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Personal Interventions for Reducing Exposure and Risk for Outdoor Air Pollution: An Official American Thoracic Society Workshop Report

Poor air quality affects the health and wellbeing of large populations around the globe. Although source controls are the most effective approaches for improving air quality and reducing health risks, individuals can also take actions to reduce their personal exposure by staying indoors, reducing physical activity, altering modes of transportation, filtering indoor air, and using respirators and other types of face masks. A synthesis of available evidence on the efficacy, effectiveness, and potential adverse effects or unintended consequences of personal interventions for air pollution is needed by clinicians to assist patients and the public in making informed decisions about use of these interventions. To address this need, the American Thoracic Society convened a workshop in May of 2018 to bring together a multidisciplinary group of international experts to review the current state of knowledge about personal interventions for air pollution and important considerations when helping patients and the general public to make decisions about how best to protect themselves. From these discussions, recommendations were made regarding when, where, how, and for whom to consider personal interventions. In addition to the efficacy and safety of the various interventions, the committee considered evidence regarding the identification of patients at greatest risk, the reliability of air quality indices, the communication challenges, and the ethical and equity considerations that arise when discussing personal interventions to reduce exposure and risk from outdoor air pollution.

63 RADIATION, THERMAL, AND OTHER ENVIRON. POLLUTAN↗

Overview of the MOSAiC expedition: Snow and sea ice

Year-round observations of the physical snow and ice properties and processes that govern the ice pack evolution and its interaction with the atmosphere and the ocean were conducted during the Multidisciplinary drifting Observatory for the Study of Arctic Climate (MOSAiC) expedition of the research vessel Polarstern in the Arctic Ocean from October 2019 to September 2020. This work was embedded into the interdisciplinary design of the 5 MOSAiC teams, studying the atmosphere, the sea ice, the ocean, the ecosystem, and biogeochemical processes. The overall aim of the snow and sea ice observations during MOSAiC was to characterize the physical properties of the snow and ice cover comprehensively in the central Arctic over an entire annual cycle. This objective was achieved by detailed observations of physical properties and of energy and mass balance of snow and ice. By studying snow and sea ice dynamics over nested spatial scales from centimeters to tens of kilometers, the variability across scales can be considered. On-ice observations of in situ and remote sensing properties of the different surface types over all seasons will help to improve numerical process and climate models and to establish and validate novel satellite remote sensing methods; the linkages to accompanying airborne measurements, satellite observations, and results of numerical models are discussed. We found large spatial variabilities of snow metamorphism and thermal regimes impacting sea ice growth. We conclude that the highly variable snow cover needs to be considered in more detail (in observations, remote sensing, and models) to better understand snow-related feedback processes. The ice pack revealed rapid transformations and motions along the drift in all seasons. The number of coupled ice–ocean interface processes observed in detail are expected to guide upcoming research with respect to the changing Arctic sea ice.

54 ENVIRONMENTAL SCIENCES↗

Insights on sources and formation mechanisms of liquid-bearing clouds over MOSAiC examined from a Lagrangian framework

Understanding Arctic stratiform liquid-bearing cloud life cycles and properly representing these life cycles in models is crucial for evaluations of cloud feedbacks as well as the faithfulness of climate projections for this rapidly warming region. Examination of cloud life cycles typically requires analyses of cloud evolution and origins on short time scales, on the order of hours to several days. Measurements from the recent Multidisciplinary drifting Observatory for the Study of Arctic Climate (MOSAiC) expedition provide a unique view of the current state of the central Arctic over an annual cycle. Here, we use the MOSAiC radiosonde measurements to detect liquid-bearing cloud layers over full atmospheric columns and to examine the cloud-generating air masses’ properties. We perform 5-day (120 h) back-trajectory calculations for every detected cloud and cluster them using a unique set of variables extracted from these trajectories informed by ERA5 reanalysis data. This clustering method enables us to separate between the air mass source regions such as ice-covered Arctic and midlatitude open water. We find that moisture intrusions into the central Arctic typically result in multilayer liquid-bearing cloud structures and that more than half of multilayer profiles include overlying liquid-bearing clouds originating in different types of air masses. Finally, we conclude that Arctic cloud formation via prolonged radiative cooling of elevated stable subsaturated air masses circulating over the Arctic can occur frequently (up to 20% of detected clouds in the sounding data set) and may lead to a significant impact of ensuing clouds on the surface energy budget, including net surface warming in some cases.

