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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 721 records · Page 40
All sourcesNASA NTRSDOE OSTI
NASA NTRS1982

Studies of clusters in the gas phase and application to an understanding of transitions from gaseous to the surface and condensed state

Studies of the structure, stability, electronic properties, and formation kinetics of small clusters were reviewed which provide information useful in furthering understanding of nucleation processes, liquid state properties, and the nature of surfaces. Using mass spectrometric coupled with various high pressure ion clustering and Stark effect-molecular beam techniques, the details of the primary clustering steps leading to the nucleation of bulk liquid from the vapor were and obtained by direct observation results are presented.

Castleman, A. W., Jr.↗
NASA NTRS1981

Histidyl-histidine catalysis of glycine condensation in fluctuating clay environments

Histidyl-histidine is a remarkably effective catalyst of peptide bond formation in the reaction of glycine in a fluctuating (hot-dry, cold-wet) clay environment. It has shown turnover numbers (molecules of glycine incorporated in oligoglycines per molecule of catalyst) as high as 18 in a single cycle and as high as 52 overall. A number of other dipeptides were tested, as well as monomeric histidine, N-acetyl histidine, and imidazole, none of which showed turnover numbers greater than one. Histidyl-histidine is a model for a prebiotic protoenzyme, and implications for the development of a simple translation mechanism are discussed.

White, D. H.↗
NASA NTRS1982

The cooling and condensation of flare coronal plasma

A model is investigated for the decay of flare heated coronal loops in which rapid radiative cooling at the loop base creates strong pressure gradients which, in turn, generate large (supersonic) downward flows. The important features of this model which distinguish it from previous models of flare cooling are: (1) Most of the thermal energy of the coronal plasma may be lost by mass motion rather than by conduction or coronal radiation. (2) Flare loops are not isobaric during their decay phase, and large downward velocities are present near the footpoints. (3) The differential emission measure has a strong temperature dependence. These results can account for recent observations of compact flare loops that are not consistent with the previous cooling models.

Antiochos, S. K.↗
NASA NTRS1981

Formation of pyrophosphate, tripolyphosphate, and phosphorylimidazole with the thioester, N, S-diacetylcysteamine, as the condensing agent

The formation of pyrophosphate, tripolyphosphate and phosphorylimidazole from orthophosphate in the presence of the thioester N, S-diacetylcysteamine is reported. Reactions performed with 0.20 M orthophosphate and 0.20 M N, S-diacetylcysteamine in 0.40 M imidazole under drying conditions at 50 C yielded pyrophosphate and tripolyphosphate after six days in the presence and absence of divalent metal ions. Reactions carried out at ambient temperature yielded phosphorylimidazole in the presence or absence of 0.05 M MgCl2, phosphorylimidazole and pyrophosphate in the presence of 0.05 M CaCl2, and pyrophosphate and tripolyphosphate in the presence of 0.15 M CaCl2. Such reactions represent potential pathways for the formation of energy-rich compounds providing free energy for use in prebiotic biopolymer synthesis.

Weber, A. L.↗
NASA NTRS1982

Homogeneous and heterogeneous condensation of nitrogen in transonic flow

Onset of both homogeneous and heterogeneous nucleation for nitrogen gas has been measured in the Langley 0.3m Transonic Cryogenic Tunnel. Homogeneous nucleation data have been taken using a DFVLR CAST-10 airfoil and are used to evaluate classical liquid droplet theory and several proposed corrections to it. A correction for differences in translational energy states between the droplet and the bulk liquid due to either Reiss (1977) or Kikuchi (1977) achieves good agreement between the predicted onset of nucleation and the data. Good agreement is also found using a Tolman constant of 0.25 x 10 to the -10th m. Onset of heterogeneous nucleation on pre-existing seed particles in the flow has also been studied, and preliminary estimates of seed size and number are 0.25 x 10 to the -6th m and 3.0 x 10 to the 12th per kilogram of the gas. It is shown that this preexisting seed population is insufficient to influence the observed onset of homogeneous nucleation.

Hall, R. M.↗
NASA NTRS1983

Condensation of solids in space. Isotope fractionation in the model system C-O

The reported chemical fractionation of a single isotope O-16 under simulated space conditions provides the first experimental proof for the hypothesis that the oxygen isotopic anomaly (and other similar anomalies) seen in meteorites is a product of chemical fractionation in interstellar or circumstellar space. Work proposed on this subject was discontinued because a peer review determined that such effects could not possibly exist and that continued support of this project would be a wasted effort. A bibliography is included of articles generated during research in this area.

