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At least 721 records · Page 40
All sourcesNASA NTRSDOE OSTI
DOE OSTI2024

Review and Summary of Corrosion Behavior for Aluminum-Clad Spent Nuclear Fuel in Dry Storage

A description of the corrosion behavior of aluminum alloys used for cladding on aluminum-based, aluminum-clad nuclear fuel used in research reactors under potential dry storage conditions has been compiled. An evaluation is made of potential additional corrosion with water postulated to not be removed during drying. The relative humidity (RH) produced by typical dryness criteria for industrial spent nuclear fuel drying is expected to be low, particularly at high temperatures (17% RH at 20°C and lower at higher temperatures). Existing corrosion data suggests that negligible vapor-phase corrosion of aluminum is expected at such low humidity, even for nominally bare aluminum surfaces. That is, the predicted relative humidity from free water (e.g., 17% RH) is below the “critical” relative humidity (~40% RH at room temperature), below which no significant corrosion is observed for bare aluminum. Furthermore, reported room-temperature corrosion rates are very low even under saturated (100% RH) water vapor. Existing results showing significant vapor-phase corrosion corresponded specifically to conditions of high temper ed with high relative humidity. A relatively large reservoir of (chemically bound) water exists in the aluminum (oxy)hydroxide films on the SNF cladding surface. The estimated total could saturate the gas even at relatively high temperature if fully released; however, its release as molecular water is expected to only be plausible if the temperature during storage exceeds both the drying temperature and the threshold for thermal decomposition of the trihydroxides (~220°C). Therefore, the combination of high temperature and high relative humidity that could drive significant corrosion is considered implausible during sealed dry storage following an appropriate drying process, to include >220°C drying for canisters that may approach or exceed this temperature during storage. Vapor-phase testing of aluminum samples with an adherent (oxy)hydroxide layer, prepared in liquid water to resemble those on actual aluminum-clad spent nuclear fuel (ASNF), did not observe evidence of additional corrosion even at combined high-temperature (up to 180°C) and high-humidity (up to 100% RH) conditions. Instead, small net mass losses were observed for most specimens and attributed to dehydration of the samples, which had been air-dried only prior to testing. ASNF being moved to dry storage is expected to have an existing (oxy)hydroxide film, suggesting that the cladding will be less prone to additional corrosion than bare aluminum metal. If significant corrosion did occur during sealed storage, the overall extent and impact is expected to be small. Corrosion post-closure of a canister would not alter the total amount of hydrogen in the canister, so it would have no effect on the maximum H 2 release already assessed in existing bounding calculations. In addition, the total amount of water in a 25-µm dense bayerite film would consume a only ~8 µm additional aluminum metal on average, if fully consumed by oxidizing aluminum metal to Al 2 O 3 . These conclusions are consistent with ASNF-in-canister simulations to date, which included a reaction pathway for corrosion using kinetics from previous literature and believed to be conservative and predicted very low rates of corrosion.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
DOE OSTI2024

Reinforcement Learning Control for Enhancing Marine Hydrokinetic Turbine Energy Generation

This paper proposes a reinforcement learning-based method to maximize power generation for a direct-drive marine hydrokinetic turbine. A high levelized cost of energy (LCOE) is preventative in the widespread adoption of many marine energy conversion technologies. A straightforward way to reduce LCOE is to increase conversion efficiency and ensure maximum energy generation. The proposed method utilizes a damping control methodology, varying applied generator torque via a linear relationship between the applied damping coefficient and rotor speed. A state-action-reward-state-action (SARSA) algorithm has been used to learn the optimal control action for a given flow velocity. The proposed SARSA methodology uses Gaussian radial basis functions to create a three-dimensional surface to estimate the relationship between damping coefficient, incoming flow velocity, and coefficient of power (C p ). Here, the SARSA algorithm was compared against a baseline optimal tip speed ratio controller over a year-long flow velocity case profile while considering the effects of biofouling on the turbine system, where the proposed RL method generated 0.92% more energy than the baseline.

