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At least 721 records · Page 40
All sourcesNASA NTRSDOE OSTI
NASA NTRS2024

Interim Measures Pilot Study Completion Report, South Repeater Building, Solid Waste Management Unit 121, Hydraulic Containment and Groundwater Treatment System for Per- and Polyfluoroalkyl Substances

This Per- and Polyfluoroalkyl Substances (PFAS) Interim Measures Pilot Study Completion Report was prepared for the National Aeronautics and Space Administration by AECOM Technical Services, Inc. under Contract 80KSC019D0010, Task Order 80KSC021F0096. The purpose of this report is to document the pilot study activities at the South Repeater Building, Solid Waste Management Unit (SWMU) 121. This report details the additional assessment activities completed from June 2023 through November 2023 and the subsequent pilot study completed at the South Repeater Building conducted in December 2023 through February 2024. Initial activities were conducted in accordance with the Pilot Study Work Plan (NASA 2023), submitted to the KSC Remediation Team and accepted by the team on October 26, 2023. The objectives of the pilot study were to: • Provide information on aquifer characteristics and to aid in future modeling and remedial design activities to mitigate off-KSC migration of PFAS compounds. • Develop information on characteristics of the surficial aquifer system, specifically transmissivity, storage coefficient, hydraulic conductivity, and vertical hydraulic conductivity. • Obtain data to support construction and calibration of a groundwater flow model. • Acquire design parameters necessary for future remedial design activities, specifically radius of influence, drawdown, flow rates, and pump settings. The following activities were completed to meet the pilot study objectives: • Groundwater and surface water sampling • Geophysical investigation via Hydraulic Profiling Tool (HPT) and soil sampling • Installation of observation and extraction wells via rotosonic techniques • Slug, step, and pump testing activities • Initial modeling efforts for a groundwater hydraulic containment system. Results of the pilot study and modeling activities are being used in the development of a groundwater containment and treatment system for the site.

PFAS↗
DOE OSTI2020

System Design of a 2.0 MWth Sodium/Molten Salt Pilot System

Nitrate molten salt concentrating solar power (CSP) systems are currently deployed globally and are considered state-of the art heat transfer fluids (HTFs) for present day high-temperature operation. Although slightly higher limits may be possible with molten salt, to fully realize SunShot efficiency goals of $15/kWhth HTFs and an LCOE of 6¢/kWh, HTF technologies working at higher temperatures (e.g., 650 °C to 750 °C) will require an alternative to molten salts, such as with alkali metal systems. This investigation explores the development of a 2.0 MWth sodium receiver system that employs a sodium receiver as the HTF, as well as with a ternary chloride (20%NaCl/40%MgCl/40%KCl by mol wt.%) salt as a thermal energy storage (TES) medium to facilitate a 6-hr. storage duration. A sodium-to-salt heat exchanger model as well as a salt-to-sCO2 primary heat exchanger model are employed and evaluated in this investigation. A thermodynamic system design model was developed using Engineering Equation Solver (EES) where state properties were calculated at inlets and outlets along both hot and cold legs of the pilot-scale plant. This investigation assesses receiver performance as well as system efficiency studies for the pump and system operational ranges. Results found that high efficiency sodium receivers were found to have higher heat transfer coefficients and required far less spreading of incident flux. The system performance model results suggest that for a pump speed of 2400 RPM, respective hot and cold pump TDH values were determined to be 260.1–307 ft. and 260.1–307 ft for pump flow rates of 90–120 GPM.

