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At least 721 records · Page 40
All sourcesNASA NTRSDOE OSTI
NASA NTRS1998

Theoretical Calculation and Validation of the Water Vapor Continuum Absorption

The primary objective of this investigation is the development of an improved parameterization of the water vapor continuum absorption through the refinement and validation of our existing theoretical formalism. The chief advantage of our approach is the self-consistent, first principles, basis of the formalism which allows us to predict the frequency, temperature and pressure dependence of the continuum absorption as well as provide insights into the physical mechanisms responsible for the continuum absorption. Moreover, our approach is such that the calculated continuum absorption can be easily incorporated into satellite retrieval algorithms and climate models. Accurate determination of the water vapor continuum is essential for the next generation of retrieval algorithms which propose to use the combined constraints of multispectral measurements such as those under development for EOS data analysis (e.g., retrieval algorithms based on MODIS and AIRS measurements); current Pathfinder activities which seek to use the combined constraints of infrared and microwave (e.g., HIRS and MSU) measurements to improve temperature and water profile retrievals, and field campaigns which seek to reconcile spectrally-resolved and broad-band measurements such as those obtained as part of FIRE. Current widely used continuum treatments have been shown to produce spectrally dependent errors, with the magnitude of the error dependent on temperature and abundance which produces errors with a seasonal and latitude dependence. Translated into flux, current water vapor continuum parameterizations produce flux errors of order 10 W/sq m, which compared to the 4 W/sq m magnitude of the greenhouse gas forcing and the 1-2 W/sq m estimated aerosol forcing is certainly climatologically significant and unacceptably large. While it is possible to tune the empirical formalisms, the paucity of laboratory measurements, especially at temperatures of interest for atmospheric applications, preclude tuning, the empirical continuum models over the full spectral range of interest for remote sensing and climate applications. Thus, we propose to further develop and refine our existing, far-wing formalism to provide an improved treatment applicable from the near-infrared through the microwave. Based on the results of this investigation, we will provide to the remote sensing/climate modeling community a practical and accurate tabulation of the continuum absorption covering the near-infrared through the microwave region of the spectrum for the range of temperatures and pressures of interest for atmospheric applications.

Ma, Qiancheng↗
NASA NTRS1998

Theoretical Calculation and Validation of the Water Vapor Continuum Absorption

The primary objective of this investigation is the development of an improved parameterization of the water vapor continuum absorption through the refinement and validation of our existing theoretical formalism. The chief advantage of our approach is the self-consistent, first principles, basis of the formalism which allows us to predict the frequency, temperature and pressure dependence of the continuum absorption as well as provide insights into the physical mechanisms responsible for the continuum absorption. Moreover, our approach is such that the calculated continuum absorption can be easily incorporated into satellite retrieval algorithms and climate models. Accurate determination of the water vapor continuum is essential for the next generation of retrieval algorithms which propose to use the combined constraints of multi-spectral measurements such as those under development for EOS data analysis (e.g., retrieval algorithms based on MODIS and AIRS measurements); current Pathfinder activities which seek to use the combined constraints of infrared and microwave (e.g., HIRS and MSU) measurements to improve temperature and water profile retrievals, and field campaigns which seek to reconcile spectrally-resolved and broad-band measurements such as those obtained as part of FIRE. Current widely used continuum treatments have been shown to produce spectrally dependent errors, with the magnitude of the error dependent on temperature and abundance which produces errors with a seasonal and latitude dependence. Translated into flux, current water vapor continuum parameterizations produce flux errors of order 10 W/ml, which compared to the 4 W/m' magnitude of the greenhouse gas forcing and the 1-2 W/m' estimated aerosol forcing is certainly climatologically significant and unacceptably large. While it is possible to tune the empirical formalisms, the paucity of laboratory measurements, especially at temperatures of interest for atmospheric applications, preclude tuning the empirical continuum models over the full spectral range of interest for remote sensing and climate applications. Thus, we propose to further develop and refine our existing far-wing formalism to provide an improved treatment applicable from the near-infrared through the microwave. Based on the results of this investigation, we will provide to the remote sensing/climate modeling community a practical and accurate tabulation of the continuum absorption covering the near-infrared through the microwave region of the spectrum for the range of temperatures and pressures of interest for atmospheric applications.

