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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 721 records · Page 40
All sourcesNASA NTRSDOE OSTI
DOE OSTI2022

Valve Regulated Lead Acid Battery Evaluation under Peak Shaving and Frequency Regulation Duty Cycles

This work highlights the performance metrics and the fundamental degradation mechanisms of lead-acid battery technology and maps these mechanisms to generic duty cycles for peak shaving and frequency regulation grid services. Four valve regulated lead acid batteries have been tested for two peak shaving cycles at different discharge rates and two frequency regulation duty cycles at different SOC ranges. Reference performance and pulse resistance tests are done periodically to evaluate battery degradation over the time. The results of the studies are expected to provide a valuable understanding of lead acid battery technology suitability for grid energy-storage applications.

25 ENERGY STORAGE↗
NASA NTRS2021

Wake Instability Behind Isolated Trip Near the Leading Edge of the BOLT-II Configuration

The BOLT-II (Holden Mission) configuration is an extended version of the BOLT flight article and depicts hypersonic boundary-layer transition in the presence of multiple and potentially interacting instability mechanisms. Several numerical studies of the boundary-layer instabilities over these configurations have been reported in the recent literature, including our previous studies of the modal instability characteristics of boundary-layer streaks adjacent to the minor-axis symmetry plane of the BOLT configuration and the wake instabilities behind a diamond planform (“pizza-box”) trip along the symmetry plane on the secondary side of the BOLT-II configuration. The present work extends the latter study to a scaled version of the same trip that is located in the region of nonzero crossflow in the vicinity of the leading edge at X/L = 0.5. Collectively, the trips along the symmetry plane and near the leading edge are the focus of the NASA roughness experiment on the secondary side of the BOLT-II configuration. The laminar basic state computation at the nominal flight design condition of Re ∞ = 5.44 x 10 6 /m and Re ∞ = 2.5 x 10 6 /m shows that the leading-edge trip with k/δ ≈ 0.70 and planform-side-length-to-height ratio of b/k = 3.0 induces multiple asymmetric, longitudinal streaks within the trip wake. The most prominent streak among these resembles a finite amplitude crossflow vortex, and it supports the amplification of multiple families of unstable modes. The application of multi-dimensional instability analysis to the wake flow reveals that the most amplified unstable mode can achieve a peak N-factor of up to 20 by X/L = 0.80, indicating that the onset of transition is more than likely to occur within eighty percent of the model length. To the best of our knowledge, the present study represents the first analysis including nonparallel and curvature effects on hypersonic tripwake instabilities in the presence of boundary-layer crossflow over a three-dimensional configuration.

Boundary layer transition↗
DOE OSTI2012

Breakthrough: Lead-free Solder

Ames Laboratory senior metallurgist Iver Anderson explains the importance of lead-free solder in taking hazardous lead out of the environment by eliminating it from discarded computers and electronics that wind up in landfills. Anderson led a team that developed a tin-silver-copper replacement for traditional lead-tin solder that has been adopted by more than 50 companies worldwide.

36 MATERIALS SCIENCE↗
DOE OSTI2012

Progress on Establishing the Feasibility of Lead Slowing Down Spectroscopy for Direct Measurement of Plutonium in Used Fuel

Developing a method for the accurate, direct, and independent assay of the fissile isotopes in bulk materials (such as used fuel) of next-generation domestic nuclear fuel cycles is a goal of the Office of Nuclear Energy, Fuel Cycle R&D, Material Protection and Control Technology (MPACT) Campaign. To meet this goal, MPACT continues to support a multi-institutional collaboration to address the feasibility of Lead Slowing Down Spectroscopy (LSDS) as an active nondestructive assay method that has the potential to provide independent, direct measurement of Pu and U isotopic masses in used fuel with an uncertainty considerably lower than the approximately 10% typical of today’s confirmatory assay methods. An LSDS is comprised of a stack of lead (typically 1-6 m3) in which materials to be measured are placed in the lead and a pulse of neutrons is injected. The neutrons in this pulse lose energy due to inelastic and (subsequently) elastic scattering and the average energy of the neutrons decreases as the time increases by a well-defined relationship. In the interrogation energy region (~0.1-1000 eV) the neutrons have little energy spread (~30%) about the average neutron energy. Due to this characteristic, the energy of the (assay) neutrons can then be determined by measuring the time elapsed since the neutron pulse. By measuring the induced fission neutrons emitted from the used fuel, it is possible to determine isotopic-mass content by unfolding the unique structure of isotopic resonances across the interrogation energy region. This paper will present efforts on the development of time-spectral analysis algorithms, fast neutron detector advances, and validation and testing measurements.

