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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 721 records · Page 40
All sourcesNASA NTRSDOE OSTI
DOE OSTI2022

Numerical Evidence for a Haagerup Conformal Field Theory

We numerically study an anyon chain based on the Haagerup fusion category and find evidence that it leads in the long-distance limit to a conformal field theory whose central charge is ~2. Fusion categories generalize the concept of finite group symmetries to noninvertible symmetry operations, and the Haagerup fusion category is the simplest one which comes from neither finite groups nor affine Lie algebras. As such, ours is the first example of conformal field theories which have truly exotic generalized symmetries. Basically the same result was independently obtained in the preceding Letter [Phys. Rev. Lett. 128, 231602 (2022)].

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2023

Detectors in weakly-coupled field theories

We initiate a study of asymptotic detector operators in weakly-coupled field theories. These operators describe measurements that can be performed at future null infinity in a collider experiment. In a conformal theory they can be identified with light-ray operators, and thus have a direct relation to the spectrum of the theory. After a general discussion of the underlying physical picture, we show how infrared divergences of general detector operators can be renormalized in perturbation theory, and how they give rise to detector anomalous dimensions. We discuss in detail how this renormalization can be performed at the intersections of the Regge trajectories where non-trivial mixing occurs, which is related to the poles in anomalous dimensions at special values of spin. Finally, we discuss novel horizontal trajectories in scalar theories and show how they contribute to correlation functions. Our calculations are done in the example of Φ 4 theory in d = 4 - ϵ dimensions, but the methods are applicable more broadly. At the Wilson-Fisher fixed point our results include an explicit expression for the Pomeron light-ray operator at two loops, as well as a prediction for the value of the Regge intercept at five loops.

47 OTHER INSTRUMENTATION↗
DOE OSTI2021

Performance-limiting formation dynamics in mixed-halide perovskites

Wide-bandgap (WBG) mixed-halide perovskites as the front cell absorber are accomplishing perovskite-based tandem solar cells with over 29% power conversion efficiency. However, their large voltage deficits limit their ultimate performance. Only a handful of studies probe the fundamental mechanisms underlying the voltage deficits, which remain an unsolved challenge in the field. In this study, we investigate the formation dynamics and defect physics of WBG mixed-halide perovskites in contrast with their corresponding triiodide-based perovskites. Our results show that the inclusion of bromide introduced a halide homogenization process that occurs during the perovskite growth stage from an initial bromide-rich phase toward the final target stoichiometry. We further elucidated a physical model that correlates the role of bromide with the formation dynamics, defect physics, and eventual optoelectronic properties of the film. This work provides a fundamental and unique perspective toward understanding the performance-limiting factors affecting WBG mixed-halide perovskites.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2020

Anomalies in the space of coupling constants and their dynamical applications I

It is customary to couple a quantum system to external classical fields. One application is to couple the global symmetries of the system (including the Poincaré symmetry) to background gauge fields (and a metric for the Poincaré symmetry). Failure of gauge invariance of the partition function under gauge transformations of these fields reflects ’t Hooft anomalies. It is also common to view the ordinary (scalar) coupling constants as background fields, i.e. to study the theory when they are spacetime dependent. We will show that the notion of ’t Hooft anomalies can be extended naturally to include these scalar background fields. Just as ordinary ’t Hooft anomalies allow us to deduce dynamical consequences about the phases of the theory and its defects, the same is true for these generalized ’t Hooft anomalies. Specifically, since the coupling constants vary, we can learn that certain phase transitions must be present. We will demonstrate these anomalies and their applications in simple pedagogical examples in one dimension (quantum mechanics) and in some two, three, and four-dimensional quantum field theories. An anomaly is an example of an invertible field theory, which can be described as an object in (generalized) differential cohomology. We give an introduction to this perspective. Also, we use Quillen’s superconnections to derive the anomaly for a free spinor field with variable mass. In a companion paper we will study four-dimensional gauge theories showing how our view unifies and extends many recently obtained results.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2020

Comparison of Numerical Methods for Modeling the Wave Field Effects Generated by Individual Wave Energy Converters and Multiple Converter Wave Farms

