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At least 721 records · Page 40

Catalyst Layer Design, Manufacturing and In-line Quality Control

In this project we successfully demonstrated the capabilities of the Reactive Spray Deposition Technology (RSDT) to fabricate large-scale CCMs for advanced PEMWEs that have one-order of magnitude lower PGM loading in their catalyst layers, and performance comparable with the commercial state-of-the-art CCMs. The RSDT is a unique methodology that combines the catalyst synthesis and CCM fabrication in one step and reduces dramatically the time for CCM manufacturing. As fabricated large-scale CCMs with geometric area of 680 cm2 demonstrated excellent activity and durability performance, and the novel duo-recombination layer design paves the way for solving the safety concerns related to PEMWEs. In addition, excellent activity and durability performance has been demonstrated with RSDT fabricated CCMs with thinner membranes and duo RL design. This is a novel approach for further performance improvement of the MEAs for PEMWEs that has been successfully demonstrated for the first time in this project. The integration of the in-situ laser diagnostics system along with the in-line optical quality control system within the RSDT that has been achieved and demonstrated in this project, is an example for possibility of designing and building advanced manufacturing technologies that can meet the requirements of the future manufacturing. Therefore, the RSDT offers a precise real-time monitoring and control of the particles size, composition, loading, porosity, thickness, and defects in the catalysts’ layers, which render this technology as the best candidate for manufacturing of cost effective CCMs for PEMWEs. By using RSDT we successfully met all project’s milestones, Go/No-Go decision, objectives, goals, and deliverables.

08 HYDROGEN↗

Active Control of Transition Using the Lorentz Force

A new concept and technique has been developed to directly control boundary-layer transition and turbulence. Near-wall vertical motions are directly suppressed through the application of Lorentz force. Current (j) and magnetic (b) fields are applied parallel to the boundary and normal to each other to produce a Lorentz force (j x B) normal to the boundary. This approach is called magnetic turbulence control (MTC). Experiments have been performed on flat-plate transitional and turbulent boundary layers in water seeded with a weak electrolyte.

Nosenchuck, Daniel↗

Control of the vortical structure in the early stages of transition in boundary layers

The effect of suction and pressure gradient on controlling the production of the three-dimensional vortical structure due to secondary instability is investigated for a boundary layer in the presence of small but finite amplitude Tollmien-Schlichting wave. The subharmonic instability is the focus of the study due to its realistic application in low disturbance flight environment. The spanwise wavelength of the most unstable secondary subharmonic disturbance increases with the increase of control indicating possible alteration of the flow structure from H-type to C-type.

El-Hady, Nabil M.↗

Active Control of Transition and Turbulence

Two active means of manipulating boundary-layer flow developed, one controlling laminar-to-turbulent transition, other controlling amplitude of turbulent fluctuation. Purpose to control skin-friction drag over surfaces inside inlets and ducts. Resulting turbulence downstream has lower skin-friction drag than equivalent flow developing over same surfaces in absence of intervention. Heating strips trigger turbulence while transition amplitude and bandwidth controlled by acoustic signal.

Maestrello, Lucio↗

Accelerating Large-Format Metal Additive Manufacturing: How Controls R&D is Driving Speed, Scale, and Efficiency

This article highlights work at Oak Ridge National Laboratory’s Manufacturing Demonstration Facility to develop closed-loop, feedback control for laser-wire based Directed Energy Deposition, a form of metal Big Area Additive Manufacturing (m-BAAM), a process being developed in partnership with GKN Aerospace specifically for the production of Ti-6Al-4V pre-forms for aerospace components. A large-scale structural demonstrator component is presented as a case-study in which not just control, but the entire 3D printing workflow for m-BAAM is discussed in detail, including design principles for large-format metal AM, toolpath generation, parameter development, process control, and system operation, as well as post-print net-shape geometric analysis and finish machining. In terms of control, a multi-sensor approach has been utilized to measure both layer height and melt pool size, and multiple modes of closed-loop control have been developed to manipulate process parameters (laser power, print speed, deposition rate) to control these variables. Layer height control and melt pool size control have yielded excellent local (intralayer) and global (component-level) geometry control, and the impact of melt pool size control in particular on thermal gradients and material properties is the subject of continuing research. Further, these modes of control have allowed the process to advance to higher deposition rates (exceeding 7.5 lb/hr), larger parts (1-meter scale), shorter build times, and higher overall efficiency. The control modes are examined individually, highlighting their development, demonstration, and lessons learned, and it is shown how they operate concurrently to enable the printing of a large-scale, near net shape Ti-6Al-4V component.