Fission Chambers↗
DOE OSTI2020

National Grid: Using the LEAD Tool Data to Target Energy Affordability Services to Eligible Customers in New York

In the following use case, investor-owned utility company, National Grid, used the Low-Income Energy Affordability Data (LEAD) Tool to support the implementation of its Home Energy Affordability Team (HEAT), a weatherization program for income-eligible residential natural gas customers in its service territory in Long Island, New York. Using LEAD Tool data, National Grid was able to determine how many households may be eligible for the program to inform additional marketing efforts. This use case is an example of how utilities of all sizes and types in the United States can use the LEAD Tool in similar ways to gain insights and better address customer energy affordability needs.

Low-Income Energy Affordability Data Tool, LEAD To↗
DOE OSTI2020

Benefits and risks of lead halide perovskite photovoltaics

Photovoltaics (PV) do not emit anything during operation, but, over their life-cycle, emissions are generated from the use of fossil-fuels in the extraction and production of materials and in the manufacturing and installation of PV components and systems. Nonetheless, these emissions are always very small compared to those from conventional combustion-based generators of electricity. The case for CO2 emissions has been well documented; over their lifetime, they range from 10 g CO2-eq / kWh for CdTe PV system installed in high-irradiation (2300 kWh/(m2-yr) locations to 80 g CO2-eq / kWh for Chinese single-crystalline silicon PV systems installed in low-irradiation (1000 kWh/(m2-yr) locations,1 compared to ~1000 g CO2-eq/kWh for electricity from coal. However, in the case of the rapidly emerging lead halide perovskite PV (LHP-PV) technology, concerns are raised regarding the potential of emissions of lead from the life-cycles of LHP-PV, including at their end of life. This warranted an evaluation of lead emissions from PV and comparisons with emissions in other power generation life-cycles.

Perovskites, PV, Lead, Risks↗
DOE OSTI2013

A measurement of the muon-induced neutron yield in lead at a depth of 2850 m water equivalent

We present results from the measurement of the neutron production rate in lead by high energy cosmic-ray muons at a depth of 2850 m water equivalent (mean muon energy of 260 GeV). A tonne-scale highly segmented plastic scintillator detector was utilised to detect both the energy depositions from the traversing muons as well as the delayed radiative capture signals of the induced neutrons. Complementary Monte Carlo simulations reproduce well the distributions of muons and detected muon-induced neutrons. Absolute agreement between simulation and data is of the order of 25%. By comparing the measured and simulated neutron capture rates a neutron yield in pure lead of (5.78{sub −0.28}{sup +0.21})×10{sup −3} neutrons/muon/(g/cm{sup 2}) has been obtained.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
DOE OSTI2015

Origin of resistivity anomaly in p-type leads chalcogenide multiphase compounds

The electrical resistivity curves for binary phase compounds of p-type lead chalcogenide (PbTe){sub (0.9−x)}(PbSe){sub 0.1}(PbS){sub x,} (x = 0.15, 0.2, 0.25), which contain PbS-rich secondary phases, show different behaviour on heating and cooling between 500-700 K. This is contrast to single phase compounds which exhibit similar behaviour on heating and cooling. We correlate these anomalies in the electrical resistivities of multiphase compounds to the variation in phase composition at high temperatures. The inhomogeneous distribution of dopants between the matrix and secondary phase is found to be crucial in the electronic transport properties of the multiphase compounds. These results can lead to further advances in designing composite Pb-chalcogenides with high thermoelectric performance.

