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At least 721 records · Page 40
All sourcesNASA NTRSDOE OSTI
DOE OSTI2016

Reactions of substituted benzene anions with N and O atoms: Chemistry in Titan’s upper atmosphere and the interstellar medium

The likely existence of aromatic anions in many important extraterrestrial environments, from the atmosphere of Titan to the interstellar medium (ISM), is attracting increasing attention. Nitrogen and oxygen atoms are also widely observed in the ISM and in the ionospheres of planets and moons. In the current work, we extend previous studies to explore the reactivity of prototypical aromatic anions (deprotonated toluene, aniline, and phenol) with N and O atoms both experimentally and computationally. The benzyl and anilinide anions both exhibit slow associative electron detachment (AED) processes with N atom, and moderate reactivity with O atom in which AED dominates but ionic products are also formed. The reactivity of phenoxide is dramatically different; there is no measurable reaction with N atom, and the moderate reactivity with O atom produces almost exclusively ionic products. The reaction mechanisms are studied theoretically by employing density functional theory calculations, and spin conversion is found to be critical for understanding some product distributions. This work provides insight into the rich gas-phase chemistry of aromatic ion-atom reactions and their relevance to ionospheric and interstellar chemistry.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2013

MAGNETIC NANOPARTICLES IN THE INTERSTELLAR MEDIUM: EMISSION SPECTRUM AND POLARIZATION

The presence of ferromagnetic or ferrimagnetic nanoparticles in the interstellar medium would give rise to magnetic dipole radiation at microwave and submillimeter frequencies. Such grains may account for the strong millimeter-wavelength emission observed from a number of low-metallicity galaxies, including the Small Magellanic Cloud. We calculate the absorption and scattering cross sections for such grains, with particular attention to metallic Fe, magnetite Fe{sub 3}O{sub 4}, and maghemite {gamma}-Fe{sub 2}O{sub 3}, all potentially present in the interstellar medium. The rate of Davis-Greenstein alignment by magnetic dissipation is also estimated. We determine the temperature of free-flying magnetic grains heated by starlight and calculate the polarization of the magnetic dipole emission from both free-fliers and inclusions. For inclusions, the magnetic dipole emission is expected to be polarized orthogonally relative to the normal electric dipole radiation. Magnetic dipole radiation will contribute significantly to the 20-40 GHz anomalous microwave emission only if a large fraction of the Fe is in metallic Fe iron nanoparticles with extreme elongations. Finally, we present self-consistent dielectric functions for metallic Fe, magnetite Fe{sub 3}O{sub 4}, and maghemite {gamma}-Fe{sub 2}O{sub 3}, enabling calculation of absorption and scattering cross sections from microwave to X-ray wavelengths.

36 MATERIALS SCIENCE↗
DOE OSTI2013

CAN INTERSTELLAR PROPENE (CH{sub 3}CHCH{sub 2}) BE FORMED VIA GAS-PHASE REACTIONS?

Propene (CH{sub 3}CHCH{sub 2}), detected in the cold core TMC-1, is a surprisingly saturated (H-rich) species for observation in such regions. In a recently proposed gas-phase formation mechanism, interstellar propene is produced from its protonated precursor C{sub 3}H{sup +}{sub 7} (CH{sub 3}CHCH{sup +}{sub 3}) via a dissociative recombination process. The precursor ion C{sub 3}H{sup +}{sub 7} is itself produced via two consecutive radiative association reactions involving H{sub 2} starting from the isomer of C{sub 3}H{sup +}{sub 3} with a linear carbon backbone (CH{sub 2}CCH{sup +}). Initial calculations showed that the radiative association reactions are efficient enough to allow the production of an abundance of propene equal to that observed. However, a combination of experiments and more refined quantum chemical ab initio calculations reported here does not corroborate the initial result. Indeed, from both of these approaches, we have learned that the radiative association reactions leading to protonated propene do not occur efficiently at interstellar temperatures due to activation energy barriers. The result is that propene cannot be produced efficiently by the suggested gas-phase synthetic route. It is still difficult to say, however, that no suitable gas-phase syntheses for propene can occur in cold cores such as TMC-1.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2013

