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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 721 records · Page 40

Interfacing DNA nanotechnology and biomimetic photonic complexes: advances and prospects in energy and biomedicine

Abstract Self-assembled photonic systems with well-organized spatial arrangement and engineered optical properties can be used as efficient energy materials and as effective biomedical agents. The lessons learned from natural light-harvesting antennas have inspired the design and synthesis of a series of biomimetic photonic complexes, including those containing strongly coupled dye aggregates with dense molecular packing and unique spectroscopic features. These photoactive components provide excellent features that could be coupled to multiple applications including light-harvesting, energy transfer, biosensing, bioimaging, and cancer therapy. Meanwhile, nanoscale DNA assemblies have been employed as programmable and addressable templates to guide the formation of DNA-directed multi-pigment complexes, which can be used to enhance the complexity and precision of artificial photonic systems and show the potential for energy and biomedical applications. This review focuses on the interface of DNA nanotechnology and biomimetic photonic systems. We summarized the recent progress in the design, synthesis, and applications of bioinspired photonic systems, highlighted the advantages of the utilization of DNA nanostructures, and discussed the challenges and opportunities they provide. Graphical Abstract

59 BASIC BIOLOGICAL SCIENCES↗

Membrane-based Ionic Liquid Absorption System for Ultra-Efficient Dehumidification and Heating

The project team – comprising the University of Florida (UF), GTI Energy, and Modine Manufacturing – sought to develop a highly efficient heat-powered absorption cycle with combined dehumidification and heat pumping. This DOE-supported project advanced the technology from a TRL of 3 to 6, culminating in the development of a 1,000 CFM system. Key innovations implemented in the system addressed the low efficiency, size, cost, and reliability challenges of conventional absorption cycles. Specifically, the system was enabled by: (1) a semi-open cycle that allowed simultaneous dehumidification and heat recovery, (2) non-crystallizing ionic liquids (ILs) that enabled “double-effect” operation at elevated temperatures without the need for costly control equipment, (3) a compact membrane-based absorber that confined the IL and directly cooled it to achieve low dew points, and (4) a novel, highly integrated desorber–condenser assembly that reduced size, weight, and cost. The technology was developed with commercial HVAC applications in mind, particularly for separate sensible and latent cooling (SSLC), an innovation aimed at achieving independent and more efficient humidity control.

42 ENGINEERING↗

Guide for extrusion dies eliminates straightening operation

To prevent distortion of extruded metal, a guidance assembly is aligned with the die. As the metal emerges from the extrusion dies, it passes directly into the receiver and straightening tube system, and the completed extrusion is withdrawn.

Gyorgak, C. A.↗

Track-train dynamics

The purpose of this paper is to outline one of the serious dynamic problems involving railroad cars and to propose an orderly approach to the definition of a dynamic model through analysis and testing that can be used to investigate various fixes. The problem in question is the hunting phenomenon involving lateral instability of the car suspension (trucks). This phenomenon has been recognized as a major contributing factor in a significant number of derailments causing millions of dollars in losses. This paper expounds on the mechanics and characteristics of hunting. The planned solution is outlined as a building block approach directed at formulating a test verified dynamic model of an open hopper freight car-truck assembly. Results obtained to date are presented together with conclusions related to the program.

Abbott, P. W.↗

A CCD scanned (Hg, Cd)Te array for earth viewing applications

A 9 channel demonstration of 10 micrometer photoconductive mercury cadmium telluride detector array, bipolar preamplifiers, and a Si CCD multiplexer, integrated into a focal plane assembly and operating at 105 K and at 17 Hz is reported. The result of a direct coupling experiment between a 5-micrometer photovoltaic mercury cadmium telluride photodiode and a CCD is revealed. No appreciable degradation in the signal-to-noise ratio was experienced.

