Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “surface passivation”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 721 records · Page 40
All sourcesNASA NTRSDOE OSTI
DOE OSTI2020

Blading Phase–Pure Formamidinium–Alloyed Perovskites for High–Efficiency Solar Cells with Low Photovoltage Deficit and Improved Stability

Currently, blade-coated perovskite solar cells (PSCs) with high power conversion efficiencies (PCEs), i.e. greater than 20%, normally employ methylammonium lead tri-iodide with a sub-optimal bandgap. Alloyed perovskites with formamidinium (FA) cation have narrower bandgap and thus enhance device photocurrent. However, FA-alloyed perovskites show low phase stability and high moisture sensitivity. Here, we report that incorporating 0.83 molar percent organic halide salts (OHs) into the perovskite inks enables phase-pure, highly crystalline FA-alloyed perovskites with extraordinary optoelectronic properties. Here, the OH molecules modulate the crystal growth, enhance the phase stability, passivate ionic defects at the surface and/or grain boundaries, and enhance the moisture stability of the perovskite film. We demonstrate a high efficiency of 22.0% under 1 sun illumination for blade-coated PSCs with an open-circuit voltage of 1.18 V, corresponding to a very small voltage deficit of 0.33 V, and significantly improved operational stability with 96% of the initial efficiency retained under one sun illumination for 500 hours.

14 SOLAR ENERGY↗
DOE OSTI2023

Purification of Lithium-Ion Battery Black Mass through Tailored Alkaline Corrosion

Obtaining high-purity material outputs is crucial to the viability of novel process aimed at direct recycling of lithium-ion batteries. Metallic impurities in recycled cathodes have been shown to inhibit performance, thereby threatening mainstream acceptance of recycled battery products. Thus, shredded black mass (BM) must be purified to remove metallic contaminants, and specifically Al and Cu originating from the electrode current collectors. We herein explore a process to ionize solid copper and aluminum to ionic form based on tailored alkaline chemistry, without incurring damage to the target cathode material (Li(NixMnyCo1-x-y)O2; NMC). Al and Cu corrosion may be enhanced through the addition of chloride salt, elevated temperatures, and the use of ultrasonication - all of which disrupt the formation of passivating films on the metallic surface, and thereby increase corrosion rate. We demonstrate optimized parameters for Al and Cu corrosion both from a kinetic and overall process cost perspective. Further, we analyze the impact of these conditions on the structural (XRD, SEM), chemical (EDS, ICP), and electrochemical (impedance, cycling, dQ/dV) properties of NMC, and suggest that the present purification method does not significantly disrupt NMC performance. Finally, we present preliminary results from a promising bench-scale demonstration of this purification process applied to a simulated black mass.

ADVANCED PROPULSION SYSTEMS,ENERGY STORAGE↗
NASA NTRS2017

One Step Plasma Passivation and Precision Cleaning

Over the past several years, Kennedy Space Center (KSC) researchers developed two solvent-free techniques for precision cleaning of ground support equipment (GSE) that possess low commodity requirements and produce small or no waste streams. During testing of low-pressure air plasma as one of these cleaning techniques, physical changes in the surface of stainless steel test pieces were observed; cursory testing revealed that the test part had developed a thick oxide layer on the surface compared to untreated parts. This result indicated that the plasma process might not only serve as a green technology for precision cleaning of parts, but it may also passivate the surface at the same time. Current methodology in use at KSC’s Components Refurbishment & Chemical Analysis (CRCA) Facility for passivation of corrosion-resistant steels for aerospace applications follows an SAE International Standard, AMS2700, where parts are submerged in either a nitric acid or nitric acid/sodium dichromate bath at predetermined temperatures and contact times. These baths require constant testing to ensure effective treatment, use corrosive and carcinogenic chemicals, and produce hazardous waste. The passivation bath is one of the multiple steps employed at the facility, while cleaning with multiple environmentally-unfriendly solvents comprise several more steps before parts are recertified to a specific cleanliness level in their clean room. Based on the behavior of the stainless steel surface during cleaning optimization studies, it was believed that the plasma technology could be extended to passivation, combining what is currently many steps into a single, solvent- and waste-free system.

