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NASA NTRS1989

A heat-pipe mechanism for volcanism and tectonics on Venus

A heat-pipe mechanism is proposed for the transport of heat through the lithosphere of Venus. This mechanism allows the crust and lithosphere on Venus to be greater than 150 km thick. A thick basaltic crust on Venus is expected to transform eclogite at a depth of 60 to 80 km; the dense eclogite would contribute to lithospheric delamination that returns the crust to the interior of the planet completing the heat-pipe cycle. Topography and the associated gravity anomalies can be explained by Airy compensation of the thick crust. The principal observation that is contrary to this hypothesis is the mean age of the surface that is inferred from crater statistics; the minimum mean age is about 130 Myr and this implies an upper limit of 2 cubic kilometers per year for the surface volcanic flux. If the heat-pipe mechanism was applicable on the earth in the Archean it would provide the thick lithosphere implied by isotopic data from diamonds.

Turcotte, D. L.↗

NASA NTRS1988

Do volcanic eruptions affect climate? Sulfur gases may cause cooling

The relationship between volcanic eruptions on earth and the observed climatic changes is investigated. The results of the comparison and analyses of volcanologic and climatologic data sets for the years between 1880 and 1980 indicate that changes in temperature caused by even of the largest eruptions recorded during this time were about the same as normal variations in temperature. However, when temperature records for several months or years preceding and following a given eruption were analyzed, a statistically significant temperature decrease of 0.2-0.5 C was found for the periods of one to two years immediately following some of the 19th and 20th century explosive events that prodiced large aerosol clouds (e.g., Krakatau and Agung eruptions). It is suggested that the content of sulfur in the erupted magma determines the size of aerosol cloud producing the cooling effect.

Self, Stephen↗

NASA NTRS1989

Venus volcanism: Rate estimates from laboratory studies of sulfur gas-solid reactions

Thermochemical reactions between sulfur-bearing gases in the atmosphere of Venus and calcium-, iron-, magnesium-, and sulfur-bearing minerals on the surface of Venus are an integral part of a hypothesized cycle of thermochemical and photochemical reactions responsible for the maintenance of the global sulfuric acid cloud cover on Venus. SO2 is continually removed from the Venus atmosphere by reaction with calcium bearing minerals on the planet's surface. The rate of volcanism required to balance SO2 depletion by reactions with calcium bearing minerals on the Venus surface can therefore be deduced from a knowledge of the relevant gas-solid reaction rates combined with reasonable assumptions about the sulfur content of the erupted material (gas + magma). A laboratory program was carried out to measure the rates of reaction between SO2 and possible crustal minerals on Venus. The reaction of CaCO3(calcite) + SO2 yields CaSO4 (anhydrite) + CO was studied. Brief results are given.

Ehlers, K.↗

NASA NTRS1989

On reported occurrences of shock-deformed clasts in the volcanic ejecta from Toba caldera, Sumatra

Reports of shock-deformed phenocrysts from the Toba ignimbrite deposits, Sumatra, have prompted considerable debate over whether shock-deformation products are clear evidence of a meteorite impact origin for the K/T boundary deposits as well as terresrial 'cryptoexplosion' structures. Evidence presented in favor of volcanically induced shock at Toba includes kinked biotites and rare occurrences of single set of lamellae in quartz grains but rests most heavily upon occurrences of mosaic extinction patterns in plagioclase phenocrysts. The present analysis of several of the same Toba samples reveals that these mosaic patterns ae related to distinct compositional zoning and cannot be attributed to deformation of the crystal lattice that shock would produce. Additionally, in more than 200 quartz grains examined, no occurrences of microdeformation features or mosaic textures similar to those associated with known impact structures and the K/T boundary are detected. It is concluded that evidence of shock deformation in the Toba deposits has not been demonstrated.

