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At least 721 records · Page 40
All sourcesNASA NTRSDOE OSTI
NASA NTRS2005

Rate of Iron Transfer Through the Horse Spleen Ferritin Shell Determined by the Rate of Formation of Prussian Blue and Fe-desferrioxamine Within the Ferritin Cavity

Iron (2+ and 3+) is believed to transfer through the three-fold channels in the ferritin shell during iron deposition and release in animal ferritins. However, the rate of iron transit in and out through these channels has not been reported. The recent synthesis of [Fe(CN)(sub 6)](3-), Prussian Blue (PB) and desferrioxamine (DES) all trapped within the horse spleen ferritin (HoSF) interior makes these measurements feasible. We report the rate of Fe(2+) penetrating into the ferritin interior by adding external Fe(2+) to [Fe(CN)(sub 6)](3-) encapsulated in the HoSF interior and measuring the rate of formation of the resulting encapsulated PB. The rate at which Fe(2+) reacts with [Fe(CN)(sub 6)](3-) in the HoSF interior is much slower than the formation of free PB in solution and is proceeded by a lag period. We assume this lag period and the difference in rate represent the transfer of Fe(2+) through the HoSF protein shell. The calculated diffusion coefficient, D approx. 5.8 x 10(exp -20) square meters per second corresponds to the measured lag time of 10-20 s before PB forms within the HoSF interior. The activation energy for Fe(2+) transfer from the outside solution through the protein shell was determined to be 52.9 kJ/mol by conducting the reactions at 10 to approximately 40 C. The reaction of Fe(3+) with encapsulated [Fe(CN)6](4-) also readily forms PB in the HoSF interior, but the rate is faster than the corresponding Fe(2+) reaction. The rate for Fe(3+) transfer through the ferritin shell was confirmed by measuring the rate of the formation of Fe-DES inside HoSF and an activation energy of 58.4 kJ/mol was determined. An attempt was made to determine the rate of iron (2+ and 3+) transit out from the ferritin interior by adding excess bipyridine or DES to PB trapped within the HoSF interior. However, the reactions are slow and occur at almost identical rates for free and HoSF-encapsulated PB, indicating that the transfer of iron from the interior through the protein shell is faster than the rate-limiting step of PB dissociation. The method described in this work presents a novel way of determining the rate of transfer of iron and possibly other small molecules through the ferritin shell.

Zhang, Bo↗
NASA NTRS1996

Protoplanetary Formation and the FU Orionis Outburst

The following three publications which reference the above grant from the NASA Origins of Solar Systems program are attached and form the final technical report for this project. The research involved comparisons of the spectral energy distributions of FU Orionis objects with theoretical models and associated studies of the structure of the outbursting accretion disks, as well as related studies on the effects of magnetic fields in disks, which will lead in the future to models of FU Orionis outbursts which include the effects of magnetic fields. The project was renewed under a new grant NAGW-4456, entitled 'Effects of FU Orionis Outbursts on Protoplanetary Disks'. Work now being prepared for publication deals more specifically with the issue of the effects of the outbursts on protoplanetary formation. Models of the spectral energy distribution of FU Orionis stars. A simple model of a buoyant magnetic dynamo in accretion disks and a numerical study of magnetic buoyancy in an accretion disk have been submitted.

Bodenheimer, P. H.↗
NASA NTRS2019

Two-Stage Autoignition Dynamics of N-Dodecane Droplets Under Normal Gravity at High Pressures

Experimental observations of two-stage, autoignition characteristics of fiber-supported, n-dodecane fuel droplets under normal gravity are reported for a wide range of ambient temperatures, and pressures varying from 1 atm to 25 atm, which encompasses the fuel critical pressure (~ 18 atm). A high-speed camera is used to obtain backlit images of the autoignition process. During two-stage ignition, a cool-flame front forms below the droplet in the natural convective plume of the fuel vapor originating from the vaporizing droplet, and propagates upward, followed by the formation of a hot-flame kernel that expands rapidly and surrounds the droplet, eventually leading to the classical diffusion flame. Experimentally measured cool, and hot flame formation locations and propagation speeds are presented for varying initial temperatures and pressures. Measured first, and second stage ignition delay times are also reported. The influences of negative temperature coefficient (NTC) regime chemistry on flame starting location, propagation speeds, and ignition delay times are described. The first-stage cool flame characteristics are found to be controlled by both the chemistry, and physical aspects such as droplet evaporation and fuel-oxidizer mixing, while the second-stage hot flame ignition is primarily controlled by chemical kinetics. Further work is currently underway to develop models to quantitatively predict the observed behavior.