Paul Hintze↗
NASA NTRS1984

Interaction of atomic oxygen with solid surfaces at orbital altitudes (A0114)

The basic approach to this experiment is to expose a wide variety of material surfaces to the atomic flux in orbit. The experiment is passive and depends on preflight and postflight measurements of the test surfaces in the laboratory. The experiment will also include a reflectometer device to measure atomic beam reflection angles and thus momentum accommodations, and a unique passive spacecraft attitude sensor. Samples consisting of solid disks or thin film coatings on substrate disks will be mounted in a panel. The face of this panel will be flown on Long Duration Exposure Facility normal to the incident stream of oxygen atoms. Each disk will have part of its front surface masked so exposure to the atomic-oxygen reaction will be limited to selected areas, the shadowed areas being used as control surfaces in the measurements. A typical sample is an optically flat quartz disk overcoated with a film of the material of interest. These include Ag, Au, Pt, Nb, Ni, Al, C, Si, Ge, LiF, and a few engineering materials. Some materials for which the expected removal rate is high, such as carbon, will be solid disks rather than thin films.

Gregory, J. C.↗
NASA NTRS1993

Electrical performance of wire mesh for spacecraft deployable reflector antennas

Mobile satellite communications systems require large, high gain antennas at the spacecraft to minimize the antenna gain and power requirements for mobile user elements. The use of a deployable reflector antenna for these applications provides a lightweight system that can be compactly stowed prior to deployment on orbit. The mesh surface material is a critical component in the deployable reflector antenna design. The mesh is required to provide the desired electrical performance as well as the mechanical properties that are necessary to deploy and maintain the reflector surface on orbit. Of particular interest in multi-channel communications applications is the generation of Passive InterModulation (PIM) products at the reflector surface that can result in interference in the receive band. Wire mesh was specifically identified by some as having a high potential for PIM generation based solely on the existence of nonpermanent metal to metal contacts at the junctions that are inherent in the mesh design. There are a number of other factors, however, that reduce the likelihood of PIM occurring at the mesh reflector surface. Experimental data presented demonstrate that mesh PIM generation is not significant for typical applications. PIM and reflectivity performance of wire mesh composed of gold plated molybdenum wire in a tricot knit are described. This type of mesh was successfully used for the deployable Single Access Antennas of the Tracking and Data Relay Satellite System.

Turner, Greg↗
DOE OSTI2022

Nitrogen plasma passivated niobium resonators for superconducting quantum circuits

Microwave loss in niobium metallic structures used for superconducting quantum circuits is limited by a native surface oxide layer formed over a timescale of minutes when exposed to an ambient environment. Here, in this work, we show that nitrogen plasma treatment forms a niobium nitride layer at the metal–air interface, which prevents such oxidation. X-ray photoelectron spectroscopy confirms the doping of nitrogen more than 5 nm into the surface and a suppressed oxygen presence. This passivation remains stable after aging for 15 days in an ambient environment. Cryogenic microwave characterization shows an average filling-factor-adjusted two-level-system loss tangent Fδ TLS of (2.9±0.5)·10 –7 for resonators with a 3 μm center strip and (1.0±0.3)·10 –7 for a 20 μm center strip, exceeding the performance of unpassivated samples by a factor of four.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
NASA NTRS2010