54 ENVIRONMENTAL SCIENCES↗

Spatiotemporal evolution of melt ponds on Arctic sea ice

Melt ponds on sea ice play an important role in the Arctic climate system. Their presence alters the partitioning of solar radiation: decreasing reflection, increasing absorption and transmission to the ice and ocean, and enhancing melt. The spatiotemporal properties of melt ponds thus modify ice albedo feedbacks and the mass balance of Arctic sea ice. The Multidisciplinary drifting Observatory for the Study of Arctic Climate (MOSAiC) expedition presented a valuable opportunity to investigate the seasonal evolution of melt ponds through a rich array of atmosphere-ice-ocean measurements across spatial and temporal scales. In this study, we characterize the seasonal behavior and variability in the snow, surface scattering layer, and melt ponds from spring melt to autumn freeze-up using in situ surveys and auxiliary observations. We compare the results to satellite retrievals and output from two models: the Community Earth System Model (CESM2) and the Marginal Ice Zone Modeling and Assimilation System (MIZMAS). During the melt season, the maximum pond coverage and depth were 21% and 22 ± 13 cm, respectively, with distribution and depth corresponding to surface roughness and ice thickness. Compared to observations, both models overestimate melt pond coverage in summer, with maximum values of approximately 41% (MIZMAS) and 51% (CESM2). This overestimation has important implications for accurately simulating albedo feedbacks. During the observed freeze-up, weather events, including rain on snow, caused high-frequency variability in snow depth, while pond coverage and depth remained relatively constant until continuous freezing ensued. Both models accurately simulate the abrupt cessation of melt ponds during freeze-up, but the dates of freeze-up differ. MIZMAS accurately simulates the observed date of freeze-up, while CESM2 simulates freeze-up one-to-two weeks earlier. This work demonstrates areas that warrant future observation-model synthesis for improving the representation of sea-ice processes and properties, which can aid accurate simulations of albedo feedbacks in a warming climate.

54 ENVIRONMENTAL SCIENCES↗

Arctic sea ice albedo: Spectral composition, spatial heterogeneity, and temporal evolution observed during the MOSAiC drift

The magnitude, spectral composition, and variability of the Arctic sea ice surface albedo are key to understanding and numerically simulating Earth’s shortwave energy budget. Spectral and broadband albedos of Arctic sea ice were spatially and temporally sampled by on-ice observers along individual survey lines throughout the sunlit season (April–September, 2020) during the Multidisciplinary drifting Observatory for the Study of Arctic Climate (MOSAiC) expedition. The seasonal evolution of albedo for the MOSAiC year was constructed from spatially averaged broadband albedo values for each line. Specific locations were identified as representative of individual ice surface types, including accumulated dry snow, melting snow, bare and melting ice, melting and refreezing ponded ice, and sediment-laden ice. The area-averaged seasonal progression of total albedo recorded during MOSAiC showed remarkable similarity to that recorded 22 years prior on multiyear sea ice during the Surface Heat Budget of the Arctic Ocean (SHEBA) expedition. In accord with these and other previous field efforts, the spectral albedo of relatively thick, snow-free, melting sea ice shows invariance across location, decade, and ice type. In particular, the albedo of snow-free, melting seasonal ice was indistinguishable from that of snow-free, melting second-year ice, suggesting that the highly scattering surface layer that forms on sea ice during the summer is robust and stabilizing. In contrast, the albedo of ponded ice was observed to be highly variable at visible wavelengths. Notable temporal changes in albedo were documented during melt and freeze onset, formation and deepening of melt ponds, and during melt evolution of sediment-laden ice. While model simulations show considerable agreement with the observed seasonal albedo progression, disparities suggest the need to improve how the albedo of both ponded ice and thin, melting ice are simulated.

