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At least 721 records · Page 40

Virtual Design of a 4-Bed Molecular Sieve for Exploration

Simulations of six new 4-Bed Molecular Sieve configurations have been performed using a COMSOL model. The preliminary results show that reductions in desiccant bed size and sorbent bed size when compared to the International Space Station configuration are feasible while still yielding a process that handles at least 4.0 kg/day CO2. The results also show that changes to the CO2 sorbent are likewise feasible. Decreasing the bed sizes was found to have very little negative effect on the adsorption process; breakthrough of CO2 in the sorbent bed was observed for two of the configurations, but water breakthrough in the desiccant beds was not observed. Nevertheless, both configurations for which CO2 breakthrough was observed still yield relatively high CO2 efficiency, and future investigations will focus on bed size in order to find the optimum configuration.

Giesy, Timothy J.↗

SWIPE: Spectral Water Inversion Processor and Emulator

Degradation of Earth’s inland water resources due to anthropogenic perturbations and climate anomalies at both local and global scales continues to place human health at substantial risk. There is now a growing necessity to develop pragmatic approaches that allow timely and effective extrapolation of local processes, to spatially resolved global products, and to promote operational and sustainable resource policy management. This presentation will be discussing the progress made developing SWIPE: Spectral Water Inversion Processor and Emulator. SWIPE is a platform for advanced modeling of coastal and inland aquatic habitats. The goal is create a comprehensive and cohesive system to leverage recent advancements in computation and machine learning to develop a synthetic training ground for sensitivity studies and algorithm development. The four principal facets of SWIPE include: 1. Advanced two-layer coated sphere bio-optical modeling and GPU radiative transfer modeling, 2. Big Data involving massive synthetic spectral libraries of optical properties of various global aquatic particles, surface reflectance, and top-of-atmosphere reflectance, all at hyperspectral resolution leveraging high-end computing systems at NASA Ames Research Center, 3. Deep Learning for algorithm development for water quality inversion of concentrations of common biogeophysical variables as well as optics, full uncertainty characterization by water type, and forward emulation, and lastly, 4. Image Processing for application of developed retrieval algorithms for both hyperspectral and multispectral sensors with experimental corrections for global adjacency, noise, sunglint, and benthic reflectance. This presentation will demonstrate the Equivalent Algal Populations (EAP) two-layer coated sphere scattering model which has been used develop spectral libraries of hyperspectral inherent optical properties of roughly 80 species of phytoplankton, covering 15 different classes and nine taxonomic functional types. The EAP model was also used to derive spectral properties of 10 different non-algal particle functional types. Examples of how the SMART-G (Speed-up Monte-carlo Advanced Radiative Transfer using GPU) radiative transfer code is used to model optically complex aquatic signals will be presented and discussed in the context of creating a massive synthetic database which can leverage the full power of next generation machine learning techniques and high end computing for water quality inversion. We will discuss our active investigation in things like appropriate model architectures, dimensionality reduction techniques such as PCA and autoencoders, uncertainty quantification and abstaining, and which variables actually benefit most from hyperspectral information versus multispectral resolution. We are also curious about questions relating to cost/benefit analysis in terms of computation resources, neural network complexity, and data volumes. Answers to these questions will hopefully elaborate on cost efficiency for potential future sensor design considerations.

SWIPE↗

An efficient routine for infrared radiative transfer in a cloudy atmosphere

A FORTRAN program that calculates the atmospheric cooling rate and infrared fluxes for partly cloudy atmospheres is documented. The IR fluxes in the water bands and the 9.6 and 15 micron bands are calculated at 15 levels ranging from 1.39 mb to the surface. The program is generalized to accept any arbitrary atmospheric temperature and humidity profiles and clouds as input and return the cooling rate and fluxes as output. Sample calculations for various atmospheric profiles and cloud situations are demonstrated.