41 EE - Solar Energy Technologies Office (EE-4S)↗
DOE OSTI2020

Operational Modes of a 2.0 MWth Chloride Molten-Salt Pilot-Scale System

The limit of traditional solar-salt thermal stability is around 600 °C with ambient air as the cover gas. Nitrate molten salt concentrating solar power (CSP) systems are currently deployed globally and are considered to be state-of the art heat transfer fluids (HTFs) for present day high-temperature operation. However, decomposition challenges occur with these salts for operation beyond 600 C. Although slightly higher limits may be possible with solar salt, to fully realize SunShot efficiency goals of $15/kWhth HTFs and an LCOE of 6¢/kWh, molten-salt technologies working at higher temperatures (e.g., 650 °C to 750 °C) will require an alternative salt chemistry composition, such as chlorides. In this investigation a 2.0MWth Pilot-scale CSP plant design is developed to assess thermodynamic performance potential for operation up to 720 C. Here, an Engineering Equation Solver (EES) model is developed with respect to 14 state-points from the base of a solar tower at the Sandia National Laboratories, National Solar Thermal Test Facility (NSTTF), to solar receiver mounted 120 ft. above the ground. The system design considers a ternary chloride ternary chloride (20%NaCl/40%MgCl/40%KCl by mol%) salt as the HTF, with 6 hrs. of storage and a 1 MWth primary salt to sCO2 heat exchanger. Preliminary system modelling results indicate a minimum non-dimensional Cv of 60 required for both cold and hot-side throttle recirculation valves for the operational pump operating between speeds of 1800 and 2400 RPM. Further receiver comparison study results suggest that the ternary salt requires an average 15.2% higher receiver flux with a slightly lower calculated receiver efficiency when compared to a binary carnelite salt to achieve a 2.0 MWth desired input power design.

associated liquids↗
NASA NTRS1981

Single-family-residence solar heating--Carlsbad, New Mexico

Solar-heating and hot-water system includes 408 square feet of flat-plate air collectors, rock storage bin, energy transport system, air-to-water heat exchanger, controls, and hot-water preheat tank. Hot-air oil furnace supplies auxiliary space heating, and electricity powers air-handler blower and hot water preheat pump. For 12 month period, system provided 43 percent of space-heating and 53 percent of hot-water energy; net energy savings were 23.072 million Btu.

Source record↗
NASA NTRS1987

Negative-Electrode Catalysts for Fe/Cr Redox Cells

Electrodes perform more consistently and less expensive. Surfaces catalyzed by bismuth and bismuth/lead developed for application on chromium electrode in iron/chromium redox electrochemical energy storage system. NASA Fe/Cr storage system incorporates two soluble electrodes consisting of acidified solutions of iron chloride (FeC13 and FeC12) and chromium chloride (CrC13 and CrC12) oxidized and reduced in power-conversion unit to store and produce electricity. Electrolytes circulated with pumps and stored in external tanks.

Gahn, R. F.↗
NASA NTRS2000

High-Q Microsphere Cavity for Laser Stabilization and Optoelectronic Microwave Oscillator

With submillimeter size and optical Q up to approximately 10 (exp 10), microspheres with whispering-gallery (WG) modes are attractive new component for fiber-optics/photonics applications and a potential core in ultra-compact high-spectral-purity optical and microwave oscillators. In addition to earlier demonstrated optical locking of diode laser to WG mode in a microsphere, we report on microsphere application in the microwave optoelectronic oscillator, OEO. In OEO, a steady-state microwave modulation of optical carrier is obtained in a closed loop including electro-optical modulator, fiber-optic delay, detector and microwave amplifier. OEO demonstrates exceptionally low phase noise (-140 dBc/Hz at l0kHz from approximately 10GHz carrier) with a fiber length approximately 2km. Current technology allows to put all parts of the OEO, except the fiber, on the same chip. Microspheres, with their demonstrated Q equivalent to a kilometer fiber storage, can replace fiber delays in a truly integrated device. We have obtained microwave oscillation in microsphere-based OEO at 5 to 18 GHz, with 1310nm and 1550nm optical carrier, in two configurations: 1) with external DFB pump laser, and 2) with a ring laser including microsphere and a fiber optic amplifier. Also reported is a simple and efficient fiber coupler for microspheres facilitating their integration with existing fiber optics devices.