Ma, Qiancheng↗
NASA NTRS1999

Design of Advanced Atmospheric Water Vapor Differential Absorption Lidar (DIAL) Detection System

The measurement of atmospheric water vapor is very important for understanding the Earth's climate and water cycle. The lidar atmospheric sensing experiment (LASE) is an instrument designed and operated by the Langley Research Center for high precision water vapor measurements. The design details of a new water vapor lidar detection system that improves the measurement sensitivity of the LASE instrument by a factor of 10 are discussed. The new system consists of an advanced, very low noise, avalanche photodiode (APD) and a state-of-the-art signal processing circuit. The new low-power system is also compact and lightweight so that it would be suitable for space flight and unpiloted atmospheric vehicles (UAV) applications. The whole system is contained on one small printed circuit board (9 x 15 sq cm). The detection system is mounted at the focal plane of a lidar receiver telescope, and the digital output is read by a personal computer with a digital data acquisition card.

Refaat, Tamer F.↗
NASA NTRS1999

Modeling and Real-Time Process Monitoring of Organometallic Chemical Vapor Deposition of III-V Phosphides and Nitrides at Low and High Pressure

The purpose of this paper is to review modeling and real-time monitoring by robust methods of reflectance spectroscopy of organometallic chemical vapor deposition (OMCVD) processes in extreme regimes of pressure. The merits of p-polarized reflectance spectroscopy under the conditions of chemical beam epitaxy (CBE) and of internal transmission spectroscopy and principal angle spectroscopy at high pressure are assessed. In order to extend OMCVD to materials that exhibit large thermal decomposition pressure at their optimum growth temperature we have designed and built a differentially-pressure-controlled (DCP) OMCVD reactor for use at pressures greater than or equal to 6 atm. We also describe a compact hard-shell (CHS) reactor for extending the pressure range to 100 atm. At such very high pressure the decomposition of source vapors occurs in the vapor phase, and is coupled to flow dynamics and transport. Rate constants for homogeneous gas phase reactions can be predicted based on a combination of first principles and semi-empirical calculations. The pressure dependence of unimolecular rate constants is described by RRKM theory, but requires variational and anharmonicity corrections not included in presently available calculations with the exception of ammonia decomposition. Commercial codes that include chemical reactions and transport exist, but do not adequately cover at present the kinetics of heteroepitaxial crystal growth.

Bachmann, K. J.↗
NASA NTRS1999

Clouds and Water Vapor in the Climate System: Remotely Piloted Aircraft and Satellites

The objective of this work was to attack unanswered questions that lie at the intersection of radiation, dynamics, chemistry and climate. Considerable emphasis was placed on scientific collaboration and the innovative development of instruments required to address these scientific issues. The specific questions addressed include: Water vapor distribution in the Tropical Troposphere: An understanding of the mechanisms that dictate the distribution of water vapor in the middle-upper troposphere; Atmospheric Radiation: In the spectral region between 200 and 600/cm that encompasses the water vapor rotational and continuum structure, where most of the radiative cooling of the upper troposphere occurs, there is a critical need to test radiative transfer calculations using accurate, spectrally resolved radiance observations of the cold atmosphere obtained simultaneously with in situ species concentrations; Thin Cirrus: Cirrus clouds play a central role in the energy and water budgets of the tropical tropopause region; Stratosphere-Troposphere Exchange: Assessment of our ability to predict the behavior of the atmosphere to changes in the boundary conditions defined by thermal, chemical or biological variables; Correlative Science with Satellite Observations: Linking this research to the developing series of EOS observations is critical for scientific progress.

Anderson, James G.↗
NASA NTRS1999

Numerical Modeling of Crystal of ZnSe by Physical Vapor Transport - Towards a more Comprehensive Formulations