Gossamer Technology to Deorbit LEO Non-Propulsion Fitted Satellite

Since 2004, CNES has decided to apply the end of life Code of Conduct rules to debris mitigation. Originally drawn up by the main European space agencies, it contains basic rules to be applied in space in order to limit the increase of orbital debris. In low Earth orbit, the rule is to limit in-orbit lifetime to 25 years after the end of the operational mission, or else to transfer to a graveyard orbit above 2000 km. In order to follow these instructions, a task force was set up in 2005 to find the best way to implement them on MICROSCOPE and CNES microsatellite family (MYRIADE). This 200-kg spacecraft should be launched in 2014 on a 790-km high circular orbit. Without targeted action, its natural re-entry would occur in 67 years. Two strategies to reduce this time period were compared: propulsive maneuvers at the end of the mission or the deployment of large surfaces to increase significantly the ballistic coefficient. At the end of the trade off, it was recommended: .. For the non-propulsive system fitted satellites, to use passive aerobraking by deployment of added surface, .. For satellites having propulsive subsystem in baseline for mission purposes, to keep sufficient propellant and implement specific maneuvers. The poster gives an overview of the process that led to the development of a deployable aerobraking wing using a lightweight aluminized Kapton membrane and an inflatable aluminum laminate boom. The main requirements; The trade off among various aerobraking solutions; The development plan. This technology presents a very attractive potential and it could be a first step in using of inflatable technology on spaces vehicles, before to deal with others more exigent applications.

Dupuy, C.↗
NASA NTRS1979

Surface tension driven convection

In a normal gravitational environment, the free surface of a liquid in a container plays a passive role in the transport processes. However, at microgravity, the free surface can become the dominant factor. A simple but meaningful spaceflight experiment is proposed to investigate the nature and extent of flows induced by surface-tension gradients along the free surface. The influences of container geometry, wetability, contamination, and imposed heating modes will be investigated.

Ostrach, S.↗
NASA NTRS1985

The First International Satellite Land-Surface Climatology Project (ISLSCP) Field Experiment (FIFE)

The International Satellite Land Surface Climatology Project (ISLSCP) will verify the use of satellite data for the estimation of land-surface properties through field experiments using point measurements on the ground and areal measurements from aircraft overflights. In addition to validating satellite estimates of surface properties, it studies approaches for obtaining areal averages of the radiation, moisture and heat fluxes made using remotely sensed data. The procedure suggested combines the surface point measurements of the fluxes with the aircraft areal observations using a surface energy balance model to interpolate between the point estimates of these fluxes and calculate area-averaged quantities. The surface parameters to be estimated from aircraft observations include: surface radiation temperature, albedo, land cover or vegetation index, and surface soil moisture (the latter to be obtained using passive and active microwave approaches). The area-averages of the surface properties are compared with satellite data where possible. The First ISLSCP Field Experiment is planned for l987 at a site having relatively uniform vegetation cover in the central great plains of the USA. for 1987 at a site having relatively uniform vegetation cover in the central great plains of the USA.

Schmugge, T. J.↗
NASA NTRS1986

The first International Satellite Land Surface Climatology Project (ISLSCP) Field Experiment - FIFE

The International Satellite Land Surface Climatology Project (ISLSCP) will verify the use of satellite data for the estimation of land-surface properties through field experiments using point measurements on the ground and areal measurements from aircraft overflights. It will study approaches for obtaining areal averages of the radiation, moisture, and heat fluxes made using remotely sensed data, by combining the surface point measurements of the fluxes with the aircraft areal observations using a surface energy balance model. Surface parameters to be estimated from aircraft observations include: surface radiation temperature, albedo, land cover or vegetation index, and surface soil moisture. The latter will be obtained using passive and active microwave approaches. The area-averages of the surface properties will be compared with satellite data. The First ISLSCP Field Experiment is planned for a site having relatively uniform vegetation cover in the central great plains of the U.S.A.

Schmugge, T. J.↗
NASA NTRS2014

Global-Scale Comparison of Passive (SMOS) and Active (ASCAT) Satellite Based Microwave Soil Moisture Retrievals with Soil Moisture Simulations (MERRA-Land)