This numerical study compares the wave field generated by the spectral wave action balance code, SNL-SWAN, to the linear-wave boundary-element method (BEM) code, WAMIT. The objective of this study is to assess the performance of SNL-SWAN for modeling wave field effects produced by individual wave energy converters (WECs) and wave farms comprising multiple WECs by comparing results from SNL-SWAN with those produced by the BEM code WAMIT. BEM codes better model the physics of wave-body interactions and thus simulate a more accurate near-field wave field than spectral codes. In SNL-SWAN, the wave field’s energy extraction is modeled parametrically based on the WEC’s power curve. The comparison between SNL-SWAN and WAMIT is made over a range of incident wave conditions, including short-, medium-, and long-wavelength waves with various amounts of directional spreading, and for three WEC archetypes: a point absorber (PA), a pitching flap (PF) terminator, and a hinged raft (HR) attenuator. Individual WECs and wave farms of five WECs in various configuration were studied with qualitative comparisons made of wave height and spectra at specific locations, and quantitative comparisons of the wave fields over circular arcs around the WECs as a function of radial distance. Results from this numerical study demonstrate that in the near-field, the difference between SNL-SWAN and WAMIT is relatively large (between 20% and 50%), but in the far-field from the array the differences are minimal (between 1% and 5%). The resultant wave field generated by the two different numerical approaches is highly dependent on parameters such as: directional wave spreading, wave reflection or scattering, and the WEC’s power curve.

16 TIDAL AND WAVE POWER↗
DOE OSTI2023

Offshore Geologic Carbon Storage (GCS) Inventory

The Offshore Geological Carbon Storage Inventory Web Map is an online web mapping application designed to help users explore and visualize the Offshore Geologic Carbon Storage Inventory. This dataset is an inventory of offshore geologic carbon storage (GCS) projects and studies, gathered to summarize ongoing GCS efforts taking place offshore globally. This inventory includes both actualized projects as well as characterization studies and aggregates a variety of attribute fields for each project / study. It is intended to be used for research and comparison purposes, see full disclaimer and credits.

Assessment↗
DOE OSTI2022

Limitations of Bin and Bulk Microphysics in Reproducing the Observed Spatial Structure of Light Precipitation

Abstract Coarse-gridded atmospheric models often account for subgrid-scale variability by specifying probability distribution functions (PDFs) of process rate inputs such as cloud and rainwater mixing ratios ( q c and q r , respectively). PDF parameters can be obtained from numerous sources: in situ observations, ground- or space-based remote sensing, or fine-scale modeling such as large-eddy simulation (LES). LES is appealing to constrain PDFs because it generates large sample sizes, can simulate a variety of cloud regimes/case studies, and is not subject to the ambiguities of observations. However, despite the appeal of using model output for parameterization development, it has not been demonstrated that LES satisfactorily reproduces the observed spatial structure of microphysical fields. In this study, the structure of observed and modeled microphysical fields are compared by applying bifractal analysis, an approach that quantifies variability across spatial scales, to simulations of a drizzling stratocumulus field that span a range of domain sizes, drop concentrations (a proxy for mesoscale organization), and microphysics schemes (bulk and bin). Simulated q c closely matches observed estimates of bifractal parameters that measure smoothness and intermittency. There are major discrepancies between observed and simulated q r properties, though, with bulk simulated q r consistently displaying the bifractal properties of observed clouds (smooth, minimally intermittent) rather than rain while bin simulations produce q r that is appropriately intermittent but too smooth. These results suggest fundamental limitations of bulk and bin schemes to realistically represent higher-order statistics of the observed rain structure.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2020

Multiple Tunable Hyperbolic Resonances in Broadband Infrared Carbon-Nanotube Metamaterials

