Advanced Thin Zeolite/Metal Flat Sheet Membrane for Energy Efficient Air Dehumidification and Conditioning
Traditional vapor compression cooling has high power consumption in warm and humid climates due to the water condensation on the evaporator coils. The combining membrane dehumidification and vapor compression cooling process holds promise for efficient drying and conditioning of warm and humid air. In this approach, the water vapor content in fresh incoming air is first reduced below dew point through a high-efficient, in-line membrane dehumidifier, followed by sensible cooling. A membrane with excellent air/water separation performance and low cost is needed to realize this design idea. In this paper, we, for the first time, report on the development of novel thin flat sheet of zeolite membranes for air dehumidification application. The membrane is prepared by deposition of an ultra-thin H 2 O-selective zeolite membrane film (< 2 µm) on a thin (~ 50 µm) porous metal sheet support. Under the testing condition of 32oC and 90% RH feed air, the optimal membrane shows water permeance as high as 1.74×10 -5 mol m -2 Pa -1 s -1 , which is about 1 to 3 orders of magnitude higher than previously reported in the literature, and a water vapor/air separation factor over 500, which allows selective and energy-efficient removal of water out of the humid air by vacuum. In addition, this zeolite/metal sheet membrane exhibits excellent stability as no apparent decline of separation performance is observed during 8-day continuous testing with humid in-house air. To simulate various climate conditions, the membrane is tested over a wide range of separation conditions which include variation in feed air temperature, feed air RH, and permeate pressure. It is estimated that 50% or higher energy efficiency gain over the conventional vapor compression system can be obtained when the membrane separation factor is equal or high than 200. A sensitivity analysis shows that the membrane separation factor and the condenser pressure have significant impacts on the process energy efficiency.