Ilchenko, Vladimir S.↗
NASA NTRS2012

NASA Tech Briefs, July 2012

Topics covered include: Instrument Suite for Vertical Characterization of the Ionosphere-Thermosphere System; Terahertz Radiation Heterodyne Detector Using Two-Dimensional Electron Gas in a GaN Heterostructure; Pattern Recognition Algorithm for High-Sensitivity Odorant Detection in Unknown Environments; Determining Performance Acceptability of Electrochemical Oxygen Sensors; Versatile Controller for Infrared Lamp and Heater Arrays; High-Speed Scanning Interferometer Using CMOS Image Sensor and FPGA Based on Multifrequency Phase-Tracking Detection; Ultra-Low-Power MEMS Selective Gas Sensors; Compact Receiver Front Ends for Submillimeter-Wave Applications; Dynamically Reconfigurable Systolic Array Accelerator; Blocking Losses With a Photon Counter; Motion-Capture-Enabled Software for Gestural Control of 3D Mod; Orbit Software Suite; CoNNeCT Baseband Processor Module Boot Code SoftWare (BCSW); Trajectory Software With Upper Atmosphere Model; ALSSAT Version 6.0; Employing a Grinding Technology to Assess the Microbial Density for Encapsulated Organisms; Demonstration of Minimally Machined Honeycomb Silicon Carbide Mirrors; Polyimide Aerogel Thin Films; Nanoengineered Thermal Materials Based on Carbon Nanotube Array Composites; Composite Laminate With Coefficient of Thermal Expansion Matching D263 Glass; Robust Tensioned Kevlar Suspension Design; Focal Plane Alignment Utilizing Optical CMM; Purifying, Separating, and Concentrating Cells From a Sample Low in Biomass; Virtual Ultrasound Guidance for Inexperienced Operators; Beat-to-Beat Blood Pressure Monitor; Non-Contact Conductivity Measurement for Automated Sample Processing Systems; An MSK Radar Waveform; Telescope Alignment From Sparsely Sampled Wavefront Measurements Over Pupil Subapertures; Method to Remove Particulate Matter from Dusty Gases at Low Pressures; Terahertz Quantum Cascade Laser With Efficient Coupling and Beam Profile; Measurement Via Optical Near-Nulling and Subaperture Stitching; 885-nm Pumped Ceramic Nd:YAG Master Oscillator Power Amplifier Laser System; Airborne Hyperspectral Imaging System; Heat Shield Employing Cured Thermal Protection Material Blocks Bonded in a Large-Cell Honeycomb Matrix; and Asymmetric Supercapacitor for Long-Duration Power Storage.

Source record↗
DOE OSTI2024

Geological Thermal Energy Storage (GeoTES) Charged with Solar Thermal Technology Using Depleted Oil/Gas Reservoirs and Carnot-Battery Technique Using Shallow Reservoirs: Preprint

Geological thermal energy storage (GeoTES) utilizes the underground reservoirs to storage and dispatch energy per given demand schedule over a time scale up to seasons of a year. The energy input can be of various sources/forms; in this paper, we investigate 1) the GeoTES technology with solar thermal hybridization and using depleted oil/gas reservoirs; 2) the GeoTES technology with heat pumps charged by excess renewable electricity and using low-temperature shallow reservoirs. For each GeoTES technology, we carry out the suitability analysis of candidate reservoirs, develop initial techno-economic models, and validate the model with selected case study. The paper provides an overview of our technical progress on the topics of concern and aims to promote a wider acceptance of the GeoTES technologies in the future energy market.

