Stellar molecular abundances. I - Polyatomic molecules.
Abundance of molecules, ions and atoms in late- type dwarf, giant and supergiant atmospheres
ATMOSPHERE MODEL↗
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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
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Failure of the adiabatic criterion, structure and coherence in the low energy excitation of helium atoms by helium ions
Producing optical excitations by low energy ion atom and ion molecule collisions
Dworetsky, S.↗
Distributions and lifetimes of N and NO between 100 and 280 kilometers.
Altitude distribution and lifetimes of N atoms and NO molecules from loss process data in atmosphere
Ghosh, S. N.↗
Molecular collisions. X.
Rotational excitation and scattering of diatomic molecules by structureless atoms, comparing approximation methods
Bernstein, R. B.↗
HBr-CO2 continuous-wave chemical laser
Continuous wave chemical laser operation at 10.6 micron in carbon dioxide pumped by vibrational energy from hydrogen atoms and bromine molecules reaction
Cool, T. A.↗
Interstellar abundances - Gas and dust
Data on abundances of interstellar atoms, ions and molecules in front of zeta Oph are assembled and analyzed. The gas-phase abundances of at least 11 heavy elements are significantly lower, relative to hydrogen, than in the solar system. The abundance deficiencies of certain elements correlate with the temperatures derived theoretically for particle condensation in stellar atmospheres or nebulae, suggesting that these elements have condensed into dust grains near stars. There is evidence that other elements have accreted onto such grains after their arrival in interstellar space. The extinction spectrum of zeta Oph can be explained qualitatively and, to a degree, quantitatively by dust grains composed of silicates, graphite, silicon carbide, and iron, with mantles composed of complex molecules of H, C, N, and O. This composition is consistent with the observed gas-phase deficiencies.
Field, G. B.↗
The influence of molecular rotation on vibration-translation energy transfer
A three-dimensional vibration-rotation collision model is formulated within a semiclassical framework to study the effect of coupled rotational motion on the rate of vibrational energy transfer for collisions between anharmonic diatomic molecules and structureless atoms. Emphasis is on the net rates of vibrational energy transfer summed over all final rotational states rather than those for individual vibration-rotation transitions. The corresponding three-dimensional rate parameters are cast into forms that may be identified with equivalent parameters associated with the collinear approximation. Their comparisons allow the validity of a collinear model to be evaluated and some constraints on its application to be implied. The mechanisms of vibrational energy transfer including rotational transitions are shown to be separable into three classes which are identified and discussed
Mckenzie, R. L.↗
Preliminary evaluation of the role of K2S in MHD hot stream seed recovery
Results are presented for recent analytical and experimental studies of the role of K2S in MHD hot stream seed recovery. The existing thermodynamic data base was found to contain large uncertainties and to be nonexistent for vapor phase K2S. Knudsen cell mass spectrometric experiments were undertaken to determine the vapor species in equilibrium with K2S(c). K atoms and S2 molecules ere found to be the major vapor phase species in vacuum, accounting for greater than 99 percent of the vapor phase. Combustion gas deposition studies using No. 2 Diesel fuel were also undertaken and revealed that condensed phase K2SO3 may potentially be an important compound in the MHD stream at near-stoichiometric combustion.
Bennett, J. E.↗
Method of cross-linking polyvinyl alcohol and other water soluble resins
A self supporting sheet structure comprising a water soluble, noncrosslinked polymer such as polyvinyl alcohol which is capable of being crosslinked by reaction with hydrogen atom radicals and hydroxyl molecule radicals is contacted with an aqueous solution having a pH of less than 8 and containing a dissolved salt in an amount sufficient to prevent substantial dissolution of the noncrosslinked polymer in the aqueous solution. The aqueous solution is then irradiated with ionizing radiation to form hydrogen atom radicals and hydroxyl molecule radicals and the irradiation is continued for a time sufficient to effect crosslinking of the water soluble polymer to produce a water insoluble polymer sheet structure. The method has particular application in the production of battery separators and electrode envelopes for alkaline batteries.
Phillipp, W. H.↗
Pristine nature of comets as revealed by their UV spectrum
Satellite and rocket VUV observations of comets are discussed with reference to observations of OH and NH; the Lyman-alpha halo of hydrogen; and C, O, S atoms, ions, and molecules. Attention is also given to the study of production rates, and elemental and molecular abundances. It is shown that the observation of the VUV spectrum of comets has revealed new clues about comets, which could serve as a link between interstellar molecules and planetary atmospheres as well as between stellar and planetary astrophysics.
Delsemme, A. H.↗
The 1981 NASA ASEE Summer Faculty Fellowship Program, volume 2
A collection of papers on miscellaneous subjects in aerospace research is presented. Topics discussed are: (1) Langmuir probe theory and the problem of anisotropic collection; (2) anthropometric program analysis of reach and body movement; (3) analysis of IV characteristics of negatively biased panels in a magnetoplasma; (4) analytic solution to classical two body drag problem; (5) fast variable step size integration algorithm for computer simulations of physiological systems; (6) spectroscopic experimental computer assisted empirical model for the production of energetics of excited oxygen molecules formed by atom recombination shuttle tile surfaces; and (7) capillary priming characteristics of dual passage heat pipe in zero-g.
Robertson, N. G.↗
The violet interstellar medium associated with the Carina Nebula
The interstellar spectrum of HD 93205, an 03V star in the cluster Tr16, located inside the most active part of the Great Carina Nebula was analyzed using data extracted directly from raw IUE images. From the analysis of 67 lines of 25 atoms, ions and molecules, up to six discrete absorption components spanning a maximum velocity range of approximately 375 km 5/1 were identified. The component structure for different species is tabulated and sample absorption lines, indicating at the top the positions of the six components, labelled A to F are shown. Ion column densities appropriate to each component which can be resolved in at least one line were derived by constructing empirical curves of growth and by fitting the observations with corresponding theoretical absorption line profiles. The most important results concerning each component are discussed.