H{sub 2} MOLECULAR CLUSTERS WITH EMBEDDED MOLECULES AND ATOMS AS THE SOURCE OF THE DIFFUSE INTERSTELLAR BANDS

We suggest that the diffuse interstellar bands (DIBs) arise from absorption lines of electronic transitions in molecular clusters primarily composed of a single molecule, atom, or ion ({sup s}eed{sup )}, embedded in a single-layer shell of H{sub 2} molecules. Less abundant variants of the cluster, including two seed molecules and/or a two-layer shell of H{sub 2} molecules, may also occur. The lines are broadened, blended, and wavelength-shifted by interactions between the seed and surrounding H{sub 2} shell. We refer to these clusters as contaminated H{sub 2} clusters (CHCs). We show that CHC spectroscopy matches the diversity of observed DIB spectral profiles and provides good fits to several DIB profiles based on a rotational temperature of 10 K. CHCs arise from {approx}centimeter-sized, dirty H{sub 2} ice balls, called contaminated H{sub 2} ice macro-particles (CHIMPs), formed in cold, dense, giant molecular clouds (GMCs), and later released into the interstellar medium (ISM) upon GMC disruption. Attractive interactions, arising from Van der Waals and ion-induced dipole potentials, between the seeds and H{sub 2} molecules enable CHIMPs to attain centimeter-sized dimensions. When an ultraviolet (UV) photon is absorbed in the outer layer of a CHIMP, it heats the icy matrix and expels CHCs into the ISM. While CHCs are quickly destroyed by absorbing UV photons, they are replenished by the slowly eroding CHIMPs. Since CHCs require UV photons for their release, they are most abundant at, but not limited to, the edges of UV-opaque molecular clouds, consistent with the observed, preferred location of DIBs. An inherent property of CHCs, which can be characterized as nanometer size, spinning, dipolar dust grains, is that they emit in the radio-frequency region. We also show that the CHCs offer a natural explanation for the anomalous microwave emission feature in the {approx}10-100 GHz spectral region.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2013

THE STRUCTURE, ORIGIN, AND EVOLUTION OF INTERSTELLAR HYDROCARBON GRAINS

Many materials have been considered for the carrier of the hydrocarbon absorption bands observed in the diffuse interstellar medium (ISM). In order to refine the model for ISM hydrocarbon grains, we analyze the observed aromatic (3.28, 6.2 {mu}m) and aliphatic (3.4 {mu}m) hydrocarbon absorption features in the diffuse ISM along the line of sight toward the Galactic center Quintuplet Cluster. Observationally, sp {sup 2} bonds can be measured in astronomical spectra using the 6.2 {mu}m CC aromatic stretch feature, whereas the 3.4 {mu}m aliphatic feature can be used to quantify the fraction of sp {sup 3} bonds. The fractional abundance of these components allows us to place the Galactic diffuse ISM hydrocarbons on a ternary phase diagram. We conclude that the Galactic hydrocarbon dust has, on average, a low H/C ratio and sp {sup 3} content and is highly aromatic. We have placed the results of our analysis within the context of the evolution of carbon dust in the ISM. We argue that interstellar carbon dust consists of a large core of aromatic carbon surrounded by a thin mantle of hydrogenated amorphous carbon (a-C:H), a structure that is a natural consequence of the processing of stardust grains in the ISM.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2013

ELECTRON IRRADIATION OF CARBON DISULFIDE-OXYGEN ICES: TOWARD THE FORMATION OF SULFUR-BEARING MOLECULES IN INTERSTELLAR ICES

