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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 721 records · Page 40
All sourcesNASA NTRSDOE OSTI
DOE OSTI2024

Nano-Plasticity of an Electrified Ionic Liquid/Electrode Interface: Uncovering Hard–Soft Structuring via Controlled Metal Fill Factor

Here, ionic liquids (ILs) nanostructuring at electrified interfaces is of both fundamental and practical interest as these materials are increasingly gaining prominence in energy storage and conversion processes. However, much remains unresolved about IL potential-controlled (re)organization under highly polarized interfaces, mostly due to the difficulty of selectively probing both the distal and proximal surface layers of adsorbed ions. In this work, the structural dynamics of the innermost layer (<10 nm from the surface) were independently interrogated from that of the ionic layers in the sub-surface region (>100 nm from the surface), using an infrared (IR) spectroscopy approach. By tuning the metal fill factor of gold films deposited on conductive metal oxide-modified IR internal reflection elements, the charge-driven (re)structuring of the inner and distal layers of 1-butyl-1-methylpyrrolidinium trifluoromethanesulfonate is unveiled. Within a relatively wide potential region (~±1 V) bounding the potential of zero charges, the ionic liquid is shown to undergo a reversible (i.e., soft) reorganization whereby the innermost layer of anions (cations) is exchanged by a layer of cations (anions). Kinetically unhindered changes in the number density of constituent cations and anions largely follow electrostatic expectations in the subsurface region, whereas the innermost layer exhibits a pronounced hysteresis and very slow relaxation. Under larger negative potential bias, IL restructuring is characterized by a highly irreversible (i.e., hard) and intense interfacial densification of the BMPy + cations, consistent with the formation of nanoscale segregated liquids. The outcomes of this work reveal a plastic IL nanostructuring under a strong electric field.

36 MATERIALS SCIENCE↗
DOE OSTI2023

Giant uniaxial negative thermal expansion in FeZr 2 alloy over a wide temperature range

Negative thermal expansion (NTE) alloys possess great practical merit as thermal offsets for positive thermal expansion due to its metallic properties. However, achieving a large NTE with a wide temperature range remains a great challenge. Herein, a metallic framework-like material FeZr 2 is found to exhibit a giant uniaxial (1D) NTE with a wide temperature range (93-1078 K, $\overline{α}_{l}$=–34.01×10 –6 K –1 ). Such uniaxial NTE is the strongest in all metal-based NTE materials. The direct experimental evidence and DFT calculations reveal that the origin of giant NTE is the couple with phonons, flexible framework-like structure, and soft bonds. Interestingly, the present metallic FeZr 2 excites giant 1D NTE mainly driven by high-frequency optical branches. It is unlike the NTE in traditional framework materials, which are generally dominated by low energy acoustic branches. In the present study, a giant uniaxial NTE alloy is reported, and the complex mechanism has been revealed. It is of great significance for understanding the nature of thermal expansion and guiding the regulation of thermal expansion.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Structural stability of mechanically alloyed amorphous (FeCoNi) 70 Ti 10 B 20 under high-temperature and high-pressure

Nanostructured (FeCoNi) 70 Ti 10 B 20 (at%) alloy was synthesized by mechanical alloying from elemental powder mixture of Fe, Co, Ni, Ti and B using ball milling. The effect of ball milling time on the evolution of structure and morphology was investigated by X-ray diffraction, scanning and transmission electron microscopy and differential thermal analysis. It was observed that the formation of solid solution of (FeCoNi) 70 Ti 10 B 20 started from the very onset of the milling process. Crystallite size and lattice strains seemed to be leveled off after 20 h of milling with no further major changes. The milling process for longer periods introduced severe plastic deformations causing formation of amorphous phase of (FeCoNi) 70 Ti 10 B 20 . The amorphous alloy composition was confirmed by energy dispersive X-ray spectroscopy analysis that showed an excellent homogeneity of the alloying elements. The phase stability of the mechanically alloyed amorphous sample was further verified by employing high-temperature and high-pressure studies. The alloy samples heat-treated at 700 °C revealed crystallization of the amorphous phase. However, synchrotron-based high-pressure ambient temperature X-ray diffraction studies confirmed that the amorphous phase of the alloy remained stable up to the pressure of 30 GPa. Here, the 50 h milled sample after being annealed at 350 °C showed improvement in the soft magnetic properties of the alloy, which was due to the probable elimination of the residual stress in the amorphous phase of the alloy powders.