Crystal growth from the vapor phase has various advantages over melt growth. The main advantage is from a lower processing temperature which makes the process more amenable in instances where the melting temperature of the crystal is high. Other benefits stem from the inherent purification mechanism in the process due to differences in the vapor pressures of the native elements and impurities, and the enhanced interfacial morphological stability during the growth process. Further, the implementation of PVT growth in closed ampoules affords experimental simplicity with minimal needs for complex process control which makes it an ideal candidate for space investigations in systems where gravity tends to have undesirable effects on the growth process. Bulk growth of wide band gap II-VI semiconductors by physical vapor transport has been developed and refined over the past several years at NASA MSFC. Results from a modeling study of PVT crystal growth of ZnSe are reported in this paper. The PVT process is numerically investigated using both two-dimensional and fully three-dimensional formulation of the governing equations and associated boundary conditions. Both the incompressible Boussinesq approximation and the compressible model are tested to determine the influence of gravity on the process and to discern the differences between the two approaches. The influence of a residual gas is included in the models. The results show that both the incompressible and compressible approximations provide comparable results and the presence of a residual gas tends to measurably reduce the mass flux in the system. Detailed flow, thermal and concentration profiles will be provided in the final manuscript along with computed heat and mass transfer rates. Comparisons with the 1-D model will also be provided. The effect of gravity on the process from numerical computations shows subtle effects although experimental evidence from vertically and horizontally grown samples show dramatic evidence of gravitational effects. The shortcomings of the problem formulation will be discussed and a framework will be provided leading up towards a more comprehensive model of PVT systems.

Ramachandran, N.↗
NASA NTRS2000

A Regional-Scale Assessment of Satellite Derived Precipitable Water Vapor Across The Amazon Basin

Atmospheric water vapor is widely recognized as a key climate variable, linking an assortment of poorly understood and complex processes. It is a major element of the hydrological cycle and provides a mechanism for energy exchange among many of the Earth system components. Reducing uncertainty in our current knowledge of water vapor and its role in the climate system requires accurate measurement, improved modeling techniques, and long-term prediction. Satellites have the potential to satisfy these criteria, as well as provide high resolution measurements that are not available from conventional sources. The focus of this paper is to examine the temporal and mesoscale variations of satellite derived precipitable water vapor (PW) across the Amazon Basin. This region is pivotal in the functioning of the global climate system through its abundant release of latent heat associated with heavy precipitation events. In addition, anthropogenic deforestation and biomass burning activities in recent decades are altering the conditions of the atmosphere, especially in the planetary boundary layer. A physical split-window (PSW) algorithm estimates PW using images from the GOES satellites along with the NCEP/NCAR Reanalysis data that provides the first guess information. Retrievals are made at a three-hourly time step during daylight hours in the Amazon Basin and surrounding areas for the months of June and October in 1988 (dry year) and 1995 (wet year). Spatially continuous fields are generated 5 times daily at 12Z, 15Z, 18Z, 21Z, and 00Z. These fields are then averaged to create monthly and 3 hourly monthly grids. Overall, the PSW estimates PW reasonable well in the Amazon with MAE ranging from 3.0 - 9.0 mm and MAE/observed mean around 20% in comparison to radiosonde observations. The distribution of PW generally mimics that of precipitation. Maximum values (42 - 52 mm) are located in the Northwest whereas minimum values (18 - 27 mm) are found along Brazil's East coast. Aside from the East coast, PW has a stronger north-south gradient than that of rainfall. As for the temporal variation of PW, June (1988 and 1995) experiences a peak about 1400 local time, corresponding to a maximum in air temperature. In contrast, October (1988 and 1995) experiences a maximum early in the day, 1100 local time, with a gradual decrease toward nighttime.

DeLiberty, Tracy↗
NASA NTRS1997

The Effect of Clouds on Water Vapor Profiling from the Millimeter-Wave Radiometric Measurements

Simultaneous measurements with the millimeter-wave imaging radiometer (MIR), cloud lidar system (CLS), and the MODIS airborne simulator (MAS) were made aboard the NASA ER-2 aircraft over the western Pacific Ocean on 17-18 January 1993. These measurements were used to study the effects of clouds on water vapor profile retrievals based on millimeter-wave radiometer measurements. The CLS backscatter measurements (at 0.532 and 1.064 am) provided information on the heights and a detailed structure of cloud layers; the types of clouds could be positively identified. All 12 MAS channels (0.6-13 Am) essentially respond to all types of clouds, while the six MIR channels (89-220 GHz) show little sensitivity to cirrus clouds. The radiances from the 12-/Am and 0.875-gm channels of the MAS and the 89-GHz channel of the MIR were used to gauge the performance of the retrieval of water vapor profiles from the MIR observations under cloudy conditions. It was found that, for cirrus and absorptive (liquid) clouds, better than 80% of the retrieval was convergent when one of the three criteria was satisfied; that is, the radiance at 0.875 Am is less than 100 W/cm.sr, or the brightness at 12 Am is greater than 260 K, or brightness at 89 GHz is less than 270 K (equivalent to cloud liquid water of less than 0.04 g/cm). The range of these radiances for convergent retrieval increases markedly when the condition for convergent retrieval was somewhat relaxed. The algorithm of water vapor profiling from the MIR measurements could not perform adequately over the areas of storm-related clouds that scatter radiation at millimeter wavelengths.

