Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “phase transfer”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 721 records · Page 40

Deoxydehydration and Catalytic Transfer Hydrogenation: New Strategy to Valorize Tartaric Acid and Succinic Acid to γ-Butyrolactone and Tetrahydrofuran

Hydrogenation of succinic acid and maleic acid produces C4 value-added chemicals such as γ-butyrolactone and tetrahydrofuran. Here, unsupported ReOx nanoparticles transform succinic acid to γ-butyrolactone and tetrahydrofuran via catalytic transfer hydrogenation with isopropanol as a liquid phase hydrogen donor. This catalyst is also active for the sequential reaction of deoxydehydration and transfer hydrogenation in isopropanol, synthesizing renewable succinic acid and its esters from tartaric acid. One-step conversion of tartaric acid to γ-butyrolactone is achieved in a moderate yield and the possible reaction pathway is discussed.

10 SYNTHETIC FUELS↗

Heat-Storage Modules Containing LiNO3-3H2O and Graphite Foam

A heat-storage module based on a commercial open-cell graphite foam (Poco-Foam or equivalent) imbued with lithium nitrate trihydrate (LiNO3-3H2O) has been developed as a prototype of other such modules for use as short-term heat sources or heat sinks in the temperature range of approximately 28 to 30 C. In this module, the LiNO3-3H2O serves as a phase-change heat-storage material and the graphite foam as thermally conductive filler for transferring heat to or from the phase-change material. In comparison with typical prior heat-storage modules in which paraffins are the phase-change materials and aluminum fins are the thermally conductive fillers, this module has more than twice the heat-storage capacity per unit volume.

Bootle, John↗

Evaluation of active thermal control options for Space Station

An analysis of various Space Station (MSS) active thermal control systems options under consideration because of their potential low weight, efficiency and reliability is reported. The study addressed ordinary and diode-action body mounted radiators, thermal storage, the area and pumping power requirements for single-phase cooling of cold plates, and single-phase and two-phase active cooling loops. The base configuration considered was a core MSS formed by four habitable modules on which are mounted heat pipe radiators articulated to be always edge-on to the sun. A simulation was performed which accounted for the available heat sinks, several thermal loads and the heat rejection capability. No benefits were found with diode-action radiators if the solar absorption is 0.1 or less, although diode-action heat pipes will maintain a higher level of performance in the presence of coating degradation. Thermal storage becomes important only with radiator coating degradation. Water can be up to three times as efficient as Freon as a heat transfer medium. Finally, single-phase cooling offers a lower system mass than two-phase cooling if varying temperature heat loads can be accommodated.

Schuster, J. R.↗

ATRP Enhances Structural Correlations In Polymerization–Induced Phase Separation**

Synthetic methods to control the structure of materials at sub–micron scales are typically based on the self–assembly of structural building blocks with precise size and morphology. On the other hand, many living systems can generate structure across a broad range of length scales in one step directly from macromolecules, using phase separation. Here, we introduce and control structure at the nano– and microscales through polymerization in the solid state, which has the unusual capability of both triggering and arresting phase separation. In particular, we show that atom transfer radical polymerization (ATRP) enables control of nucleation, growth, and stabilization of phase–separated poly–methylmethacrylate (PMMA) domains in a solid polystyrene (PS) matrix. ATRP yields durable nanostructures with low size dispersity and high degrees of structural correlations. Furthermore, we demonstrate that the length scale of these materials is controlled by the synthesis parameters.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Zero g manual cargo handling

A series of studies were conducted utilizing a water-immersion simulator facility to better define the cargo that can realistically be handled by man. The initial phase of the program was a parametric study to define man's intravehicular (IV) cargo transfer capabilities, and its results are reported. Additional phases of the study, deal with: (1) man's ability to perform extravehicular (EV) cargo transfer, (2) the ability to transfer cargo through a 1.5 m (5-foot) diameter tunnel (IV), and (3) the utilization of electroadhesive/electromagnetic mobility aids for both IV and EV self-locomotion and cargo transfer.