The formation of sulfur-bearing molecules in interstellar ices was investigated during the irradiation of carbon disulfide (CS{sub 2})-oxygen (O{sub 2}) ices with energetic electrons at 12 K. The irradiation-induced chemical processing of these ices was monitored online and in situ via Fourier transform infrared spectroscopy to probe the newly formed products quantitatively. The sulfur-bearing molecules produced during the irradiation were sulfur dioxide (SO{sub 2}), sulfur trioxide (SO{sub 3}), and carbonyl sulfide (OCS). Formations of carbon dioxide (CO{sub 2}), carbon monoxide (CO), and ozone (O{sub 3}) were observed as well. To fit the temporal evolution of the newly formed products and to elucidate the underlying reaction pathways, kinetic reaction schemes were developed and numerical sets of rate constants were derived. Our studies suggest that carbon disulfide (CS{sub 2}) can be easily transformed to carbonyl sulfide (OCS) via reactions with suprathermal atomic oxygen (O), which can be released from oxygen-containing precursors such as water (H{sub 2}O), carbon dioxide (CO{sub 2}), and/or methanol (CH{sub 3}OH) upon interaction with ionizing radiation. This investigation corroborates that carbonyl sulfide (OCS) and sulfur dioxide (SO{sub 2}) are the dominant sulfur-bearing molecules in interstellar ices.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2014

C{sup +} in the interstellar medium: Collisional excitation by H{sub 2} revisited

C{sup +} is a critical constituent of many regions of the interstellar medium, as it can be a major reservoir of carbon and, under a wide range of conditions, the dominant gas coolant. Emission from its 158 μm fine structure line is used to trace the structure of photon-dominated regions in the Milky Way and is often employed as a measure of the star formation rate in external galaxies. Under most conditions, the emission from the single [C II] line is proportional to the collisional excitation rate coefficient. We here used improved calculations of the deexcitation rate of [C II] by collisions with H{sub 2} to calculate more accurate expressions for interstellar C{sup +} fine structure emission, its critical density, and its cooling rate. The collision rates in the new quantum calculation are ∼25% larger than those previously available, and narrow the difference between rates for excitation by atomic and molecular hydrogen. This results in [C II] excitation being quasi-independent of the molecular fraction and thus dependent only on the total hydrogen particle density. A convenient expression for the cooling rate at temperatures between 20 K and 400 K, assuming an LTE H{sub 2} ortho to para ratio is Λ=(11.5+4.0 e{sup −100} {sup K/T{sup k{sup i{sup n}}}}) e{sup −91.25} {sup K/T{sup k{sup i{sup n}}}} n(C{sup +}) n(H{sub 2})×10{sup −24} erg cm{sup −3} s{sup −1}. The present work should allow more accurate and convenient analysis of the [C II] line emission and its cooling.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2014

Laboratory determination of the infrared band strengths of pyrene frozen in water ice: Implications for the composition of interstellar ices

Broad infrared emission features (e.g., at 3.3, 6.2, 7.7, 8.6, and 11.3 μm) from the gas phase interstellar medium have long been attributed to polycyclic aromatic hydrocarbons (PAHs). A significant portion (10%-20%) of the Milky Way's carbon reservoir is locked in PAH molecules, which makes their characterization integral to our understanding of astrochemistry. In molecular clouds and the dense envelopes and disks of young stellar objects (YSOs), PAHs are expected to be frozen in the icy mantles of dust grains where they should reveal themselves through infrared absorption. To facilitate the search for frozen interstellar PAHs, laboratory experiments were conducted to determine the positions and strengths of the bands of pyrene mixed with H{sub 2}O and D{sub 2}O ices. The D{sub 2}O mixtures are used to measure pyrene bands that are masked by the strong bands of H{sub 2}O, leading to the first laboratory determination of the band strength for the CH stretching mode of pyrene in water ice near 3.25 μm. Our infrared band strengths were normalized to experimentally determined ultraviolet band strengths, and we find that they are generally ∼50% larger than those reported by Bouwman et al. based on theoretical strengths. These improved band strengths were used to reexamine YSO spectra published by Boogert et al. to estimate the contribution of frozen PAHs to absorption in the 5-8 μm spectral region, taking into account the strength of the 3.25 μm CH stretching mode. It is found that frozen neutral PAHs contain 5%-9% of the cosmic carbon budget and account for 2%-9% of the unidentified absorption in the 5-8 μm region.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2014

