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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 721 records · Page 40
All sourcesNASA NTRSDOE OSTI
DOE OSTI2015

Highlights from Faraday Discussion 172: Carbon in Electrochemistry, Sheffield, UK, July 2014

Faraday Discussions have been very true to their name, focusing genuinely on healthy, in-depth, and fruitful discussions rather than just serving as a platform for one to one researcher interaction and collaboration. So the first experience of a Faraday Discussion is always an eye-opener about how lively conference discussions can become. The format follows that presenters submit full papers a few months in advance which are lightly reviewed before all the papers are circulated to each of the registered participants. Participants arrive at the conference prepared with their queries and arguments after having read the circulated manuscripts. At the conference the authors present their work for five minutes each followed by extensive discussion of 20–25 minutes, which is practically a ‘‘live peer-review’’. Moreover, this experience of a discussion-cum-peer review with participants ranging for PhD students to experts in the relevant field is both a daunting and a very enriching experience at the same time. This has been the trend since the first Faraday Discussions held in London in 1907 in London which debated ‘‘osmotic pressure’’,1 and this format clearly sets it apart from any other conference to date. All discussions form part of the peer review process and are sequentially recorded and published with the accepted manuscripts.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2018

Conforming nanoparticle sheets to surfaces with Gaussian curvature

Nanoparticle monolayer sheets are ultrathin inorganic–organic hybrid materials that combine highly controllable optical and electrical properties with mechanical flexibility and remarkable strength. Like other thin sheets, their low bending rigidity allows them to easily roll into or conform to cylindrical geometries. Nanoparticle monolayers not only can bend, but also cope with strain through local particle rearrangement and plastic deformation. This means that, unlike thin sheets such as paper or graphene, nanoparticle sheets can much more easily conform to surfaces with complex topography characterized by non-zero Gaussian curvature, like spherical caps or saddles. Here, we investigate the limits of nanoparticle monolayers’ ability to conform to substrates with Gaussian curvature by stamping nanoparticle sheets onto lattices of larger polystyrene spheres. Tuning the local Gaussian curvature by increasing the size of the substrate spheres, we find that the stamped sheet morphology evolves through three characteristic stages: from full substrate coverage, where the sheet extends over the interstices in the lattice, to coverage in the form of caps that conform tightly to the top portion of each sphere and fracture at larger polar angles, to caps that exhibit radial folds. Through analysis of the nanoparticle positions, obtained from scanning electron micrographs, we extract the local strain tensor and track the onset of strain-induced dislocations in the particle arrangement. By considering the interplay of energies for elastic and plastic deformations and adhesion, we construct arguments that capture the observed changes in sheet morphology as Gaussian curvature is tuned over two orders of magnitude.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2020

Spectroscopic evidence for intact carbonic acid stabilized by halide anions in the gas phase

Here we show elusive carbonic acid being effectively stabilized in the gas phase by interacting with halide anions X – (X = F, Cl, Br, and I). The formed H 2 CO 3 ·X – complexes, characterized by negative ion photoelectron spectroscopy and ab initio calculations, all contain intact trans – trans carbonic acid binding onto the respective halide via two identical strong ionic O–H...X – hydrogen bonds. For X = Cl, Br, and I, the complex spectra exhibit the corresponding X – signature by simply shifting to the higher binding energy side, while an extremely 2 eV wide broader band is observed for X = F. This spectroscopic evidence indicates that an excess electron is removed from each halide in the former case, while a proton is transferred from carbonic acid to fluoride upon electron detachment for the latter. The above H 2 CO 3 ·X – structures as well as those of the previously studied H 2 SO 4 ·X – along the homologous halogen series cannot be explained using the proton affinity (PA) argument. Instead, a qualitative correlation is found between these structural motifs and the constituent acid p K a values, strongly suggesting that p K a is a more suitable factor to predict correct acid–base chemistry between these diprotic oxyacids and halides.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2020

Understanding the thermally activated charge transport in NaPb m SbQ m+2 (Q = S, Se, Te) thermoelectrics: weak dielectric screening leads to grain boundary dominated charge carrier scattering