36 MATERIALS SCIENCE↗
NASA NTRS1993

Comparative study of x ray and microwave emissions during solar flares

The work supported by the grant consisted of two projects. The first project involved making detailed case studies of two flares using SMM data in conjunction with ground based observations. The first flare occurred at 1454 UT on June 20, 1989 and involved the eruption of a prominence near the limb. In the study we used data from many wavelength regimes including the radio, H-alpha, hard X-rays, and soft X-rays. We used a full gyrosynchrotron code to model the apparent presence of a 1.4 GHz source early in the flare that was in the form of a large coronal loop. The model results lead us to conclude that the initial acceleration occurs in small, dense loops which also produced the flare's hard X-ray emission. We also found evidence that a source at 1.4 GHz later in the event was due to second harmonic plasma emission. This source was adjacent to a leg of the prominence and comes from a dense column of material in the magnetic structure supporting the prominence. Finally, we investigated a source of microwaves and soft X-rays, occurring approximately 10 min after the hard X-ray peak, and calculate a lower limit for the density of the source. The second flare that was studied occurred at 2156 UT on June 20, 1989 and was observed with the VLA and the Owens Valley Radio Observatory (OVRO) Frequency Agile Array. We have developed a gyrosynchrotron model of the sources at flare peak using a new gyrosynchrotron approximation which is valid at very low harmonics of the gyrofrequency. We found that the accelerated particle densities of the sources decreased much more with radius from the source center than had been supposed in previous work, while the magnetic field varied less. We also used the available data to analyze a highly polarized source which appeared late in the flare. The second project involved compiling a statistical base for the relative timing of the hard X-ray peak, the turbulent and blue-shift velocities inferred from soft X-ray line emissions observed by SMM and the microwave peak as determined from ground-based observations. This timing was then used to aid the testing of newly developed global models for flares that incorporate the global magnetic topology as well as the electron dynamics that are responsible for the hard X-rays and microwaves.

Winglee, Robert M.↗
NASA NTRS2018

Sample Return Systems for Extreme Environments (SaRSEE)

Sample return missions offer a greater science yield when compared to missions that only employ in situ experiments or remote sensing observations, since they allow the application of more complex technological and analytical methodologies in controlled terrestrial laboratories,that are both repeatable and can be independently verified. The successful return of extraterrestrial materials over the last four decades has contributed to our understanding of the solar system, but retrieval techniques have largely depended on the use of either soft-landing, or touch-and-go procedures that result in high V requirements, larger spacecraft mass ratios, and return yields typically limited to a few grams of surface materials that have experienced varying degrees of alteration from space weathering. Hard-landing methods using planetary penetrators offer an alternative for sample return that significantly reduce a mission's V and mass ratios,increase sample yields, and allow for the collection of subsurface materials, and lessons can be drawn from previous sample return missions. The following details progress in the design,development, and testing of penetrator/sampler technology capable of surviving subsonic and low, supersonic impact velocities (<700 m/s) that would enable the collection of geologic materials using tether technology to return the sample to a passing spacecraft. The testing of energy absorbing material for protecting the sample, design evolution and field testing of the penetrator, and dynamic modeling of tether behavior during sampling are discussed. It is shown through both modeling and field testing that penetrators at speeds between 300-600 m/s (~Mach 1-2) can penetrator into the ground to depths of 1-2 m with overall structural integrity attained.The first flight tests demonstrated the potential for survivability at these speeds. The second flight series demonstrated core sample collection with partial ejection of the sample return canister. The 3rd flight series demonstrated self-ejection of the sample return system fully intact and with the core retaining the full stratigraphy of the rock bed. The tether analysis shows that the forces on the tether during release and return of the sample to the main spacecraft are all at levels that can easily be handled by existing tether materials. The mass analysis of the requirements indicates that sample return form the asteroids could be handled with Discovery or New Frontier range of missions dependent on the number of samples to be returned to the Earth.

