from this result, we develop an adaptive multi-angle polarimetric data screening (MAPDS) approach to evaluate data quality by comparing measurements with their best-fitted forward model. The FastMAPOL retrieval algorithm is used to retrieve scene geophysical values, by matching an efficient, deep learning-based, radiative transfer emulator to observations. The data screening method effectively identifies and removes viewing angles affected by thin cirrus clouds and other anomalies, improving retrieval performance. This was tested with AirHARP data, and we found agreement with the High Spectral Resolution Lidar-2 (HSRL-2) aerosol data. The data screening approach can be applied to modern satellite remote sensing missions, such as PACE, where a large amount of multi-angle, hyperspectral, polarimetric measurements will be collected.

multi-angle polarimeter↗

New Global Ocean Color Sensor: OCI on PACE

- OCI will provide TOA radiances at ~1km spatial resolution, from 340nm (315nm?) to 2260nm, hyperspectral from 340nm to 890nm, 2 day global coverage - OCI will continue and enhance NASA’s earth system data records for ocean color (heritage sensors: SeaWiFS, MODIS, VIIRS) - OCI flight unit is close to being ready for testing (planned for March 2022 to September 2022) - OCI ETU (Engineering Test Unit) completed testing summer 2021, results look promising (see next presentation) - On-orbit calibration will combine successful trending approaches from previous sensors (2 solar diffusers, QVD, lunar gain trending, spectral trending) - New calibration approaches for OCI: large QVD, dim diffuser for linearity trending, lunar hysteresis trending - OCI will be characterized prelaunch with an ambitious goal of 0.5% relative uncertainty; absolute uncertainty will be about 2% (before vicarious calibration); expected on-orbit gain trending accuracy is 0.2% or better - More info on PACE and OCI can be found at https://pace.oceansciences.org/

radiometer↗

Pulse Response of the Short-Wave Infrared Detection System of the Ocean Color Instrument for the NASA PACE Mission

The Ocean Color Instrument (OCI) on NASA’s Plankton, Aerosol, Cloud, ocean Ecosystem (PACE) mission is a hyperspectral Earth imager with a spatial resolution of 1 km x 1 km and a spectral resolution of 5 nm in 2.5 nm steps over 342-887 nm. In addition, OCI provides 7 discrete bands in the 940-2260 nm Short-Wave InfraRed (SWIR) range. The front-end optical imager is a rotating mirror-based system that images the ground scene onto a slit with an instantaneous field of view of 16 km x 1 km. For the SWIR bands, the slit-image is re-imaged onto a 16x1 micro-lens array that effectively acts as the focal plane since each lens element is fiber coupled to wavelength filtered InGaAs and HgCdTe Photo Diodes (PDs). The pulse response of the detection system is critical to OCI SWIR performance. We find that PDs introduce an inherent slow tail in the pulse response due to slow diffusion moving carriers in their n and p regions. We show that this introduces response errors ranging from 1 down to 0.01 % for up to tens of science pixels after the pulse depending on the PD design and materials. It is shown that the response is distinctly different for the InGaAs and HgCdTe PDs. We explain how the front-end design can further increase this error. Finally, we detail the cause of the slow pulse response tail, how to model it, its impact on OCI performance and how it is characterized and corrected to meet OCI requirements.

ocean color↗

Pulse Response of the Short-Wave Infrared Detection System of the Ocean Color Instrument for the NASA Pace Mission

The Ocean Color Instrument (OCI) on NASA’s Plankton, Aerosol, Cloud, ocean Ecosystem (PACE) mission is a hyperspectral Earth imager with a spatial resolution of 1 km x 1 km and a spectral resolution of 5 nm in 2.5 nm steps over 342-887 nm. In addition, OCI provides 7 discrete bands in the 940-2260 nm Short-Wave InfraRed (SWIR) range. The front-end optical imager is a rotating mirror-based system that images the ground scene onto a slit with an instantaneous field of view of 16 km x 1 km. For the SWIR bands, the slit-image is re-imaged onto a 16x1 micro-lens array that effectively acts as the focal plane since each lens element is fiber coupled to wavelength filtered InGaAs and HgCdTe Photo Diodes (PDs). The pulse response of the detection system is critical to OCI SWIR performance. We find that PDs introduce an inherent slow tail in the pulse response due to slow diffusion moving carriers in their n and p regions. We show that this introduces response errors ranging from 1 down to 0.01 % for up to tens of science pixels after the pulse depending on the PD design and materials. It is shown that the response is distinctly different for the InGaAs and HgCdTe PDs. We explain how the front-end design can further increase this error. Finally, we detail the cause of the slow pulse response tail, how to model it, its impact on OCI performance and how it is characterized and corrected to meet OCI requirements.