Chou, M. D.↗

Tank Tests of a Powered Model of a Compression Plane, NACA Model 171A-2

The compression plane is intended for operation on or close to the surface of the water, and has a hull with a concave bottom which forms the upper surface of a tunnel into which air is forced under pressure to support part of the load. The results of the tests made in Langley tank no. 1 include values of the horizontal forces, trimming moment, and static pressure in the tunnel for a wide range of loads and speeds and two power conditions, and are presented in the form of curves against speed with load as a parameter. The results are scaled up to 10 times the model size for three conditions at which the model is self-propelled at a steady speed. Lift is obtained from the static pressure of air in the tunnel. In general, the ratio of the gross load to the total resistance increases with increase in load and decrease in speed. This ratio varies between l-7 and 5.7 at high speeds and has a maximum value of 7. The total resistance is nearly the same for both power conditions except at low speeds and heavy loads. No abrupt change in forces on the hull or flow around the hull occurs in. the region of zero draft. The centers of pressure are generally far aft. At the most efficient trim (1.2'), considerable bow-up moment would be required for practicable operation. There is no abrupt transition from the air-borne to the water- borne condition.

Mottard, Elmo J.↗

Water in Planetary and Cometary Atmospheres: H2O/HDO Transmittance and Fluorescence Models

We developed a modern methodology to retrieve water (H2O) and deuterated water (HDO) in planetary and cometary atmospheres, and constructed an accurate spectral database that combines theoretical and empirical results. On the basis of a greatly expanded set of spectroscopic parameters, we built a full non-resonance cascade fluorescence model and computed fluorescence efficiencies for H2O (500 million lines) and HDO (700 million lines). The new line list was also integrated into an advanced terrestrial radiative transfer code (LBLRTM) and adapted to the CO2 rich atmosphere of Mars, for which we adopted the complex Robert-Bonamy formalism for line shapes. We retrieved water and D/H in the atmospheres of Mars, comet C/2007 W1 (Boattini), and Earth by applying the new formalism to spectra obtained with the high-resolution spectrograph NIRSPEC/Keck II atop Mauna Kea (Hawaii). The new model accurately describes the complex morphology of the water bands and greatly increases the accuracy of the retrieved abundances (and the D/H ratio in water) with respect to previously available models. The new model provides improved agreement of predicted and measured intensities for many H2O lines already identified in comets, and it identifies several unassigned cometary emission lines as new emission lines of H2O. The improved spectral accuracy permits retrieval of more accurate rotational temperatures and production rates for cometary water.

comets↗

Reduction of Equivalent System Mass of a Trash Compaction Processing System with an Emphasis on Improved Thermal Efficiency

A device known as the Trash Compaction Processing System or TCPS has been under development at NASA as part of the Advanced Life Support and Logistics Reduction Program Waste Management element. The TCPS processes trash that includes a variety of components such as plastic pouches that contain wet food and drinks, used cloth towels and t-shirts, adhesive tapes, deodorant, and many other items. The TCPS uses heat and pressure to compact the waste composite into a sturdy and well-defined shape designed to fit in a storage area on a spacecraft. The TCPS removes water from the trash and renders it safe against microbial activity. The focus of this paper is on methods for reducing the Equivalent System Mass of a TCPS with an emphasis on increasing the thermal efficiency of the system.

Trash Compaction Processing System↗

Emergence of Simple Ion Channels by Self-Assembly of Short Peptides

As protocells transitioned from structures bound by membranes made of simple amphiphiles, such as fatty acids, to structures containing phospholipid membranes, they became nearly impermeable to charged species. Yet, the ability to transport ions across membranes was vital to regulating cellular volume, pH homeostasis, generating energy and sensing the environment. For this reason, life evolved ion channels, protein structures surrounding water-filled pores in the membrane that facilitated ion transport. In contemporary cells, ion channels are complex protein assemblies. Could the same function be carried out, even if less efficiently and selectively, by much simpler peptides at the origins of life? To answer this question, we turned to trichogen (GAIV), an 11-residue peptide that was found to permeabilize membrane, causing leakage of the vesicle content including ions. Since GAIV is synthesized non-gnomically, it represents as excellent model for the earliest, poorly optimized channels. Understanding the mechanism by which short peptides, such as GAIV, mediate ion transport across membranes provides crucial information on the emergence, structure and the mechanism of action of the earliest ion channels. In this study, we used extensive molecular dynamics (MD) simulations to investigate directly spontaneous assembly of GAIV peptide and its structural dynamics, the formation of an induced water pore across the membrane and consequently ion conduction through the membrane.