Many thermoelectric materials feature irregular electrical conductivity with thermally activated transport below ~600 K and metallic behavior at high temperatures, despite possessing degenerate carrier concentrations. The suppression of the electrical conductivity ultimately degrades the thermoelectric performance on the cold side and limits the device energy conversion efficiency. As such, establishing the origin of the low temperature scattering and developing strategies to mitigate its effect are paramount issues. To date, the correct microscopic description of the low temperature carrier scattering remains an open issue, and there is little work addressing why some thermoelectric materials are more susceptible to the deleterious behavior. Here, we use the promising thermoelectric alloys of PbQ and NaSbQ 2 (Q = S, Se, Te) as model systems to address these concerns. We directly show the thermally activated transport stems from the scattering of charge carriers by the grain boundaries (GBs), and that the expected metallic electrical conductivity is recovered by preparing large grained samples with reduced densities of GBs. We furthermore study the electrical properties NaPb m SbSe m+2 as a function of NaSbSe 2 fraction, as well as those of the chalcogenide analogues, PbTe–NaSbTe 2 and PbS–NaSbS 2 , and demonstrate that the strength of GB scattering can be understood by utilizing simple chemical principles. By considering the polarizability of the host atoms, we directly relate the magnitude of GB scattering to the relative degree of charge carrier screening in each material, and demonstrate that GB scattering is strongest in the ionic NaSbQ 2 -rich compounds and weakest in more polarizable PbQ-rich phases. We finally show how these chemical arguments elegantly explain the strong GB scattering in numerous other thermoelectric materials. By uniting the deleterious charge transport properties exhibited by many different compounds into a common picture, we discuss how our work gives design principles for proper microstructure engineering in emerging thermoelectric materials.

36 MATERIALS SCIENCE↗
DOE OSTI2022

Control over emergence and alignment of transient blisters in thermo-responsive gels using hierarchically patterned substrates

Surfaces with tunable microscale textures are vital in a large variety of technological applications, including heat transfer, antifouling and adhesion. To facilitate such broad-scale use, there is a need to create surfaces that undergo reconfigurable changes in topology and thus, enable switchable functionality. To date, there is a relative dearth of methods for engineering surfaces that can be actuated to change topography over a range of length scales, and hence, form tunable hierarchically structured layers. Combining modeling and experiments, we design a geometrically patterned, thermo-responsive poly (N-isopropylacrylamide) gel film that undergoes controllable hierarchical changes in topology with changes in temperature. At the bottom, the film is covalently bound to a solid, curved substrate; at the top, the film encompasses longitudinal rectangular ridges that are oriented perpendicular to the underlying cylindrical curves. At temperatures below lower critical solution temperature (LCST), the swollen gel exhibits 3D variations in polymer density and thickness defined by the gel's top and bottom topography. As the temperature rises above LCST, the interplay between the upper ridges and lower curves in the gel drives non-uniform, directional solvent transport, the nucleation and propagation of a phase-separated higher-density skin layer, and the resulting pressure buildup within the film. These different, interacting kinetic processes lead to an instability, which produces transient microscopic blisters in the film. Through simulations, we show how tuning the width of the ridges modifies the propagation of a skin layer and creates localized pressure build-up points, which enables control over the emergence, distribution, and alignment of the microscopic blisters. Futhermore, we provide a simple argument to predict the size of such microscopic features. Experiments confirm our predictions and further highlight how our computational model enables the rational design of topographical transitions in these tunable films. The development of actuatable, hierarchically structured films provides new routes for achieving switchable functionality in actuators, drug release systems and adhesives.

42 ENGINEERING↗
DOE OSTI2022

Wetting behavior of polyelectrolyte complex coacervates on solid surfaces

The wetting behavior of complex coacervates underpins their use in many emerging applications of surface science, particularly wet adhesives and coatings. Many factors dictate if a coacervate phase will condense on a solid surface, including solution conditions, the nature of the polymer–substrate interaction, and the underlying supernatant–coacervate bulk phase behavior. In this work, we use a simple inhomogeneous mean-field theory to study the wetting behavior of complex coacervates on solid surfaces both off-coexistence (wetting transitions) and on-coexistence (contact angles). Here we focus on the effects of salt concentration, the polycation/polyanion surface affinity, and the applied electrostatic potential on the wettability. We find that the coacervate generally wets the surface via a first order wetting transition with second order transitions possible above a surface critical point. Applying an electrostatic potential to a solid surface always improves the surface wettability when the polycation/polyanion–substrate interaction is symmetric. For asymmetric surface affinity, the wettability has a nonmonotonic dependence with the applied potential. We use simple scaling and thermodynamic arguments to explain our results.