Damp↗
DOE OSTI2020

Accounting for Training Data Error in Machine Learning Applied to Earth Observations

Remote sensing, or Earth Observation (EO), is increasingly used to understand Earth system dynamics and create continuous and categorical maps of biophysical properties and land cover, especially based on recent advances in machine learning (ML). ML models typically require large, spatially explicit training datasets to make accurate predictions. Training data (TD) are typically generated by digitizing polygons on high spatial-resolution imagery, by collecting in situ data, or by using pre-existing datasets. TD are often assumed to accurately represent the truth, but in practice almost always have error, stemming from (1) sample design, and (2) sample collection errors. The latter is particularly relevant for image-interpreted TD, an increasingly commonly used method due to its practicality and the increasing training sample size requirements of modern ML algorithms. TD errors can cause substantial errors in the maps created using ML algorithms, which may impact map use and interpretation. Despite these potential errors and their real-world consequences for map-based decisions, TD error is often not accounted for or reported in EO research. Here we review the current practices for collecting and handling TD. We identify the sources of TD error, and illustrate their impacts using several case studies representing different EO applications (infrastructure mapping, global surface flux estimates, and agricultural monitoring), and provide guidelines for minimizing and accounting for TD errors. To harmonize terminology, we distinguish TD from three other classes of data that should be used to create and assess ML models: training reference data, used to assess the quality of TD during data generation; validation data, used to iteratively improve models; and map reference data, used only for final accuracy assessment. We focus primarily on TD, but our advice is generally applicable to all four classes, and we ground our review in established best practices for map accuracy assessment literature. EO researchers should start by determining the tolerable levels of map error and appropriate error metrics. Next, TD error should be minimized during sample design by choosing a representative spatio-temporal collection strategy, by using spatially and temporally relevant imagery and ancillary data sources during TD creation, and by selecting a set of legend definitions supported by the data. Furthermore, TD error can be minimized during the collection of individual samples by using consensus-based collection strategies, by directly comparing interpreted training observations against expert-generated training reference data to derive TD error metrics, and by providing image interpreters with thorough application-specific training. We strongly advise that TD error is incorporated in model outputs, either directly in bias and variance estimates or, at a minimum, by documenting the sources and implications of error. TD should be fully documented and made available via an open TD repository, allowing others to replicate and assess its use. To guide researchers in this process, we propose three tiers of TD error accounting standards. Finally, we advise researchers to clearly communicate the magnitude and impacts of TD error on map outputs, with specific consideration given to the likely map audience.

58 GEOSCIENCES↗
DOE OSTI2021

Peeking Between the Pulses: The Far-UV Spectrum of the Previously Unseen White Dwarf in AR Scorpii

The compact object in the interacting binary AR Sco has widely been presumed to be a rapidly rotating, magnetized white dwarf (WD), but it has never been detected directly. Isolating its spectrum has proven difficult because the spin-down of the WD generates pulsed synchrotron radiation that far outshines the WD's photosphere. As a result, a previous study of AR Sco was unable to detect the WD in the averaged far-ultraviolet spectrum from a Hubble Space Telescope (HST) observation. In an effort to unveil the WD's spectrum, we reanalyze these HST observations by calculating the average spectrum in the troughs between synchrotron pulses. We identify weak spectral features from the previously unseen WD and estimate its surface temperature to be 11,500 ± 500 K. Additionally, during the synchrotron pulses, we detect broad Lyα absorption consistent with hot WD spectral models. We infer the presence of a pair of hotspots, with temperatures between 23,000 and 28,000 K, near the magnetic poles of the WD. As the WD is not expected to be accreting from its companion, we describe two possible mechanisms for heating the magnetic poles. Here, the Lyα absorption of the hotspots appears relatively undistorted by Zeeman splitting, constraining the WD's field strength to be ≲100 MG, but the data are insufficient to search for the subtle Zeeman splits expected at lower field strengths.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2022

Dependence of the Ratio of Total to Visible Mass on Observable Properties of Sloan Digital Sky Survey MaNGA Galaxies

Abstract Using spectroscopic observations from the Sloan Digital Sky Survey Mapping Nearby Galaxies at Apache Point Observatory Data Release 15, we study the relationships between the ratio of total to visible mass and various parameters characterizing the evolution and environment of the galaxies in this survey. Measuring the rotation curve with the relative velocities of the H α emission line across a galaxy’s surface, we estimate each galaxy’s total mass. We develop a statistical model to describe the observed distribution in the ratio of total to visible mass, from which we extract the most probable value of this mass ratio for a given sample of galaxies. We present the relationships between the ratio of total to visible mass and several characteristics describing galactic evolution, such as luminosity, gas-phase metallicity, distance to the nearest neighbor, and position on the color–magnitude diagram. We find that faint galaxies with low metallicities, typically in the blue cloud, have the highest ratios of total to visible mass. This mass ratio is significantly reduced when we include the H i mass in the total visible mass, implying that feedback mechanisms are not as strong in low-mass galaxies as previously thought. Those galaxies that exhibit the second-highest ratios of total to visible mass are the brightest with high metallicities, typically members of the red sequence or green valley. Active galactic nucleus activity is likely both the quenching mechanism and the feedback that drives the mass ratio higher in these massive galaxies. Finally, we introduce a parameterization that predicts a galaxy’s ratio of total to visible mass based only on its photometry and luminosity.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2020