Spady, A. A., Jr.↗

Fidelity-preserving enhancement of ptychography with foundational text-to-image models

Ptychographic phase retrieval enables high-resolution imaging of complex samples but often suffers from artifacts such as grid pathology and multislice crosstalk, which degrade reconstructed images. We propose a plug-and-play (PnP) framework that integrates physics model-based phase retrieval with text-guided image editing using foundational diffusion models. By employing the alternating direction method of multipliers, our approach ensures consensus between data fidelity and artifact removal subproblems, maintaining physical consistency while enhancing image quality. Artifact removal is achieved using a text-guided diffusion image editing method (LEDITS++) with a pre-trained foundational diffusion model, allowing users to specify artifacts for removal in natural language. Demonstrations on simulated and experimental datasets show significant improvements in artifact suppression and structural fidelity, validated by metrics such as peak signal-to-noise ratio and diffraction pattern consistency. This work highlights the combination of text-guided generative models and model-based phase retrieval algorithms as a transferable and fidelity-preserving method for high-quality diffraction imaging.

image editing↗

Thermodynamic Vent System Test in a Low Earth Orbit Simulation

A thermodynamic vent system for a cryogenic nitrogen tank was tested in a vacuum chamber simulating oxygen storage in low earth orbit. The nitrogen tank was surrounded by a cryo-shroud at -40 F. The tank was insulated with two layers of multi-layer insulation. Heat transfer into cryogenic tanks causes phase change and increases tank pressure which must be controlled. A thermodynamic vent system was used to control pressure as the location of vapor is unknown in low gravity and direct venting would be wasteful. The thermodynamic vent system consists of a Joule-Thomson valve and heat exchanger installed on the inlet side of the tank mixer-pump. The combination is used to extract thermal energy from the tank fluid, reducing temperature and ullage pressure. The system was sized so that the tank mixer-pump operated a small fraction of the time to limit motor heating. Initially the mixer used sub-cooled liquid to cool the liquid-vapor interface inducing condensation and pressure reduction. Later, the thermodynamic vent system was used. Pressure cycles were performed until steady-state operation was demonstrated. Three test runs were conducted at tank fills of 97, 80, and 63 percent. Each test was begun with a boil-off test to determine heat transfer into the tank. The lower tank fills had time averaged vent rates very close to steady-state boil-off rates showing the thermodynamic vent system was nearly as efficient as direct venting in normal gravity.

VanOverbeke, Thomas J.↗

Polyampholyte physics: Liquid–liquid phase separation and biological condensates

Here we review the current understanding of molecular interactions that govern liquid-liquid phase separation (LLPS) of biological condensates. The connection between sequence, chain conformation, and phase separation of intrinsically disordered proteins (IDPs) and their model polyampholytes is discussed. In particular, we highlight how the charge pattern influences the conformation and phase behavior of natural IDPs. We then describe recent results from theoretical treatments of polyampholytes implementing random phase approximation, field-theoretic simulations, and transfer matrix theory that show an increase in charge segregation results in an increased tendency to phase separate.

59 BASIC BIOLOGICAL SCIENCES↗

Real time estimation of the heaving and pitching motions of a ship, using a Kalman filter

In the present study the estimation of the heave and pitch motion of a ship is considered, using Kalman filtering techniques. A significant part of the study is devoted to constructing appropriate models for the sea and the ship. The governing equations are obtained from hydrodynamic considerations in the form of linear differential equations with frequency dependent coefficients. In addition, nonminimum phase characteristics are obtained due to the spatial integration of the water wave forces. The resulting transfer matrix function is irrational and nonminimum phase. The conditions for a finite-dimensional approximation are considered and the impact of the various parameters is assessed. A numerical application is considered for a DD-963 destroyer.