36 MATERIALS SCIENCE↗
DOE OSTI2022

Optimizing the accuracy of viscoelastic characterization with AFM force–distance experiments in the time and frequency domains

Atomic Force Microscopy (AFM) force-distance (FD) experiments have emerged as an attractive alternative to traditional micro-rheology measurement techniques owing to their versatility of use in materials of a wide range of mechanical properties. Here, we show that the range of time dependent behaviour which can reliably be resolved from the typical method of FD inversion (fitting constitutive FD relations to FD data) is inherently restricted by the experimental parameters: sampling frequency, experiment length, and strain rate. Specifically, we demonstrate that violating these restrictions can result in errors in the values of the parameters of the complex modulus. In the case of complex materials, such as cells, whose behaviour is not specifically understood a priori, the physical sensibility of these parameters cannot be assessed and may lead to falsely attributing a physical phenomenon to an artifact of the violation of these restrictions. We use arguments from information theory to understand the nature of these inconsistencies as well as devise limits on the range of mechanical parameters which can be reliably obtained from FD experiments. The results further demonstrate that the nature of these restrictions depends on the domain (time or frequency) used in the inversion process, with the time domain being far more restrictive than the frequency domain. Lastly, we demonstrate how to use these restrictions to better design FD experiments to target specific timescales of a material's behaviour through our analysis of a polydimethylsiloxane (PDMS) polymer sample.

information theory↗
DOE OSTI2013

Radio to gamma-ray variability study of blazar S5 0716+714

In this paper, we present the results of a series of radio, optical, X-ray, and γ-ray observations of the BL Lac object S50716+714 carried out between April 2007 and January 2011. The multifrequency observations were obtained using several ground- and space-based facilities. The intense optical monitoring of the source reveals faster repetitive variations superimposed on a long-term variability trend on a time scale of ~350 days. Episodes of fast variability recur on time scales of ~60-70 days. The intense and simultaneous activity at optical and γ-ray frequencies favors the synchrotron self-Compton mechanism for the production of the high-energy emission. Two major low-peaking radio flares were observed during this high optical/γ-ray activity period. The radio flares are characterized by a rising and a decaying stage and agrees with the formation of a shock and its evolution. We found that the evolution of the radio flares requires a geometrical variation in addition to intrinsic variations of the source. Different estimates yield robust and self-consistent lower limits of δ ≥ 20 and equipartition magnetic field B eq ≥ 0.36 G. Causality arguments constrain the size of emission region θ ≤ 0.004 mas. We found a significant correlation between flux variations at radio frequencies with those at optical and γ-rays. Theoptical/GeV flux variations lead the radio variability by ~65 days. The longer time delays between low-peaking radio outbursts and optical flares imply that optical flares are the precursors of radio ones. An orphan X-ray flare challenges the simple, one-zone emission models, rendering them too simple. Finally, here we also describe the spectral energy distribution modeling of the source from simultaneous data taken through different activity periods.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2013

Constraining the location of rapid gamma-ray flares in the flat spectrum radio quasar 3C 273 [Constraining the location of rapid gamma-ray flares in the FSRQ 3C 273]

Here, we present a γ-ray photon flux and spectral variability study of the flat-spectrum radio quasar 3C 273 over a rapid flaring activity period between September 2009 to April 2010. Five major flares were observed in the source during this period. The most rapid flare observed in the source has a flux doubling time of 1.1 hr. The rapid γ-ray flares allow us to constrain the location and size of the γ-ray emission region in the source. The γγ-opacity constrains the Doppler factor δ γ ≥ 10 for the highest energy (15 GeV) photon observed by the Fermi -Large Area Telescope (LAT). Causality arguments constrain the size of the emission region to 1.6 × 10 15 cm. The γ-ray spectra measured over this period show clear deviations from a simple power law with a break in the 1–2 GeV energy range. We discuss possible explanations for the origin of the γ-ray spectral breaks. Our study suggests that the γ-ray emission region in 3C 273 is located within the broad line region (< 1.6 pc). As a result, the spectral behavior and temporal characteristics of the individual flares indicate the presence of multiple shock scenarios at the base of the jet.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2014