54 ENVIRONMENTAL SCIENCES↗

Tethered balloon-borne profile measurements of atmospheric properties in the cloudy atmospheric boundary layer over the Arctic sea ice during MOSAiC: Overview and first results

The tethered balloon-borne measurement system BELUGA (Balloon-bornE moduLar Utility for profilinG the lower Atmosphere) was deployed over the Arctic sea ice for 4 weeks in summer 2020 as part of the Multidisciplinary drifting Observatory for the Study of Arctic Climate expedition. Using BELUGA, vertical profiles of dynamic, thermodynamic, aerosol particle, cloud, radiation, and turbulence properties were measured from the ground up to a height of 1,500 m. BELUGA was operated during an anomalously warm period with frequent liquid water clouds and variable sea ice conditions. Three case studies of liquid water phase, single-layer clouds observed on 3 days (July 13, 23, and 24, 2020) are discussed to show the potential of the collected data set to comprehensively investigate cloud properties determining cloud evolution in the inner Arctic over sea ice. Simulated back-trajectories show that the observed clouds have evolved within 3 different air masses (“aged Arctic,” “advected over sea ice,” and “advected over open ocean”), which left distinct fingerprints in the cloud properties. Strong cloud top radiative cooling rates agree with simulated results of previous studies. The weak warming at cloud base is mostly driven by the vertical temperature profile between the surface and cloud base. In-cloud turbulence induced by the cloud top cooling was similar in strength compared to former studies. From the extent of the mixing layer, it is speculated that the overall cloud cooling is stronger and thus faster in the warm oceanic air mass. Larger aerosol particle number concentrations and larger sizes were observed in the air mass advected over the sea ice and in the air mass advected over the open ocean.

Arctic↗

Overview of the MOSAiC expedition—Atmosphere

With the Arctic rapidly changing, the needs to observe, understand, and model the changes are essential. To support these needs, an annual cycle of observations of atmospheric properties, processes, and interactions were made while drifting with the sea ice across the central Arctic during the Multidisciplinary drifting Observatory for the Study of Arctic Climate (MOSAiC) expedition from October 2019 to September 2020. An international team designed and implemented the comprehensive program to document and characterize all aspects of the Arctic atmospheric system in unprecedented detail, using a variety of approaches, and across multiple scales. These measurements were coordinated with other observational teams to explore cross-cutting and coupled interactions with the Arctic Ocean, sea ice, and ecosystem through a variety of physical and biogeochemical processes. This overview outlines the breadth and complexity of the atmospheric research program, which was organized into 4 subgroups: atmospheric state, clouds and precipitation, gases and aerosols, and energy budgets. Atmospheric variability over the annual cycle revealed important influences from a persistent large-scale winter circulation pattern, leading to some storms with pressure and winds that were outside the interquartile range of past conditions suggested by long-term reanalysis. Similarly, the MOSAiC location was warmer and wetter in summer than the reanalysis climatology, in part due to its close proximity to the sea ice edge. The comprehensiveness of the observational program for characterizing and analyzing atmospheric phenomena is demonstrated via a winter case study examining air mass transitions and a summer case study examining vertical atmospheric evolution. Overall, the MOSAiC atmospheric program successfully met its objectives and was the most comprehensive atmospheric measurement program to date conducted over the Arctic sea ice. The obtained data will support a broad range of coupled-system scientific research and provide an important foundation for advancing multiscale modeling capabilities in the Arctic.