Winglee, R. M.↗
NASA NTRS1985

The role of silver in self-lubricating coatings for use at extreme temperatures

The advantages and disadvantages of elemental silver as a tribological material are discussed. It is demonstrated that the relatively high melting point of 961 deg C, softness, marked plasticity, and thermochemical stability of silver combine to make this metal useful in thin film solid lubricant coatings over a wide temperature range. Disadvantages of silver during sliding, except when used as a thin film, are shown to be gross ploughing due to plastic deformation under load with associated high friction and excessive transfer to counterface surfaces. This transfer generates an irregular surface topography with consequent undesirable changes in bearing clearance distribution. Research to overcome these disadvantages of element silver is described. A comparison is made of the tribological behavior of pure silver with that of silver formulated with other metals and high-temperature solid lubricants. The composite materials are prepared by co-depositing the powdered components with an airbrush followed by furnace heat treatment or by plasma-spraying. Composite coatings were formulated which are shown to be self-lubricating over repeated, temperature cycles from low temperature to about 900 deg C.

Sliney, H. E.↗
NASA NTRS1986

The use of silver in self-lubricating coatings for extreme temperatures

The advantages and disadvantages of elemental silver as a tribological material are discussed. It is demonstrated that the relatively high melting point of 961 deg C, softness, marked plasticity, and thermochemical stability of silver combine to make this metal useful in thin film solid lubricant coatings over a wide temperature range. Disadvantages of silver during sliding, except when used as a thin film, are shown to be gross ploughing due to plastic deformation under load with associated high friction and excessive transfer to counterface surfaces. This transfer generates an irregular surface topography with consequent undesirable changes in bearing clearance distribution. Research to overcome these disadvantages of element silver is described. A comparison is made of the tribological behavior of pure silver with that of silver formulated with other metals and high-temperature solid lubricants. The composite materials are prepared by co-depositing the powdered components with an airbrush followed by furnace heat treatment or by plasma-spraying. Composite coatings were formulated which are shown to be self-lubricating over repeated, temperature cycles from low temperature to about 900 deg C.

Sliney, H. E.↗
DOE OSTI2024

Ligand Substituent Effects on the Electronic Properties of Lindqvist‐Type Polyoxometalate Multi‐Level‐Switches in the Gas Phase, Solution and on Surfaces

Abstract Although the intrinsic electronic properties of polyoxometalates (POMs) can be greatly influenced by modifying them with organic substituents, their resistive switching behavior on surfaces dependent on the organic substituents remains largely unexplored. In this work, we assessed the importance of electron‐withdrawing and electron‐donating ligand substituents on the material properties of a series of hybrid Lindqvist‐type hexavanadates TBA 2 [V 6 O 13 ((OCH 2 ) 3 CCH 2 OH) 2 ] (TBA 2 V 6 ‐OH), TBA 2 [V 6 O 13 ((OCH 2 ) 3 CMe) 2 ] (TBA 2 V 6 ‐Me), TBA 2 [V 6 O 13 ((OCH 2 ) 3 CNHCOCH 2 Cl) 2 ] (TBA 2 V 6 ‐Cl), and TBA 2 [V 6 O 13 ((OCH 2 ) 3 CNHCOCH 2 ‐OOCC 10 H 15 ) 2 ] (TBA 2 V 6 ‐Ad) as potential resistive random‐access memory (ReRAM) components. Compared to their redox behavior in solution, changing the ligand substituents on surfaces results in no significant effect on the potential and, thus, no effect on the resistance steps in the current‐voltage profiles. However, while the current‐voltage characteristics do not change, the peripheral metal‐free substituents in the trisalkoxide framework of Lindqvist‐type hexavanadate molecules influence the adsorption and switching stability of these POMs on gold. This work highlights the noticeable differences between hexavanadate's redox properties in solution (which follow the trend observed in the gas phase) and hexavanadate's resistive switching properties on conducting surfaces. Importantly, their multi‐state switching behavior is not significantly altered by the different type of substituent at the periphery of the trisalkoxo ligands.