Carnot battery↗
DOE OSTI2023

Peak Reduction Using Mode Adjustment of Heat Pump Water Heaters in a Residential Neighborhood

Building electrification is putting pressure on distribution grid worldwide. Peak reduction is an important concern that can help reduce the growing stress and allow to defer investments in new capacity. Water heaters represent a convenient way of reducing peak because they are less dependent on weather, and their storage volume allows for asynchronous water heating and hot water use. Previous empirical studies investigated the ability of water heaters to reduce peak through the adjustment of the temperature setpoint. However, not all equipment vendors offer this option. This study aims at understanding the feasibility of peak reduction with an alternative configuration available in the market - by adjusting the device mode rather than temperature setpoint. The peak reduction methodology is tested in an occupied 46-townhome neighborhood located in Atlanta, GA. We find that peak shifting is possible with the adjustable mode approach, with the change in the peak load by 30-60%.

demand response↗
NASA NTRS1990

New laser materials for laser diode pumping

The potential advantages of laser diode pumped solid state lasers are many with high overall efficiency being the most important. In order to realize these advantages, the solid state laser material needs to be optimized for diode laser pumping and for the particular application. In the case of the Nd laser, materials with a longer upper level radiative lifetime are desirable. This is because the laser diode is fundamentally a cw source, and to obtain high energy storage, a long integration time is necessary. Fluoride crystals are investigated as host materials for the Nd laser and also for IR laser transitions in other rare earths, such as the 2 micron Ho laser and the 3 micron Er laser. The approach is to investigate both known crystals, such as BaY2F8, as well as new crystals such as NaYF8. Emphasis is on the growth and spectroscopy of BaY2F8. These two efforts are parallel efforts. The growth effort is aimed at establishing conditions for obtaining large, high quality boules for laser samples. This requires numerous experimental growth runs; however, from these runs, samples suitable for spectroscopy become available.

Jenssen, H. P.↗
NASA NTRSDate not supplied

Thermal Management Challenges and Technology Options for Lunar Regenerative Fuel Cells

Regenerative Fuel Cells (RFCs) enable lunar surface hardware, from pressurized rovers to surface habitats, to survive the lunar night by providing the required energy storage with a lower mass than state of the art battery systems. RFCs consist of fuel cell and electrolyzer electrochemical stack(s), a fluidic balance of plant, and electrical balance of plant. Fuel cells operate by converting the stored chemical energy of reactants into DC electrical power, heat, and water. When supplied DC power from an available external source, electrolyzers regenerate the reactants through electrolysis. The balance of plant is a critical part of the integrated system consisting of many individual components and provides fluid pressure management and conditioning, fluid storage, and thermal management. Component technology development is required to create an RFC system that will be capable of surviving the harsh lunar environment and maximize specific energy (W-hr/kg). One critical component requiring development includes a kW-scale high flux thermal switch. The primary requirement for the thermal switch is the ability to maintain low thermal resistance with the RFC heat rejection interface during the lunar day to maximize heat rejection while switching to a high thermal resistance during the lunar night such that the RFC can conserve as much thermal energy as possible. Different technology including freeze tolerant pumped loop, passive louvers, and variable conductance heat pipes were assessed as potential solutions. NASA is exploring development options through internal and external partnerships to develop this technology critical for a spaceflight RFC system.

Energy Storage↗
DOE OSTI2022

Material Selection and Corrosion Studies of Candidate Bearing Materials for Use in Molten Chloride Salt

Molten chloride salts are being given strong consideration for use in heat transfer and storage in concentrating solar power (CSP) systems as well as in some nuclear reactor applications. Containment of the molten salt, particularly at the highest temperatures, is a major material concern and has received considerable study. Another material issue is the pumps that will be required to move the molten salt along with the bearing materials that will be required to have sufficient corrosion resistance as well as wear resistance in the high temperature salt. A pair of coordinated studies in our laboratory has addressed the corrosion, and the wear issues of candidate bearing materials including the selection of candidate materials as well as their performance in a molten sodium chloride-potassium chloride-magnesium chloride salt environment. This work addresses the selection of candidate materials and their chemical compatibility with the molten salt. The studies have identified material pairs that have suitable properties for use as bearings that would be immersed in molten chloride salt.