54 ENVIRONMENTAL SCIENCES↗

High temporal resolution estimates of Arctic snowfall rates emphasizing gauge and radar-based retrievals from the MOSAiC expedition

This article presents the results of snowfall rate and accumulation estimates from a vertically pointing 35-GHz radar and other sensors deployed during the Multidisciplinary drifting Observatory for the Study of Arctic Climate (MOSAiC) expedition. The radar-based retrievals are the most consistent in terms of data availability and are largely immune to blowing snow. The total liquid-equivalent accumulation during the snow accumulation season is around 110 mm, with more abundant precipitation during spring months. About half of the total accumulation came from weak snowfall with rates less than approximately 0.2 mmh–1. The total snowfall estimates from a Vaisala optical sensor aboard the icebreaker are similar to those from radar retrievals, though their daily and monthly accumulations and instantaneous rates varied significantly. Compared to radar retrievals and the icebreaker optical sensor data, measurements from an identical optical sensor at an ice camp are biased high. Blowing snow effects, in part, explain differences. Weighing gauge measurements significantly overestimate snowfall during February–April 2020 as compared to other sensors and are not well suited for estimating instantaneous snowfall rates. The icebreaker optical disdrometer estimates of snowfall rates are, on average, relatively little biased compared to radar retrievals when raw particle counts are available and appropriate snowflake mass-size relations are used. These counts, however, are not available during periods that produced more than a third of the total snowfall. While there are uncertainties in the radar-based retrievals due to the choice of reflectivity-snowfall rate relations, the major error contributor is the uncertainty in the radar absolute calibration. The MOSAiC radar calibration is evaluated using comparisons with other radars and liquid water cloud–drizzle processes observed during summer. Overall, this study describes a consistent, radar-based snowfall rate product for MOSAiC that provides significant insight into Central Arctic snowfall and can be used for many other purposes.

54 ENVIRONMENTAL SCIENCES↗

Toward a more realistic representation of surface albedo in NASA CERES-derived surface radiative fluxes

Accurate multidecadal radiative flux records are vital to understand Arctic amplification and constrain climate model uncertainties. Uncertainty in the NASA Clouds and the Earth’s Radiant Energy System (CERES)-derived irradiances is larger over sea ice than any other surface type and comes from several sources. The year-long Multidisciplinary drifting Observatory for the Study of Arctic Climate (MOSAiC) expedition in the central Arctic provides a rare opportunity to explore uncertainty in CERES-derived radiative fluxes. First, a systematic and statistically robust assessment of surface shortwave and longwave fluxes was conducted using in situ measurements from MOSAiC flux stations. The CERES Synoptic 1degree (SYN1deg) product overestimates the downwelling shortwave flux by +11.40 Wm –2 and underestimates the upwelling shortwave flux by –15.70 Wm –2 and downwelling longwave fluxes by –12.58 Wm –2 at the surface during summer. In addition, large differences are found in the upwelling longwave flux when the surface approaches the melting point (approximately 0°C). The biases in downwelling shortwave and longwave fluxes suggest that the atmosphere represented in CERES is too optically thin. The large negative bias in upwelling shortwave flux can be attributed in large part to lower surface albedo (–0.15) in satellite footprint relative to surface sensors. Additionally, the results show that the spectral surface albedo used in SYN1deg overestimates albedo in visible and mid-infrared bands. A series of radiative transfer model perturbation experiments are performed to quantify the factors contributing to the differences. The CERES-MOSAiC broadband albedo differences (approximately 20 Wm –2 ) explain a larger portion of the upwelling shortwave flux difference than the spectral albedo shape differences (approximately 3 Wm –2 ). In addition, the differences between perturbation experiments using hourly and monthly MOSAiC surface albedo suggest that approximately 25% of the sea ice surface albedo variability is explained by factors not correlated with daily sea ice concentration variability. Biases in net shortwave and longwave flux can be reduced to less than half by adjusting both albedo and cloud inputs toward observed values. The results indicate that improvements in the surface albedo and cloud data would substantially reduce the uncertainty in the Arctic surface radiation budget derived from CERES data products.