The host galaxy and Fermi -LAT counterpart of HESS J1943+213

The very-high energy (VHE, E> 100 GeV) gamma-ray sky shows diverse Galactic and extragalactic source populations. For some sources the astrophysical object class could not be identified so far. The nature (Galactic or extragalactic) of the VHE gamma-ray source HESS J1943+213 is explored. We specifically investigate the proposed near-infrared counterpart 2MASS J19435624+2118233 of HESS J1943+213 and investigate the implications of a physical association. We present K-band imaging from the 3.5 m CAHA telescope of 2MASS J19435624+2118233. Furthermore, 5 years of Fermi-LAT data were analyzed to search for a high-energy (HE, 100 MeV stat ± 0.6 sys ) × 10 -15 cm -2 s -1 MeV -1 at the decorrelation energy Edec = 15.1 GeV and a spectral index of Γ = 1.59 ± 0.19stat ± 0.13sys. This gamma-ray spectrum shows a rather sharp break between the HE and VHE regimes of ΔΓ = 1.47 ± 0.36. In conclusion, the infrared and HE data strongly favor an extragalactic origin of HESS J1943+213, where the infrared counterpart traces the host galaxy of an extreme blazar and where the rather sharp spectral break between the HE and VHE regime indicates attenuation on extragalactic background light. The source is most likely located at a redshift between 0.03 and 0.45 according to extension and EBL attenuation arguments.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2015

The first full orbit of η Carinae seen by Fermi

The binary system η Carinae has completed its first 5.54 y orbit since the beginning of science operation of the Fermi Large Area Telescope (LAT). We are now able to investigate the high-energy γ-ray source at the position of η Carinae over its full orbital period. By this, we can address and confirm earlier predictions for temporal and spectral variability. Here, newer versions of the LAT datasets, instrument response functions and background models allow for a more accurate analysis. Therefore it is important to re-evaluate the previously analyzed time period along with the new data to further constrain location, spectral shape, and flux time history of the γ-ray source. As a result, we confirm earlier predictions of increasing flux values above 10 GeV toward the next periastron passage. For the most recent part of the data sample, flux values as high as those before the first periastron passage in 2008 are recorded. A comparison of spectral energy distributions around periastron and apastron passages reveals strong variation in the high-energy band. This is due to a second spectral component that is present only around periastron. In conclusion, improved spatial consistency with the γ-ray source at the position of η Carinae along with the confirmation of temporal variability above 10 GeV in conjunction with the orbital period strengthens the argument for unambiguous source identification. Spectral variability provides additional constraints for future modeling of the particle acceleration and γ-ray emission in colliding-wind binary systems.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2017

Location of γ -ray emission and magnetic field strengths in OJ 287

We report the γ-ray BL Lac object OJ 287 is known to exhibit inner-parsec “jet-wobbling”, high degrees of variability at all wavelengths and quasi-stationary features, including an apparent (≈100°) position-angle change in projection on the sky plane. Sub-50 micro-arcsecond resolution 86 GHz observations with the global mm-VLBI array (GMVA) supplement ongoing multi-frequency VLBI blazar monitoring at lower frequencies. Using these maps, together with cm/mm total intensity and γ-ray observations from Fermi-LAT from 2008-2014, we aim to Observations with the GMVA offer approximately double the angular resolution compared with 43 GHz VLBA observations and enable us to observe above the synchrotron self-absorption peak frequency. Fermi-LAT γ-ray data were reduced and analysed. The jet was spectrally decomposed at multiple locations along the jet. From this, we could derive estimates of the magnetic field using equipartition and synchrotron self-absorption arguments. How the field decreases down the jet provided an estimate of the distance to the jet apex and an estimate of the magnetic field strength at the jet apex and in the broad line region. Combined with accurate kinematics, we attempt to locate the site of γ-ray activity, radio flares, and spectral changes. Strong γ-ray flares appeared to originate from either the so-called core region, a downstream stationary feature, or both, with γ-ray activity significantly correlated with radio flaring in the downstream quasi-stationary feature. Magnetic field estimates were determined at multiple locations along the jet, with the magnetic field found to be ≥1.6 G in the core and ≤0.4 G in the downstream quasi-stationary feature. Finally, we therefore found upper limits on the location of the VLBI core as ≲6.0 pc from the jet apex and determined an upper limit on the magnetic field near the jet base of the order of thousands of Gauss.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2024

