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NASA NTRS2010

Polycyclic Aromatic Hydrocarbons

Carbonaceous materials play an important role in space. Polycyclic Aromatic Hydrocarbons (PAHs) are a ubiquitous component of the carbonaceous materials. PAHs are the best-known candidates to account for the IR emission bands. They are also thought to be among the carriers of the diffuse interstellar absorption bands (DIBs). PAH ionization states reflect the ionization balance of the medium while PAH size, composition, and structure reflect the energetic and chemical history of the medium. A major challenge is to reproduce in the laboratory the physical conditions that exist in the emission and absorption interstellar zones. The harsh physical conditions of the ISM -low temperature, collisionless, strong UV radiation fields- are simulated in the laboratory by associating a molecular beam with an ionizing discharge to generate a cold plasma expansion. PAH ions and radicals are formed from the neutral precursors in an isolated environment at low temperature and probed with high-sensitivity cavity ringdown spectroscopy in the NUV-NIR range. Carbon nanoparticles are also formed during the short residence time of the precursors in the plasma and are characterized with time-offlight mass spectrometry. These experiments provide unique information on the spectra of large carbonaceous molecules and ions in the gas phase that can now be directly compared to interstellar and circumstellar observations (IR emission bands, DIBs, extinction curve). These findings also hold great potential for understanding the formation process of interstellar carbonaceous grains. We will review recent progress in the experimental and theoretical studies of PAHs, compare the laboratory data with astronomical observations and discuss the global implications.

Salama, Farid↗
NASA NTRS2011

The Very Local Universe in X-Rays

There are many open questions in X-ray observations of the Galactic neighborhood and nearby galaxies, such as the properties of the hot ISM and accreting sources, the X-ray/star-formation rate correlation and how the X-ray luminosity function of starburst galaxies. We discuss how these would be addressed by very wide-area (> 100 sq. deg.) X-ray surveys and upcoming X-ray missions. In particular planned NuStar observations of the Galaxy and nearby galaxies will be highlighted.

Ptak, A.↗
NASA NTRS2010

Interstellar Magnetic Fields and Polarimetry of Dust Emission

Magnetic fields are an important ingredient in the stormy cosmos. Magnetic fields: (1) are intimately involved with winds from Active Galactic Nuclei (AGN) and stars (2) create at least some of the structures observed in the ISM (3) modulate the formation of clouds, cores, and stars within a turbulent medium (4) may be dynamically important in protostellar accretion disks (5) smooth weak shocks (C-shocks).

stormy cosmos↗
NASA NTRS2011

Anions in Cometary Comae

The presence of negative ions (anions) in cometary comae is known from Giotto mass spectrometry of IP/Halley. The anions 0-, OH-, C-, CH- and CN- have been detected, as well as unidentified anions with masses 22-65 and 85-110 amu (Chaizy et al. 1991). Organic molecular anions are known to have a significant impact on the charge balance of interstellar clouds and circumstellar envelopes and have been shown to act as catalysts for the gas-phase synthesis of larger hydrocarbon molecules in the ISM, but their importance in cometary comae has not yet been explored. We present details of the first attempt to model the chemistry of anions in cometary comae. Based on the combined chemical and hydro dynamical model of Rodgers & Charnley (2002), we investigate the role of large carbon-chain anions in cometary coma chemistry. We calculate the effects of these anions on coma thermodynamics, charge balance and examine their impact on molecule formation.

Charnley, Steven B.↗
NASA NTRS2003

Wireless Temperature-Monitoring System

A relatively inexpensive instrumentation system that includes units that are connected to thermocouples and that are parts of a radio-communication network has been developed to enable monitoring of temperatures at multiple locations. Because there is no need to string wires or cables for communication, the system is well suited for monitoring temperatures at remote locations and for applications in which frequent changes of monitored or monitoring locations are needed. The system can also be adapted to monitoring of slowly varying physical quantities, other than temperature, that can be transduced by solid-state electronic sensors. The system comprises any number of transmitting units and a single receiving unit (see figure). Each transmitting unit includes connections for as many as four external thermocouples, a signal-conditioning module, a control module, and a radio-communication module. The signal- conditioning module acts as an interface between the thermocouples and the rest of the transmitting unit and includes a built-in solid ambient-temperature sensor that is in addition to the external thermocouples. The control module is a "system-on-chip" embedded processor that includes analog-to-digital converters, serial and parallel data ports, and an interface for local connection to an analog meter that is used during installation to verify correct operation. The radio-communication module contains a commercial spread-spectrum transceiver that operates in the 900-MHz industrial, scientific, and medical (ISM) frequency band. This transceiver transmits data to the receiving unit at a rate of 19,200 baud. The receiving unit includes a transceiver like that of a transmitting unit, plus a control module that contains a system-on-chip processor that includes serial data port for output to a computer that runs monitoring and/or control software, a parallel data port for output to a printer, and a seven-segment light-emitting-diode display.