The Global Methane Budget 2000–2017

Understanding and quantifying the global methane (CH 4 ) budget is important for assessing realistic pathways to mitigate climate change. Atmospheric emissions and concentrations of CH 4 are continuing to increase, making CH 4 the second most important human-influenced greenhouse gas in terms of climate forcing, after carbon dioxide (CO 2 ). Assessing the relative importance of CH 4 in comparison to CO 2 is complicated by its shorter atmospheric lifetime, stronger warming potential, and atmospheric growth rate variations over the past decade, the causes of which are still debated. Two major difficulties in reducing uncertainties arise from the variety of geographically overlapping CH 4 sources and from the destruction of CH 4 by short-lived hydroxyl radicals (OH). To address these difficulties, we have established a consortium of multi-disciplinary scientists under the umbrella of the Global Carbon Project to synthesize and stimulate new research aimed at improving and regularly updating the global methane budget. Following Saunois et al. (2016), we present here the second version of the living review paper dedicated to the decadal methane budget, integrating results of top-down studies (atmospheric observations within an atmospheric inverse-modelling framework) and bottom-up estimates (including process-based models for estimating land surface emissions and atmospheric chemistry, inventories of anthropogenic emissions, and data-driven extrapolations).

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
NASA NTRS1962

Estimation of Critical Temperature for Surface Ion Currents from Electron Emission Data

A method of calculating a relation for the critical surface temperature for ion current emission is presented. The method is based on the S-shaped electron emission curves for surfaces in the presence of ionizable vapors and upon the assumptions of thermodynamic equilibrium involved in the Saha-Langmuir relation. A comparison of the critical temperatures so calculated with the relation obtained from actual ion emission data on the cesium-tungsten system shows good agreement over a wide current density range. Critical temperatures for cesium ion current densities of 0.21 and 1.9 amperes per square centimeter calculated by this method are presented for surfaces of rhenium, molybdenum, tantalum, and niobium. Tentative relations of the form log j equals A (sub p) plus (B (sub p) over T) are presented for these same systems, where j is the ion current density, A (sub p) and B (sub p) are constants, and T is the temperature.

ELECTRON EMISSION↗
NASA NTRS1966

Microwave radiometric temperatures of terrain

Microwave radiometers to measure radiation temperatures for several types of terrain for application to estimation of surface temperature from observed antenna temperature

MICROWAVE RADIOMETER↗
NASA NTRS1971

Studies of reaction geometry in oxidation and reduction of the alkaline silver electrode

Two methods of surface area estimations of sintered silver electrodes have given roughness factors of 58 and 81. One method is based on constant current oxidation, the other is based on potentiostatic oxidation. Examination of both wire and sintered silver electrodes via scanning electron microscopy at various stages of oxidation have shown that important structural features are mounds of oxide. In potentiostatic oxidations these appear to form on sites instantaneously nucleated while in constant current oxidations progressive nucleation is indicated.

Butler, E. A.↗
NASA NTRS1973

Gravity - Mare Humorum.

Global tracking coverage of the Apollo 15 subsatellite has provided gravity measurements from 50 km altitudes over the entire Humorum basin. An estimate of surface mass points at 2 degree intervals, which best fit the data reveals a mass distribution having a lesser mass excess for the very central area. When two different profiles were fit using a two disk model it was again found for each profile that the smaller central disk decreased the central mass by approximately 30%. The mass distribution per unit area however for the major portion of the mascon is still consistent with the other mascons (Crisium, Nectaris and Serenitatis) of approximately 800-900 kg/sq cm. The surface mass point solution seems to correlate somewhat with the dark areas on Whitaker's IR-UV map.

Sjogren, W. L.↗
NASA NTRS1975

Spoked wheels to deploy large surfaces in space-weight estimates for solar arrays

Extensible booms were used to deploy and support solar cell arrays of varying areas. Solar cell array systems were built with one or two booms to deploy and tension a blanket with attached cells and bussing. A segmented and hinged rim supported by spokes joined to a common hub is described. This structure can be compactly packaged and deployed.