Rose, Evan↗
NASA NTRS1992

Dehydration kinetics and thermochemistry of selected hydrous phases, and simulated gas release pattern in carbonaceous chondrites

As part of our continued program of study on the volatile bearing phases and volatile resource potential of carbonaceous chondrite, results of our experimental studies on the dehydration kinetics of talc as a function of temperature and grain size (50 to 0.5 microns), equilibrium dehydration boundary of talc to 40 kbars, calorimetric study of enthalpy of formation of both natural and synthetic talc as a function of grain size, and preliminary results on the dehydration kinetics of epsomite are reported. In addition, theoretical calculations on the gas release pattern of Murchison meteorite, which is a C2(CM) carbonaceous chondrite, were performed. The kinetic study of talc leads to a dehydration rate constant for 40-50 microns size fraction of k = (3.23 x 10(exp 4))exp(-Q/RT)/min with the activation energy Q = 376 (plus or minus 20) kJ/mole. The dehydration rate was found to increase somewhat with decreasing grain size. The enthalpy of formation of talc from elements was measured to be -5896(10) kJ/mol. There was no measurable effect of grain size on the enthalpy beyond the limits of precision of the calorimetric studies. Also the calorimetric enthalpy of both synthetic and natural talc was found to be essentially the same, within the precision of measurements, although the natural talc had a slightly larger field of stability in our phase equilibrium studies. The high pressure experimental data the dehydration equilibrium of talc (talc = enstatite + coesite + H2O) is in strong disagreement with that calculated from the available thermochemical data, which were constrained to fit the low pressure experimental results. The calculated gas release pattern of Murchison meteorite were in reasonable agreement with that determined by stepwise heating in a gas chromatograph.

Bose, Kunal↗
NASA NTRS2008

Enigmatic Isovaline: Investigating the Stability, Racemization, and Formation of a Non-biological Meteoritic Amino Acid

Among the Murchison meteoritic amino acids, isovaline stands out as being both nonbiological (non-protein) and having a relatively high abundance. While approximately equal amounts of D- and L-isovaline have been reported in Murchison and other CM meteorites, the molecule's structure appears to prohibit its racemization in aqueous solutions. We recently have investigated the low-temperature solid-phase chemistry of both isovaline and valine with an eye toward each molecule's formation, stability, and possible interconversions of D and L enantiomers. Ion-irradiated isovaline- and valinecontaining ices were examined by IR spectroscopy and highly-sensitive liquid chromatography/time-of-flight mass spectral methods to assess both amino acid destruction and racemization. Samples were studied in the presence and in the absence of water-ice, and the destruction of both isovaline and valine was measured as a function of radiation dose. In addition, we have undertaken experiments to synthesize isovaline, valine, and their amino acid isomers by solid-phase radiation-chemical pathways other than the oft-invoked Strecker process. This presentation will review and summarize some of our recent findings. -- Our work has been supported by a grant to the Goddard Center for Astrobiology through the NASA Astrobiology Institute. Experiments were performed in the Cosmic Ice Laboratory (RLH, MHM, AL) and the Astrobiology Analytical Laboratory (JPD, DPG) at the NASA Goddard Space Flight Center.

Hudson, Reggie↗
NASA NTRS1995

Setting priorities for space research: An experiment in methodology

In 1989, the Space Studies Board created the Task Group on Priorities in Space Research to determine whether scientists should take a role in recommending priorities for long-term space research initiatives and, if so, to analyze the priority-setting problem in this context and develop a method by which such priorities could be established. After answering the first question in the affirmative in a previous report, the task group set out to accomplish the second task. The basic assumption in developing a priority-setting process is that a reasoned and structured approach for ordering competing initiatives will yield better results than other ways of proceeding. The task group proceeded from the principle that the central criterion for evaluating a research initiative must be its scientific merit -- the value of the initiative to the proposing discipline and to science generally. The group developed a two-stage methodology for priority setting and constructed a procedure and format to support the methodology. The first of two instruments developed was a standard format for structuring proposals for space research initiatives. The second instrument was a formal, semiquantitative appraisal procedure for evaluating competing proposals. This report makes available complete templates for the methodology, including the advocacy statement and evaluation forms, as well as an 11-step schema for a priority-setting process. From the beginning of its work, the task group was mindful that the issue of priority setting increasingly pervades all of federally supported science and that its work would have implications extending beyond space research. Thus, although the present report makes no recommendations for action by NASA or other government agencies, it provides the results of the task group's work for the use of others who may study priority-setting procedures or take up the challenge of implementing them in the future.