ocean color↗

Two‐Color Amplified Spontaneous Emission from Auger‐Suppressed Quantum Dots in Liquids

Abstract Colloidal quantum‐dot (QD) lasing is normally achieved in close‐packed solid‐state films, as a high QD volume fraction is required for stimulated emission to outcompete fast Auger decay of optical‐gain‐active multiexciton states. Here a new type of liquid optical‐gain medium is demonstrated, in which compact compositionally‐graded QDs (ccg‐QDs) that feature strong suppression of Auger decay are liquefied using a small amount of solvent. Transient absorption measurements of ccg‐QD liquid suspensions reveal broad‐band optical gain spanning a wide spectral range from 560 (green) to 675 nm (red). The gain magnitude is sufficient to realize a two‐color amplified spontaneous emission (ASE) at 637 and 594 nm due to the band‐edge (1S) and the excited‐state (1P) transition, respectively. Importantly, the ASE regime is achieved using quasicontinuous excitation with nanosecond pulses. Furthermore, the ASE is highly stable under prolonged excitation, which stands in contrast to traditional dyes that exhibit strong degradation under identical excitation conditions. These observations point toward a considerable potential of high‐density ccg‐QD suspensions as liquid, dye‐like optical gain media that feature readily achievable spectral tunability and stable operation under intense photoexcitation.

Li, Xueyang↗

Birefringent Color Filter by Layered Metal‐Organic Chalcogenides: In‐Plane Anisotropy and Odd/Even Effect

Anisotropic 2D materials are gaining interest recently as building blocks for angular‐dependent optical/electrical devices. However, the fundamental understanding of their structure‐property‐relationship is limited, which hinders further modulation of their unique characteristics via structure tailoring. Here the in‐plane structural anisotropy and the tunable optical/electrical properties of a series of radiation‐sensitive (X‐ray, e‐beam) metal‐organic chalcogenide (MOC) single crystals are comprehensively revealed with ligands of variable length/parity. Their monoclinic crystallography is determined at atomic resolution by a simple method that couples X‐ray/electron diffraction with first‐principles calculations. The in‐plane inorganic backbone of the MOCs exhibits a strong lattice anisotropy with odd/even alternations, which originates from that of the out‐of‐plane organic motifs via organic/inorganic accommodation. Such structural anisotropy is implied mechanically by the preferred orientation of crystal cleavage. It triggers a maximum ≈8 × distinction of in‐plane electrical conductivity of the semiconducting MOCs, plus a distinct birefringence (maximum Δn ≈ 0.03) with a dispersive orientation of dielectric axes, which rotate up to 25.7° from UV to visible‐light regime, inspiring an emerging pathway for color filtering via single crystal rotation. Such in‐plane optical characteristics also exhibit odd/even alternation and can be flexibly tuned by the designable out‐of‐plane ligands.

birefringence↗

Self‐Standing Chiral Covalent Organic Framework Thin Films with Full‐Color Tunable Guest‐Induced Circularly Polarized Luminescence