Interstellar silicate dust in the z = 0.685 absorber toward TXS 0218+357

We report the detection of interstellar silicate dust in the z {sub abs} = 0.685 absorber along the sightline toward the gravitationally lensed blazar TXS 0218+357. Using Spitzer Space Telescope Infrared Spectrograph data, we detect the 10 μm silicate absorption feature with a detection significance of 10.7σ. We fit laboratory-derived silicate dust profile templates obtained from the literature to the observed 10 μm absorption feature and find that the best single-mineral fit is obtained using an amorphous olivine template with a measured peak optical depth of τ{sub 10} = 0.49 ± 0.02, which rises to τ{sub 10} ∼ 0.67 ± 0.04 if the covering factor is taken into account. We also detected the 18 μm silicate absorption feature in our data with a >3σ significance. Due to the proximity of the 18 μm absorption feature to the edge of our covered spectral range, and associated uncertainty about the shape of the quasar continuum normalization near 18 μm, we do not independently fit this feature. We find, however, that the shape and depth of the 18 μm silicate absorption are well matched to the amorphous olivine template prediction, given the optical depth inferred for the 10 μm feature. The measured 10 μm peak optical depth in this absorber is significantly higher than those found in previously studied quasar absorption systems. However, the reddening, 21 cm absorption, and velocity spread of Mg II are not outliers relative to other studied absorption systems. This high optical depth may be evidence for variations in dust grain properties in the interstellar medium between this and the previously studied high redshift galaxies.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2014

The structure of the local interstellar medium. VI. New Mg II, Fe II, and Mn II observations toward stars within 100 pc

We analyze high-resolution spectra obtained with the Space Telescope Imaging Spectrograph onboard the Hubble Space Telescope toward 34 nearby stars (≤100 pc) to record Mg II, Fe II, and Mn II absorption due to the local interstellar medium (LISM). Observations span the entire sky, probing previously unobserved regions of the LISM. The heavy ions studied in this survey produce narrow absorption features that facilitate the identification of multiple interstellar components. We detected one to six individual absorption components along any given sight line, and the number of absorbers roughly correlates with the pathlength. This high-resolution near-ultraviolet (NUV) spectroscopic survey was specifically designed for sight lines with existing far-UV (FUV) observations. The FUV spectra include many intrinsically broad absorption lines (i.e., of low atomic mass ions) and are often observed at medium resolution. The LISM NUV narrow-line absorption component structure presented here can be used to more accurately interpret the archival FUV observations. As an example of this synergy, we present a new analysis of the temperature and turbulence along the line of sight toward ε Ind. The new observations of LISM velocity structure are also critical in the interpretation of astrospheric absorption derived from fitting the saturated H I Lyα profile. As an example, we reanalyze the spectrum of λ And and find that this star likely does have an astrosphere. Two stars in the sample that have circumstellar disks (49 Cet and HD141569) show evidence for absorption due to disk gas. Finally, the substantially increased number of sight lines is used to test and refine the three-dimensional kinematic model of the LISM and search for previously unidentified clouds within the Local Bubble. We find that every prediction made by the Redfield and Linsky kinematic model of the LISM is confirmed by an observed component in the new lines of sight.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2014

Star formation and the interstellar medium in nearby tidal streams (SAINTS): Spitzer mid-infrared spectroscopy and imaging of intergalactic star-forming objects

