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A review of recent theoretical studies of gas-phase molecular rate processes, including various effects of laser radiation, is presented in the context of the extensive and influential work of Joseph O. Hirschfelder during the past half-century. The topics addressed are energy transfer, chemical reactions, unimolecular dissociation, transition states, and bound-continuum interactions.
The presence of narrow, shifted absorption features superposed on the wide P Cygni profiles of the UV resonance lines in the spectra of O and B stars is studied and possible explanations of the narrow components are discussed. Spectra from 26 stars of spectral types O4f to B1 Ib were examined for the presence of narrow components in the absorption part of the profiles, and positive evidence was detected in 17. The central velocities of the features are found to be similar for different ions of the same star, and typically equal to 0.75 times the terminal velocity of the stellar wind. The width of the narrow absorptions is about 18% of the terminal stellar wind velocity, with a column density generally not correlated with the effective temperature or mass loss rate. Possible explanations for the narrow components include peaks in the degree of ionization, a stationary stellar shell, a plateau in the stellar wind velocity law, a decelerating stellar wind, a variable mass loss rate or a two component stellar wind with low-velocity, low-density material found at a distance greater than 2 stellar radii, which explanation appears most likely.
Several examples are presented to illustrate the behavior of the 989- to 7990-A complex. For the most part, these are chosen to correspond to particular observations of the airglow and aurora. In particular, the 989-A dayglow is computed for comparison with the data of Gentieu et al. (1979). In addition, line ratios are provided for comparison with the high-resolution data reported by Christensen et al. (1982). Several examples of auroral phenomena, including expected emissions from the dayside cleft region, are adduced, and the implications of high-resolution observations of line ratios and selective absorption by N2 are addressed. Finally, the utility of 989- to 7990-A multiplets as diagnostics of the atmospheric O I abundance is studied.
Spectral classifications in the two-dimensional system are given for 53 additional O stars in the southern hemisphere. A number of these stars are members of the interesting clusters NGC 3324, Trumpler 14/16, NGC 3603, and NGC 6334, which are discussed in particular. A 4-m H-alpha photograph of the remarkable nebulosities associated with NGC 6334 is reproduced.
Numerous radial velocity measurements of medium dispersion were made for the 10 brighter stars given in Stone's list of very probable O type runaways. All plates were measured with the KPNO PDS microdensitometer, and a new iterative reductional analysis was used to derive plate velocities, which are estimated to be 1.6 times more accurate internally than those found by using the traditional method. Of thse stars, psi Per, alpha Cam, HD 188209, and 26 Cep are identified as probable velocity variables, while 9 Sge, lambda Cep, and HD 218915 are classed as possible variables. If the source of this variability is Keplerian rather than atmospheric, which cannot be established unequivocally from the observations of this paper, psi Per could be a spectroscopic binary with a black hole companion, and at least 1.2 solar mass. The detection of runaway binary systems from radial velocity measurements is discussed.
The reported chemical fractionation of a single isotope O-16 under simulated space conditions provides the first experimental proof for the hypothesis that the oxygen isotopic anomaly (and other similar anomalies) seen in meteorites is a product of chemical fractionation in interstellar or circumstellar space. Work proposed on this subject was discontinued because a peer review determined that such effects could not possibly exist and that continued support of this project would be a wasted effort. A bibliography is included of articles generated during research in this area.
Twelve very hot O-type subdwarfs were observed with the IUE-satellite in the low dispersion mode. Temperatures were derived from the slopes of the UV continua and distances were estimated from the color excesses. Most of them are hotter than 60,000 K, i.e., they are the hottest known subdwarfs. From their spectral appearance and location in a H.R.-diagram they form a rather inhomogeneous group. Three of them turned out to be central stars or nearly central stars, and four are definitely near the white dwarf stage. The surface helium to hydrogen ratio varies from about normal to the extreme case. Most of them appear to be post EHB objectives of 0.5 solar mass with a helium burning shell as their energy source, and their peculiar helium-to-hydrogen ratios are most likely the result of diffusion and convective mixing in surface layers.
Tests were conducted on the Mod-O 100 kW experimental wind turbine to provide data on yaw alignment characteristics of a large horizontal axis wind turbine with its yaw restraint removed (i.e., in free yaw). The wind turbine consisted of a downwind horizontal axis rotor mounted on a tubular tower. Three rotor configurations were tested. Each rotor was teetered, coned 3 deg and tip-controlled. Two of the rotors had pitch-flap coupling or Delta-3, and one rotor had none. The two rotors with Delta-3 differed in the airfoil used in the tip sections. Test results indicate the rotor without pitch-flap coupling did not align closer than 25 deg with the wind, and pitch-flap coupling improved the wind turbine's alignment with the wind. Yaw damping was shown to have a favorable effect on free yaw characteristics. The change in the tip airfoil section was shown to affect the free yaw alignment also. The rotors with Delta-3 were shown to be capable of responding to wind shifts and exhibited stable operating properties.
The discharge-flow resonance fluorescence technique has been used to obtain absolute rate data for the O + HO2 reaction from 229 to 372 K at a total pressure of 1 torr. Pseudo-first-order conditions were used with HO2 concentrations in large excess over initial atomic oxygen in order to minimize interference from secondary reactions. The results are independent of the method used to generate HO2 and atomic oxygen. At 299 K, the result is (6.1 + or - 0.4) x 10 to the -11th cu cm/molecule s. The temperature dependence expressed in Arrhenius form is (3.1 + or - 0.3) x 10 to the -11th exp/(+200 + or - 28)/T/. The error limits given are twice the standard deviation; overall experimental error is estimated to be + or - 25%.