Source record↗
NASA NTRS1973

Evaluate the application of ERTS-A data for detecting and mapping sea ice

The author has identified the following significant results. The results of the analysis of data collected during the spring and summer demonstrate that ERTS-1 imagery has a high potential for monitoring arctic sea ice conditions during the time for maximum ice extent through ice-breakup season. In the eastern Beaufort Sea area, the combination of ERTS-1 orbital overlap and a high incidence of cloud-free conditions during the spring assures a high frequency of repetitive satellite coverage. In the mid-Beaufort Sea, numerous fractures and leads can be identified, even in the early spring data. Ice features that can be identified include: development of fractures leading to the formation of distinct ice floes; growth and deterioration of leads; evidence of shearing movements of ice masses; formation of new grey ice within leads; distinction between grey, grey-white, and older forms of ice; and the deterioration of the ice surface evidenced by the formation of puddles, thaw holes, and drainage patterns. Ice conditions in the Bering Sea near St. Lawrence Island reported by aircraft observers participating in the Bering Sea Expedition are in close agreement with the ice conditions mapped from the corresponding ERTS-1 imagery. Ice features identified were: boundaries between grey ice and first year ice, shear leads, and occurrence of open water.

Barnes, J. C.↗
NASA NTRS1988

Research On The CH-47B Helicopter

Report describes equipment added to, and research capabilities of CH-47B helicopter. Programmable symbol generator provides display formats for variety of missions - those of vertical-takeoff-and-landing aircraft and helicopters. Powerful general-purpose flight computer in operation. Computer programmable in high-level languages and supports research more efficiently. Flight-control software developed to improve capability of helicopter to perform simulations in flight.

Hilbert, Kathryn B.↗
NASA NTRS1990

Role of photocurrent in low-temperature photoemission studies of Schottky-barrier formation

Photoelectron spectroscopy is frequently used to study band bending in semiconductors due to charge stored in surface or interface states. This paper examines how such experimental results are modified by photovoltages generated within the band-bending region not only by ambient light sources, but by the incident X-rays themselves. Recent experiments which have suggested dopant-dependent and reversible temperature-dependent band bending in the initial stages of formation of the metal-GaAs(110) interface are used as an example. It is shown that the reported dependence derives from a photovoltaic effect.

Hecht, M. H.↗
NASA NTRS1991

Chromite and olivine in type II chondrules in carbonaceous and ordinary chondrites - Implications for thermal histories and group differences

Unequilibrated chromite and olivine margin compositions in type II chondrules are noted to differ systematically among three of the chondrite groups, suggesting that type II liquids differed in composition among the groups. These differences may be interpreted as indicators of different chemical compositions of the precursor solids which underwent melting, or, perhaps, as differences in the extent to which immiscible metal sulfide droplets were lost during chondrule formation. Because zinc is detectable only in type II chromites which have undergone reequilibration, the high zinc contents reported for chondritic chromites in other studies probably reflect redistribution during thermal metamorphism.

Johnson, Craig A.↗
NASA NTRS1992

Structure in gamma ray burst time profiles: Statistical Analysis 1

Since its launch on April 5, 1991, the Burst And Transient Source Experiment (BATSE) has observed and recorded over 500 gamma-ray bursts (GRB). The analysis of the time profiles of these bursts has proven to be difficult. Attempts to find periodicities through Fourier analysis have been fruitless except one celebrated case. Our goal is to be able to qualify the observed time-profiles structure. Before applying this formation to bursts, we have tested it on profiles composed of random Poissonian noise. This paper is a report of those preliminary results.

Lestrade, John Patrick↗
NASA NTRS1993

The hydrodynamics of galaxy formation on Kiloparsec scales

Two dimensional numerical simulations of Zeldovich pancake fragmentation in a dark matter dominated universe were carried out to study the hydrodynamical and gravitational effects on the formation of structures such as protogalaxies. Preliminary results were given in Yuan, Centrella and, Norman (1991). Here we report a more exhaustive study to determine the sensitivity of protogalaxies to input parameters. The numerical code we used for the simulations combines the hydrodynamical code ZEUS-2D (Stone and Norman, 1992) which was modified to include the expansion of the universe and radiative cooling of the gas with a particle-mesh code which follows the motion of dark matter particles. The resulting hybrid code is able to handle highly nonuniform grids which we utilized to obtain a high resolution (much greater than 1 kpc) in the dense region of the pancake.

Norman, Michael L.↗
NASA NTRS1994

Shocked materials from the Dutch Peak diamictite, Utah

Evidence of shock metamorphism in the Dutch Peak diamictite in the Sheeprock Mountains, Utah, is reported. The Dutch Peak diamictite is of Proterozoic age and is a minor part of the Dutch Peak formation. A shocked sample, specimen A250, was collected during a brief visit of the Harker Canyon area of the Sheeprock Mountains. This sample consists of equant, anhedral grains of quartz, K-feldspar, and plagioclase. The crystallographic orientation of 244 lamellae systems in 106 grains was measured. It is presently difficult to evaluate the significance of this single specimen. Without additional and substantial field work, and petrographic characterization of this formation, a number of scenarios for the presence of a shocked clast and the emplacement of the entire formation remain viable.