Wei, Chenyu↗

A double-moment multiple-phase four-class bulk ice scheme, Part 1: Description

A detailed ice-phase bulk microphysical scheme has been developed for simulating the hydrometeor distributions of convective and stratiform precipitation in different large-scale environmental conditions. The proposed scheme involves 90 distinct microphysical processes, which predict the mixing ratios and the number concentrations of small ice crystals, snow, graupel, and frozen drops/hail, as well as the mixing ratios of liquid water on wet precipitation ice (snow, graupel, frozen drops). The number of adjustable coefficients has been significantly reduced in comparison with other bulk schemes. Additional improvements have been made to the parameterization in the following areas: (1) representing small ice crystals with nonzero terminal fall velocities and dispersive size distributions, (2) accurate and computationally efficient calculations of precipitation collection processes, (3) reformulating the collection equation to prevent unrealistically large accretion rates, (4) more realistic conversion by riming between different classes of precipitation ice, (5) preventing unrealistically large rates of raindrop freezing and freezing of liquid water on ice, (6) detailed treatment of various rime-splintering ice multiplication mechanisms, (7) a simple representation of the Hobbs-Rangno ice enhancement process, (8) aggregation of small ice crystals and snow, and (9) allowing explicit competition between cloud water condensation and ice deposition rates rather than using saturation adjustment techniques. For the purposes of conserving the higher moments of the particle distributions, preserving the spectral widths (or slopes) of the particle spectra is shown to be more important than strict conservation of particle number concentration when parameterizing changes in ice-particle number concentrations due to melting, vapor transfer processes (sublimation of dry ice, evaporation from wet ice), and conversion between different hydrometeor species. The microphysical scheme is incorporated into a nonhydrostatic cloud model in Part 2 of this study. The model performed well in simulating the radar and microphysical structures of a midlatitude-continental squall lines and a tropical-maritime squall system with minimal tuning of the parameterization, even though the vertical profiles of radar reflectivity differed substantially between these storms.

Ferrier, Brad Shoenberg↗

A New Neural Network Approach Including First-Guess for Retrieval of Atmospheric Water Vapor, Cloud Liquid Water Path, Surface Temperature and Emissivities Over Land From Satellite Microwave Observations

The analysis of microwave observations over land to determine atmospheric and surface parameters is still limited due to the complexity of the inverse problem. Neural network techniques have already proved successful as the basis of efficient retrieval methods for non-linear cases, however, first-guess estimates, which are used in variational methods to avoid problems of solution non-uniqueness or other forms of solution irregularity, have up to now not been used with neural network methods. In this study, a neural network approach is developed that uses a first-guess. Conceptual bridges are established between the neural network and variational methods. The new neural method retrieves the surface skin temperature, the integrated water vapor content, the cloud liquid water path and the microwave surface emissivities between 19 and 85 GHz over land from SSM/I observations. The retrieval, in parallel, of all these quantities improves the results for consistency reasons. A data base to train the neural network is calculated with a radiative transfer model and a a global collection of coincident surface and atmospheric parameters extracted from the National Center for Environmental Prediction reanalysis, from the International Satellite Cloud Climatology Project data and from microwave emissivity atlases previously calculated. The results of the neural network inversion are very encouraging. The r.m.s. error of the surface temperature retrieval over the globe is 1.3 K in clear sky conditions and 1.6 K in cloudy scenes. Water vapor is retrieved with a r.m.s. error of 3.8 kg/sq m in clear conditions and 4.9 kg/sq m in cloudy situations. The r.m.s. error in cloud liquid water path is 0.08 kg/sq m . The surface emissivities are retrieved with an accuracy of better than 0.008 in clear conditions and 0.010 in cloudy conditions. Microwave land surface temperature retrieval presents a very attractive complement to the infrared estimates in cloudy areas: time record of land surface temperature will be produced.

Aires, F.↗

Total Water Content Measurements with an Isokinetic Sampling Probe

The NASA Glenn Research Center has developed a Total Water Content (TWC) Isokinetic Sampling Probe. Since it is not sensitive to cloud water particle phase nor size, it is particularly attractive to support super-cooled large droplet and high ice water content aircraft icing studies. The instrument is comprised of the Sampling Probe, Sample Flow Control, and Water Vapor Measurement subsystems. Analysis and testing have been conducted on the subsystems to ensure their proper function and accuracy. End-to-end bench testing has also been conducted to ensure the reliability of the entire instrument system. A Stokes Number based collection efficiency correction was developed to correct for probe thickness effects. The authors further discuss the need to ensure that no condensation occurs within the instrument plumbing. Instrument measurements compared to facility calibrations from testing in the NASA Glenn Icing Research Tunnel are presented and discussed. There appears to be liquid water content and droplet size effects in the differences between the two measurement techniques.