14 SOLAR ENERGY↗
NASA NTRS1989

Frequency stable high power lasers in space

The concept of a laser heterodyne gravity wave antenna that would operate in solar orbit with a one million kilometer path length is discussed. Laser technology that would be appropriate for operation of this space-based gravity wave detector is also discussed. The rapid progress in diode laser coupled with the energy storage and potentially sub-Hertz linewidths of solid state lasers, and the possibility of efficient frequency conversion by nonlinear optical techniques defines a technology that is appropriate for laser interferometry in space. The present status of diode-laser-pumped, solid state lasers is summarized and future progress is projected in areas of linewidth control, high average power, operating efficiency, and operational lifetimes that are essential for space-based applications.

Byer, Robert L.↗
DOE OSTI2026

Development, Monitoring, and Control of Fracture Thermal Energy Storage (FTES) in Crystalline Rock Formations (DEMO-FTES) (CRADA Final Report)

The DEMO-FTES project sought to demonstrate the thermal efficiency of fracture thermal energy storage (FTES) through numerical simulations, laboratory and meso-scale field tests. A detailed dimensional and scaling analysis was performed to identify key parameters and how they can be most effectively scaled to the laboratory and decameter scale. Numerical models were developed and used for three purposes: 1. Before field experiments, numerical modelling can be used to estimate fracture properties based on previous data from the EGS Collab experiment and then predict thermal hydrological behaviors of the fracture system with hot water injection/withdrawal, therefore, help to design the experiments (e.g., to decide the duration of the cycles based on the flow rate the pump can provide, and the estimated fracture properties); 2. After the field experiment, to estimate the system properties during the experiment (as the size and shape of a fracture could change over time), and understand why system performance is different than what has been predicted, i.e., to help understand the meso-scale test; and, 3. To model the lab experiments and estimate fracture properties and storage efficiency. Ultimately, the experiment and numerical models could shed light on the processes and uncertainty happening during fracture activation and help understand the scaling between lab and field test, and finally, the design and optimization of potential fracture thermal energy storage systems.

25 ENERGY STORAGE↗
DOE OSTI2022

The cost savings potential of controlling solar thermal collectors with storage for time-of-use electricity rates

Homes and commercial buildings account for roughly 40% of U.S. energy consumption. A significant portion of this energy consumption, and therefore utility cost, comes from domestic hot-water use. Solar collectors such as flat plate collectors, evacuated tubes, and combined photovoltaic/thermal panels, are renewable options that collect thermal energy and could help reduce utility costs. Hot water is generated by pumping a working fluid through the solar collector, where the fluid captures thermal energy via absorbed solar radiation incident on the collector surface. The collection of heat coincides with the availability of solar radiation, but the best time to use this thermal energy depends on the utility rate at a given time, which often changes throughout the day. In this work, we implement and simulate a control strategy using Transient System Simulation Tool (TRNSYS) that reduces utility costs by controlling when the system stores and uses thermal energy based on solar availability and time-of-use electricity rates. Our modeled results show that the control strategy can reduce utility costs associated with using hot water between 3% and 30%. Here, we also show how the on-peak utility rates, the size and type of the solar collectors, and the location's climate impact the results.

14 SOLAR ENERGY↗
NASA NTRSDate not supplied

A Passive fuel-Cell Surface power System (PaCeSS)

This effort produces a fully-passive surface power generation capability for fuel cell technology. The concept replaces the actively pumped thermal management of a state of the art (SOA) fuel cell/electrolyzer stack with a passive 2-phase thermosyphon for heat transport and a passive shape memory actuating radiator for temperature management. The concept addresses NASA fuel cell technology roadmap needs for greater reliability and longer operating life by eliminating life limiting elements of SOA fuel cell system design that drive failure modes associated with moving parts and control complexity. Applications map to surface power (primary fuel cell), surface energy storage (regenerable fuel cell) and in-situ resource utilization (electrolyzer/unitized reversible fuel cell). The first year of this effort concluded with independent demonstrations of 2-phase thermosyphon heat transport from a simulated fuel cell and temperature driven actuation of a shape memory actuating radiator. Results are in-character with underlying physics and demonstrate the potential to realize the objectives of this concept. his effort produces a fully-passive surface power generation capability for fuel cell technology. The concept replaces the actively pumped thermal management of a state of the art (SOA) fuel cell/electrolyzer stack with a passive 2-phase thermosyphon for heat transport and a passive shape memory actuating radiator for temperature management.