Triantafyllou, M.↗

Real time estimation of ship motions using Kalman filtering techniques

The estimation of the heave, pitch, roll, sway, and yaw motions of a DD-963 destroyer is studied, using Kalman filtering techniques, for application in VTOL aircraft landing. The governing equations are obtained from hydrodynamic considerations in the form of linear differential equations with frequency dependent coefficients. In addition, nonminimum phase characteristics are obtained due to the spatial integration of the water wave forces. The resulting transfer matrix function is irrational and nonminimum phase. The conditions for a finite-dimensional approximation are considered and the impact of the various parameters is assessed. A detailed numerical application for a DD-963 destroyer is presented and simulations of the estimations obtained from Kalman filters are discussed.

Triantafyllou, M. S.↗

Cryogenic Flow Boiling Parabolic Flight Experiment and Universal Correlations for Cryogens

Cryogenic fluids are employed in many industries and play crucial roles in space applications, including nuclear thermal propulsion systems, LOX/LCH4 ascent and descent stage feedlines, LOX/LH2 transfer lines for in-space fuel depots, and LHe transfer lines that cool space experiments. Due to the ultra-low boiling point of cryogens, phase change is inevitable in these systems, which leads to complex boiling behavior in reduced gravity. For cost-effective design and sizing of the aforementioned systems, accurate knowledge of two-phase parameters such as pressure drop, heat transfer coefficient (HTC), and critical heat flux (CHF) is desired. Since 2018, researchers from Purdue University and NASA Glenn Research Center (GRC) have been collaborating to investigate the effects of reduced gravity on cryogenic pool boiling, flow boiling ins tubes, and spray cooling. Using a variety of both terrestrial and parabolic flight experimental rigs, extensive LN2 data have been amassed and combined with cryogenic data from World literature to develop both ‘universal’ empirical correlations and CFD models, which are expected to serve as foundation for design of future space systems involving cryogenic fluids. This presentation will provide an overview of both the experimental work and predictive tools that have resulted from the joined Purdue-Glenn studies.

Flow Boiling↗

Movement of Decaying Quasi-2-day Wave in the Austral Summer-time Mesosphere

The Quasi-2-Day Wave (Q2DW) is a large temperature disturbance in the austral summer-time mesosphere. Its decay-phase movement and phase-speed are poorly understood. Q2DW events observed by the Microwave Limb Sounder (MLS) onboard the NASA Aura satellite reveal that during the temperature Q2DW’s decay-phase, the Q2DW temperature disturbance is still substantial, but its phase-speed reduces exponentially, on average, from around -70 m/s to -20 13 m/s in around 30-days. Observations also reveal significant interannual variability in these phase-speed values. Q2DW events simulated by the extended Canadian Middle Atmosphere Model (eCMAM) reveal that during the Q2DW decay-phase, the temperature Q2DW phase- speed is strongly correlated with the Summer Mesosphere Easterly Jet (SMEJ) wind values. eCMAM also shows that the phase-speed interannual variabilities partially reflect the interannual variabilities of the SMEJ. Planetary-wave diagnostics indicate that during the Q2DW’s decay phase, there is still an active transfer of momentum from the SMEJ into Q2DW. The model simulations therefore indicate that the SMEJ plays a substantial role in the decaying temperature Q2DW phase-speed variabilities observed by MLS. This adds to our knowledge of how the SMEJ affects the Q2DW.

Cornelius Csar Jude H Salinas↗

Experimental Heat Transfer Results and Flow Visualization of Vertical Upflow Boiling in Earth Gravity with Subcooled Inlet Conditions – In Preparation for Experiments Onboard the International Space Station