In-depth analysis of solar models with high-metallicity abundances and updated opacity tables

Context. As a result of the high-quality constraints available for the Sun, we are able to carry out detailed combined analyses using neutrino, spectroscopic, and helioseismic observations. These studies lay the ground for future improvements of the key physical components of solar and stellar models because ingredients such as the equation of state, the radiative opacities, or the prescriptions for macroscopic transport processes of chemicals are then used to study other stars in the Universe. Aims. We study the existing degeneracies in solar models using the recent high-metallicity spectroscopic abundances by comparing them to helioseismic and neutrino data and discuss the effect on their properties of changes in the micro and macro physical ingredients. Methods. We carried out a detailed study of solar models computed with a high-metallicity composition from the literature based on averaged 3D models that were claimed to resolve the solar modelling problem. We compared these models to helioseismic and neutrino constraints. Results. The properties of the solar models are significantly affected by the use of the recent OPLIB opacity tables and the inclusion of macroscopic transport. The properties of the standard solar models computed using the OPAL opacities are similar to those for which the OP opacities were used. We show that a modification of the temperature gradient just below the base of the convective zone is required to remove the discrepancies in solar models, particularly in the presence of macroscopic mixing. This can be simulated by a localised increase in the opacity of a few percent. Conclusions. We conclude that the existing degeneracies and issues in solar modelling are not removed by using an increase in the solar metallicity, in contradiction to what has been suggested in the recent literature. Therefore, standard solar models cannot be used as an argument for a high-metallicity composition. While further work is required to improve solar models, we note that direct helioseismic inversions indicate a low metallicity in the convective envelope, in agreement with spectroscopic analyses based on full 3D models.

74 ATOMIC AND MOLECULAR PHYSICS↗
DOE OSTI2025

Studying baryon acoustic oscillations using photometric redshifts from the DESI Legacy Imaging survey DR9

Context. The Dark Energy Spectroscopic Instrument (DESI) Legacy Imaging Survey DR9 (DR9 hereafter), with its extensive dataset of galaxy locations and photometric redshifts, presents an opportunity to study baryon acoustic oscillations (BAOs) in the region covered by the ongoing spectroscopic survey with DESI. Aims. We aim to investigate differences between different parts of the DR9 footprint. Furthermore, we want to measure the BAO scale for luminous red galaxies within them. Our selected redshift range of 0.6–0.8 corresponds to the bin in which a tension between DESI Y1 and eBOSS was found. Methods. We calculated the anisotropic two-point correlation function in a modified binning scheme to detect the BAOs in DR9 data. We then used template fits based on simulations to measure the BAO scale in the imaging data. Results. Our analysis reveals the expected correlation function shape in most of the footprint areas, showing a BAO scale consistent with Planck’s observations. Aside from identified mask-related data issues in the southern region of the South Galactic Cap, we find a notable variance between the different footprints. Conclusions. We find that this variance is consistent with the difference between the DESI Y1 and eBOSS data, and it supports the argument that that tension is caused by sample variance. Additionally, we also uncovered systematic biases not previously accounted for in photometric BAO studies. We emphasize the necessity of adjusting for the systematic shift in the BAO scale associated with typical photometric redshift uncertainties to ensure accurate measurements.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2017

Isomer-delayed gamma-ray spectroscopy of neutron-rich 166 Tb

Here, this short paper presents the identification of a metastable, isomeric-state decay in the neutron-rich odd-odd, prolate-deformed nucleus 166 Tb. The nucleus of interest was formed using the in-flight fission of a 345 MeV per nucleon 238 U primary beam at the RIBF facility, RIKEN, Japan. Gamma-ray transitions decaying from the observed isomeric states in 166 Tb were identified using the EURICA gamma-ray spectrometer, positioned at the final focus of the BigRIPS fragments separator. The current work identifies a single discrete gamma-ray transition of energy 119 keV which de-excites an isomeric state in 166 Tb with a measured half-life of 3.5(4) μs. The multipolarity assignment for this transition is an electric dipole and is made on the basis internal conversion and decay lifetime arguments. Possible two quasi-particle Nilsson configurations for the initial and final states which are linked by this transition in 166 Tb are made on the basis of comparison with Blocked BCS Nilsson calculations, with the predicted ground state configuration for this nucleus arising from the coupling of the v(1-/2)[521] and π(3+/2) Nilsson orbitals.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
DOE OSTI2021