Sharpton, V. L.↗

NASA NTRS1990

Carbon dioxide emissions from Deccan volcanism and a K/T boundary greenhouse effect

A greenhouse warming caused by increased emissions of carbon dioxide from the Deccan Traps volcanism has been suggested as the cause of the terminal Cretaceous extinctions on land and in the sea. Total eruptive and noneruptive CO2 output by the Deccan eruptions (from 6 to 20 x 10 to the 16th moles) over a period of several hundred thousand years is estimated based on best estimates of the CO2 weight fraction of the original basalts and basaltic melts, the fraction of CO2 degassed, and the volume of the Deccan Traps eruptions. Results of a model designed to estimate the effects of increased CO2 on climate and ocean chemistry suggest that increases in atmospheric pCO2 due to Deccan Traps CO2 emissions would have been less than 75 ppm, leading to a predicted global warming of less than 1 C over several hundred thousand years. It is concluded that the direct climate effects of CO2 emissions from the Deccan eruptions would have been too weak to be an important factor in the end-Cretaceous mass extinctions.

Caldeira, Ken↗

NASA NTRS1990

Western Eisila Regio, Venus - Radar properties of volcanic deposits

The 1988 Arecibo Observatory dual-polarization radar images are presented for Western Eisila Regio, Venus. The polarization information and Pioneer-Venus Orbiter reflectivity and altimetry data are analyzed for volcanic deposits on two 400-500 km radius constructs, Sif and Gula Montes. Many of the large effusive deposits studied appear to require superposed flows or multiple vents to explain the observed progression of roughness along their length. High Fresnel reflectivity material may be present along the summit region of Gula Mons and in an embayed tessera-like region to the N. Radar-dark units on the flanks of Sif Mons are inferred to be pyroclastic deposits, but radar-dark features near the summits of both edifices are more consistent with very smooth lava flows. Higher spatial resolution Magellan data will be useful in testing these predictions.

Campbell, Bruce A.↗

NASA NTRS1991

Volcanic aerosols: Chemistry, evolution, and effects

Stratospheric aerosols have been the subject of scientific speculation since the 1880s, when the powerful eruption of Krakatoa attracted worldwide attention to the upper atmosphere through spectacular optical displays. The presence of a permanent tenuous dust layer in the lower stratosphere was postulated in the 1920s following studies of the twilight glow. Junge collected the first samples of these 'dust' particles and demonstrated that they were actually composed of sulfates, most likely concentrated sulfuric acid (Junge and Manson, 1961; Junge, 1963). Subsequent research has been spurred by the realization that stratospheric particles can influence the surface climate of earth through their effects on atmospheric radiation. Such aerosols can also influence, through chemical and physical effects, the trace composition of the atmosphere, ozone concentrations, and atmospheric electrical properties. The properties of stratospheric aerosols (both the background particles and those enhanced by volcanic eruptions) were measured in situ by balloon ascents and high altitude aircraft sorties. The aerosols were also observed remotely from the ground and from satellites using both active (lidar) and passive (solar occultation) techniques (remote sensing instruments were carried on aircraft and balloon platforms as well). In connection with the experimental work, models were developed to test theories of particle formation and evolution, to guide measurement strategies, to provide a means of connecting laboratory and field data, and to apply the knowledge gained to answer practical questions about global changes in climate, depletion of the ozone layer, and related environmental problems.

Turco, Richard↗

NASA NTRS1989

Remote sensing of volcanos and volcanic terrains

The possibility of using remote sensing to monitor potentially dangerous volcanoes is discussed. Thermal studies of active volcanoes are considered along with using weather satellites to track eruption plumes and radar measurements to study lava flow morphology and topography. The planned use of orbiting platforms to study emissions from volcanoes and the rate of change of volcanic landforms is considered.

Mouginis-Mark, Peter J.↗

NASA NTRS1991

Fluid volcanism on Miranda and Ariel - Flow morphology and composition

Several types of volcanic units have been recognized on the icy Uranian satellites Miranda and Ariel. On Miranda, ridges characterized by crest grooves are up to 10 km wide and 500 m high. A continuous flat-topped flow band also 10 km wide and 500 m high forms the outer southern margin of Elsinore Corona, which appears to comprise coalesced flow bands and ridges. On Ariel, in addition to at least one ridge unit similar to those on Miranda, flood plains material has covered the floors of deep chasmata (grabens) and an irregular depression. Flows on both satellites are characterized by linear vent geometries and distinct topographic margins, which indicate extrusion of a relatively viscous material. The topography of the flows can be used to estimate flow viscosity or yield strength using a Bingham plastic model. Extrusion viscosity estimates, incorporating plausible volcanologically based emplacement time scales and a rigid crust correction, range from 10 MP to 1 GP (10 TP in the unlikely absence of a chilled crust). Viscosity estimates are dependent on the assumed emplacement time scale, however, and could be as high as 10 PP, if a solid-state-based time scale is assumed.