A spectroscopic analysis of 10 intergalactic star-forming objects (ISFOs) and a photometric analysis of 67 ISFOs in a sample of 14 interacting systems is presented. The majority of the ISFOs have relative polycyclic aromatic hydrocarbon (PAH) band strengths similar to those of nearby spiral and starburst galaxies. In contrast to what is observed in blue compact dwarfs (BCDs) and local giant H II regions in the Milky Way (NGC 3603) and the Magellanic Clouds (30 Doradus and N 66), the relative PAH band strengths in ISFOs correspond to models with a significant PAH ion fraction (<50%) and bright emission from large PAHs (∼100 carbon atoms). The [Ne III]/[Ne II] and [S IV]/[S III] line flux ratios indicate moderate levels of excitation with an interstellar radiation field that is harder than the majority of the Spitzer Infrared Nearby Galaxies Survey and starburst galaxies, but softer than BCDs and local giant H II regions. The ISFO neon line flux ratios are consistent with a burst of star formation ≲6 million years ago. Most of the ISFOs have ∼10{sup 6} M {sub ☉} of warm H{sub 2} with a likely origin in photo-dissociation regions (PDRs). Infrared Array Camera photometry shows the ISFOs to be bright at 8 μm, with one-third having [4.5] – [8.0] > 3.7, i.e., enhanced non-stellar emission, most likely due to PAHs, relative to normal spirals, dwarf irregulars, and BCD galaxies. The relative strength of the 8 μm emission compared to that at 3.6 μm or 24 μm separates ISFOs from dwarf galaxies in Spitzer two-color diagrams. The infrared power in two-thirds of the ISFOs is dominated by emission from grains in a diffuse interstellar medium. One in six ISFOs have significant emission from PDRs, contributing ∼30%-60% of the total power. ISFOs are young knots of intense star formation.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2014

Implications of Voyager 1 observations beyond the heliopause for the local interstellar electron spectrum

Cosmic-ray observations made by the Voyager 1 spacecraft outside the dominant modulating influence of the heliosphere finally allow the comparison of computed galactic spectra with experimental data at lower energies. These computed spectra, based on galactic propagation models, can now be compared with observations at low energies by Voyager 1 and at high energies by the PAMELA space detector at Earth. This improves understanding of basic propagation effects and also provides solar modulation studies with reliable input spectra from 1 MeV to 100 GeV. We set out to reproduce the Voyager 1 electron observations in the energy range of 6-60 MeV, as well as the PAMELA electron spectrum above 10 GeV, using the GALPROP code. By varying the source spectrum and galactic diffusion parameters, specifically the rigidity dependence of spatial diffusion, we find local interstellar spectra that agree with both power-law spectra observed by Voyager 1 beyond the heliopause. The local interstellar spectrum between ∼1 MeV and 100 GeV indicates that it is the combination of two power laws, with E {sup –(1.45} {sup ±} {sup 0.15)} below ∼100 MeV and E {sup –(3.15} {sup ±} {sup 0.05)} above ∼100 MeV. A gradual turn in the spectral shape matching the power laws is found, between 2.0 ± 0.5) GeV and (100 ± 10) MeV. According to our simplified modeling, this transition is caused primarily by galactic propagation effects. We find that the intensity beyond the heliopause at 10 MeV is (350 ± 50) electrons m{sup –2} s{sup –1} sr{sup –1} MeV{sup –1}, decreasing to (50 ± 5) electrons m{sup –2} s{sup –1} sr{sup –1} MeV{sup –1} at 100 MeV.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2014