Iwasa, S.↗

Method of producing silicon

A liquid reactant injector assembly suited for the injection of liquid reactant into a high temperature metal reductant vapor and carrier gas stream for the production of metal is presented. The assembly is especially adapted for the continuous production of high purity silicon by the reduction of SiCl4 with sodium. The assembly includes a refractory-lined, hollow metal shell having ten equally-spaced, concentric, radially directed ports provided in the shell and wall. A hydraulic, atomizing type spray nozzle is mounted in each of the ports recessed from the inner wall surface.

Wolf, C. B.↗

Mars exploration in the 1990's

Science objectives for a Mars exploration program in the 1990s, set forth by NASA's Committee on Planetary Exploration, are presented. They include: an intensive study of the Martian surface, the exploration of the structure and general circulation of the atmosphere, the exploration of the nature and dynamics of the planet's interior, the nature of Mars's magnetic field, the character of the upper atmosphere and its interaction with the solar wind, and the establishment of the global chemical and physical characteristics of the Martian surface. Several low cost missions, which have been suggested by the Committee for NASA's CORE program, such as the Mars Geoscience Climatology Observer, the Mars Aeronomy Orbiter, and the Mars Surface Network and Surface Probing missions are also covered. Direct Entry-Direct Return and Out-of-Orbit Entry-Orbital Rendezvous and Docking are two versions of a Mars Rover and Sample Return (MRSR) mission discussed in detail. It is concluded that a MRSR mission will require the combination of full Centaur capability, aerocapture at Mars and earth, and direct return to earth to meet major scientific goals. Further studies should be made in orbit assembly, fuel transfer technology, aeromaneuvering, terminal guidance, rover technology, and robotics.

Albee, A. L.↗

Passive Orbital Disconnect Strut (PODS 3) structural test program

A passive orbital disconnect strut (PODS-3) was analyzed structurally and thermally. Development tests on a graphite/epoxy orbit tube and S glass epoxy launch tube provided the needed data to finalize the design. A detailed assembly procedure was prepared. One strut was fabricated. Shorting loads in both the axial and lateral direction (vs. load angle and location) were measured. The strut was taken to design limit loads at both ambient and 78 K (cold end only). One million fatigue cycles were performed at predicted STS loads (half in tension, half in compression) with the cold end at 78 K. The fatigue test was repeated at design limit loads. Six struts were then fabricated and tested as a system. Axial loads, side loads, and simulated asymmetric loads due to temperature gradients around the vacuum shell were applied. Shorting loads were measured for all tests.

Parmley, R. T.↗

Emitted vibration measurement device and method

This invention is directed to a method and apparatus for measuring emitted vibrational forces produced by a reaction wheel assembly due to imbalances, misalignment, bearing defects and the like. The apparatus includes a low mass carriage supported on a large mass base. The carriage is in the form of an octagonal frame having an opening which is adapted for receiving the reaction wheel assembly supported thereon by means of a mounting ring. The carriage is supported on the base by means of air bearings which support the carriage in a generally frictionless manner when supplied with compressed air from a source. A plurality of carriage brackets and a plurality of base blocks provided for physical coupling of the base and carriage. The sensing axes of the load cells are arranged generally parallel to the base and connected between the base and carriage such that all of the vibrational forces emitted by the reaction wheel assembly are effectively transmitted through the sensing axes of the load cells. In this manner, a highly reliable and accurate measurment of the vibrational forces of the reaction wheel assembly can be had. The output signals from the load cells are subjected to a dynamical analyzer which analyzes and identifies the rotor and spin bearing components which are causing the vibrational forces.

Gisler, G. L.↗

Uprated fine guidance sensor study

Future orbital observatories will require star trackers of extremely high precision. These sensors must maintain high pointing accuracy and pointing stability simultaneously with a low light level signal from a guide star. To establish the fine guidance sensing requirements and to evaluate candidate fine guidance sensing concepts, the Space Telescope Optical Telescope Assembly was used as the reference optical system. The requirements review was separated into three areas: Optical Telescope Assembly (OTA), Fine Guidance Sensing and astrometry. The results show that the detectors should be installed directly onto the focal surface presented by the optics. This would maximize throughput and minimize point stability error by not incoporating any additional optical elements.