36 MATERIALS SCIENCE↗
DOE OSTI2018

Reducibility of PbO in Lead Silicate Glasses

X-ray diffraction data and X-ray fluorescence analysis data for microchannel plates are presented. From X-ray diffraction patterns, one can estimate the amount of reduced lead in microchannel plates and make sure of the presence of both metallic lead and semiconducting PbO{sub x} with a variable oxygen content.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2023

Triiodide Attacks the Organic Cation in Hybrid Lead Halide Perovskites: Mechanism and Suppression

Molecular I 2 can be produced from iodide-based lead perovskites under thermal stress; triiodide, I 3 − , is formed from this I 2 and I − . Triiodide attacks protic cation MA + - or FA + -based lead halide perovskites (MA + , methylammonium; FA + , formamidinium) as explicated through solution-based nuclear magnetic resonance (NMR) studies: triiodide has strong hydrogen-bonding affinity for MA + or FA + , which leads to their deprotonation and perovskite decomposition. Triiodide is a catalyst for this decomposition that can be obviated through perovskite surface treatment with thiol reducing agents. In contrast to methods using thiol incorporation into perovskite precursor solutions, no penetration of the thiol into the bulk perovskite is observed, yet its surface application stabilizes the perovskite against triiodide-mediated thermal stress. Thiol applied to the interface between FAPbI 3 and Spiro-OMeTAD (“Spiro”) prevents oxidized iodine species penetration into Spiro and thus preserves its hole-transport efficacy. Surface-applied thiol affects the perovskite work function; it ameliorates hole injection into the Spiro overlayer, thus improving device performance. It helps to increase interfacial adhesion (“wetting”): fewer voids are observed at the Spiro/perovskite interface if thiols are applied. Perovskite solar cells (PSCs) incorporating interfacial thiol treatment maintain over 80% of their initial power conversion efficiency (PCE) after 300 h of 85 °C thermal stress.

36 MATERIALS SCIENCE↗
DOE OSTI2019

Iron-Nanoparticle Driven Tribochemistry Leading to Superlubric Sliding Interfaces

Any moving mechanical system consisting of sliding/rolling or rotating interfaces experiences friction and wear. High contact pressure and shear during relative movement of the sliding interfaces in the presence of lubricants often lead to interesting tribochemical activity at nanoscale, which then greatly influences the tribological performance of the mechanical systems at macroscale. Understanding these tribochemical interactions and to be able to manipulate them will be a key in designing smart solid lubricants that can self-generate at the sliding interfaces and thus help in drastically improving the overall efficiency of these moving mechanical systems. In this study, it is demonstrated that solid lubricant consisting graphene mixed with iron nanoparticles (NPs) under high contact pressures at the sliding interface undergo tribochemical reaction leading to the formation of onion-like-carbon nanostructures (OLCs). Combining with atomistic molecular dynamic simulations, the tribochemical mechanism of formation of OLC with pure iron NPs and how that depends sensitively on the core-shell chemistry of the nanoparticle is elucidated. Interestingly, the formed OLCs lead to the near-zero friction (superlubricity) during sliding in dry conditions, thus demonstrating great potential to be used as a solid lubricant for various tribological applications.

36 MATERIALS SCIENCE↗
DOE OSTI2025

Observation of Extraordinary Vibration Scatterings Induced by Strong Anharmonicity in Lead‐Free Halide Double Perovskites

Abstract Lead‐free halide double perovskites provide a promising solution for the long‐standing issues of lead‐containing halide perovskites, i.e., the toxicity of Pb and the low stability under ambient conditions and high‐intensity illumination. Their light‐to‐electricity or thermal‐to‐electricity conversion is strongly determined by the dynamics of the corresponding lattice vibrations. Here, the measurement of lattice dynamics is presented in a prototypical lead‐free halide double perovskite(Cs 2 NaInCl 6 ). The quantitative measurements and first‐principles calculations show that the scatterings among lattice vibrations at room temperature are at the timescale of ≈1 ps, which stems from the extraordinarily strong anharmonicity in Cs 2 NaInCl 6 . Further the degree of anharmonicity of each type of atom is quantitatively characterized in the Cs 2 NaInCl 6 single crystal, which stems from the interatomic forces, and demonstrate that this strong anharmonicity is synergistically contributed by the bond hierarchy, the tilting of the NaCl 6 and InCl 6 octahedral units, and the rattling of Cs + ions. Consequently, the crystalline Cs 2 NaInCl 6 possesses an ultralow thermal conductivity of ≈0.43 W mK −1 at room temperature, and a weak temperature dependence ofT −0.41 . These findings uncovered the underlying mechanisms behind the dynamics of lattice vibrations in double perovskites, which can largely benefit the design of optoelectronics and thermoelectrics based on halide double perovskites.