Solano, Wanda↗
NASA NTRS2012

Morphological Study of Insoluble Organic Matter Residues from Primitive

Insoluble organic matter (IOM) constitutes a major proportion, 70-99%, of the total organic carbon found in primitive chondrites [1, 2]. One characteristic morphological component of IOM is nanoglobules [3, 4]. Some nanoglobules exhibit large N-15 and D enrichments relative to solar values, indicating that they likely originated in the ISM or the outskirts of the protoplanetary disk [3]. A recent study of samples from the Tagish Lake meteorite with varying levels of hydrothermal alteration suggest that nanoglobule abundance decreases with increasing hydrothermal alteration [5]. The aim of this study is to further document the morphologies of IOM from a range of primitive chondrites in order to determine any correlation of morphology with petrographic grade and chondrite class that could constrain the formation and/or alteration mechanisms.

Changela, H. G.↗
NASA NTRS2011

Gas Modelling in the Disc of HD 163296

We present detailed model fits to observations of the disc around the Herbig Ae star HD 163296. This well-studied object has an age of approx. 4Myr, with evidence of a circumstellar disc extending out to approx. 540AU. We use the radiation thermo-chemical disc code ProDiMo to model the gas and dust in the circumstellar disc of HD 163296, and attempt to determine the disc properties by fitting to observational line and continuum data. These include new Herschel/PACS observations obtained as part of the open-time key program GASPS (Gas in Protoplanetary Systems), consisting of a detection of the [Oi] 63 m line and upper limits for several other far infrared lines. We complement this with continuum data and ground-based observations of the CO-12 3-2, 2-1 and CO-13 J=1-0 line transitions, as well as the H2 S(1) transition. We explore the effects of stellar ultraviolet variability and dust settling on the line emission, and on the derived disc properties. Our fitting efforts lead to derived gas/dust ratios in the range 9-100, depending on the assumptions made. We note that the line fluxes are sensitive in general to the degree of dust settling in the disc, with an increase in line flux for settled models. This is most pronounced in lines which are formed in the warm gas in the inner disc, but the low excitation molecular lines are also affected. This has serious implications for attempts to derive the disc gas mass from line observations. We derive fractional PAH abundances between 0.007 and 0.04 relative to ISM levels. Using a stellar and UV excess input spectrum based on a detailed analysis of observations, we find that the all observations are consistent with the previously assumed disc geometry

Tilling, I.↗
NASA NTRS2012

Observations of Nitrogen Fractionation in Prestellar Cores: Nitriles Tracing Interstellar Chemistry

Primitive materials provide important clues on the processes that occurred during the formation and early evolution of the Solar System. Space-based and ground-based observations of cometary comae show that comets appear to contain a mixture of the products of both interstellar and nebular chemistries. Significant 15-nitrogen enrichments have been measured in CN and HCN towards a number of comets and may suggest an origin of interstellar chemical fractionation. Additionally, large N-15 enhancements are found in meteorites and has also led to to the view that the N-15 traces material formed in the interstellar medium (ISM), although multiple sources cannot be excluded. Here, we show the results of observations of the nitrogen and carbon fractionation in prestellar cores for various N-bearing species to decipher the origin of primitive material isotopic enrichments.