Abstract Exploring self‐standing chiral covalent organic framework (COF) thin films with controllable circularly polarized luminescence (CPL) is of paramount significance but remains a challenging task. Herein, we demonstrate the first example of self‐standing chiral COF films employing a polymerization‐dispersion‐filtration strategy. Pristine, low‐quality chiral COF films were produced by interfacial polymerization and then re‐dispersed into COF colloidal solutions. Via vacuum assisted assembly, these COF colloids were densely stacked and assembled into self‐standing, pure chiral COF films ( L‐ / D‐ CCOF‐F) that were transparent, smooth, crack‐free and highly crystalline. These films were tunable in thicknesses, areas, and roughness, along with strong diffuse reflectance circular dichroism (DRCD) and cyan CPL signals, showing an intrinsic luminescence asymmetric factor ( g lum ) of ~4.3×10 −3 . Furthermore, these COF films served as host adsorbents to load various achiral organic dye guests through adsorption. The effective chiral transfer and energy transfer between CCOF‐F and achiral fluorescent dyes endowed the dyes with strong chirality and tunable DRCD, resulting in intense, full‐color‐tunable solid‐state CPL. Notably, the ordered arrangement of dye guest molecules within the preferentially oriented chiral pores of CCOF‐F contributed to an amplified | g lum | factor of up to 7.2×10 −2 , which is state‐of‐the‐art for COF‐based CPL materials. This work provides new insights into the design and fabrication of self‐standing chiral COF films, demonstrating their great potential for chiroptical applications.

Tang, Xihao↗

Surfactant-Induced Interfacial Aggregation of Porphyrins for Structuring Color-Tunable Liquids

Locking nonequilibrium shapes of liquids into targeted architectures by interfacial jamming of nanoparticles is an emerging area in material science. 5,10,15,20-tetrakis(4-sulfonatophenyl) porphyrin (H 6 TPPS) shows three different aggregation states that present an absorption imaging platform to monitor the assembly and jamming of supramolecular polymer surfactants (SPSs) at the liquid/liquid interface. The interfacial interconversion of H 6 TPPS, specifically H 4 TPPS 2- dissolved in water, from J- to an H-aggregation was induced by strong electrostatic interactions with amine-terminated polystyrene dissolved in toluene at the water/toluene interface. We find that this resulted in color-tunable liquids due to interfacial jamming of the SPSs formed between H 4 TPPS 2- and amine-terminated polystyrene. However, the formed SPSs cannot lock in nonequilibrium shapes of liquids. In addition, a self-wrinkling behavior was observed when amphiphilic triblock copolymers of PS-block-poly(2-vinylpyridine)-block-poly(ethylene oxide) were used to interact with H 4 TPPS 2- . Subsequently, the SPSs formed can lock in nonequilibrium shapes of liquids.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Novel color center platforms enabling fundamental scientific discovery

Abstract Color centers are versatile systems that generate quantum light, sense magnetic fields and produce spin‐photon entanglement. We review how these properties have pushed the limits of fundamental knowledge in a variety of scientific disciplines, from rejecting local‐realistic theories to sensing superconducting phase transitions. In the light of recent progress in material processing and device fabrication, we identify new opportunities for interdisciplinary fundamental discoveries in physics and geochemistry. image

24 POWER TRANSMISSION AND DISTRIBUTION↗

$t\overline{t}t\overline{t}$ signatures through the lens of color-octet scalars

We reinterpret two recent LHC searches for events containing four top quarks ($t\overline{t}t\overline{t}$) in the context of supersymmetric models with Dirac gauginos and color-octet scalars (sgluons). We explore whether sgluon contributions to the four-top production cross section σ ($pp$ → $t\overline{t}t\overline{t}$) can accommodate an excess of four-top events recently reported by the ATLAS collaboration. We also study constraints on these models from an ATLAS search for new phenomena with high jet multiplicity and significant missing transverse energy ($E^{miss}_{T}$) sensitive to signals with four top quarks. We find that these two analyses provide complementary constraints, with the jets + $E^{miss}_{T}$ search exceeding the four-top cross section measurement in sensitivity for sgluons heavier than about 800 GeV. We ultimately find that either a scalar or a pseudoscalar sgluon can currently fit the ATLAS excess in a range of reasonable benchmark scenarios, though a pseudoscalar in minimal Dirac gaugino models is ruled out. We finally offer sensitivity projections for these analyses at the HL-LHC, mapping the 5σ discovery potential in sgluon parameter space and computing exclusion limits at 95% CL in scenarios where no excess is found.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Fiducial $q_T$ resummation of color-singlet processes at N$^3$LL+NNLO