54 ENVIRONMENTAL SCIENCES↗

Surface temperature comparison of the Arctic winter MOSAiC observations, ERA5 reanalysis, and MODIS satellite retrieval

Atmospheric model systems, such as those used for weather forecast and reanalysis production, often have significant and systematic errors in their representation of the Arctic surface energy budget and its components. The newly available observation data of the Multidisciplinary drifting Observatory for the Study of Arctic Climate (MOSAiC) expedition (2019/2020) enable a range of model analyses and validation in order to advance our understanding of potential model deficiencies. In the present study, we analyze deficiencies in the surface radiative energy budget over Arctic sea ice in the ERA5 global atmospheric reanalysis by comparing against the winter MOSAiC campaign data, as well as, a pan-Arctic level-2 MODIS ice surface temperature remote sensing product. We find that ERA5 can simulate the timing of radiatively clear periods, though it is not able to distinguish the two observed radiative Arctic winter states, radiatively clear and opaquely cloudy, in the distribution of the net surface radiative budget. The ERA5 surface temperature over Arctic sea ice has a conditional error with a positive bias in radiatively clear conditions and a negative bias in opaquely cloudy conditions. The mean surface temperature error is 4°C for radiatively clear situations at MOSAiC and up to 15°C in some parts of the Arctic. The spatial variability of the surface temperature, given by 4 observation sites at MOSAiC, is not captured by ERA5 due to its spatial resolution but represented in the level-2 satellite product. The sensitivity analysis of possible error sources, using satellite products of snow depth and sea ice thickness, shows that the positive surface temperature errors during radiatively clear events are, to a large extent, caused by insufficient sea ice thickness and snow depth representation in the reanalysis system. A positive bias characterizes regions with ice thickness greater than 1.5 m, while the negative bias for thinner ice is partly compensated by the effect of snow.

54 ENVIRONMENTAL SCIENCES↗

Low ozone dry deposition rates to sea ice during the MOSAiC field campaign: Implications for the Arctic boundary layer ozone budget

Dry deposition to the surface is one of the main removal pathways of tropospheric ozone (O 3 ). We quantified for the first time the impact of O 3 deposition to the Arctic sea ice on the planetary boundary layer (PBL) O 3 concentration and budget using year-round flux and concentration observations from the Multidisciplinary drifting Observatory for the Study of Arctic Climate (MOSAiC) campaign and simulations with a single-column atmospheric chemistry and meteorological model (SCM). Based on eddy-covariance O 3 surface flux observations, we find a median surface resistance on the order of 20,000 s m –1 , resulting in a dry deposition velocity of approximately 0.005 cm s –1 . This surface resistance is up to an order of magnitude larger than traditionally used values in many atmospheric chemistry and transport models. The SCM is able to accurately represent the yearly cycle, with maxima above 40 ppb in the winter and minima around 15 ppb at the end of summer. However, the observed springtime ozone depletion events are not captured by the SCM. In winter, the modelled PBL O 3 budget is governed by dry deposition at the surface mostly compensated by downward turbulent transport of O 3 towards the surface. Advection, which is accounted for implicitly by nudging to reanalysis data, poses a substantial, mostly negative, contribution to the simulated PBL O 3 budget in summer. During episodes with low wind speed (<5 m s –1 ) and shallow PBL (<50 m), the 7-day mean dry deposition removal rate can reach up to 1.0 ppb h –1 . Our study highlights the importance of an accurate description of dry deposition to Arctic sea ice in models to quantify the current and future O 3 sink in the Arctic, impacting the tropospheric O 3 budget, which has been modified in the last century largely due to anthropogenic activities.