Milam, S. N.↗
NASA NTRS2011

The SEDs and Host Galaxies of the Dustiest GRB Afterglows

The afterglows and host galaxies of long gamma-ray bursts (GRBs) offer unique opportunities to study star-forming galaxies in the high-z Universe, Until recently, however. the information inferred from GRB follow-up observations was mostly limited to optically bright afterglows. biasing all demographic studies against sight-lines that contain large amounts of dust. Aims. Here we present afterglow and host observations for a sample of bursts that are exemplary of previously missed ones because of high visual extinction (A(sub v) (Sup GRB) approx > 1 mag) along the sight-line. This facilitates an investigation of the properties, geometry and location of the absorbing dust of these poorly-explored host galaxies. and a comparison to hosts from optically-selected samples. Methods. This work is based on GROND optical/NIR and Swift/XRT X-ray observations of the afterglows, and multi-color imaging for eight GRB hosts. The afterglow and galaxy spectral energy distributions yield detailed insight into physical properties such as the dust and metal content along the GRB sight-line as well as galaxy-integrated characteristics like the host's stellar mass, luminosity. color-excess and star-formation rate. Results. For the eight afterglows considered in this study we report for the first time the redshift of GRBs 081109 (z = 0.97S7 +/- 0.0005). and the visual extinction towards GRBs 0801109 (A(sub v) (Sup GRB) = 3.4(sup +0.4) (sub -0.3) mag) and l00621A (A(sub v) (Sup GRB) = 3.8 +/- 0.2 mag), which are among the largest ever derived for GRB afterglows. Combined with non-extinguished GRBs. there is a strong anti-correlation between the afterglow's metals-to-dust ratio and visual extinction. The hosts of the dustiest afterglows are diverse in their properties, but on average redder(((R - K)(sub AB)) approximates 1.6 mag), more luminous ( approximates 0.9 L (sup *)) and massive ((log M(sup *) [M(solar]) approximates 9.8) than the hosts of optically-bright events. We hence probe a different galaxy population. suggesting that previous host samples miss most of the massive. chemically-evolved and metal-rich members. This also indicates that the dust along the sight-line is often related to host properties, and thus probably located in the diffuse ISM or interstellar clouds and not in the immediate GRB environment. Some of the hosts in our sample. are blue, young or of small stellar mass illustrating that even apparently non-extinguished galaxies possess very dusty sight-lines due to a patchy dust distribution. Conclusions. The afterglows and host galaxies of the dustiest GRBs provide evidence for a complex dust geometry in star-forming galaxies. In addition, they establish a population of luminous. massive and correspondingly chemically-evolved GRB hosts. This suggests that GRBs trace the global star-formation rate better than studies based on optically-selected host samples indicate, and the previously-claimed deficiency of high-mass host galaxies was at least partially a selection effect.

Kruhler, T.↗
NASA NTRS2012

Chemical and Hydrodynamical Models of Cometary Comae

Multi-fluid modelling of the outflowing gases which sublimate from cometary nuclei as they approach the Sun is necessary for understanding the important physical and chemical processes occurring in this complex plasma. Coma chemistry models can be employed to interpret observational data and to ultimately determine chemical composition and structure of the nuclear ices and dust. We describe a combined chemical and hydrodynamical model [1] in which differential equations for the chemical abundances and the energy balance are solved as a function of distance from the cometary nucleus. The presence of negative ions (anions) in cometary comae is known from Giotto mass spectrometry of 1P/Halley. The anions O(-), OH(-), C(-), CH(-) and CN(-) have been detected, as well as unidentified anions with masses 22-65 and 85-110 amu [2]. Organic molecular anions such as C4H(-) and C6H(-) are known to have a significant impact on the charge balance of interstellar clouds and circumstellar envelopes and have been shown to act as catalysts for the gas-phase synthesis of larger hydrocarbon molecules in the ISM, but their importance in cometary comae has not yet been fully explored. We present details of new models for the chemistry of cometary comae that include atomic and molecular anions and calculate the impact of these anions on the coma physics and chemistry af the coma.

Charnley, Steven↗
NASA NTRS2012

Models for Cometary Comae Containing Negative Ions

The presence of negative ions (anions) in cometary comae is known from Giotto mass spectrometry of IP/Halley. The anions O(-), OH(-), C(-), CH(-) and CN(-) have been detected, as well as unidentified anions with masses 22-65 and 85-110 amu [I]. Organic molecular anions such as C4H(-) and C6H(-) are known to have a significant impact on the charge balance of interstellar clouds and circumstellar envelopes and have been shown to act as catalysts for the gas phase synthesis of larger hydrocarbon molecules in the ISM, but their importance in cometary comae has not yet been fully explored. We present details of our new models for the chemistry of cometary comae that include atomic and molecular anions. We calculate the impact of these anions on the charge balance and examine their importance for cometary coma chemistry.