36 MATERIALS SCIENCE↗
DOE OSTI2026

Molecular Programming of Diorganyl Dichalcogenides for Rational Nanocrystal Design

Soft-chemistry nanocrystal synthesis leverages low-temperature, solution-phase reactions to access materials that can be kinetically stabilized rather than thermodynamically favored. Under such mild conditions, reaction pathways are governed not only by precursor composition but also by the molecular details that dictate how reactive atomic species are generated and delivered. Furthermore, harnessing this kinetic sensitivity offers a powerful opportunity: by deliberately programming precursor reactivity, nanocrystal composition, structure, and morphology can be rationally designed rather than empirically discovered.

Chalcogenides↗
DOE OSTI2025

Generating forces in confinement via polymerization

Understanding how to produce forces using biomolecular building blocks is essential for the development of adaptive synthetic cells and living materials. Here we ask whether a dynamic polymer system can generate deformation forces in soft shells by pure self-assembly, motivated by the fact that biological polymer networks like the cytoskeleton can exert forces, move objects, and deform membranes by simply growing, even in the absence of molecular motors. We address this question by investigating polymer force generation by varying the release rate, the structure, and the interactions of self-assembling monomers. First, we develop a toy computational model of polymerization in a soft elastic shell that reveals the emergence of spontaneous bundling which enhances shell deformation. We then extend our model to account more explicitly for monomer binding dynamics. We find that the rate at which monomers are released into the interior of the shell is a crucial parameter for achieving deformation through polymer growth. Lastly, we demonstrate that the introduction of multivalent particles that can join polymers can either improve or impede polymer performance, depending on the amount and on the structure of the multivalent particles. Our results provide guidance for the experimental realization of polymer systems that can perform work at the nanoscale, for example through rationally designed self-assembling proteins or nucleic acids.

Osmanović, Dino [University of California at Los A↗
DOE OSTI2023

Chemically recyclable polyolefin-like multiblock polymers

Polyolefins are the most important and largest volume plastics produced. Unfortunately, the enormous use of plastics and lack of effective disposal or recycling options have created a plastic waste catastrophe. Here in this work, we report an approach to create chemically recyclable polyolefin-like materials with diverse mechanical properties through the construction of multiblock polymers from hard and soft oligomeric building blocks synthesized with ruthenium-mediated ring-opening metathesis polymerization of cyclooctenes. The multiblock polymers exhibit broad mechanical properties, spanning elastomers to plastomers to thermoplastics, while integrating a high melting transition temperature (T m ) and low glass transition temperature (T g ), making them suitable for use across diverse applications (T m as high as 128°C and T g as low as –60°C). After use, the different plastics can be combined and efficiently deconstructed back to the fundamental hard and soft building blocks for separation and repolymerization to realize a closed-loop recycling process.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1984

Surface analysis of space telescope material specimens

Surface analysis by electron spectroscopy for chemical analysis (ESCA) was used to characterize a number of the material samples for the space telescope. With ESCA, the sample is irradiated with monoenergetic soft X-rays and the resulting emitted electrons are energy analyzed to determine the binding energy of electrons to the surface atoms. The major peaks were used in the quantitative determination of the surface composition. The presence of trace elements (impurities below 1% atomic composition) was also detailed. Initially a survey scan was run for each sample to deduce the elemental composition. Then the major peaks of interest and those of the trace elements were individually examined. After this, the samples were argon sputtered to etch away surface layers, and then additional measurements were carried out in order to obtain depth profile information. In this way it was possible for those species present only on the surface to be distinguished from those having a significant depth distribution within the sample.

Fromhold, A. T.↗
NASA NTRS1986

Evidence for explosive chromospheric evaporation in a solar flare observed with SMM

SMM soft X-ray data and Sacramento Peak Observatory H-alpha observations are combined in a study of the impulsive phase of a solar flare. A blue asymmetry, indicative of upflow motions, was observed in the coronal Ca XIX line during the soft X-ray rise phase. H-alpha redshifts, indicative of downward motions, were observed simultaneously in bright flare kernels during the period of hard X-ray emission. It is shown that, to within observational errors, the impulsive phase momentum transported by the upflowing soft X-ray plasma is equivalent to that of the downward moving chromospheric material.