Reehorst, Andrew L.↗

Electrochemical Hydrogen Peroxide Generator

Two-electron reduction of oxygen to produce hydrogen peroxide is a much researched topic. Most of the work has been done in the production of hydrogen peroxide in basic media, in order to address the needs of the pulp and paper industry. However, peroxides under alkaline conditions show poor stabilities and are not useful in disinfection applications. There is a need to design electrocatalysts that are stable and provide good current and energy efficiencies to produce hydrogen peroxide under acidic conditions. The innovation focuses on the in situ generation of hydrogen peroxide using an electrochemical cell having a gas diffusion electrode as the cathode (electrode connected to the negative pole of the power supply) and a platinized titanium anode. The cathode and anode compartments are separated by a readily available cation-exchange membrane (Nafion 117). The anode compartment is fed with deionized water. Generation of oxygen is the anode reaction. Protons from the anode compartment are transferred across the cation-exchange membrane to the cathode compartment by electrostatic attraction towards the negatively charged electrode. The cathode compartment is fed with oxygen. Here, hydrogen peroxide is generated by the reduction of oxygen. Water may also be generated in the cathode. A small amount of water is also transported across the membrane along with hydrated protons transported across the membrane. Generally, each proton is hydrated with 3-5 molecules. The process is unique because hydrogen peroxide is formed as a high-purity aqueous solution. Since there are no hazardous chemicals or liquids used in the process, the disinfection product can be applied directly to water, before entering a water filtration unit to disinfect the incoming water and to prevent the build up of heterotrophic bacteria, for example, in carbon based filters. The competitive advantages of this process are: 1. No consumable chemicals are needed in the process. The only raw materials needed are water and oxygen or air. 2. The product is pure and can therefore be used in disinfection applications directly or after proper dilution with water. 3. Oxygen generated in the anode compartment is used in the electrochemical reduction process; in addition, external oxygen is used to establish a high flow rate in the cathode compartment to remove the desired product efficiently. Exiting oxygen can be recycled after separation of liquid hydrogen peroxide product, if so desired. 4. The process can be designed for peroxide generation under microgravity conditions. 5. High concentrations of the order of 6-7 wt% can be generated by this method. This method at the time of this reporting is superior to what other researchers have reported. 6. The cell design allows for stacking of cells to increase the hydrogen peroxide production. 7. The catalyst mix containing a diquaternary ammonium compound enabled not only higher concentration of hydrogen peroxide but also higher current efficiency, improved energy efficiency, and catalyst stability. 8. The activity of the catalyst is maintained even after repeated periods of system shutdown. 9. The catalyst system can be extended for fuel-cell cathodes with suitable modifications.

Tennakoon, Charles L. K.↗

An assessment of NASA master directory/catalog interoperability for interdisciplinary study of the global water cycle

The most important issue facing science is understanding global change; the causes, the processes involved and their consequences. The key to success in this massive Earth science research effort will depend on efficient identification and access to the most data available across the atmospheric, oceanographic, and land sciences. Current mechanisms used by earth scientists for accessing these data fall far short of meeting this need. Scientists must as a result frequently rely on a priori knowledge and informal person to person networks to find relevant data. The Master Directory/Catalog Interoperability Program (MC/CI) undertaken by NASA is an important step in overcoming these problems. The stated goal of the MD project is to enable researchers to efficiently identify, locate, and obtain access to space and Earth science data.

Peuquet, Donna J.↗

Martian atmospheric chemistry during the time of low water abundance

The importance of odd hydrogen (or HO(x)) radicals in the catalytic recombination of carbon monoxide and oxygen in the Martian atmosphere is a well known fact. The inclusion of recent chemical kinetics data, specifically temperature-dependent CO2 absorption cross sections, into our one dimensional photochemical model shows that HO(x) is too efficient in this regard. The absorption cross sections of CO2 are smaller than previously assumed; this leads to a reduction in the photolysis rate of CO2 while the photolysis rate of H2O has increased. As a consequence the predicted mixing ratio of CO in our models is substantially less than the observed value of 6.5(10)(exp -4). Simultaneous measurements of water, ozone, and carbon monoxide were obtained in the Martian atmosphere in early Dec. 1990 (L(sub s) for Mars was 344 deg.).