PICKUP ION MEDIATED PLASMAS. I. BASIC MODEL AND LINEAR WAVES IN THE SOLAR WIND AND LOCAL INTERSTELLAR MEDIUM

Pickup ions (PUIs) in the outer heliosphere and the local interstellar medium are created by charge exchange between protons and hydrogen (H) atoms, forming a thermodynamically dominant component. In the supersonic solar wind beyond >10 AU, in the inner heliosheath (IHS), and in the very local interstellar medium (VLISM), PUIs do not equilibrate collisionally with the background plasma. Using a collisionless form of Chapman-Enskog expansion, we derive a closed system of multi-fluid equations for a plasma comprised of thermal protons and electrons, and suprathermal PUIs. The PUIs contribute an isotropic scalar pressure to leading order, a collisionless heat flux at the next order, and a collisionless stress tensor at the second-order. The collisionless heat conduction and viscosity in the multi-fluid description results from a non-isotropic PUI distribution. A simpler one-fluid MHD-like system of equations with distinct equations of state for both the background plasma and the PUIs is derived. We investigate linear wave properties in a PUI-mediated three-fluid plasma model for parameters appropriate to the VLISM, the IHS, and the solar wind in the outer heliosphere. Five distinct wave modes are possible: Alfvén waves, thermal fast and slow magnetoacoustic waves, PUI fast and slow magnetoacoustic waves, and an entropy mode. The thermal and PUI acoustic modes propagate at approximately the combined thermal magnetoacoustic speed and the PUI sound speed respectively. All wave modes experience damping by the PUIs through the collisionless PUI heat flux. The PUI-mediated plasma model yields wave properties, including Alfvén waves, distinctly different from those of the standard two-fluid model.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2015

CYANOMETHANIMINE ISOMERS IN COLD INTERSTELLAR CLOUDS: INSIGHTS FROM ELECTRONIC STRUCTURE AND KINETIC CALCULATIONS

New insights into the formation of interstellar cyanomethanimine, a species of great relevance in prebiotic chemistry, are provided by electronic structure and kinetic calculations for the reaction CN + CH{sub 2} = NH. This reaction is a facile formation route of Z,E-C-cyanomethanimine, even under the extreme conditions of density and temperature typical of cold interstellar clouds. E-C-cyanomethanimine has been recently identified in Sgr B2(N) in the Green Bank Telescope (GBT) PRIMOS survey by P. Zaleski et al. and no efficient formation routes have been envisaged so far. The rate coefficient expression for the reaction channel leading to the observed isomer E-C-cyanomethanimine is 3.15 × 10-10 × (T/300){sup 0.152} × e{sup (−0.0948/T)}. According to the present study, the more stable Z-C-cyanomethanimine isomer is formed with a slightly larger yield (4.59 × 10{sup −10} × (T/300){sup 0.153} × e{sup (−0.0871/T)}. As the detection of E-isomer is favored due to its larger dipole moment, the missing detection of the Z-isomer can be due to the sensitivity limit of the GBT PRIMOS survey and the detection of the Z-isomer should be attempted with more sensitive instrumentation. The CN + CH{sub 2} = NH reaction can also play a role in the chemistry of the upper atmosphere of Titan where the cyanomethanimine products can contribute to the buildup of the observed nitrogen-rich organic aerosols that cover the moon.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2014

SOLAR PHOTOIONIZATION RATES FOR INTERSTELLAR NEUTRALS IN THE INNER HELIOSPHERE: H, He, O, AND Ne

Extreme UV (EUV) spectra from the Thermosphere Ionosphere Mesosphere Energetics and Dynamics (TIMED)/Solar EUV Experiment are used to infer photoionization rates in the inner heliosphere. Relating these rates to various proxies describing the solar EUV radiation, we construct a multi-linear model which allows us to extrapolate ionization rates back to periods when no routine measurements of the solar EUV spectral distribution have been available. Such information is important, e.g., for comparing conditions of the interstellar neutral particles in the inner heliosphere at the time of Ulysses/GAS observations with conditions during the more recent observations of the Interstellar Boundary Explorer. From a period of 11 yr when detailed spectra from both TIMED and three proxies—Solar and Heliospheric Observatory/CELIAS/SEM-rates, F10.7 radio flux, and Mg II core-to-wing indices—have been available, we conclude that the simple model is able to reproduce the photoionization rates with an uncertainty of typically 5%.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2014