Aligned densely packed carbon-nanotube metamaterials prepared using vacuum filtration are an emerging infrared nanophotonic material. We report multiple hyperbolic plasmon resonances, together spanning the mid-infrared, in individual resonators made from aligned and densely packed carbon nanotubes. In a near-field scanning optical microscopy (NSOM) imaging study of nanotube metamaterial resonators, we observe distinct deeply subwavelength field profiles at the fundamental and higher-order resonant frequencies. The wafer-scale area of the nanotube metamaterials allows us to combine this near-field imaging with a systematic far-field spectroscopic study of the scaling properties of many resonator arrays. Thorough theoretical modeling agrees with these measurements and identifies the resonances as higher-order Fabry-Perot (FP) resonances of hyperbolic waveguide modes. Nanotube resonator arrays show broadband extinction from 1.5–10 µm and reversibly switchable extinction in the 3–5 µm atmospheric transparency window through the coexistence of multiple modes in individual ribbons. Broadband carbon-nanotube metamaterials supporting multiple resonant modes are a promising candidate for ultracompact absorbers, tunable thermal emitters, and broadband sensors in the mid-infrared.

36 MATERIALS SCIENCE↗
DOE OSTI2024

Wind and structural loads data measured on parabolic trough solar collectors at an operational power plant

Abstract Wind loading is a primary contributor to structural design costs of concentrating solar-thermal power collectors, such as heliostats and parabolic troughs. These structures must resist the mechanical forces generated by turbulent wind, while the reflector surfaces must maintain optimal optical performance. Studying wind-driven loads at a full-scale, operational concentrating solar-thermal power plant provides insights into the wind impact on the solar collector field beyond the capabilities of wind tunnel tests or state-of-the-art simulations. We conducted comprehensive field measurements of the atmospheric turbulent wind conditions and the resulting structural wind loads on parabolic troughs at the Nevada Solar One plant over a two-year period. The measurement setup included meteorological masts and structural load sensors on four trough rows. Additionally, a lidar scanned the horizontal plane above the trough field. In this study, we describe the high-resolution dataset characterizing the complex flow field and resulting structural loads. This first-of-its-kind dataset will enhance the understanding of wind loading on collector structures and will help in designing the next-generation solar collectors and photovoltaic trackers.

14 SOLAR ENERGY↗
DOE OSTI2024

Strain phase equilibria and phase‐field method of ferroelectric polydomain: A case study of monoclinic K x Na 1 − x NbO 3 thin films

Abstract Knowledge of the thermodynamic equilibria and domain structures of ferroelectrics is critical to establishing their structure–property relationships that underpin their applications from piezoelectric devices to nonlinear optics. Here, we establish the strain condition for strain phase separation and polydomain formation and analytically predict the corresponding domain volume fractions and wall orientations of, relatively low symmetry and theoretically more challenging, monoclinic ferroelectric thin films by integrating thermodynamics of ferroelectrics, strain phase equilibria theory, microelasticity, and phase‐field method. Using monoclinic K x Na 1 − x NbO 3 (0.5 < x < 1.0) thin films as a model system, we establish the polydomain strain–strain phase diagrams, from which we identify two types of monoclinic polydomain structures. The analytically predicted strain conditions of formation, domain volume fractions, and domain wall orientations for the two polydomain structures are consistent with phase‐field simulations and in good agreement with experimental results in the literature. The present study demonstrates a general, powerful analytical theoretical framework to predict the strain phase equilibria and domain wall orientations of polydomain structures applicable to both high‐ and low‐symmetry ferroelectrics and provide fundamental insights into the equilibrium domain structures of ferroelectric K x Na 1 − x NbO 3 thin films that are of technology relevance for lead‐free dielectric and piezoelectric applications.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Sign reversal in magnetic field amplification by relativistic laser-driven microtube implosions

In this work, we demonstrate and explain the surprising phenomenon of sign reversal in magnetic field amplification by the laser-driven implosion of a structured target. Relativistically intense laser pulses incident on the outer surface of a microtube target consisting of a thin opaque shell surrounding a μm-scale cylindrical void drive an initial ion implosion and later explosion capable of generating and subsequently amplifying strong magnetic fields. While the magnetic field generation is enhanced and spatially smoothed by the application of a kilotesla-level seed field, the sign of the generated field does not always follow the sign of the seed field. One unexpected consequence of the amplification process is a reversal in the sign of the amplified magnetic field when, for example, the target outer cross section is changed from square to circular. Using 2D particle-in-cell simulations, we demonstrate that sign reversal is linked to the stability of the surface magnetic field of opposite sign from the seed, which arises at the target inner surface during laser irradiation. The stability of the surface magnetic field and, consequently, the sign of the final amplified field depend sensitively on the target, laser, and seed magnetic field conditions, which could be leveraged to make laser-driven microtube implosions an attractive platform for the study of magnetic fields in high energy density plasma in regimes where sign reversal either is or is not desired.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2021