Cordiner, M. A.↗
NASA NTRS2012

Nucleobases and Prebiotic Molecules in Organic Residues Produced from the Ultraviolet Photo-Irradiation of Pyrimidine in NH3 and H2O+NH3 Ices

Although not yet identified in the interstellar medium (ISM), N-heterocycles including nucleobases the information subunits of DNA and RNA are present in carbonaceous chondrites, which indicates that molecules of biological interest can be formed in non-terrestrial environments via abiotic pathways. Recent laboratory experiments and ab-initio calculations have already shown that the irradiation of pyrimidine in pure H2O ices leads to the formation of a suite of oxidized pyrimidine derivatives, including the nucleobase uracil. In the present work, NH3:pyrimidine and H2O:NH3:pyrimidine ice mixtures with different relative proportions were irradiated with UV photons under astrophysically relevant conditions. Liquid- and gas-chromatography analysis of the resulting organic residues has led to the detection of the nucleobases uracil and cytosine, as well as other species of prebiotic interest such as urea and small amino acids. The presence of these molecules in organic residues formed under abiotic conditions supports scenarios in which extraterrestrial organics that formed in space and were subsequently delivered to telluric planets via comets and meteorites could have contributed to the inventory of molecules that triggered the first biological reactions on their surfaces.

Nuevo, Michel↗
NASA NTRS2012

Hydrocarbons on Saturns Satellites: Relationship to Interstellar Dust and the Solar Nebula

To understand the origin and evolution of our Solar System, and the basic components that led to life on Earth, we study interstellar and planetary spectroscopic signatures. The possible relationship of organic material detected in carbonaceous meteorites, interplanetary dust particles (IDPs), comets and the interstellar medium have been the source of speculation over the years as the composition and processes that governed the early solar nebula have been explored to understand the extent to which primitive material survived or became processed. The Cassini VIMS has provided new data relevant to this problem. Three of Saturn's satellites, Phoebe, Iapetus, and Hyperion, are found to have aromatic and aliphatic hydrocarbons on their surfaces. The aromatic hydrocarbon signature (C-H stretching mode at 3.28 micrometers) is proportionally significantly stronger (relative to the aliphatic bands) than that seen in other Solar System bodies (e.g., comets) and materials (Stardust samples, IDPs, meteorites) and the distinctive sub-features of the 3.4 micrometer aliphatic band (CH2 and CH3 groups) are reminiscent of those widely detected throughout the diffuse ISM. Phoebe may be a captured object that originated in the region beyond the present orbit of Neptune, where the solar nebula contained a large fraction of original interstellar ice and dust that was less processed than material closer to the Sun. Debris from Phoebe now resident on Iapetus and Hyperion, as well as o Phoebe itself, thus presents a unique blend of hydrocarbons, amenable to comparisons with interstellar hydrocarbons and other Solar System materials. The dust ring surrounding Saturn, in which Phoebe is embedded, probably originated from a collision with Phoebe. Dust ring particles are the likely source of the organic-bearing materials, and perhaps the recently identified small particles of Fe detected on Saturn's satellites. Lab measurements of the absolute band strengths of representative aliphatic and aromatic molecules, together with measurements from the VIMS data, allow us to calculate the number of C atoms to find the relative abundances of C atoms in the two kinds of organic molecules. The strength of the prominent aromatic C-H stretch band relative to the aliphatic band complex in Phoebe and Iapetus indicates that the relative abundance of aromatic to aliphatic carbon is very large (greater than 200). In contract, the aromatic band is nearly imperceptible in spectra of interplanetary dust particles (IDP), returned samples from comet 91P/Wild 2, insoluable carbonaceous material in most meteorites, and the diffuse interstellar dust (DISM) (although aromatics are known in all these materials-here we consider only the spectroscopic signature)

Cruikshank, D. P.↗
NASA NTRS2012

Interstellar Abundances Toward X Per, Revisited

The nearby X-ray binary X Per (HD 24534) provides a useful beacon with which to measure elemental abundances in the local ISM. We examine absorption features of O, Mg, and Si along this line of sight using spectra from the Chandra Observatory's LETG/ACIS-S and XMM-Newton's RGS instruments. In general, we find that the abundances and their ratios are similar to those of young F and G stars and the most recent solar values. We compare our results with abundances required by dust grain models.