Chemistry↗
DOE OSTI2017

High-Pressure Band-Gap Engineering in Lead-Free Cs 2 AgBiBr 6 Double Perovskite

Novel inorganic lead-free double perovskites with improved stability are regarded as alternatives to state-of-art hybrid lead halide perovskites in photovoltaic devices. The recently discovered Cs2AgBiBr6 double perovskite exhibits attractive optical and electronic features, making it promising for various optoelectronic applications. However, its practical performance is hampered by the large band gap. In this work, remarkable band gap narrowing of Cs2AgBiBr6 is, for the first time, achieved on inorganic photovoltaic double perovskites through high pressure treatments. Moreover, the narrowed band gap is partially retainable after releasing pressure, promoting its optoelectronic applications. This work not only provides novel insights into the structure–property relationship in lead-free double perovskites, but also offers new strategies for further development of advanced perovskite devices.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2016

Thermodynamic Stability and Defect Chemistry of Bismuth-Based Lead-Free Double Perovskite Cs 2 AgBiBr 6

Bismuth or antimony based lead-free double perovskites represented by Cs 2 AgBiBr 6 have recently been considered promising alternatives to the emerging lead-based perovskites for solar cell applications. These new perovskites belong to the Fm -3 m space group and consist of two types of octahedra alternating in a rock-salt face-centered cubic structure. We show, by density functional theory calculation, that the stable chemical potential region for pure Cs 2 AgBiBr 6 is narrow. Silver vacancy is a shallow accepter and can easily form, leading to intrinsic p -type conductivity. Bi vacancy and Ag Bi antisite are deep acceptors and should be the dominant defects under the Br-rich growth conditions. Our results suggest that the growth of Cs 2 AgBiBr 6 under Br-poor/Bi-rich conditions is preferred for suppressing the formation of the deep defects, which is beneficial for maximizing the photovoltaic performance.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2023

Single inclusive hadron production in DIS at small x: next to leading order corrections

We calculate the one-loop corrections to single inclusive hadron production in Deep Inelastic Scattering (DIS) at small x in the forward rapidity region using the Color Glass Condensate formalism. We show that the divergent parts of the next to leading order (NLO) corrections either cancel among each other or lead to x (rapidity) evolution of the leading order (LO) dipole cross section according to the JIMWLK evolution equation and DGLAP evolution of the parton-hadron fragmentation function. The remaining finite parts constitute the NLO (α s ) corrections to the LO single inclusive hadron production cross section in DIS at small x.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2026

Super-leading logarithms in top-quark pair production at hadron colliders

To date, the appearance and resummation of “super-leading” logarithms in hadron-hadron collisions has been studied only for massless parton states. We extend the formalism to include an arbitrary number of massive final states. We derive the corresponding anomalous dimension and identify an additional Coulomb phase that gives rise to a new source of super-leading logarithms. We then perform a systematic leading-logarithmic resummation of these contributions for 2 → M processes. Finally, we analyze the numerical impact in partonic scattering processes for $t\bar{t}$ production, including a treatment of the Sommerfeld enhancement observed near threshold.

Effective Field Theories of QCD↗
DOE OSTI2015

Gluon fragmentation into quarkonium at next-to-leading order

Here, we present the first calculation at next-to-leading order (NLO) in α s of a fragmentation function into quarkonium whose form at leading order is a nontrivial function of z, namely the fragmentation function for a gluon into a spin-singlet S-wave state at leading order in the relative velocity. To calculate the real NLO corrections, we introduce a new subtraction scheme that allows the phase-space integrals to be evaluated in 4 dimensions. We extract all ultraviolet and infrared divergences in the real NLO corrections analytically by calculating the phase-space integrals of the subtraction terms in 4 – 2ϵ dimensions. We also extract the divergences in the virtual NLO corrections analytically, and detail the cancellation of all divergences after renormalization. The NLO corrections have a dramatic effect on the shape of the fragmentation function, and they significantly increase the fragmentation probability.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