Arrhenius, G.↗
NASA NTRS1985

Laboratory infrared spectra of predicted condensates in carbon-rich stars

Laboratory spectra and mass absorption coefficients of MgS, CaS, FeS, SiS2, FeS2, Fe3C, and a commercial iron carbide are presented over the wavelength range 125-15 microns. These spectra confirm that MgS is the most likely source of the unidentified 30-micron emission in carbon-rich sources and that FeS, Fe3C, and 'iron carbide' cannot be responsible for this feature although they could contribute to the continuum in this region. CaS and FeS2 may contribute to the 30-micron feature; however, both higher resolution and higher precision astronomical observations are needed before their presence can be established. SiS2 has a peak near 22 microns and therefore cannot be a significant component of the dust in such regions.

Nuth, J. A.↗
NASA NTRS1986

Models of glycolysis: Glyceraldehyde as a source of energy and monomers for prebiotic condensation reactions

All organisms require energy in a chemical form for maintenance and growth. In contemporary life this chemical energy is obtained by the synthesis of the phosphoanhydride bonds of ATP. Among the biological processes that yield ATP, fermentation is generally considered primitive, because it operates under anaerobic conditions by substrate-level phosphorylation which does not require compartmentation by membranes. Fermentation by the glycolytic pathway, which is found in almost every living cell, is an especially attractive energy source for primitive life. Glycolysis not only produces useful chemical energy (ATP), but intermediates of this pathway are also involved in amino acid synthesis and photosynthetic carbon-fixation. It is believed that energy and substrates needed for the origin of life were provided by nonenzymatic chemical reactions that resemble the enzyme-mediated reactions of glycolysis. These nonenzymatic reactions would have provided a starting point for the evolutionary development of glycolysis.

Weber, A. L.↗
NASA NTRS1986

Evidence for successive episodes of condensation at high temperature in a part of the solar nebula

A polished thin section of a Ca-Al-rich inclusion CAI 3643 from the Allende meteorite has been studied by means of light and scanning electron microscopes, and electron and proton microprobes. The appearance and the mineral composition of the inclusion's three concentric layers: core, mantle, and crust are described. Despite differences in texture and composition, the three layers display a continuity in their modal mineralogical compositions, their extreme Al2O3 enrichments (53-69 percent, compared to 25-45 percent in other CAIs), and their trace element complementarity. This implies that all the layers of CAI 3643 have formed from the same cooling gaseous reservoir within a limited interval of time and space, consistent with an origin in a local transient heating event in the CV chondrite formation region of the nebula.

Wark, D. A.↗
NASA NTRS1986

Experimental studies of the vapor phase nucleation of refractory compounds. III - The condensation of silver

Measurements are reported of the critical supersaturation necessary to initiate the vapor phase nucleation of silver over the ambient temperature range 500-950 K at total pressures of 250 and 500 torr of hydrogen. The results are compared with the predictions of both classical nucleation theory and the theory of a physical spinodal developed by Rasmussen (1982), neither of which adequately describes the present observations. The nucleation of silver appears to be dependent on the total pressure of the system in a manner which suggests that three-body reactions are necessary in order to form the initial silver cluster (e.g., dimers) from the monoatomic vapor.

Nuth, J. A.↗
NASA NTRS1987

Condensate phenomena in the polar regions of Mars

Models used to study the changes in Martian climate must of necessity adequately describe the current volatile cycles. The focus is on mathematical modeling of current volatile cycles and modest extrapolation to past regimes. Water cycle, dust storms, polar variabilty, and north polar clouds data were compared to the model predictions.

James, Philip B.↗
NASA NTRS1987

DC electrical, thermal, and spectroscopic properties of various condensation polyimides containing surface cobalt oxide

Doping polyimides with cobalt ion causes the room temperature direct current electrical resistivity to decrease relative to the polymer alone, the reduction being most pronounced for the air-side of the cobalt modified polyimides. At a constant electrical field, resistivity for the volume, air-side and glass-side modes decreases yet further with an increase in temperature as expected for semiconductors and insulators. X-ray photoelectron spectroscopy indicates the air-side of the cobalt modified polyimides is predominantly Co3O4. The bulk resistivity of the air-side and activation energy of conduction for this surface are comparable to high purity sintered Co3O4. Charging characteristics at room temperature indicate a substantial polymer matrix contribution to both the glass-side and volume mode measurements but a negligible contribution to the air-side electrical properties. Volume electrical resistivity for similar additive levels is reduced by increasing the molecular flexibility of the host polymer.

Rancourt, J. D.↗