Exotic $\mathbb{Z}_N$ symmetries, duality, and fractons in 3+1-dimensional quantum field theory

Following our earlier analyses of nonstandard continuum quantum field theories, we study here gapped systems in 3+1 dimensions, which exhibit fractonic behavior. In particular, we present three dual field theory descriptions of the low-energy physics of the X-cube model. A key aspect of our constructions is the use of discontinuous fields in the continuum field theory. Spacetime is continuous, but the fields are not.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2020

Direct visualization of electromagnetic wave dynamics by laser-free ultrafast electron microscopy

Integrating femtosecond lasers with electron microscopies has enabled direct imaging of transient structures and morphologies of materials in real time and space. Here, we report the development of a laser-free ultrafast electron microscopy (UEM) offering the same capability but without requiring femtosecond lasers and intricate instrumental modifications. We create picosecond electron pulses for probing dynamic events by chopping a continuous beam with a radio frequency (RF)–driven pulser with the pulse repetition rate tunable from 100 MHz to 12 GHz. As a first application, we studied gigahertz electromagnetic wave propagation dynamics in an interdigitated comb structure. We reveal, on nanometer space and picosecond time scales, the transient oscillating electromagnetic field around the tines of the combs with time-resolved polarization, amplitude, and local field enhancement. This study demonstrates the feasibility of laser-free UEM in real-space visualization of dynamics for many research fields, especially the electrodynamics in devices associated with information processing technology.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2020

Acetonitrile Transition Metal Interfaces from First Principles

Acetonitrile is among the most commonly used nonaqueous solvents in catalysis and electrochemistry. Here, we study its interfaces with multiple facets of the metals Ag, Cu, Pt, and Rh using density functional theory calculations; the structures reported shed new light on experimental observations and underscore the importance of solvent–solvent interactions at high coverage. We investigate the relationship of potential of zero charge (PZC) to metal work function, reporting results in agreement with experimental measurements. We develop a model to explain the effects of solvent chemisorption and orientation on the PZC to within a mean absolute deviation of 0.08–0.12 V for all facets studied. Our electrostatic field dependent phase diagram agrees with spectroscopic observations and sheds new light on electrostatic field effects. This work provides new insight into experimental observations on acetonitrile metal interfaces and provides guidance for future studies of acetonitrile and other nonaqueous solvent interfaces with transition metals.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2021

Modeling Study of Reduced Tubing Size Effects on Flow in Depleted Reservoir Natural Gas Storage Wells

This report explores the effects of tubing size reductions on natural gas flow from representative depleted reservoir underground storage wells and fields using basic models for coupled reservoir and pipe flow. This work was motivated by interest at the U.S. Department of Transportation, Pipeline and Hazardous Materials Safety Administration, in evaluating the effects of tubing and packer as a potential safety upgrade to implement double-barrier systems to existing underground natural gas storage wells. Reservoir and well flow models were developed from widely accepted industry equations, verified against a commercial process simulator model, and validated against field data. The study utilized U.S. operator survey data to provide context and assure that modeling parameters including aver age deliverability rates for wells and fields, operating pressures, well depths, and storage capacities were all carefully considered to keep the modeling relevant to the known range of U.S. operations. The models generally found that wells and fields with inherently low deliverability were relatively insensitive to reductions in tubing diameter, primarily because the hydraulics in those cases were controlled by reservoir properties. For the high-producing wells and fields, the models found that reducing tubing diameter could produce significant reductions in deliverability, both at the field- and well-level. When put into context with occurrence data regarding average deliverability of fields and wells, it appears that most wells and most fields across the U.S. would experience deliverability reductions on the low end of what was simulated here, generally below 20%. For fields with moderate to high deliverability, reductions were generally larger, and could reach as high as 60% for the highest-producing wells and fields.