Wang, J. R.↗
NASA NTRS2000

The Discrepancy Between Measured and Modeled Downwelling Solar Irradiance at the Ground: Dependence on Water Vapor

Moderate resolution spectra of the downwelling solar irradiance at the around in north central Oklahoma were measured during the Department of Energy Atmospheric Radiation Measurement Program Intensive Observation Period in the fall of 1997. Spectra obtained under cloud-free conditions were compared with calculations using a coarse resolution radiative transfer model to examine the dependency of model-measurement bias on water vapor. It was found that the bias was highly correlated with water vapor and increased at a rate of 9 W/sq m per cm of water. The source of the discrepancy remains undetermined because of the complex dependencies of other variables, most notably aerosol optical depth, on water vapor.

Pilewskie, P.↗
NASA NTRS2000

The Discrepancy Between Measured and Modeled Downwelling Solar Irradiance at the Ground: Dependence on Water Vapor

Moderate resolution spectra of the downwelling solar irradiance at the ground in north central Oklahoma were measured during the Department of Energy Atmospheric Radiation Measurement Program Intensive Observation Period in the fall of 1997. Spectra obtained under-cloud-free conditions were compared with calculations using a coarse resolution radiative transfer model to examine the dependency of model-measurement bias on water vapor. It was found that the bias was highly correlated with water vapor and increased at a rate of 9 Wm per cm of water. The source of the discrepancy remains undetermined because of the complex dependencies of other variables, most notably aerosol optical depth, on water vapor.

Pilewski, P.↗
NASA NTRS1999

Detecting 1mm/Year Signals in Altimetric Global Sea Level: Effect of Atmospheric Water Vapor and Precipitation

Several research efforts exist to use Topography Experiment (TOPEX)/ Projet d'Observatorie de Surveillance et d'Etudes Integrees de la Dynamique des Oceans (Poseidon) (T/P) to detect changes in global sea level possibly associated with climate change. This requires much better than 1 mm/yr accuracy, something that none of the instruments in T/P [or the European Remote Sensing (ERS-2) satellite, or the U.S. Navy's Geosat Follow-On (GFO) satellite] were designed for. This work focuses on the ability of the T/P microwave radiometer (TMR) to retrieve the path delay due to atmospheric water vapor along the altimeter's path with accuracy in the time changes below 1 mm/yr on global average. In collaboration with Stephen Keihm of JPL and Christopher Ruf of Pennsylvania State University, we compared TMR path delay (PD) estimates with atmospheric precipitable water (PW) from the Special Sensor Microwave Imager (SSMI) aboard the Defense Meteorological Satellite Program (DMSP) series of satellites for 1992-1998 to selected radiosondes, and we also looked at the brightness temperatures measured by TMR in the lowest 1% of the histogram. The conclusion is that TMR had a slow instrumental drift, associated with the 18-GHz channel, which causes an approximate underestimation of water vapor at a rate equivalent to 1.2 mm/yr in path delay between 1992 and 1996; this effect stopped and no drift is detected in 1997. The same study concluded that there is no detectable scale error (one which is proportional to measured vapor) in TMR. In related work, carried out with graduate student Damien Cailliau, we investigated the relative abilities of TMR, SSMI and the UP dual-frequency radar altimeter to detect rain, relative to a climatology of shipborne observations. Rain is a crucial but poorly measured variable in studies of the climate system, and a dedicated mission, Tropical Rainfall Measuring Mission (TRMM), was recently launched to measure it. However, the climatologies built over the past 10 years used passive radiometers, such as SSMI, or infrared observation from National Oceanic and Atmospheric Administration (NOAA) geostationary satellites. We concluded that the dual-frequency altimeter does an excellent job at retrieving rain on scales much smaller than the passive radiometer, and a better job at retrieving total precipitation (rain as well as snow) at high latitudes. This work improves the sea level observations by allowing better flagging of observations contaminated by rain, and more importantly, provides an alternative way to measure rainfall over the oceans.