Crawford, R. F.↗
NASA NTRS1975

A simple method to incorporate water vapor absorption in the 15 microns remote temperature sounding

The water vapor absorption in the 15 micron CO2 band, which can affect the remotely sensed temperatures near the surface, are estimated with the help of an empirical method. This method is based on the differential absorption properties of the water vapor in the 11-13 micron window region and does not require a detailed knowledge of the water vapor profile. With this approach Nimbus 4 IRIS radiance measurements are inverted to obtain temperature profiles. These calculated profiles agree with radiosonde data within about 2 C.

Dallu, G.↗
NASA NTRS1977

Estimation of ground temperature from GFCR radiometric signal

A procedure was developed which demonstrates the feasibility of estimating actual surface temperature from the effective brightness temperature which can be conveniently measured by a radiometer from remote sensing platforms. Atmospheric corrections to the effective brightness temperature are computed corresponding to the 'base model' atmosphere and several modifications of this caused by deviations of the various atmospheric or surface parameters from their base model values. Simple analytical relations were established between the deviations of these parameters and the additional temperature corrections required to compensate for them. Effects of simultaneous variation of several parameters also were examined. Use of these analytical relations, instead of radiative transfer calculations, results in tremendous savings in data reduction costs.

Gupia, S. K.↗
NASA NTRS1978

Radar scattering laws and wavelength dependence of the lunar surface

Data from Apollo lunar bistatic radar experiments have been processed to give probability density functions for surface slopes. These show best agreement with a Hagfors scattering law, though data having both gaussian and exponential characteristics also exist. Surface roughness estimates range from 4 deg in maria to at least 8 deg in highlands, values which are appropriate to 25 m horizontal scales and which are areal averages over tens of square kilometers. Roughness varies with wavelength, most strongly in maria.

Simpson, R. A.↗
NASA NTRS1977

Ultraviolet absorption spectrum of hydrogen peroxide vapor

The ultraviolet absorption cross sections of hydrogen peroxide vapor have been determined over the wavelength range 210 to 350 nm at 296 K. At the longer wavelengths, the gas phase absorptivities are significantly larger than the corresponding values in condensed phase. The atmospheric H2O2 photodissociation rate for overhead sun at the earth's surface is estimated to be about 1.3 x 10 to the -5th/sec.

Molina, L. T.↗
NASA NTRS1979

Preliminary results of SAR soil moisture experiment, November 1975

The experiment was performed using the Environmental Research Institute of Michigan's (ERIM) dual-frequency and dual-polarization side-looking SAR system on board a C-46 aircraft. For each frequency, horizontally polarized pulses were transmitted and both horizontally and vertically polarized return signals were recorded on the signal film simultaneously. The test sites were located in St. Charles, Missouri; Centralia, Missouri; and Lafayette, Indiana. Each test site was a 4.83 km by 8.05 km (3 mile by 5 mile) rectangular strip of terrain. Concurrent with SAR overflight, ground soil samples of 0-to-2.5 cm and 0-to-15 cm layers were collected for soil moisture estimation. The surface features were also noted. Hard-copy image films and the digital data produced via optical processing of the signal films are analyzed in this report to study the relationship of radar backscatter to the moisture content and the surface roughness. Many difficulties associated with processing and analysis of the SAR imagery are noted. In particular, major uncertainty in the quantitative analysis appeared due to the difficulty of quality reproduction of digital data from the signal films.

Choudhury, B. J.↗
NASA NTRS1980

Earth radiation budget measurements from satellites and their interpretation for climate modeling and studies

The annual and seasonal averaged Earth atmosphere radiation budgets derived from the most complete set of satellite observations available are presented. The budgets were derived from a composite of 48 monthly mean radiation budget maps. Annually and seasonally averaged radiation budgets are presented as global averages and zonal averages. The geographic distribution of the various radiation budget quantities is described. The annual cycle of the radiation budget was analyzed and the annual variability of net flux was shown to be largely dominated by the regular semi and annual cycles forced by external Earth-Sun geometry variations. Radiative transfer calculations were compared to the observed budget quantities and surface budgets were additionally computed with particular emphasis on discrepancies that exist between the present computations and previous surface budget estimates.

Vonderhaar, T. H.↗