The results of a survey of 50 O stars in the J, H, K, L, and M bands are described. The observations are described, and the fitting of reddening relations to them is discussed. The zero points in the reddening relations are related to the intrinsic colors of the samples of normal stars, and these are compared with theoretical colors. The comparison reveals anomalies at L and M, which are discussed. The residuals for an individual star from the reddening relations are a measure of its infrared excesses, if indeed it has any. How the excesses can be fitted to a stellar wind model to derive a parameter that involves the rate of mass loss in the wind, the stellar radius and temperature, and wind terminal velocity is considered. The results for a number of individual stars are discussed and compared with other mass loss measurements, and it is concluded that no single model is capable of reconciling the IR, UV, radio, and H-alpha observations for the stars.
A first set of observations of the forbidden O I 3P0-3P1 (145.5 micron) transition has been obtained. The line was observed both in a 1 x 1 arcmin beam centered on the Trapezium and in a 7 x 7 arcmin beam encompassing most of the Orion Nebula; a wide-beam (7 x 7 arcmin) map of the region has also been constructed which shows that most of the emission is confined to the central regions of the nebula. These observations are consistent with optically thin emission in the 145.5 micron line and self-absorbed 63.2 micron emission lines. Mechanisms for the excitation of neutral oxygen are considered, and it is concluded that much of the observed emission originates in the thin radio recombination line-emitting C II/H I envelope bordering on the H II region.
The noise of a MOD-O wind turbine generator rotor equipped with plain and balanced partial span ailerons for lift and drag control was measured. Data were obtained for a wide range of aileron deflection angles and for limited ranges of wind velocity and power output. Noise levels increased as deflection angles increased and were higher in the upwind than in the downwind direction. The plain aileron exhibited a howling noise in the frequency range 400-800 Hz at deflection angles for which flow induced cavity resonances were significant.
A nonlinear least-squares fitting procedure has been used to derive absolute intensities for lines in the P, R, and Q branches of the (11/1/0)II-00/0/0 band of (C-12)(O-16)2 (band center = 1932/cm) from long-path 0.01/cm resolution laboratory spectra. The spectral data were recorded at room temperature and low pressure (less than 10 torr) with the Fourier transform spectrometer in the McMath solar telescope complex at Kitt Peak National Observatory. The observed line intensities were analyzed to derive the vibrational band intensity and F-factor coefficients. To obtain a good fit to the data, it was necessary to include terms in the expression for the F factor, which account for Coriolis-type and Fermi-type interactions and centrifugal distortion effects.
Molecular oxygen, O2, is predicted to be an important constituent of the interstellar gas, but it has not yet been detected in interstellar clouds. In this paper, the gas phase production and destruction of O2 are reconsidered, a non-LTE calculation of level populations at cloud temperatures is presented, and O2 column densities in diffuse and dark clouds are predicted. Ground-based detection of the 234 GHz line of O-16O-18 is shown to be feasible; if CO and O2 are comparable in abundance in clouds similar to the Taurus molecular cloud or in giant molecular clouds, the brightness temperature is predicted to be 0.1 K.
Twelve very hot O-type subdwarfs were observed with the IUE-satellite in the low dispersion mode. Temperatures were derived from the slopes of the UV continua and distances were estimated from the color excesses. Most of them are hotter than 60,000 K, i.e., they are the hottest known subdwarfs. From their spectral appearance and location in a H.R.-diagram, they form a rather inhomogeneous group. Three of them turned out to be central stars or nearly central stars, and four are definitely near the white dwarf stage. The surface helium to hydrogen ratio varies from about normal to the extreme case. Most of them appear to be post EHB objectives of 0.5 solar mass with a helium burning shell as their energy source, and their peculiar helium-to-hydrogen ratios are most likely the result of diffusion and convective mixing in surface layers. Previously announced in STAR as N83-23254
An ab initio study of hydrogen atom migration in methylenebis(oxy)H2CO2(3B2) to form triplet formic acid HCOOH (3A1) is reported. From HF, MCHF, and CI calculated energy barriers, the activation energy is estimated to be no less than 30 kcal/mol. It is concluded that the hydrogen migration channel is not accessible in recent room temperature experiments on the O(3P) + H2CO reaction.
The radiative lifetime of the 5S(0)2 metastable level of O(2+) was measured as 1.22 + or - 0.08 ms at the 90 percent confidence level by observing the time dependence of the spontaneous emission from metastable ions created and stored in a cylindrical radio-frequency ion trap. The intersystem line emission 2s(2)2p(2) 3P - 2s2p(3) 5S(0) was observed at 1660.8 and 1666.2 A. Discrepancies between measured and calculated values indicate that certain calculated transition probabilities for intersystem lines may be less reliable than previously believed.
The essential features of the potential energy surfaces governing hydrogen abstraction from formaldehyde by oxygen atom and hydroxyl radical have been characterized with ab inito multiconfiguration Hartree-Fock (MCHF) and configuration interaction (CI) wave functions. The results are consistent with a very small activation energy for the OH + H2CO reaction, and an activation energy of a few kcal/mol for the O + H2CO reaction. In the transition state structure of both systems, the attacking oxygen atom is nearly collinear with the attacked CH bond.