03 NATURAL GAS↗
DOE OSTI2023

Final Report DE-FE0031785 Mohsen Ahmadian, Ph.D. Demonstration of Proof of Concept of a Multiphysics Approach for Real-Time Remote Monitoring of Dynamic Changes in Pressure and Salinity in Hydraulically Fractured Networks

Hydraulic fracturing has evolved into a multistep process with varying flow rates, carrier fluids (e.g., gel or slickwater), proppant loadings, and proppant grain sizes. As a result, primary recovery from a hydraulically fractured tight-oil reservoir is often a tiny fraction of the original oil in place, ranging between 5 and 10%. As stated in the FOA1990, “part of this problem is due to the inability of current well completion processes to effectively stimulate the entire reservoir volume in contact with the wellbore. Innovative technologies are needed that can help improve the effectiveness of reservoir completion methods, maximize stimulated reservoir volumes, and optimize recovery over the entire producing life span of a well”. We first need to enhance the current fracture diagnostic techniques to improve a well-completion design. However, detecting and delineating a subsurface hydraulic fracture is extremely difficult because the induced fracture network is only fractionally propped, and these propped fractures are generally very thin. Microseismic and tiltmeter monitoring techniques can provide information on the fracture extent but provide little or no information on the movement and final distribution of proppant or production fluids. On the other hand, electromagnetic (EM) imaging has shown the capability to monitor proppant distribution throughout the fracture area, especially in the presence of Electrically Active Proppants (EAPs). A previous EM survey of hydraulic fracturing at the Devine Fracture Pilot Site (DFPS) and subsequent EM code developments demonstrated this survey as a robust technique to remotely interrogate the extent of the EAP-filled hydraulic fracture during its propagation. The objectives of the project were threefold: (1) to capitalize on the material properties of an EAP to demonstrate remote monitoring of relative changes in pressure, pressure, and flow that are commonly encountered during production from a hydraulically fractured reservoir; (2) to evaluate EM imaging tools, to achieve Objective 1 in near real-time; and (3) to develop a multi-physics joint inversion approach to precisely predict flow patterns and physiochemical changes within an EAP-filled fracture network. This research project was built upon our previous work at the Devine Test Site managed by the Bureau of Economic Geology (BEG) at The University of Texas at Austin (UT-Austin). It also leveraged a significant investment from the Advanced Energy Consortium (AEC) to address the DOE's interest in subsurface flow, containment, and characterization by multiple signals. This three-year and three-month project succeeded in demonstrating the feasibility of a real-time dynamic fluid flow mapping technique at Technology Readiness Level 5 (TRL5) by utilizing a commercially available surface-based Controlled-Source Electromagnetic (CSEM) method (Objectives 1, 2). We demonstrated that injections into an EAP-filled fracture could be successfully coupled with real-time electric field measurements on the surface, leading to remote monitoring of dynamic changes within the EAP-filled fracture. Furthermore, the observed electric field in our study is influenced by bottomhole pressure, flow rate, and salinity, which is demonstrated by comparing these parameters with the electrical field potentials. EM simulations solely based on assumptions of fracture conductivity changes during injection did not reproduce the whole measured electric field magnitudes. Preliminary estimates showed that including Streaming Potential (SP) in our geophysical model is likely needed to reduce the simulation misfit.

02 PETROLEUM↗
DOE OSTI2020

In-Field Performance of Biomass Balers

Herbaceous biomass will contribute significantly to meeting renewable energy goals. Harvesting equipment for hay is generally suitable for mowing, raking, and baling grasses such as switchgrass; however, there is a need for field data to better understand machine performance in energy crops. The purpose of this study was to collect field data to estimate baler field capacity, throughput, and speed. Data gathered with a Differential Global Positioning System (DGPS) unit during baling provided time-motion studies of baler productivity. Six fields were used to compare field capacity, speed, and throughput results from four round balers and one large-square baler. The results show that in-field performance of round balers is significantly affected by yield, but that the relationship can be represented with machinery management concepts, knowledge of maximum throughput, and wrap-eject time. Baler performance will be overestimated if the yield, maximum throughput, and wrap-eject time are not correctly accounted for.

Grisso, Robert “Bobby” (ORCID:0000000267893558)↗