INTERACTION BETWEEN THE BROAD-LINED TYPE Ic SUPERNOVA 2012ap AND CARRIERS OF DIFFUSE INTERSTELLAR BANDS

Diffuse interstellar bands (DIBs) are absorption features observed in optical and near-infrared spectra that are thought to be associated with carbon-rich polyatomic molecules in interstellar gas. However, because the central wavelengths of these bands do not correspond to electronic transitions of any known atomic or molecular species, their nature has remained uncertain since their discovery almost a century ago. Here we report on unusually strong DIBs in optical spectra of the broad-lined Type Ic supernova SN 2012ap that exhibit changes in equivalent width over short (≲ 30 days) timescales. The 4428 Å and 6283 Å DIB features get weaker with time, whereas the 5780 Å feature shows a marginal increase. These nonuniform changes suggest that the supernova is interacting with a nearby source of DIBs and that the DIB carriers possess high ionization potentials, such as small cations or charged fullerenes. We conclude that moderate-resolution spectra of supernovae with DIB absorptions obtained within weeks of outburst could reveal unique information about the mass-loss environment of their progenitor systems and provide new constraints on the properties of DIB carriers.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2014

INTERSTELLAR MAGNETIC FIELDS OBSERVED BY VOYAGER 1 BEYOND THE HELIOPAUSE

Voyager 1 (V1) was beyond the heliopause between 2013.00 and 2014.41, where it was making in situ observations of the interstellar magnetic field (ISMF). The average azimuthal angle and elevation angle of the magnetic field B were (λ) = 292.°5 ± 1.°4 and (δ) = 22.°1 ± 1.°2, respectively. The angles λ and δ varied linearly at (1.°4 ± 0.°1) yr{sup –1} and (–1.°1 ± 0.°1) yr{sup –1}, respectively, suggesting that V1 was measuring the draped ISMF around the heliopause. The distributions of hourly averages of λ and δ were Gaussian distributions, with most probable values 292.°5 and 22.°1, and standard deviations (SDs) 1.°3 and 1.°1, respectively. The small SD indicates little or no turbulence transverse to B . An abrupt decrease in B from 0.50 nT on 2013/129.9 to 0.46 nT on 2013/130.6 was observed, possibly associated with a weak reverse shock or magnetoacoustic pressure wave following a burst of electron plasma oscillations. Between 2013/130.6 and 2013/365.3, (B) = 0.464 ± 0.009 nT, (λ) = 292.°6 ± 0.°8, and (δ) = 22.°1 ± 1.°1. The corresponding distribution of hourly averages of B was Gaussian with the most probable value 0.464 nT and σ = 0.009 nT. Since the uncertainty σ corresponds to the instrument and digitization noise, these observations provided an upper limit to the turbulence in the ISMF. The distributions of the hourly increments of B were Gaussian distributions with σ = 0.05 nT, 0.°4, and 0.°4, respectively, indicating that the V1 did not detect evidence of ''intermittent bursts'' of interstellar turbulence.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2014

LABORATORY FORMATION OF FULLERENES FROM PAHS: TOP-DOWN INTERSTELLAR CHEMISTRY

Interstellar molecules are thought to build up in the shielded environment of molecular clouds or in the envelope of evolved stars. This follows many sequential reaction steps of atoms and simple molecules in the gas phase and/or on (icy) grain surfaces. However, these chemical routes are highly inefficient for larger species in the tenuous environment of space as many steps are involved and, indeed, models fail to explain the observed high abundances. This is definitely the case for the C{sub 60} fullerene, recently identified as one of the most complex molecules in the interstellar medium. Observations have shown that, in some photodissociation regions, its abundance increases close to strong UV-sources. In this Letter we report laboratory findings in which C{sub 60} formation can be explained by characterizing the photochemical evolution of large polycyclic aromatic hydrocarbons (PAHs). Sequential H losses lead to fully dehydrogenated PAHs and subsequent losses of C{sub 2} units convert graphene into cages. Our results present for the first time experimental evidence that PAHs in excess of 60 C-atoms efficiently photo-isomerize to buckminsterfullerene, C{sub 60}. These laboratory studies also attest to the importance of top-down synthesis routes for chemical complexity in space.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