54 ENVIRONMENTAL SCIENCES↗

Modelling the coupled mercury-halogen-ozone cycle in the central Arctic during spring

Near-surface mercury and ozone depletion events occur in the lowest part of the atmosphere during Arctic spring. Mercury depletion is the first step in a process that transforms long-lived elemental mercury to more reactive forms within the Arctic that are deposited to the cryosphere, ocean, and other surfaces, which can ultimately get integrated into the Arctic food web. Depletion of both mercury and ozone occur due to the presence of reactive halogen radicals that are released from snow, ice, and aerosols. In this work, we added a detailed description of the Arctic atmospheric mercury cycle to our recently published version of the Weather Research and Forecasting model coupled with Chemistry (WRF-Chem 4.3.3) that includes Arctic bromine and chlorine chemistry and activation/recycling on snow and aerosols. The major advantage of our modelling approach is the online calculation of bromine concentrations and emission/recycling that is required to simulate the hourly and daily variability of Arctic mercury depletion. We used this model to study coupling between reactive cycling of mercury, ozone, and bromine during the Multidisciplinary drifting Observatory for the Study of Arctic Climate (MOSAiC) spring season in 2020 and evaluated results compared to land-based, ship-based, and remote sensing observations. The model predicts that elemental mercury oxidation is driven largely by bromine chemistry and that particulate mercury is the major form of oxidized mercury. The model predicts that the majority (74%) of oxidized mercury deposited to land-based snow is re-emitted to the atmosphere as gaseous elemental mercury, while a minor fraction (4%) of oxidized mercury that is deposited to sea ice is re-emitted during spring. Our work demonstrates that hourly differences in bromine/ozone chemistry in the atmosphere must be considered to capture the springtime Arctic mercury cycle, including its integration into the cryosphere and ocean.

54 ENVIRONMENTAL SCIENCES↗

Relationships between summertime surface albedo and melt pond fraction in the central Arctic Ocean: The aggregate scale of albedo obtained on the MOSAiC floe

As part of the Multidisciplinary drifting Observatory for the Study of Arctic Climate (MOSAiC), the HELiX uncrewed aircraft system (UAS) was deployed over the sea ice in the central Arctic Ocean during summer 2020. Albedo measurements were obtained with stabilized pyranometers, and melt pond fraction was calculated from orthomosaic imagery from a surface-imaging multispectral camera. This study analyzed HELiX flight data to provide insights on the temporal and spatial evolution of albedo and melt pond fraction of the MOSAiC floe during the melt season as it drifted south through Fram Strait. The surface albedo distributions showed peak values changing from high albedo (0.55–0.6) to lower values (0.3) as the season advanced. Inspired by methods developed for satellite data, an algorithm was established to retrieve melt pond fraction from the orthomosaic images. We demonstrate that the near-surface observations of melt pond fraction were highly dependent on sample area, offering insight into the influence of subgrid scale features and spatial heterogeneity in satellite observations. Vertical observations conducted with the HELiX were used to quantify the influence of melt pond scales on observed surface albedo as a function of sensor footprint. These scaling results were used to link surface-based measurements collected during MOSAiC to broader-scale satellite data to investigate the influence of surface features on observed albedo. Albedo values blend underlying features within the sensor footprint, as determined by the melt pond size and concentration. This study framed the downscaling (upscaling) problem related to the airborne (surface) observations of surface albedo across a variety of spatial scales.

54 ENVIRONMENTAL SCIENCES↗

Warm air intrusions reaching the MOSAiC expedition in April 2020—The YOPP targeted observing period (TOP)

In the spring period of the Multidisciplinary drifting Observatory for the Study of Arctic Climate (MOSAiC) expedition, an initiative was in place to increase the radiosounding frequency during warm air intrusions in the Atlantic Arctic sector. Two episodes with increased surface temperatures were captured during April 12–22, 2020, during a targeted observing period (TOP). The large-scale circulation efficiently guided the pulses of warm air into the Arctic and the observed surface temperature increased from -30°C to near melting conditions marking the transition to spring, as the temperatures did not return to values below -20°C. Back-trajectory analysis identifies 3 pathways for the transport. For the first temperature maximum, the circulation guided the airmass over the Atlantic to the northern Norwegian coast and then to the MOSAiC site. The second pathway was from the south, and it passed over the Greenland ice sheet and arrived at the observational site as a warm but dry airmass due to precipitation on the windward side. The third pathway was along the Greenland coast and the arriving airmass was both warm and moist. The back trajectories originating from pressure levels between 700 and 900 hPa line up vertically, which is somewhat surprising in this dynamically active environment. The processes acting along the trajectory originating from 800 hPa at the MOSAIC site are analyzed. Vertical profiles and surface energy exchange are presented to depict the airmass transformation based on ERA5 reanalysis fields. The TOP could be used for model evaluation and Lagrangian model studies to improve the representation of the small-scale physical processes that are important for airmass transformation. A comparison between MOSAiC observations and ERA5 reanalysis demonstrates challenges in the representation of small-scale processes, such as turbulence and the contributions to various terms of the surface energy budget, that are often misrepresented in numerical weather prediction and climate models.