Source record↗

Lunar campsite concept: Space transfer concepts and analysis for exploration missions

The lunar Campsite concept responds to a perceived need to identify early manned science and exploration missions that require minimal initial funding. The Campsite concept defers the build-up of many infrastructure components without escalating total program costs. The lunar Campsite has been sized nominally for four crew for 42 days (1 lunar night and 2 lunar days), but can be modified to span two lunar nights up to 60 days. Total mission fulfillment requires five Earth-to-LEO launches, four (100 mt class launch vehicle) for the two vehicle assemblies and one (PLS or NSTS) for the crew. The lunar Campsite mission mode is tandem direct using a booster stage and a lander stage. The booster is separated from the lander after the TLI burn and is expended into the Earth's atmosphere. In the Campsite mode, the lander lands on the surface not to be returned. In the crew delivery mode, the lander is guided to a precision landing about 500 m from the Campsite, and with enough propellant to return the crew to Earth. The Campsite consists of a habitat and airlock, body mounted radiators with a surface shield, sun tracking solar arrays, and an Earth-tracking high-gain antenna. The CV is very similar to the campsite delivery vehicle. The CV does not, however, have radiators or solar arrays. The vehicle stacks are essentially common in that they utilize the same structure system and engines, the same propellant tanks, the same 'cut-out' in which the CRV and payloads are incorporated, and the same RCS locations. The booster and lander stage propellant tank propellant capacities are identical and have margins which would allow additional fueling for propulsive capture of the boost stage into Earth orbit. This contractual study was performed to identify Campsite and vehicle interfaces and vehicle requirements, and to surface issues related to the integration of the Campsite and LTV's.

Source record↗

In-Flight Position Calibration of the Cassini Articulated Reaction Wheel Assembly

NASA's long-lived Cassini-Huygens spacecraft is currently in its 14th year of flight and in the midst of its second, and final, extended mission. Cassini is a massive interplanetary spacecraft that is three axis stabilized and can maintain attitude control using either its reaction control system thrusters or using reaction wheel control. Cassini has four identical reaction wheels, of which three are mutually orthogonal and have a fixed orientation. The fourth reaction wheel has an articulation motor that allows this reaction wheel to be aligned with the momentum direction of any of the other three fixed reaction wheels. The articulation motor allows this reaction wheel to be used as a replacement for any of the other three wheels without any performance degradation. However, due to limitations in the design of this backup system, there are few telemetric indications of the orientation of this reaction wheel following an articulation. This investigation serves to outline the procedures that have been developed by the Cassini Attitude and Articulation Control Subsystem to calibrate the position of the articulated reaction wheel assembly in the event that the momentum direction of this reaction wheel must be reoriented.

Brown, Todd S.↗

Structural basis of Gabija anti-phage defence and viral immune evasion

Bacteria encode hundreds of diverse defence systems that protect them from viral infection and inhibit phage propagation. Gabija is one of the most prevalent anti-phage defence systems, occurring in more than 15% of all sequenced bacterial and archaeal genomes, but the molecular basis of how Gabija defends cells from viral infection remains poorly understood. Here we use X-ray crystallography and cryo-electron microscopy (cryo-EM) to define how Gabija proteins assemble into a supramolecular complex of around 500 kDa that degrades phage DNA. Gabija protein A (GajA) is a DNA endonuclease that tetramerizes to form the core of the anti-phage defence complex. Two sets of Gabija protein B (GajB) dimers dock at opposite sides of the complex and create a 4:4 GajA–GajB assembly (hereafter, GajAB) that is essential for phage resistance in vivo. We show that a phage-encoded protein, Gabija anti-defence 1 (Gad1), directly binds to the Gabija GajAB complex and inactivates defence. A cryo-EM structure of the virally inhibited state shows that Gad1 forms an octameric web that encases the GajAB complex and inhibits DNA recognition and cleavage. Our results reveal the structural basis of assembly of the Gabija anti-phage defence complex and define a unique mechanism of viral immune evasion.