Schenk, Paul M.↗

NASA NTRS1991

The evolution of volcanism, tectonics, and volatiles on Mars - An overview of recent progress

Significant results of the 'Mars: Evolution of Volcanism, Tectonics, and Volatiles' (MEVTV) project are presented. The data for the project are based on geological mapping from the Viking images, petrologic and chemical analyses of SNC meteorites, and both mapping and temporal grouping of major fault systems. The origin of the planet's crustal dichotomy is examined in detail, the kinematics and formation of wrinkle ridges are discussed, and some new theories are set forth. Because the SNC meteorites vary petrologically and isotopically, the sources of the parental Martian magma are heterogeneous. Transcurrent faulting coupled with the extensional strains that form Valles Marineris suggest early horizontal movement of lithospheric blocks. A theory which connects the formation of the crustal dichotomy to the Tharsis region associates the horizontal motions with plate tectonics that generated a new lithosphere.

Zimbelman, James R.↗

NASA NTRS1991

Global relationships between volcanic vents and fractures radial to large impact basins on Mars

The relation of volcanic vents on Mars to impact basins has been previously studied. It has been asserted that the concentric fractures around impact basins extend into the crust and might localize some features, including volcanoes. Herein, the possibility is assessed of radial fractures inferred to be associated with impact basins as an additional control on the location of volcanoes on Mars. Geologic mapping at 1:2 million scale enabled 250 central vents and fissure vents to be identified. Pattern of vent distribution superimposed on a globe show that most are located on three distinct circles. In addition, there are two more possible great circles which may be superimposed onto the Martian globe. These five Martian circles are briefly examined for their geological relationship to volcanoes.

Schneid, Byron D.↗

NASA NTRS1992

Chemical models of volcanic outgassing on Mars

During the MSATT workshop in Boulder, CO, several participants emphasized the importance of constraints on the composition and temporal evolution of outgassed volatiles on Mars. I present the results of some preliminary calculations that model the composition of volcanic gases as a function of temperature, pressure, oxygen fugacity, and quench function of temperature. These results can be used in combination with cosmochemical models for the accretion of Mars to assess the plausibility of different atmospheric compositions during the planet's early history.

Fegley, Bruce, Jr.↗

NASA NTRS1992

Volcanic recycling of carbonate deposits on Mars

One question of great interest to those who study the evolution of the Martian atmosphere is: if there was an early, dense atmosphere that was removed, is there any mechanism that could restore it? In the case of an atmosphere removed largely by the formation of carbonates, the only obvious means of restoring it is by the thermal decomposition of the carbonates. Decomposition of carbonates under turbulently flowing lava holds great promise as a means of resupplying the atmosphere with CO2. Huppert and colleagues have modeled the emplacement of terrestrial komatiite flows and found that komatiites, even when flowing over previously emplaced and cooled komatiite flows, could melt and erode this rock to a significant depth. Based on this work, I have begun modeling the erosion of Martian carbonate deposits under turbulently flowing, komatiitic lava. Initial results from this modeling indicate that a high-volume lava flow, emerging at a temperature of, say, 1600 degrees, is capable of eroding several meters of carbonate deposits per day. If such a flow is active for a hundred days, several hundreds of meters of carbonate could be decomposed. If this process occurred over a large area, a bar or more of CO2 could be injected back into the atmosphere over an extremely short period of time. The implications of such an occurrence are intriguing. For instance, if a relatively late pulse of volcanism (such as is suggested by Frey) were to cause a large flow of lava over carbonate deposits in the northern lowlands, the resulting pulse of CO2 into the atmosphere could conceivably restore the climate to one in which liquid water could exist on the surface, or ice could flow.