Gibson, Brian↗

Environmental Controls on Water Vapor Deuterium Excess in the Coastal Boundary Layer: An Information Theory Perspective

We use information theory to quantify the environmental controls on water vapor deuterium excess (D-excess) in coastal Southern California from June 2023 through February 2024. Using Shannon entropy, mutual information (MI), and joint mutual information, metrics that capture both linear and nonlinear relationships, we identify the most informative variables and variable combinations governing D-excess across contrasting marine and continental regimes. Relative humidity with respect to sea surface temperature (RHS) is consistently the strongest individual predictor, explaining up to 27% of D-excess variability during marine conditions but only 10% in continental air masses. The Relative humidity(RHS) + sea surface temperature (SST) combination demonstrates synergistic effects, where their joint influence (explaining up to 36% of D-excess variability) exceeds what either variable achieves individually, confirming their coupled influence on deuterium excess. Wind direction complements RHS most effectively during continental conditions. The best three-variable combination (RHS + SST + Planetary Boundary Layer height) explains 38% of D-excess variability in marine air, while no combination exceeds 20% explanatory power during continental periods. Information theory shows that heteroscedasticity in D-excess relationships indicates regime shifts in controlling processes and quantifies fundamental constraints on predictor variables: some environmental factors like surface pressure or water vapor flux contain insufficient information content to explain D-excess variability regardless of their physical relevance. These results highlight the different predictability limits between marine and continental regimes, challenging the adequacy of linear models and providing a rigorous framework for quantifying the information content of isotope-climate relationships with implications for both modern and paleoclimate applications.

information theory↗

Sensitivity of mixing layers to three-dimensional forcing

It is well known that turbulent mixing layers are dominated by large scale, fairly coherent structures, and that these structures are related to the stability characteristics of the flow. These facts have led researchers to attempt controlling such flows by selectively forcing certain unstable modes, which can in addition have the effect of suppressing other modes. Much of the work on controlling the mixing layer has relied on forcing 2-D instabilities. The results of forcing 3-D instabilities are addressed. The objectives of the work are twofold: to understand how a mixing layer responds to 3-D perturbations, and to test the validity of an amplitude expansion in predicting the mixing layer development. The amplitude expansion could be very useful in understanding and predicting the 3-D response of the flow to a variety of initial conditions.

Riley, J. J.↗

A design philosophy for multi-layer neural networks with applications to robot control

A system is proposed which receives input information from many sensors that may have diverse scaling, dimension, and data representations. The proposed system tolerates sensory information with faults. The proposed self-adaptive processing technique has great promise in integrating the techniques of artificial intelligence and neural networks in an attempt to build a more intelligent computing environment. The proposed architecture can provide a detailed decision tree based on the input information, information stored in a long-term memory, and the adapted rule-based knowledge. A mathematical model for analysis will be obtained to validate the cited hypotheses. An extensive software program will be developed to simulate a typical example of pattern recognition problem. It is shown that the proposed model displays attention, expectation, spatio-temporal, and predictory behavior which are specific to the human brain. The anticipated results of this research project are: (1) creation of a new dynamic neural network structure, and (2) applications to and comparison with conventional multi-layer neural network structures. The anticipated benefits from this research are vast. The model can be used in a neuro-computer architecture as a building block which can perform complicated, nonlinear, time-varying mapping from a multitude of input excitory classes to an output or decision environment. It can be used for coordinating different sensory inputs and past experience of a dynamic system and actuating signals. The commercial applications of this project can be the creation of a special-purpose neuro-computer hardware which can be used in spatio-temporal pattern recognitions in such areas as air defense systems, e.g., target tracking, and recognition. Potential robotics-related applications are trajectory planning, inverse dynamics computations, hierarchical control, task-oriented control, and collision avoidance.

Vadiee, Nader↗

Carbon nanotube thermoelectric devices by direct printing: Toward wearable energy converters

Thermoelectric devices convert thermal energy to electrical energy and are particularly well-suited for energy harvesting from waste heat. Even as the number of electronic devices used in daily life proliferates, technical advances diminish the average power such devices require to perform a given function. Here, localized thermal gradients that abound in our living environments, despite having modest energy densities, are therefore becoming increasingly viable and attractive to power such devices. With this motivation, we report the design, fabrication, and characterization of single-wall carbon nanotube thermoelectric devices (CNT-TDs) on flexible polyimide substrates as a basis for wearable energy converters. Our aqueous-solution-based film fabrication process could enable readily scalable, low-cost TDs; here, we demonstrate CNT-hydroxypropyl cellulose (HPC) composite thermoelectric films by aerosol jet printing. The electrical conductivity of the composite films is controlled through the number of CNT/HPC layers printed in combination with control of the annealing conditions.