Since 2012, researchers at the Purdue University Boiling and Two-Phase Flow Laboratory (PU-BTPFL) and NASA Glenn Research Center have been collaborating on a long-term effort to study flow boiling and condensation in microgravity. The ultimate goal has been to develop the Flow Boiling and Condensation Experiment (FBCE) for the International Space Station (ISS). Based on the findings from prior flow boiling experiments both at different orientations in Earth gravity and onboard parabolic flights simulating short durations of microgravity, a final refined experiment design, construction, and operating procedure have been arrived at for long-duration microgravity flow boiling experiments onboard the ISS. This study investigates flow boiling of n-Perfluorohexane with subcooled inlet in a rectangular channel of dimensions 114.6 mm heated length, 2.5 mm width, and 5 mm height. These pre-launch experiments (Mission Sequence Testing) were conducted in vertical upflow orientation in Earth gravity using the same experimental rig that was launched to the ISS in August 2021. The various operating parameters varied are heating configuration (single- and double-sided), mass velocity (180 – 3200 kg/m2s), inlet subcooling (+0 – 32°C, encompassing both highly subcooled and near-saturated inlet conditions), and inlet pressure (119 – 191 kPa). High-speed video flow visualization images are presented to explain the two-phase interfacial physics within the channel’s heated section. Heat transfer results in terms of flow boiling curves, streamwise profiles of wall temperature and heat transfer coefficient, and averaged heat transfer coefficients are analyzed and parametric effects elucidated. Severe temporal thermodynamic equilibrium is observed for near-saturated inlet at very low velocities. Nucleate boiling degradation starts at larger heat fluxes for single-sided heating than double sided at low mass velocities with highly subcooled inlet, and conversely at high mass velocities with near-saturated inlet. Nucleate boiling degradation can be delayed to higher heat fluxes by highly subcooling the inlet and increasing mass velocity. The entire local heat transfer coefficient profiles are degraded at higher heat fluxes for near-saturated inlet, but only the downstream part for highly subcooled inlet. This study also confirmed reliability of the upcoming ISS experimental data for subcooled inlet conditions and the collected Earth-gravity data will be used for comparison against the ISS data.

flow boiling↗

Data correlation and analysis of arc tunnel and wind tunnel tests of RSI joints and gaps, phase 2. Volume 1: Technical report

Heat transfer data measured in gaps representative of those being employed for joints in the space shuttle reusable surface insulation (RSI) thermal protection systems (TPS) were assimilated, analyzed, and correlated. Several types of gap were investigated with emphasis on simple butt joints. Gap widths ranged from 0.0 to 0.76 cm and depths ranged from 1 to 6 cm. Laminar, transitional, and turbulent boundary layer flows over the gap opening were investigated. The angle between gap axis and external flow was varied between 0 and pi/2 radians. The contoured cross section gap performed significantly better than all other wide gaps and slightly better than all other narrow gap geometries. Three dimensional heating variations were observed within gaps in the absence of external flow pressure gradients. Interactions between heating within gaps and heating of adjacent top tile surfaces were observed. Gaps aligned with the flow were observed to promote boundary layer transition. Heat transfer correlation equations were obtained for many of the tests. The TPS thickness requirements with and without gaps were computed for a current shuttle entry trajectory. Experimental data employed in the study are summarized. A description of each test facility, run schedule and test conditions, model descriptive information, and heat flux data are included.

Cristensen, H. E.↗

Reduced-gravity two-phase flow experiments in the NASA KC-135

An adequate understanding is sought of flow and heat transfer behavior in reduced and zero gravity conditions. Microgravity thermal-hydraulic analysis capabilities were developed for application to space nuclear power systems. A series of reduced gravity two phase flow experiments using the NASA KC-135 were performed. The objective was to supply basic thermal hydraulic information that could be used in development of analytical tools for design of space power systems. The experiments are described. Two main conclusions were drawn. First, the tests demonstrate that the KC-135 is a suitable test environment for obtaining two phase flow and heat transfer data in reduced gravity conditions. Second, the behavior of two phase flow in low gravity is sufficiently different from that obtained in 1 g to warrant intensive investigation of the phenomenon if adequate analytical tools are to be developed for microgravity conditions.

Cuta, Judith M.↗

Internal heat transfer coefficients of porous metals

The internal heat transfer coefficients of porous metals have been experimentally determined in order to develop correlations between approximately defined Nusselt and Reynolds numbers. Scaled-up models of porous materials, and actual porous metal specimens, were subjected to countercurrent heat and mass transfer boundary conditions. Solid and gas phase temperatures were measured for both the scaled-up models and the actual porous metal specimens. On the basis of these measurements, the average internal heat transfer coefficient was evaluated, and a correlation between the Nusselt and Reynolds numbers was derived.

Kar, K. K.↗