Zlotnicki, Victor↗
NASA NTRS2000

Calibration of Atmospherically Induced Delay Fluctuations Due to Water Vapor

We have completed a new generation of water vapor radiometers (WVR), the A- series, in order to support radio science experiments with the Cassini spacecraft. These new instruments sense three frequencies in the vicinity of the 22 GHz emission line of atmospheric water vapor within a 1 degree beamwidth from a clear aperture antenna that is co-pointed with the radio telescope down to 10 degree elevation. The radiometer electronics features almost an order of magnitude improvement in temperature stability compared with earlier WVR designs. For many radio science experiments, the error budget is likely to be dominated by path delay fluctuations due to variable atmospheric water vapor along the line-of-sight to the spacecraft. In order to demonstrate the performance of these new WVRs we are attempting to calibrate the delay fluctuations as seen by a radio interferometer operating over a 21 km baseline with a WVR near each antenna. The characteristics of these new WVRs will be described and the results of our preliminary analysis will be presented indicating an accuracy of 0.2 to 0.5 mm in tracking path delay fluctuations over time scales of 10 to 10,000 seconds.

Resch, George↗
NASA NTRS2000

Advanced Atmospheric Water Vapor DIAL Detection System

Measurement of atmospheric water vapor is very important for understanding the Earth's climate and water cycle. The remote sensing Differential Absorption Lidar (DIAL) technique is a powerful method to perform such measurement from aircraft and space. This thesis describes a new advanced detection system, which incorporates major improvements regarding sensitivity and size. These improvements include a low noise advanced avalanche photodiode detector, a custom analog circuit, a 14-bit digitizer, a microcontroller for on board averaging and finally a fast computer interface. This thesis describes the design and validation of this new water vapor DIAL detection system which was integrated onto a small Printed Circuit Board (PCB) with minimal weight and power consumption. Comparing its measurements to an existing DIAL system for aerosol and water vapor profiling validated the detection system.

Refaat, Tamer F.↗
NASA NTRS2000

Continuous Water Vapor Profiles from Operational Ground-Based Active and Passive Remote Sensors

The Atmospheric Radiation Measurement program's Southern Great Plains Cloud and Radiation Testbed site central facility near Lamont, Oklahoma, offers unique operational water vapor profiling capabilities, including active and passive remote sensors as well as traditional in situ radiosonde measurements. Remote sensing technologies include an automated Raman lidar and an automated Atmospheric Emitted Radiance Interferometer (AERI), which are able to retrieve water vapor profiles operationally through the lower troposphere throughout the diurnal cycle. Comparisons of these two water vapor remote sensing methods to each other and to radiosondes over an 8-month period are presented and discussed, highlighting the accuracy and limitations of each method. Additionally, the AERI is able to retrieve profiles of temperature while the Raman lidar is able to retrieve aerosol extinction profiles operationally. These data, coupled with hourly wind profiles from a 915-MHz wind profiler, provide complete specification of the state of the atmosphere in noncloudy skies. Several case studies illustrate the utility of these high temporal resolution measurements in the characterization of mesoscale features within a 3-day time period in which passage of a dryline, warm air advection, and cold front occurred.

Turner, D. D.↗
NASA NTRS2000

Water Vapor Tacers as Diagnostics of the Regional Atmospheric Hydrologic Cycle

Understanding of the local and remote sources of water vapor can be a valuable diagnostic in understanding the regional atmospheric hydrologic cycle, especially in North America where moisture transport and local evaporation are important sources of water for precipitation. In the present study, we have implemented passive tracers as prognostic variables to follow water vapor evaporated in predetermined regions until the water tracer precipitates. All evaporative sources of water are accounted for by tracers, and the water vapor variable provides the validation of the tracer water and the formulation of the sources and sinks. The Geostationary Operational Environmental Satellites General Circulation Model (GEOS GCM) is used to simulate several summer periods to determine the source regions of precipitation for the United States and India. Using this methodology, a detailed analysis of the recycling of water, interannual variability of the sources of water and links to the Great Plains low-level jet and North American monsoon will be presented. Potential uses in GCM sensitivity studies, predictability studies and data assimilation especially regarding the North American monsoon and GEWEX America Prediction Project (GAPP) will be discussed.