Pettini, M.↗
On photochemical heating of cometary comae - The cases of H2O and CO-rich comets
It is found that the effect of energy addition due to photochemical processes in the cometary coma on the heating and accelerating of the expanding neutral gas is limited by the kinematic property of the energy transfer from the energetic fragments to the bulk flow. The effective scale length of the photochemical zone for an H2O comet is estimated to be only 10% of the dimension of the collision region due to the large mass ratio of H atom and H2O molecule. When this physical property is taken into consideration, the H2O gas is found to be expanding at a highly supersonic speed. In addition, it is shown that the addition of a mixture of CO and/or CO2 molecules in a medium-bright comet with total production rate of 10 to the 29th molecules/s would not change this conclusion since the photodissiation length scales of these molecules are a factor of 10-30 larger than that of the H2O molecules. Thus, most of the CO and CO2 molecules will be dissociated outside of the collision zone without depositing the excess kinetic energy to the neutral atmosphere. However, if the gas production rate is controlled by CO or CO2, the dimension of the collision zone of a CO comet at 1 AU will be increased by a factor of seven. The photochemical heating due to CO dissociation would thus be more effective, causing the atmospheric flow to be weakly supersonic. It is concluded that the neutral gas outflows from H2O comets and CO comets could be substantially different.
Ip, W.-H.↗
Non-catalytic surfaces for metallic heat shields
The magnitude of the atom recombination coefficients needed for metal heat shield surfaces on Shuttle-type vehicles is analyzed and discussed. Prior work which identifies surfaces having low catalytic activity is reviewed. Arc tunnel tests to evaluate catalytic activity are described and the difficulties of such tests are discussed. Results are presented which show major differences between atom recombination and atom exchange from molecules. Results of surface analysis show that bulk and surface composition of a coating are different.
Swann, R. T.↗
Photochemistry of the atmosphere of Titan - Comparison between model and observations
Updated chemical schemes and estimates of key rate coefficients are used in the present investigation of the photochemistry of Titan atmosphere C- H- and O-atom containing simple molecules, according to a model incorporating exospheric boundary conditions, vertical transport, and condensation processes at the tropopause. It is suggested that the composition, climatology, and evolution of the Titan atmosphere are controlled by five major processes: CH4 photolysis and photosensitized dissociation, H-to-H2 conversion and hydrogen escape, higher hydrocarbon synthesis, nitrogen and hydrocarbon coupling, and oxygen and hydrocarbon coupling. The model accounts for the minor species concentrations observed by Voyager instruments. Implications of abiotic organic synthesis on Titan for the origin of life on earth are briefly discussed.
Yung, Y. L.↗
Oxygen isotopes in deep sea spherules
The determination of the genetic relationships between the dust and small particles in the solar system, and the meteorites and larger bodies are examined. Oxygen isotopes proved useful in the identification of such relationships between one meteorite group and another. Of the various samples of submillimeter extraterrestrial particles available for laboratory study, only the deep sea spherules are abundant enough for precise oxygen isotope analysis using existing techniques. Complications arise in interpretation of the isotopic data, since these particles were melted during passage through the Earth's atmosphere, and have been in contact with seawater for prolonged periods. Spherules that were originally silicates are considered with the originally metallic ones to deduce their preterrestrial isotopic compositions. The type 1 spherules which enter the atmosphere as metallic particles, contain only atmospheric oxygen. The type S spherules contain a mixture of atmospheric oxygen and their original extraterrestrial oxygen. It is suggested that the Earth's mesosphere is strongly enriched in heavy isotopes of oxygen at altitudes near 90 km at which the iron particles are oxidized. Fractionation due to the combined diffusion of O atoms and O2 molecules may be responsible.
Mayeda, T. K.↗
Interstellar Medium Absorption Profile Spectrograph (IMAPS)
The design and fabrication of an objective-grating echelle spectrograph to fly on sounding rockets and record spectra of stars from approximately 920 to 1120A with a resolving power lambda/delta lambda = 200,000 is discussed. The scientific purpose of the program is to observe, with ten times better velocity resolution than before, the plentiful absorption lines in this spectral region produced by atoms, ions and molecules in the interstellar medium. In addition, an important technical goal is to develop and flight-quality a new ultraviolet, photon-counting image sensor which has a windowless, opaque photocathode and a CCD bombarded directly by the accelerated photoelectrons. Except for some initial difficulties with the performance of CCDs, the development of the payload instrument is relatively straightforward and our overall design goals are satisfied. The first flight occurred in late 1984, but no data were obtained because of an inrush of air degraded the instrument's vacuum and caused the detector's high voltage to arc. A second flight in early 1985 was a complete success and obtained a spectrum of pi Sco. Data from this mission are currently being reduced; quick-look versions of the spectra indicate that excellent results will be obtained. Currently, the payload is being reconfigured to fly on a Spartan mission in 1988.
Jenkins, E. B.↗
Hydrogenated amorphous carbon (a:C-H) in the planetary nebula NGC 7027
A spectroscopic identification of the infrared continuum radiation is proposed for the planetary nebula NGC 7027. Hydrogenated amorphous carbon (a:C-H) is shown to account for the undulating spectrum between 5 and 15 microns. The unidentified infrared emission bands lie at the peaks in the a:C-H spectrum, pointing to their association with a carbon polymorph, possibly a:C-H or polycyclic aromatic hydrocarbon molecules. Except for atomic emission lines, all the infrared emission from NGC 7027 comes from one or another polymorph of carbon.
Goebel, John H.↗