Global surface soil moisture (SSM) datasets are being produced based on active and passive microwave satellite observations and simulations from land surface models (LSM). This study investigates the consistency of two global satellite-based SSM datasets based on microwave remote sensing observations from the passive Soil Moisture and Ocean Salinity (SMOS;SMOSL3 version 2.5) and the active Advanced Scatterometer (ASCAT; version TUWien- WARP 5.5) with respect to LSM SSM from the MERRA-Land data product. The relationship between the global-scale SSM products was studied during the 2010-2012 period using (1) a time series statistics (considering both original SSM data and anomalies), (2) a space-time analysis using Hovmoller diagrams, and (3) a triple collocation error model. The SMOSL3 and ASCAT retrievals are consistent with the temporal dynamics of modeled SSM (correlation R (is) greater than 0.70 for original SSM) in the transition zones between wet and dry climates, including the Sahel, the Indian subcontinent, the Great Plains of North America, eastern Australia, and southeastern Brazil. Over relatively dense vegetation covers, a better consistency with MERRA-Land was obtained with ASCAT than with SMOSL3. However, it was found that ASCAT retrievals exhibit negative correlation versus MERRA-Land in some arid regions (e.g., the Sahara and the Arabian Peninsula). In terms of anomalies, SMOSL3 better captures the short term SSM variability of the reference dataset (MERRA-Land) than ASCAT over regions with limited radio frequency interference (RFI) effects (e.g., North America, South America, and Australia). The seasonal and latitudinal variations of SSM are relatively similar for the three products, although the MERRALand SSM values are generally higher and their seasonal amplitude is much lower than for SMOSL3 and ASCAT. Both SMOSL3 and ASCAT have relatively comparable triple collocation errors with similar spatial error patterns: (i) lowest errors in arid regions (e.g., Sahara and Arabian Peninsula), due to the very low natural variability of soil moisture in these areas, and Central America, and (ii) highest errors over most of the vegetated regions (e.g., northern Australia, India, central Asia, and South America). However, the ASCAT SSM product is prone to larger random errors in some regions (e.g., north-western Africa, Iran, and southern South Africa). Vegetation density was found to be a key factor to interpret the consistency with MERRA-Land between the two remotely sensed products (SMOSL3 and ASCAT) which provides complementary information on SSM. This study shows that both SMOS and ASCAT have thus a potential for data fusion into long-term data records.

ASCAT↗
DOE OSTI2026

Operational stability of mixed Sn–Pb perovskite solar cells: Mechanisms, mitigation strategies, and perspectives

Mixed Sn–Pb perovskites provide the 1.2–1.3 eV narrow-bandgap absorber needed for high efficiency of all perovskite tandems, but their deployment is limited by operational instability under light. This review synthesizes mechanistic origins and recent mitigation strategies for mixed Sn–Pb perovskite solar cells. The oxidation of Sn 2+ to Sn 4+ , often driven by iodine formation under light and bias, is the primary failure pathway; it creates Sn vacancies, self-doping, and nonradiative loss. Surface/grain-boundary defects, halide migration, reactive oxygen species, and interfacial redox at charge-transport layers, along with hole accumulation from poor band alignment, further accelerate Sn–Pb perovskite degradation. Here we survey recent stability advances across additive chemistry, surface and grain-boundary passivation, buried-interface redesign with modified or alternative hole transport layers, and solvent systems that preserve Sn 2+ and correct Sn–Pb speciation for scalable coating. Together, these recent advances have enabled devices to retain 80%–90% output for hundreds to over a thousand hours. Lastly, we provide our perspectives on further improving the operational stability of Sn–Pb perovskite and solar cells.

14 SOLAR ENERGY↗
DOE OSTI2020

Bio-reduction of ferrihydrite-montmorillonite-organic matter complexes: Effect of montmorillonite and fate of organic matter