Bosilovich, Michael G.↗
NASA NTRS1999

On the Accuracy of In Situ Water Vapor Measurements in the Troposphere and Lower Stratosphere with the Harvard Lyman-Alpha Hygrometer

In an effort to better constrain atmospheric water vapor mixing ratios and to understand the discrepancies between different measurements of water vapor in the stratosphere and troposphere, we have carefully examined data from the Harvard Lyman-alpha photofragment fluorescence hygrometer, which has flown on the NASA ER-2 aircraft from 1992 through 1998. The instrument is calibrated in the laboratory before and after each deployment, and the calibration is checked by direct absorption measurements in the troposphere. On certain flights, the ER-2 flew level tracks during which water vapor varied by up to 80 ppmv, under nearly constant atmospheric conditions. These flights provide a stringent test of our calibration via direct absorption and indicate agreement to within 3%. During the 1997 Photochemistry of Ozone Loss in the Arctic Region In Summer (POLARIS) mission, our Lyman-alpha instrument was compared with a new diode laser hygrometer from the Jet Propulsion Laboratory. Overall agreement was 5% during the June/July deployment and 1% for potential temperatures of 490 to 540 K. The accuracy of our instrument is shown to be +/-5 %, with an additional offset of at most 0.1 ppmv. Data from this instrument, combined with simultaneous measurements of CH4, and H2, are therefore ideal for studies of the hydrogen budget of the lower stratosphere.

Hintsa, Eric J.↗
NASA NTRS2001

Retrievals of Column Water Vapor Using Millimeter-Wave Radiometric Measurements

Water vapor is one of the most important atmospheric constituents that has a critical impact on cloud formation (ice or liquid). It is also a source that needs to be accounted for in remote measurements of surface parameters. In the high-latitude regions, e.g., Antarctica, monitoring of the state of water vapor and its transport into and out of these regions is important towards our understanding the state of balance of ice sheets and its effect on the global sea level. The technique of retrieving low amount of column water vapor using the millimeter-wave radiometric measurements, as presented in this paper, will be very useful for these regions, especially during winter times when the atmosphere is relatively dry.

Wang, J. R.↗
NASA NTRS1995

Modeling of Vapor Bubble Growth Under Nucleate Boiling Conditions in Reduced Gravity

A dynamic model is developed to describe the evolution of a vapor bubble growing at a nucleation site on a superheated surface under arbitrary gravity. The bubble is separated from the surface by a thin microlayer and grows due to the evaporation from the microlayer interface. The average thickness of the microlayer increases as the bubble expands along the surface if the evaporation rate is lower than some critical value. The corresponding threshold value of the surface temperature has to be associated with the burn-out crisis. Two main reasons make for bubble separation, which are the buoyancy force and a force caused by the vapor momentum that comes to the bubble with vapor molecules. The latter force is somewhat diminished if condensation takes place at the upper bubble surface in subcooled liquids. The action of the said forces is opposed by inertia of the additional mass of liquid as the bubble center rises above the surface and by inertia of liquid being expelled by the growing bubble in radial directions. An extra pressure force arises due to the liquid inflow into the microlayer with a finite velocity. The last force helps in holding the bubble close to the surface during an initial stage of bubble evolution. Two limiting regimes with distinctly different properties can be singled out, depending on which of the forces that favor bubble detachment dominates. Under conditions of moderately reduced gravity, the situation is much the same as in normal gravity, although the bubble detachment volume increases as gravity diminishes. In microgravity, the buoyancy force is negligible. Then the bubble is capable of staying near the surface for a long time, with intensive evaporation from the microlayer. It suggests a drastic change in the physical mechanism of heat removal as gravity falls below a certain sufficiently low level. Inferences of the model and conclusions pertaining to effects caused on heat transfer processes by changes in bubble hydrodynamics induced by gravity are discussed in connection with experimental evidence, both available in current and in as yet unpublished literature.

Buyevich, Yu A.↗