Zarro, D. M.↗
NASA NTRS1990

Photoelectron energy spectra of opaque photocathodes in the extreme and far ultraviolet

Measurements of the EUV quantum detection efficiency (QDE) of opaque RbBr, CsBr, and KBr photocathodes are described and investigations of their photoemission characteristics over the 44-1560 A wavelength range are reported. The results show that high QDEs can be obtained in the EUV. Narrow QDE peaks at soft X-ray wavelengths occur at slightly different wavelengths for each of the materials studied. The long-wavelength thresholds vary according to the material band gap. Data on the photoemission from the photocathode layer on the microchannel plate interchannel web area are used to determine the number and energy distribution of the emitted photoelelectrons as a function of wavelength.

Siegmund, Oswald H. W.↗
NASA NTRS1990

Ductility enhancement from interface dislocation sources in a directionally solidified beta + gamma + gamma-prime Ni-Fe-Al composite alloy

A directionally solidified beta + gamma + gamma-prime Ni-Fe-Al in situ composite alloy of composition Ni50Fe30Al20 has been used to investigate the effect of a plastically soft second phase on the mechanical behavior of a B2 ordered intermetallic alloy. This material exhibits extensive plasticity during compressive deformation at room temperature and fails in shear with extensive gamma + gamma-prime lamellar or rod pullout. The material also exhibits about 10 percent tensile elongation to fracture at room temperature, with final fracture that includes substantial necking of the gamma + gamma-prime lamellae or rods. Observation of slip lines and dislocation substructures discloses that the normally brittle beta matrix undergoes extensive plasticity in order to deform compatibly with the more ductile gamma phase. The plasticity of the beta matrix is accomplished by the generation of glissile dislocations into the beta matrix from the beta/gamma interface region and is enhanced because of a favorable beta-gamma orientation relationship for slip transfer. Ductility enhancement from interface-generated mobile dislocations generated from beta-gamma interfaces is compared to that observed in film-coated beta-NiAl single crystals and FeAl polycrystals.

Larsen, M.↗
NASA NTRS1993

Pressure-Coupled Acoustic-Transducer Assembly

Improved acoustic-transducer assembly easy to assemble, relocatable, and used at high temperatures. In assembly, piezoelectric acoustic transducer pressure-coupled to delay line or fixture through soft metal like aluminum, copper or gold. Transducer subassembly includes layered structure of coupling material, transducer, thin disk of coupling material acting as cushion for transducer, electrode disk with coaxial cable lead attached, insulation/damping material, and pressure plate. Pressure coupling precludes problem of matching coefficients of thermal expansion of transducer, coupling material, and delay line.

Parker, F. Raymond↗
NASA NTRS2005

Characterization of Ice for Return-to-Flight of the Space Shuttle: Soft Ice - Part 2

In support of characterizing ice debris for return-to-flight (RTF) of NASA's space shuttle, we have determined the microstructure, density and compressive strength (at -10 C at approximately 0.3 per second) of porous or soft ice that was produced from both atmospheric water and consolidated snow. The study showed that the atmospheric material was generally composed of a mixture of very fine (0.1 to 0.3 millimeters) and coarser (5 to 10 millimeter) grains, plus air bubbles distributed preferentially within the more finely-grained part of the microstructure. The snow ice was composed of even finer grains (approximately 0.05 millimeters) and contained more pores. Correspondingly, the snow ice was of lower density than the atmospheric ice and both materials were significantly less dense than hard ice. The atmospheric ice was stronger (approximately 3.8 MPa) than the snow ice (approximately 1.9 MPa), but weaker by a factor of 2 to 5 than pore-free hard ice deformed under the same conditions. Zero Values are given for Young's modulus, compressive strength and Poisson's ratio that can be used for modeling soft ice from the external tank (ET).

Schulson, Erland M.↗