CMS Full Simulation for Run 3

We report the status of the CMS full simulation for Run 3. During the long shutdown of the LHC a significant update has been introduced to the CMS code for simulation. The CMS geometry description is reviewed. Several important modifications were needed. CMS detector description software is migrated to the DD4Hep community developed tool. We will report on our experience obtained during the process of this migration. Geant4 10.7 is the CMS choice for Run 3 simulation productions. We will discuss arguments for this choice, the strategy of adaptation of a new Geant4 version, and will report on the physics performance of the CMS simulation. A special Geant4 Physics List configuration FTFP_BERT_EMM will be described, which provides a compromise between simulation accuracy and CPU performance. A significant fraction of time for simulation of CMS events is spent on tracking of charged particles in a magnetic field. In the CMS simulation a dynamic choice of Geant4 parameters for tracking in field is implemented. A new method is introduced into simulation of electromagnetic components of hadronic showers in the electromagnetic calorimeter of CMS. For low-energy electrons and positrons a parametrization of GFlash type is applied. Results of tests of this method will be discussed. In summary, we expect about 25% speedup of the CMS simulation production for Run 3 compared to the Run 2 simulations.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2010

Treatment of Uncertainty in Groundwater Modeling: A (Limited) Research Perspective

Groundwater systems are complex, exhibiting significant heterogeneity across multiple scales, multiple interacting processes, and nonlinear behaviors. Groundwater systems are also open, often with poorly defined boundaries and time-dependent, uncertain boundary forcings (e.g., recharge). As a consequence, a groundwater model cannot be expected to precisely reflect the system it represents and the model results are uncertain quantities. The dominant language of uncertainty is probability and the majority of research in the treatment of uncertainty in groundwater modeling has been directed at developing and improving probabilistic methods for these models. One area of recent research has been methods for assessing the impact of model uncertainty in groundwater analyses. This line of research is part of a long-term trend of increasing appreciation for the importance of providing estimates of uncertainty in groundwater model outputs. The research was motivated by observations of nonuniqueness in model parameterizations, the sensitivity of groundwater model output to model structural choices, and a history of practice that established the importance of iterative improvement in the conceptual basis of groundwater models. Among the methods proposed for assessing model uncertainty, we discuss Bayesian model averaging, it’s theoretical basis and research development. We outline critical arguments and discuss alternative approaches. Finally, we briefly describe a regulatory application of groundwater modeling that used Bayesian model averaging concepts to resolve a key conceptual model uncertainty.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2010

Phase transitions in the liquid-vapor interface of dilute alloys of Bi in Ga: New experimental studies

We report the results of measurements of x-ray reflectivity and grazing incidence x-ray diffraction from the liquid-vapor interfaces of four dilute alloys of Bi in Ga with mole fractions x{sub Bi} = 0.0032, 0.0023, 0.00037, and 0.000037. The monolayer coverage of the alloys with x{sub Bi} = 0.0023, and x{sub Bi} = 0.00037 is about 0.85 and only very slightly temperature dependent. The monolayer coverage in the lowest-concentration alloy, with x{sub Bi} = 0.000037, ranged from 0.82 at 29 C to 0.58 at 110 C. In none of these alloys, down to the lowest temperature used, 29 C, can we find any evidence for crystallization of the Bi monolayer that segregates as the outermost stratum of the liquid-vapor interface. Drawing on theoretical arguments we propose that the transitions inferred from the second-harmonic generation and plasma generation studies of dilute Bi in Ga alloys are from the liquid state to the hexatic state of the Bi monolayer. The data for the alloy with x{sub Bi} = 0.000037 suggest that near 80 C there is a disordered phase-to-disordered phase transition.

36 MATERIALS SCIENCE↗