Valencic, Lynne A.↗
NASA NTRS2012

Multi-Wavelength Observations of Supernova Remnants

Supernova remnants (SNRs) provide a laboratory for studying various astrophysical processes, including particle acceleration, thermal and non thermal emission processes across the spectrum, distribution of heavy elements, the physics of strong shock waves, and the progenitor systems and environments of supernovae. Long studied in radio and X-rays, the past decade has seen a dramatic increase in the detection and subsequent study of SNRs in the infrared and gamma-ray regimes. Understanding the evolution of SNRs and their interaction with the interstellar medium requires a multi-wavelength approach. I will review the various physical processes observed in SNRs and how these processes are intertwined. In particular, I will focus on X-ray and infrared observations, which probe two very different but intrinsically connected phases of the ISM: gas and dust. I will discuss results from multi-wavelength studies of several SNRs at various stages of evolution, including Kepler, RCW 86, and the Cygnus Loop.

Williams, B.↗
NASA NTRS2012

Near-Infrared Band Strengths of Molecules Diluted in N2 and H20 Ice Mixtures Relevant to Interstellar and Planetary Ices

In order to determine the column density of a component of an ice from its infrared absorption features, the strengths of these features must be known. The peak positions, widths, profiles, and strengths of a certain ice component's infrared absorption features are affected be the overall composition of the ice. Many satellites within the solar system have surfaces that are dominated by H2O or N2 and ices in the interstellar medium (ISM) are primarily composed of H2O. The experiments presented here focus on the near-infrared absorption features of CO, CO2, CH4, and NH3 (nu=10,000-4,000/cm, lambda=1-2.5 microns) and the effects of diluting these molecules in N2 or H2O ice (mixture ratio of 5:1). This is a continuation of previous results published by our research group.

Richey, C. R.↗
NASA NTRS2012

Photochemistry of Pyrimidine in Astrophysical Ices: Formation of Nucleobases and Other Prebiotic Species

Nucleobases are N-heterocycles that are the informational subunits of DNA and RNA. They are divided into two molecular groups: pyrimidine bases (uracil, cytosine, and thymine) and purine bases (adenine and guanine). Nucleobases have been detected in meteorites, and their extraterrestrial origin confirmed by isotopic measurements. Although no N-heterocycles have ever been observed in the ISM, the positions of the 6.2- m interstellar emission features suggest a population of such molecules is likely to be present. However, laboratory experiments have shown that the ultraviolet (UV) irradiation of pyrimidine in ices of astrophysical relevance such as H2O, NH3, CH3OH, CH4, CO, or combinations of these at low temperature (less than or equal to 20 K) leads to the formation of several pyrimidine derivatives including the nucleobases uracil and cytosine, as well as precursors such as 4(3H)-pyrimidone and 4-aminopyrimidine. Quantum calculations on the formation of 4(3H)-pyrimidone and uracil from the irradiation of pyrimidine in pure H2O ices are in agreement with their experimental formation pathways.10 In those residues, other species of prebiotic interest such as urea as well as the amino acids glycine and alanine could also be identified. However, only very small amounts of pyrimidine derivatives containing CH3 groups could be detected, suggesting that the addition of methyl groups to pyrimidine is not an efficient process. For this reason, the nucleobase thymine was not observed in any of the samples. In this work, we study the formation of nucleobases and other photo-products of prebiotic interest from the UV irradiation of pyrimidine in ices containing H2O, NH3, CH3OH, and CO, mixed in astrophysical proportions.

Nuevo, Michel↗
NASA NTRS2012

Laboratory Spectra of CO2 Vibrational Modes in Planetary Ice Analogs

Laboratory spectra have shown that CO2 is a powerful diagnostic tool for analyzing infrared data from remote observations, as it has been detected on icy moons in the outer Solar System as well as dust grain surfaces in the interstellar medium (ISM). IR absorption band profiles of CO2 within ice mixtures containing H2O and CH3OH change with respect to temperature and mixture ratios. In this particular study, the CO2 asymmetric stretching mode near 4.3 m (2350 cm (exp-1)), overtone mode near 1.97 m (5080 cm (exp-1)), and the combination bands near 2.7 m (3700 cm (exp-1)), 2.8 m (3600 cm (exp-1)), and 2.02 m (4960 cm (exp -1)), are systematically observed in different mixtures with H2O and CH3OH in temperature ranges from 15K to 150 K. Additionally, some high-temperature deposits (T greater than 50 K) of H2O, CH3OH, and CO2 ice mixtures were performed. These data may then be used to interpret infrared observational data obtained from icy surfaces in the outer Solar System and beyond.

White, Douglas↗