59 BASIC BIOLOGICAL SCIENCES↗

Electron transport across the cell envelope via multiheme c -type cytochromes in Geobacter sulfurreducens

Extracellular electron transfer (EET) enables certain microorganisms to respire using soluble and insoluble extracellular electron acceptors by transporting electrons across the cell envelope. Among these, G. sulfurreducens serves as a model organism for understanding direct EET pathways, where multiheme c-type cytochromes mediate electron transport from intracellular redox carriers to extracellular acceptors such as Fe(III) oxides and electrodes. This review focuses on heme-dependent electron transfer in Geobacter sulfurreducens, detailing the roles of inner membrane cytochromes, periplasmic carriers, outer membrane conduits, and recently characterized extracellular nanowires formed by polymerized multiheme c-type cytochromes, including OmcS, OmcE, and OmcZ. We examine the state of understanding of their physiological function, their structural features, expression patterns, and essentiality under various respiratory conditions. These insights advance our understanding of microbial anaerobic respiration and have implications for biogeochemical cycling, bioenergy generation, and bioremediation. The molecular architecture, assembly mechanisms, and secretion pathways of multiheme c-type cytochrome nanowires remain active areas of investigation, offering promising directions for future research and biotechnological innovation in engineered microbial systems.

Chemistry↗

NOPCHAP1 is a PAQosome cofactor that helps loading NOP58 on RUVBL1/2 during box C/D snoRNP biogenesis

Abstract The PAQosome is a large complex composed of the HSP90/R2TP chaperone and a prefoldin-like module. It promotes the biogenesis of cellular machineries but it is unclear how it discriminates closely related client proteins. Among the main PAQosome clients are C/D snoRNPs and in particular their core protein NOP58. Using NOP58 mutants and proteomic experiments, we identify different assembly intermediates and show that C12ORF45, which we rename NOPCHAP1, acts as a bridge between NOP58 and PAQosome. NOPCHAP1 makes direct physical interactions with the CC-NOP domain of NOP58 and domain II of RUVBL1/2 AAA+ ATPases. Interestingly, NOPCHAP1 interaction with RUVBL1/2 is disrupted upon ATP binding. Moreover, while it robustly binds both yeast and human NOP58, it makes little interactions with NOP56 and PRPF31, two other closely related CC-NOP proteins. Expression of NOP58, but not NOP56 or PRPF31, is decreased in NOPCHAP1 KO cells. We propose that NOPCHAP1 is a client-loading PAQosome cofactor that selects NOP58 to promote box C/D snoRNP assembly.

Abel, Yoann↗

Characterization of a Sulfonated Poly(Ionic Liquid) Block Copolymer as an Ionomer for Proton Exchange Membrane Fuel Cells using Rotating Disk Electrode

Ionic liquid (IL) additives to both traditional and advanced oxygen reduction reaction (ORR) electrocatalysts have yielded remarkable improvements in catalyst performance and durability. However, incorporating ILs or IL-modified catalysts into the electrodes of a proton exchange membrane fuel cell (PEMFC) membrane electrode assembly (MEA) has proven to be challenging. Sulfonated poly(ionic liquid) block copolymers (S-PILBCP) present an opportunity to incorporate IL functionality directly into the ionomer, orthogonal to protonic conductivity. Here, we use a rotating disc electrode (RDE) to characterize the interface between a S-PILBCP and Pt catalyst in comparison to Nafion. Catalyst thin films prepared with S-PILBCP show an 80% improvement in the ORR activity over those containing Nafion. Thin films of S-PILBCP also show a significantly reduced degree of poisoning sulfonate adsorption on a Pt(111) surface in comparison to Nafion. Furthermore, these half-cell results provide useful insights that help to highlight the source of the impact of the S-PILBCP on PEMFC MEA performance.

25 ENERGY STORAGE↗