Schaefer, M. W.↗

NASA NTRS1992

A New Raman DIAL Technique for Measuring Stratospheric Ozone in the Presence of Volcanic Aerosols

This paper describes a new lidar scheme to measure stratospheric ozone in the presence of heavy volcanic aerosol loading. The eruptions of the Philippine volcano Pinatubo during June 1991 ejected large amounts of sulfur dioxide into the atmosphere to altitudes of at least 30 km. The resulting aerosols have severely affected the measurements of stratospheric ozone when using traditional Rayleigh differential absorption lidar (DIAL) technique, in which the scattering mechanism is almost entirely Rayleigh and which assumes a small amount or no aerosols. In order to extract an ozone profile in the regions below about 30 km where the Rayleigh lidar returns are contaminated by aerosol scattering from Mt. Pinatubo cloud, we have used a Raman lidar technique, where the scattering mechanism depends solely on molecular nitrogen. In this scheme there is no aerosol scattering component to the backscattered lidar return. Using this technique in conjunction with the Rayleigh DIAL measurement, the GSFC stratospheric ozone lidar has measured ozone profiles between 15 and 50 km during the recently held UARS correlative measurement campaign (February-March 1992) at JPL's Table Mountain Facility in California.

Upendra N. Singh↗

NASA NTRS1992

Lidar Observations of the Pinatubo Volcanic Cloud over Hampton, Virginia

A series of eruptions of Mt. Pinatubo climaxed in a cataclysmic eruption on June 15-16, which greatly perturbed the stratospheric aerosol layer. These eruptions yielded an estimated 20 megatons of SO2, which is three times the amount produced by El Chichon. Lidar measurements taken by the 48-inch lidar system at Langley Research Center show the vertical distribution, intensity and spread of the Pinatubo aerosol layers over the middle latitude locations. A few observations have also been made using an airborne lidar system which measures scattering and depolarization. The magnitude and transport time of the volcanic aerosols following Pinatubo and El Chichon are compared. In addition, comparisons are made between the ground-based lidar measurements and near-coincident Stratospheric Aerosol and Gas Experiment (SAGE) 2 satellite observations of the Pinatubo aerosol layers.

Osborn, M. T.↗

NASA NTRS1992

Lidar Observations of Stratospheric Clouds After Volcanic Eruption of Pinatubo

A very large increase of backscattered light from the stratospheric aerosol layer was observed by using a ruby laser in Beijing (39 degrees 54 minutes N, 116 degrees 27 minutes E) from the end of July 1991 to March 1992. It was concluded that this increase was almost certainly due to the volcanic eruption of Mt. Pinatubo in the Philippines in June 1991. The measuring instruments used are described. Information is given in graphical form for vertical profiles, fluctuation of the maximum backscattering ratio above 20 km during the nine month period, and the time variation of the integrated backscattering coefficient at a height of 15 to 30 km.

Sun, Jinhui↗

NASA NTRS1991

Thermodynamic models of the chemistry of lunar volcanic gases

Thermodynamic models and mass-balance arguments are used to constrain the chemistry of lunar volcanic gases. The results predict that lunar gases were dominated by reduced C and S gases such as CO, COS, CS2, S2. The more oxidized gases CO2 and SO2 were also important, but only in limited temperature ranges. Gases such as Cl2, CCl4, and CF4 were more abundant than HF and HCl, which were the two major H compounds in the lunar gases. Chlorides and fluorides were important species for transporting many volatile and ore-forming metals, and the implications for fractionating and concentrating metals into lunar ore-deposits merit further study.

Fegley, Bruce, Jr.↗

NASA NTRS1991

Brine volcanism and the interior structures of asteroids and icy satellites

Brine vulcanism, in which MgSO4 and Na2SO4 are shown by carbonaceous chondrite mineralogies and elemental abundances to be the most important solutes, is presently suggested to account for the resurfacing observed on such icy satellites as Europa and Ganymede, and to have been a significant factor in the evolution of chondritic asteroids. Hypersaline brines have lower viscosities than familiar silicate lavas, although they remain more viscous than pure water; aqueous sulfate flows are seen as capable of constructing the vast, low-relief volcanic plains observed on Ganymede and Europa.

Kargel, Jeffrey S.↗