deionized water↗
NASA NTRS2023

Large-Scale Groundwater Monitoring in Brazil Assisted With Satellite-Based Artificial Intelligence Techniques

Here, we develop and test an artificial intelligence (AI)-based approach to monitor major Brazilian aquifers. The approach combines Gravity Recovery and Climate Experiment (GRACE) data and ground-based hydrogeological measurements from Brazil’s Integrated Groundwater Monitoring Network at hundreds of wells distributed in twelve aquifers across the country. We tested model ensembles based on three AI approaches: Extreme Gradient Boost, Light Gradient Boosting Model and CatBoost, followed by a Linear Regression (LR) step. The approach is further boosted with wavelet and seasonal decomposition processes applied to GRACE data. To determine the AI-based model’s sensitivity to data availability, we propose four experiments combining hydrogeological measurements from different aquifers. Groundwater storage estimates from the Global Land Data Assimilation System (GLDAS) are used as benchmark. A sensitivity analysis shows that the LR-based model ensemble is the best suited and to reproduce groundwater storage change in all studied Brazilian aquifers. Results show that the proposed approach outperforms GLDAS in all experiments, with an RMSE value of 2.68cm for the experiment that covers all monitored wells in Brazil. GLDAS resulted in RMSE=6.76cm. Using our AI model outputs, we quantified the groundwater storage change of two major aquifers, Urucuia and Bauru-Caiuá, over the past two decades: -31km 3 and -6km 3 , respectively. Water loss is driven by a prolonged drought across most of the country and intensification of groundwater pumping for irrigation. This study demonstrates that combining satellite data and AI can be a cost-effective alternative to monitor poorly equipped aquifers at the continental scale, with possible global replicability.

GRACE↗
DOE OSTI2021

Mitigation of Acute Ammonia Emissions With Biochar During Swine Manure Agitation Before Pump-Out: Proof-of-the-Concept

Ammonia (NH 3 ) emissions from animal agriculture can cause eutrophication of water ecosystems and are precursors to secondary particulate matter (PM 2 .5 ). NH 3 emissions from stored swine manure represent nutrient loss affecting the fertilizing value of manure. The short-term emission bursts occur when farmers agitate manure before emptying storage and fertilizing fields. There is no proven technology to mitigate gaseous emissions during agitation, while the hazards of acute releases (e.g., H 2 S) are well-known. Biochar mitigates NH 3 emissions from manure over the long-term. The objective of this research was to evaluate the mitigation of acute NH 3 emissions during/after agitation. Two biochars, highly alkaline and porous (HAP from corn stover) and red oak (RO), were tested. The 6 and 12 mm-thick layers of biochar powder were surficial applied followed by 3 min agitation. NH 3 concentrations were measured before/during/after agitation. Mitigation was assessed by comparing: (i) the maximum (peak) flux, (ii) total emission (from agitation start till NH 3 concentration returned to the before-agitation), and (iii) the total emissions during agitation. The 12 mm HAP significantly ( p < 0.05) reduced (i–iii) by 63, 70, and 85%, respectively. The 6 mm HAP significantly reduced (i–iii) by 76, 75, and 78%, respectively. The 12 mm RO significantly reduced (i–iii) by 9, 53, and 57%, respectively. The 6 mm RO significantly reduced (i–iii) by 61, 86, and 63%, respectively. The NH 3 emission kinetics model confirmed that a 6 mm dose was just as effective as the larger dose. More research is needed to optimize and scale-up mitigating emissions and retention of nutrients in manure with biochar.

Chen, Baitong↗