54 ENVIRONMENTAL SCIENCES↗

Sea ice heat and mass balance measurements from four autonomous buoys during the MOSAiC drift campaign

As part of the Multidisciplinary drifting Observatory for the Study of Arctic Climate (MOSAiC), four autonomous seasonal ice mass balance buoys were deployed in first- and second-year ice. These buoys measured position, barometric pressure, snow depth, ice thickness, ice growth, surface melt, bottom melt, and vertical profiles of temperature from the air, through the snow and ice, and into the upper ocean. Observed air temperatures were similar at all four sites; however, snow–ice interface temperatures varied by as much as 10°C, primarily due to differences in snow depth. Observed winter ice growth rates (November to May) were <1 cm day -1 , with summer melt rates (June to July) as large as 5 cm day -1 . Air temperatures changed as much as 2°C hour -1 but were dampened to <0.3°C hour -1 at the snow–ice interface. Initial October ice thicknesses ranged from 0.3 m in first-year ice to 1.2 m in second-year ice. By February, this range was only 1.20–1.46 m, due in part to differences in the onset of basal freezing. In second-year ice, this delay was due to large brine-filled voids in the ice; propagating the cold front through this ice required freezing the brine. Mass balance results were similar to those measured by autonomous buoys deployed at the North Pole from 2000 to 2013. Winter average estimates of the ocean heat flux ranged from 0 to 3 W m -2 , with a large increase in June 2020 as the floe moved into warmer water. Estimates of average snow thermal conductivity measured at two buoys during periods of linear temperature profiles were 0.41 and 0.42 W m -1 °C -1 , higher than previously published estimates. Results from these ice mass balance buoys can contribute to efforts to close the MOSAiC heat budget.

54 ENVIRONMENTAL SCIENCES↗

Thin and transient meltwater layers and false bottoms in the Arctic sea ice pack—Recent insights on these historically overlooked features

The rapid melt of snow and sea ice during the Arctic summer provides a significant source of low-salinity meltwater to the surface ocean on the local scale. The accumulation of this meltwater on, under, and around sea ice floes can result in relatively thin meltwater layers in the upper ocean. Due to the small-scale nature of these upper-ocean features, typically on the order of 1 m thick or less, they are rarely detected by standard methods, but are nevertheless pervasive and critically important in Arctic summer. Observations during the Multidisciplinary drifting Observatory for the Study of Arctic Climate (MOSAiC) expedition in summer 2020 focused on the evolution of such layers and made significant advancements in understanding their role in the coupled Arctic system. Here we provide a review of thin meltwater layers in the Arctic, with emphasis on the new findings from MOSAiC. Both prior and recent observational datasets indicate an intermittent yet long-lasting (weeks to months) meltwater layer in the upper ocean on the order of 0.1 m to 1.0 m in thickness, with a large spatial range. The presence of meltwater layers impacts the physical system by reducing bottom ice melt and allowing new ice formation via false bottom growth. Collectively, the meltwater layer and false bottoms reduce atmosphere-ocean exchanges of momentum, energy, and material. The impacts on the coupled Arctic system are far-reaching, including acting as a barrier for nutrient and gas exchange and impacting ecosystem diversity and productivity.