Nair, Hari↗

Parameterization of the Vertical Variability of Tropical Cirrus Cloud Microphysical and Optical Properties

Cloud Integrating Nephelometers (CIN) were flown on the U. North Dakota Citation aircraft and the NASA WB-57 aircraft for the purpose of measuring in-situ the optical extinction coefficient and the asymmetry parameter (g) at a wavelength of 635 nm of primarily ice particles encountered during the NASA CRYSTAL-FACE study of large cumulus clouds (Cu) and their anvils found in the southern Florida region. The probes performance was largely successful and produced archived data for vertical profiles of extinction, asymmetry parameter, and effective radius (Re), the latter being obtained by combining CIN and CVI (total water; Oregon State U.) measurements. Composites of the CIN and CVI data describing the average microphysical and optical behavior of the Cu and their anvils showed the following: The extinction increases with height as a result of the size of the particles also decreasing with height as shown by the Re measurements; near the top of anvils the size of the primary ice particles is about 10-um radius; and the value of g does not vary significantly with height and has a mean value of about 0.73 consistent with the idea that ambient ice crystals are primarily of complex shape and reflect solar radiation more efficiently than particles of pristine crystal shape. Other observations include: The g measurements were found to be an indicator of the phase of the cloud permitting identification of the clouds with water droplets, rain, and ice; visual ranges as small as several tens of meters were occasionally found in "extinction cores" that coincided with strong updraft cores; and comparison of the cloud probes on the Citation showed significant disagreement.

Gerber, Hermann E.↗

Some recent developments in spacecraft environmental control/life support subsystems

The subsystems considered include a flash evaporator for heat rejection, a regenerable carbon dioxide and humidity control subsystem, an iodinating subsystem for potable water, a cabin contaminant control subsystem, and a wet oxidation subsystem for processing spacecraft wastes. The flash evaporator discussed is a simple unit which efficiently controls life support system temperatures over a wide range of heat loads. For certain advanced spacecraft applications the control of cabin carbon dioxide and humidity can be successfully achieved by a regenerable solid amine subsystem.

Gillen, R. J.↗

Infrared measurements of a scramjet exhaust

Diagnostic 2 - 5 mm infrared spectra of a hydrogen burning scramjet exhaust were measured with an interferometer spectrometer. Exhaust gas temperatures and water vapor partial pressures were determined from the observed intensity and spectral profile of the H2O 2.7 mm infrared emission band. Overall engine combustion efficiencies were derived by combining these measurements with the known engine operating conditions. Efficiencies fall (70 - 50 percent) as fuel equivalence ratios rise (0.4 - 1.0). Data analysis techniques and sensitivity studies are also presented.

Reed, R. A.↗

The role of volatiles and lithology in the impact cratering process

A survey of published descriptions of 32 of the largest, least eroded terrestrial impact structures shows that the amount of melt at craters in crystalline rocks is approximately two orders of magnitude greater than that at craters in sedimentary rocks. A model is proposed for the impact process, and it is examined whether the difference in melt abundance is due to differences in the amount of melt generated in various target materials or due to differences in the fate of the melt during late stages of the impact. The model accounts semiquantitatively for the effects of porosity and water and volatile content on the cratering process. Important features of the model are noted. Even if the recondensation of released volatiles is very efficient, the cumulative effect of repeated impacts on accreting planets would be to continually transfer volatiles toward the outer surface. By this process, volatiles might be enriched toward the outer layer of a growing planet.

Kieffer, S. W.↗

Microwave ice prevention

The concept of using microwave energy to provide aircraft ice protection, specifically an anti-icing system, and the feasibility of such a system are discussed. In a microwave anti-icing system impinging supercooled water droplets are heated to above freezing by the resonant absorption of microwave energy located upstream of the aircraft. This process is inherently more efficient than existing anti-icing devices due to the saving of the latent heat of fusion (a substantial 334 joules/gm (80 cal/gm)) and the fact that only the droplets are heated, thereby reducing convective losses to the air.

Hansman, R. J., Jr.↗