We present a framework for $q_T$ resummation at N 3 LL+NNLO accuracy for arbitrary color-singlet processes based on a factorization theorem in SCET. Our implementation CuTe-MCFM is fully differential in the Born kinematics and matches to large-$q_T$ fixed-order predictions at relative order $α^2_s$. It provides an efficient way to estimate uncertainties from fixed-order truncation, resummation, and parton distribution functions. In addition to W ± , Z and H production, also the diboson processes $\gamma\gamma$, Z$\gamma$, ZH and W ± H are available, including decays. We discuss and exemplify the framework with several direct comparisons to experimental measurements as well as inclusive benchmark results. In particular, we present novel results for $\gamma\gamma$ and Z$\gamma\gamma$ at N 3 LL+NNLO and discuss in detail the power corrections induced by photon isolation requirements.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Leading-color two-loop amplitudes for four partons and a $\textit{W}$ boson in QCD

We present the leading-color two-loop QCD corrections for the scattering of four partons and a W boson, including its leptonic decay. The amplitudes are assembled from the planar two-loop helicity amplitudes for four partons and a vector boson decaying to a lepton pair, which are also used to determine the planar two-loop amplitudes for four partons and a $Z/γ^\ast$ boson with a leptonic decay. The analytic expressions are obtained by setting up a dedicated Ansatz and constraining the free parameters from numerical samples obtained within the framework of numerical unitarity. The large linear systems that must be solved to determine the analytic expressions are constructed to be in Vandermonde form. Such systems can be very efficiently solved, bypassing the bottleneck of Gaussian elimination. Our results are expressed in a basis of one-mass pentagon functions, which opens the possibility of their efficient numerical evaluation.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Soft gluon emission at two loops in full color

The soft emission factor is a central ingredient in the factorization of generic n-particle gauge theory amplitudes with one soft gluon in the external state. We present the complete two-loop soft factor, capturing the leading power behavior in the soft-gluon momentum. At two loops, the color structure and the kinematic dependence of the soft factor become nontrivial as the soft gluon can couple to three hard partons for the first time (tripole terms). The nontrivial kinematic dependence of the tripole terms is of uniform, maximal transcendental weight, and can be expressed (in a “Euclidean” region) in terms of single-valued harmonic polylogarithms. Our results are consistent with the behavior of the recently computed symbol of the two-loop five-particle amplitude in $Ν$ = 4 super-Yang-Mills theory. In the limit where the outgoing soft gluon is also collinear with an incoming hard parton, potentially dangerous factorization-violating terms can arise.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

On the differential representation and color-kinematics duality of AdS boundary correlators

The AdS boundary correlators and their dual correlation functions of boundary operators have been the main dynamic observables of the holographic duality relating a bulk AdS theory and a boundary conformal field theory. We show that tree-level AdS boundary correlators for generic states can be expressed as nonlocal differential operators of a certain structure acting on contact Witten diagrams. We further write the boundary correlators in a form that is very similar to flat space amplitudes, with Mandelstam variables replaced by certain combinations of single-state conformal generators, prove that all tree-level AdS boundary correlators have a differential representation, and detail the conversion of such differential expressions to position space. We illustrate the construction through the computation of the boundary correlators of scalars coupled to gluons and gravitons; when converted to position space, they reproduce known results. Color-kinematics duality and BCJ relations can be defined in analogy with their flat space counterparts, and are respected by the scalar correlators with a gluon exchange. We also discuss potential approaches to the double copy and find that its direct generalization may require nontrivial extensions.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Semi-inclusive single-jet production in DIS at next-to-leading order in the Color Glass Condensate

Within the Color Glass Condensate (CGC) effective field theory, we derive the next-to-leading order (NLO) cross-section for the single-jet semi-inclusive cross-section in deep inelastic scattering (DIS) at small x, for both longitudinally and transversely polarized virtual photons. We provide analytic expressions, valid at finite N c and suitable for numerical evaluation, for both the cross-section differential in rapidity and transverse momentum and the cross-section differential in rapidity only. Our NLO formulae demonstrate that the very forward rapidity regime is plagued by large double logarithmic corrections coming from phase space constraints on soft gluons close to the kinematic threshold for jet production. A joint resummation of small-x and threshold logarithms at single logarithmic accuracy is proposed to remedy the instability of the cross-section in this regime. By integrating over the single-jet phase space, we recover known results for the NLO DIS structure functions at small x, previously obtained using the optical theorem.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