Hoerz, F.↗
NASA NTRS1993

Occurrence and possible significance of rare Ti oxides (Magneli phases) in carbonaceous chondrite matrices

Rare, ultrafine-grained Ti oxides (Ti3O5 and the Magneli phases, Ti5O9 and Ti8O15) have been identified by TEM in the CM2 carbonaceous chondrite, Bells, and a carbonaceous chondrite matrix clast from the Nilpena polymict ureilite. In both meteorites the Ti oxides occur in the matrix as isolated grains and clusters of two or more grains. They are euhedral in shape and have grain sizes of 0.05-0.3 micron. Magneli phases have been recently shown to be a common component in some interplanetary dust particles, but this is the first reported occurrence in a meteorite. The morphological properties and grain size of the Ti oxides are consistent with formation by vapor phase condensation either within the solar nebula or possibly in a presolar environment.

Brearley, Adrian J.↗
NASA NTRS1994

TBell: A mathematical tool for analyzing decision tables

This paper describes the development of mathematical theory and software to analyze specifications that are developed using decision tables. A decision table is a tabular format for specifying a complex set of rules that chooses one of a number of alternative actions. The report also describes a prototype tool, called TBell, that automates certain types of analysis.

Hoover, D. N.↗
NASA NTRS1997

Application of High Resolution Topography and Remote Sensing: Imagery to the Kinematics of Fold-and-Thrust Belts

This report summarizes one year of funding for NASA contract NAGW-3691, Application of High Resolution Topography and Remote Sensing: Imagery to the Kinematics of Fold-and-Thrust Belts. I never received year three from NASA. The funds were to support on going tectonic and topographic studies along the front of the central Transverse Ranges and expand the topographic studies to the north. Below are results from the first two years of actual funds that I received from NASA (see attached Federal Cash Transaction Reports). The main focus of this contract was to define and understand the major tectonic processes affecting the formation and evolution of the topography in convergent tectonic settings. The results will be used to test ongoing space-based geodetic measurements and will be compared with present-day seismicity in the central Transverse Ranges and adjacent basins. Two major factors that controls topography in active regions are (1) tectonic uplift due to fault-normal compression and (2) subsequent erosion. The central Transverse and Temblor Ranges are excellent regions for these focused topographic studies. The tectonic processes leading to the mountain building are relatively straightforward and thus are easy to model. Available evidence suggests that the topography in this region is relatively young, - 3.5 Ma or less. In addition,, erosional processes may be relatively easier to model compared to larger and more ancient mountain belts. For example, in larger mountain belts, topographic relief may cause significant orographic effects and high elevation may result in part of the topography located above snowline. Both factors complicate interpretation of erosional processes that may be controlled by elevation. Mountain ranges that are significantly older may have experienced a much wider variety of erosional or climatic conditions over their lifetime. While erosion rates have certainly not been consistent in the Transverse or Temblor ranges over its 3.5 Ma lifetime, we are sure that the region was spared the Pleistocene glaciation that affected parts of the Sierra Nevada Range.

Rubin, Charles↗
NASA NTRS1960

Effects of Sweep Angle on the Boundary-Layer Stability Characteristics of an Untapered Wing at Low Speeds

An investigation was conducted in the Ames 12-Foot Low-Turbulence Pressure Tunnel to determine the effects of sweep on the boundary-layer stability characteristics of an untapered variable-sweep wing having an NACA 64(2)A015 section normal to the leading edge. Pressure distribution and transition were measured on the wing at low speeds at sweep angles of 0, 10, 20, 30, 40, and 50 deg. and at angles of attack from -3 to 3 deg. The investigation also included flow-visualization studies on the surface at sweep angles from 0 to 50 deg. and total pressure surveys in the boundary layer at a sweep angle of 30 deg. for angles of attack from -12 to 0 deg. It was found that sweep caused premature transition on the wing under certain conditions. This effect resulted from the formation of vortices in the boundary layer when a critical combination of sweep angle, pressure gradient, and stream Reynolds number was attained. A useful parameter in indicating the combined effect of these flow variables on vortex formation and on beginning transition is the crossflow Reynolds number. The critical values of crossflow Reynolds number for vortex formation found in this investigation range from about 135 to 190 and are in good agreement with those reported in previous investigations. The values of crossflow Reynolds number for beginning transitions were found to be between 190 and 260. For each condition (i.e., development of vortices and initiation of transition at a given location) the lower values in the specified ranges were obtained with a light coating of flow-visualization material on the surface. A method is presented for the rapid computation of crossflow Reynolds number on any swept surface for which the pressure distribution is known. From calculations based on this method, it was found that the maximum values of crossflow Reynolds number are attained under conditions of a strong pressure gradient and at a sweep angle of about 50 deg. Due to the primary dependence on pressure gradient, effects of sweep in causing premature transition are generally first encountered on the lower surfaces of wings operating at positive angles of attack.

Boltz, Frederick W.↗