54 ENVIRONMENTAL SCIENCES↗

Analysis of an Arctic cold air outbreak during autumn and related air mass transformations forced by surface changes and advection in higher altitudes

During marine cold air outbreaks (MCAOs), cold and dry Arctic air masses are transported from the central Arctic southward across the closed sea ice and much warmer open oceans. They experience significant transformations including a rapid heating and moistening, often leading to cloud formation. While intense wintertime MCAOs have been analyzed widely, the air mass transformations during other seasons have been studied sparsely. We address this gap by investigating an MCAO case observed in September 2020. To study the transformation processes, we combine the fifth generation of atmospheric reanalyses of the global climate (ERA5), trajectory calculations, as well as shipborne and airborne measurements. In the central Arctic, observations acquired from aboard the research vessel (RV) Polarstern during the Multidisciplinary drifting Observatory for the Study of Arctic Climate (MOSAiC) expedition characterized the initial state of the air mass over closed sea ice. Trajectories indicated the pathway the air mass took from RV Polarstern southward to the Fram Strait. For the first 24 h of the southbound drift, the air masses remained quasi-stationary. Then, still 15 h ahead of the marginal sea ice zone, differential advection across the boundary layer flow introduced humidity and clouds at higher altitudes between 1.5 and 2.5 km. ERA5-derived temperature and humidity tendencies indicated complex vertical interactions. Radiative cloud-top cooling, entrainment, and turbulence were significantly reduced in the lower and enhanced in the upper advected cloud layer. Eventually, the lower cloud deck dissipated. After this confluence of 2 different air masses, observations gathered by Polar 5 in Fram Strait as part of the MOSAiC Airborne observations in the Central Arctic campaign revealed cloudy, moist layers throughout the lowest 3.5 km and an increasing boundary layer height. Comparing the initial with the final state 48 h later, the largest net heating of +8 K was found close to the surface, yet the largest net moistening of +2.5 g kg -1 at an altitude of 1 km, as the initial profile was exceptionally dry here. We conclude that the observed air mass transformations were driven by the surface changes from sea ice to open ocean but additionally strongly impacted by the differential advection of clouds and moisture across the near-surface MCAO flow.

54 ENVIRONMENTAL SCIENCES↗

Snow thermal conductivity and conductive flux in the Central Arctic: Estimates from observations and implications for models

During the Arctic winter, the conductive heat flux through the sea ice and snow balances the radiative and turbulent heat fluxes at the surface. Snow on sea ice is a thermal insulator that reduces the magnitude of the conductive flux. The thermal conductivity of snow, that is, how readily energy is conducted, is known to vary significantly in time and space from observations, but most forecast and climate models use a constant value. This work begins with a demonstration of the importance of snow thermal conductivity in a regional coupled forecast model. Varying snow thermal conductivity impacts the magnitudes of all surface fluxes, not just conduction, and their responses to atmospheric forcing. Given the importance of snow thermal conductivity in models, we use observations from sea ice mass balance buoys installed during the Multidisciplinary drifting Observatory for the Study of Arctic Climate expedition to derive the profiles of thermal conductivity, density, and conductive flux. From 13 sites, median snow thermal conductivity ranges from 0.33 W m −1 K −1 to 0.47 W m −1 K −1 with a median from all data of 0.39 W m −1 K −1 from October to February. In terms of surface energy budget closure, estimated conductive fluxes are generally smaller than the net atmospheric flux by as much as 20 W m −2 , but the average residual during winter is −6 W m −2 , which is within the uncertainties. The spatial variability of conductive heat flux is highest during clear and cold time periods. Higher surface temperature, which often occurs during cloudy conditions, and thicker snowpacks reduce temporal and spatial variability. These relationships are compared between observations and the coupled forecast model, emphasizing both the importance and challenge of describing thermodynamic parameters of snow cover for modeling the Arctic as a coupled system.

54 ENVIRONMENTAL SCIENCES↗