Organic matter (OM) is often associated with Fe (hydr)oxides such as ferrihydrite (Fh) in soils and sediments, forming binary Fh-OM complexes. Microbial reduction of Fh results in destabilization of the complexes and mineral/OM transformation. However, little is known about the role of clay minerals in such processes, despite their common co-existence with Fh and OM in natural environments. Here Fh-OM complexes were synthesized in the presence of montmorillonite (SWy-2), forming ternary Fh-(SWy-2)-OM complexes. A metal-reducing bacterium Geobacter sulfurreducens was used to reduce Fh in the complexes under circumneutral pH and anoxic conditions with or without H 2 as extra electron donor. Various spectroscopy and mass spectrometry methods were used to monitor the progress of Fh bio-reduction and mineral/OM transformation. Results showed that G. sulfurreducens utilized mineral-bound OM as electron donor and/or carbon source to couple with Fh reduction. Relative to Fh-OM complex, Addition of SWy-2 to Fh-OM complex enhanced the bio-reduction extent of Fh by increasing the proportion of bioavailable OM that was weakly bound to SWy-2. However, its effect on the bio-reduction rate was variable. SWy-2 initially decreased the rate, because it spatially separated OM (electron donor) from Fh (electron acceptor). During later incubation, SWy-2 increased the reduction rate by sorbing biogenic Fe 2+ that would otherwise passivate the Fh and cell surfaces. Bio-reduction transformed mineral-bound OM to microbial products (e.g. necromass, extracellular polymeric substances), but organic compounds with aromatic structures, carboxyl groups and large molecular weight were more resistant to desorption and oxidation. The persistence of these compounds against bio-reduction induced transformation is likely due to their stronger binding with minerals and/or lower nominal oxidation states of carbon relative to other compounds. Our results provide new insights into the role of clay minerals in regulating biogeochemical cycling of solid-phase Fe and transformation of mineral-associated OM in anoxic soil environments.

58 GEOSCIENCES↗
DOE OSTI2023

Chemical durability and corrosion-induced microstructure evolution of compositionally complex titanate pyrochlore waste forms with uranium incorporation

Chemical durability of compositionally-complex rare-earth titanate pyrochlore solid solutions with or without uranium incorporation was investigated by semi-dynamic leaching testing. A Ti-enriched amorphous passivation film formed on the surface due to the surface alteration-reorganization mechanism with preferential release of the weakly oxygen-bonded rare earth elements. Elemental release was found to be strongly correlated with chemical disorder, with a negligible correlation with entropy. The release rate of the uranium gradually decreased with increasing numbers of components, implying a possibility of designing and optimizing waste form performance with enhanced chemical durability by controlling composition complexity and chemical disorder for effective nuclear waste management.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
DOE OSTI2024

Resolving the Electron Plume within a Scanning Electron Microscope

Scanning electron microscopy (SEM), a century-old technique, is today a ubiquitous method of imaging the surface of nanostructures. However, most SEM detectors simply count the number of secondary electrons from a material of interest, and thereby overlook the rich material information contained within them. Here, by simple modifications to a standard SEM tool, we resolve the momentum and energy information on secondary electrons by directly imaging the electron plume generated by the electron beam of the SEM. Leveraging these spectroscopic imaging capabilities, our technique is able to image lateral electric fields across a prototypical silicon p–n junctions and to distinguish differently doped regions, even when buried beyond depths typically accessible by SEM. Intriguingly, the subsurface sensitivity of this technique reveals unexpectedly strong surface band bending within nominally passivated semiconductor structures, providing useful insights for complex layered component designs, in which interfacial dynamics dictate device operation. Further, these capabilities for noninvasive, multimodal probing of complicated electronic components are crucial in today’s electronic manufacturing but is largely inaccessible even with sophisticated techniques. These results show that seemingly simple SEM can be extended to probe complex and useful material properties.

36 MATERIALS SCIENCE↗
DOE OSTI2021

Surface Reconstruction of Halide Perovskites During Post-treatment

Postfabrication surface treatment strategies have been instrumental to the stability and performance improvements of halide perovskite photovoltaics in recent years. However, a consensus understanding of the complex reconstruction processes occurring at the surface is still lacking. Here, we combined complementary surface-sensitive and depth-resolved techniques to investigate the mechanistic reconstruction of the perovskite surface at the microscale level. We observed a reconstruction toward a more PbI 2 -rich top surface induced by the commonly used solvent isopropyl alcohol (IPA). We discuss several implications of this reconstruction on the surface thermodynamics and energetics. Particularly, our observations suggest that IPA assists in the adsorption process of organic ammonium salts to the surface to enhance their defect passivation effects.

14 SOLAR ENERGY↗