30 DIRECT ENERGY CONVERSION↗

Hydrodynamics of two-dimensional compressible fluid with broken parity: Variational principle and free surface dynamics in the absence of dissipation

In this paper, we consider an isotropic compressible nondissipative fluid with broken parity subject to free surface boundary conditions in two spatial dimensions. The hydrodynamic equations describing the bulk dynamics of the fluid and the free surface boundary conditions depend explicitly on the parity-breaking nondissipative odd viscosity term. We construct an effective action which gives both bulk hydrodynamic equations and free surface boundary conditions. The free surface boundary conditions require an additional boundary term in the action which resembles a 1+1D chiral boson field coupled to the background geometry. We solve the linearized hydrodynamic equations for the deep water case and derive the dispersion of chiral surface waves. We show that in the long-wavelength limit the flow profile exhibits an oscillating vortical boundary layer near the free surface. The layer thickness is controlled by the ratio between the odd viscosity (ν o ) and the sound velocity (c s ), δ ~ ν o /c s . In the incompressible limit, c s → ∞, the vortical boundary layer becomes singular with the vorticity within the layer diverging as ω ~ c s . The boundary layer is formed by odd viscosity coupling the divergence of velocity ∇ • v to vorticity ∇ × v. It results in nontrivial chiral free surface dynamics even in the absence of external forces. The structure of the odd-viscosity-induced boundary layer is very different from the conventional free surface boundary layer associated with dissipative shear viscosity.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Coherent motion in excited free shear flows

The application of the inviscid instability approach to externally excited turbulent free shear flows at high Reynolds numbers is explored. Attention is given to the cases of a small-deficit plane turbulent wake, a plane turbulent jet, an axisymmetric jet, the nonlinear evolution of instabilities in free shear flows, the concept of the 'preferred mode', vortex pairing in turbulent mixing layers, and experimental results for the control of free turbulent shear layers. The special features often attributed to pairing or to the preferred mode are found to be difficult to comprehend; the concept of feedback requires further substantiation in the case of incompressible flow.

Wygnanski, Israel J.↗

Optimizing the lean hydrocarbon NO x trap: Sequential and dual-layer configurations

Vehicular emission control catalysts are ineffective in eliminating CO, hydrocarbons, and NO x during engine cold-start when exhaust temperatures are below 200 °C. In this study the performance of coupled low temperature NO x , n-C 12 H 26 (C 12 ), and C 3 H 6 trapping, release and conversion for a series of model Lean Hydrocarbon NO x Trap (LHCNT) catalysts are examined. Pd and Pt supported on small-pore (SSZ-13) and large-pore (BEA) zeolites are selected based on the performance during transient NO and C 12 uptake, release and conversion experiments. These catalysts are combined into sequential (Pt + Pd/BEA → Pd/SSZ-13; Pd/SSZ-13 → Pt + Pd/BEA) and dual-layer (Pt + Pd/BEA top, Pd/SSZ-13 bottom) configurations in an attempt to improve the trapping and conversion performance. While all three configurations trap between 75 and 100 μmolNO x /g-cat, the Pd/SSZ-13 → Pt + Pd/BEA sequential configuration is most effective in simultaneously trapping C 12 and NO in the presence of H 2 O, resulting in excellent NO and C 12 storage below 100 °C with release and/or conversion at or above 200 °C. For each configuration, C 12 oxidation lights-off below 300 °C and NO oxidation achieves ~35 % conversion in the absence of C 12 . Neither the presence of C 12 nor the order of the sequential configuration has a significant impact on NO uptake. C 12 significantly delays NO and NO 2 desorption to temperatures exceeding 300 °C. The more compact dual-layer catalyst is most effective in forming NO 2 as the release temperature lines up with the maximum NO conversion temperature but traps less C 12 than the sequential configurations. The addition of C 3 H 6 in the feed on the dual-layer catalyst leads to further delay in the NO x desorption as well as increased NO and C 12 conversion at high temperatures. Here, the overall findings provide guidance in the optimizing LHCNT configuration for realistic feeds.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Germination and elongation of flax in microgravity

This experiment was conducted as part of a risk mitigation payload aboard the Space Shuttle Atlantis on STS-101. The objectives were to test a newly developed water delivery system, and to determine the optimal combination of water volume and substrate for the imbibition and germination of flax (Linum usitatissimum) seeds in space. Two different combinations of germination paper were tested for their ability to absorb, distribute, and retain water in microgravity. A single layer of thick germination paper was compared with one layer of thin germination paper under a layer of thick paper. Paper strips were cut to fit snugly into seed cassettes, and seeds were glued to them with the micropyle ends pointing outward. Water was delivered in small increments that traveled through the paper via capillary action. Three water delivery volumes were tested, with the largest (480 microliters) outperforming the 400 microliters and 320 microliters volumes for percent germination (90.6%) and root growth (mean=4.1 mm) during the 34-hour spaceflight experiment. The ground control experiment yielded similar results, but with lower rates of germination (84.4%) and shorter root lengths (mean=2.8 mm). It is not clear if the roots emerged more quickly in microgravity and/or grew faster than the ground controls. The single layer of thick germination paper generally exhibited better overall growth than the two layered option. Significant seed position effects were observed in both the flight and ground control experiments. Overall, the design of the water delivery system, seed cassettes and the germination paper strip concept was validated as an effective method for promoting seed germination and root growth under microgravity conditions. c2003 COSPAR. Published by Elsevier Ltd. All rights reserved.

Non-NASA Center↗

Sliding-Mode Control Applied for Robust Control of a Highly Unstable Aircraft

An investigation into the application of an observer based sliding mode controller for robust control of a highly unstable aircraft and methods of compensating for actuator dynamics is performed. After a brief overview of some reconfigurable controllers, sliding mode control (SMC) is selected because of its invariance properties and lack of need for parameter identification. SMC is reviewed and issues with parasitic dynamics, which cause system instability, are addressed. Utilizing sliding manifold boundary layers, the nonlinear control is converted to a linear control and sliding manifold design is performed in the frequency domain. An additional feedback form of model reference hedging is employed which is similar to a prefilter and has large benefits to system performance. The effects of inclusion of actuator dynamics into the designed plant is heavily investigated. Multiple Simulink models of the full longitudinal dynamics and wing deflection modes of the forward swept aero elastic vehicle (FSAV) are constructed. Additionally a linear state space models to analyze effects from various system parameters. The FSAV has a pole at +7 rad/sec and is non-minimum phase. The use of 'model actuators' in the feedback path, and varying there design, is heavily investigated for the resulting effects on plant robustness and tolerance to actuator failure. The use of redundant actuators is also explored and improved robustness is shown. All models are simulated with severe failure and excellent tracking, and task dependent handling qualities, and low pilot induced oscillation tendency is shown.

Vetter, Travis Kenneth↗

Numerical investigations in three-dimensional internal flows

The present study is a preliminary investigation into the behavior of the flow within a 28 degree total geometric turning angle hypothetical Mach 10 inlet as calculated with the full three-dimensional Navier-Stokes equations. Comparison between the two-dimensional and three-dimensional solutions have been made. The overall compression is not significantly different between the two-dimensional and center plane three dimensional solutions. Approximately one-half to two-thirds of the inlet flow at the exit of the inlet behave nominally two-dimensionally. On the other hand, flow field non-uniformities in the three-dimensional solution indicate the potential significance of the sidewall boundary layer flows ingested into the inlet. The tailoring of the geometry at the inlet shoulder and on the cowl obtained in the two-dimensional parametric design study have also proved to be effective at controlling the boundary layer behavior in the three-dimensional code. The three-dimensional inlet solution remained started indicating that the two-dimensional design had a sufficient margin to allow for three-dimensional flow field effects. Although confidence is being gained in the use of SCRAM3D (three-dimensional full Navier-Stokes code) as applied to similar flow fields, the actual effects of the three-dimensional flow fields associated with sidewalls and wind tunnel installations can require verification with ground-based experiments.

Rose, William C.↗

Design of an arc-free thermal blanket

The success of a multilayer thermal blanket in eliminating arcing is discussed. Arcing is eliminated by limiting the surface potential to well below the threshold level for discharge. This is achieved by enhancing the leakage current which results in conduction of the excess charge to the spacecraft structure. The thermal blanket consists of several layers of thermal control (space approved) materials, bonded together, with Kapton on the outside, arranged in such a way that when the outer surface is charged by electron irradiation, a strong electric field is set up on the Kapton layer resulting in a greatly improved conductivity. The basic properties of matter utilized in designing this blanket method of charge removal, and optimum thermo-optical properties are summarized.

Fellas, C. N.↗

SNS Devices With Pinhole-Defined Active Regions

Superconductor/normal conductor/superconductor (SNS) microbridge devices with pinhole-defined active regions undergoing development. Device includes thin, electrically insulating layer deposited epitaxially, with controlled formation of pinholes, on one of two superconducting layers. Normally conducting metal deposited epitaxially in pinholes and on insulating layer, forming electrical contact between two superconducting layers. Junction resistances and maximum junction voltages expected to be increased.

Hunt, Brian D.↗

Viscous drag reduction in boundary layers

The present volume discusses the development status of stability theory for laminar flow control design, applied aspects of laminar-flow technology, transition delays using compliant walls, the application of CFD to skin friction drag-reduction, active-wave control of boundary-layer transitions, and such passive turbulent-drag reduction methods as outer-layer manipulators and complex-curvature concepts. Also treated are such active turbulent drag-reduction technique applications as those pertinent to MHD flow drag reduction, as well as drag reduction in liquid boundary layers by gas injection, drag reduction by means of polymers and surfactants, drag reduction by particle addition, viscous drag reduction via surface mass injection, and interactive wall-turbulence control.

Bushnell, Dennis M.↗