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At least 721 records · Page 40

Formation of Fe/mg Smectite Under Acidic Conditions from Synthetic Adirondack Basaltic Glass: an Analog to Fe/mg Smectite Formation on Mars

Smectite has been detected as layered material hundreds of meters thick, in intracrater depositional fans, in plains sediments, and deposits at depth on Mars. If early Mars hosted a dense CO2 atmosphere, then extensive carbonate should have formed in the neutral/alkaline conditions expected for smectite formation. However, large carbonate deposits on Mars have not been discovered. Instead of neutral to moderately alkaline conditions, early Mars may have experienced mildly acidic conditions that allowed for Fe/Mg smectite formation but prevented widespread carbonate formation. The objective of this work is to demonstrate that Fe(II)/Mg saponite and nontronite can form in mildly acidic solutions (e.g., pH 4). Synthetic basaltic glass (< 53 microns) of Adirondack rock class composition was exposed to pH 4 (acetic acid buffer) and N2 purged (anoxic) solutions amended with 0 and 10 mM Mg or Fe(II). Basaltic glass in these solutions was heated to 200 C in batch reactors for 1, 7, and 14 days. X-ray diffraction analysis of reacted materials detected the presence of phyllosilicates as indicated by a approx. 15.03-15.23Angstroms (001) peak. Smectite was confirmed as the phyllosilicate after treatments with glycerol and KCl and heating to 550 C. Trioctahedral saponite was confirmed by the presence of a 4.58 to 4.63 Angstroms (02l) and 1.54Angstroms (060) peaks. Saponite concentration was highest, as indicated by XRD peak intensity, in the 10 mM Mg treatment followed by the 0 mM and then 10 mM Fe(II) treatments. This order of sapontite concentration suggests that Fe(II) additions may have a role in slowing the kinetics of saponite formation relative to the other treatments. Nontronite synthesis was attempted by exposing Adirondack basaltic glass to pH 4 oxic solutions (without N2 purge) at 200 C for 14 days. X-ray diffraction analysis indicated that mixtures of trioctahedral (saponite) and dioctahedral (nontronite) may have formed in these experiments based on the 02l and 060 peaks. Moessbauer analysis coupled with future experiments are planned to verify if nontronite can be formed under mildly acidic and oxic conditions. Results of this work demonstrate that acidic conditions could have occurred on an early Mars, which allowed for smectite formation but inhibited carbonate formation.

Sutter, B.↗

Analysis/Design Tool

Excelerator II, developed by INTERSOLV, Inc., provides a complete environment for rules-based expert systems. The software incorporates NASA's C Language Integrated Production System (CLIPS), a shell for constructing expert systems. Excelerator II provides complex verification and transformation routines based on matching that is simple and inexpensive. *Excelerator II was sold to SELECT Software Tools in June 1997 and is now called SELECT Excelerator. SELECT has assumed full support and maintenance for the product line.

Source record↗

Ferredoxin and ferredoxin-NADP reductase from photosynthetic and nonphotosynthetic tissues of tomato

Ferredoxin and ferredoxin-NADP+ oxidoreductase (FNR) were purified from leaves, roots, and red and green pericarp of tomato (Lycopersicon esculentum, cv VFNT and cv Momotaro). Four different ferredoxins were identified on the basis of N-terminal amino acid sequence and charge. Ferredoxins I and II were the most prevalent forms in leaves and green pericarp, and ferredoxin III was the most prevalent in roots. Red pericarp of the VFNT cv yielded variable amounts of ferredoxins II and III plus a unique form, ferredoxin IV. Red pericarp of the Momotaro cv contained ferredoxins I, II, and IV. This represents the first demonstration of ferredoxin in a chromoplast-containing tissue. There were no major differences among the tomato ferredoxins in absorption spectrum or cytochrome c reduction activity. Two forms of FNR were present in tomato as judged by anion exchange chromatography and by sodium dodecyl sulfate-polyacrylamide gel electrophoresis. FNR II had a lower apparent relative molecular weight, a slightly altered absorption spectrum, and a lower specific activity for cytochrome c reduction than FNR I. FNR II could be a partially degraded form of FNR I. The FNRs from the different tissues of tomato plants all showed diaphorase activity, with FNR II being more active than FNR I. The presence of ferredoxin and FNR in heterotrophic tissues of tomato is consistent with the existence of a nonphotosynthetic ferredoxin/FNR redox pathway to support the function of ferredoxin-dependent enzymes.

NASA Discipline Number 52-30↗

The nature of RV Tauri variables. II- Properties of the peculiar F stars

Basic atmospheric parameters for six RV Tauri variables are considered. The Fe/H abundance ratios for the stars are found to be between -1 and - 1.7, inclusively. Stars of the Preston (1962) type B and C subclasses do not appear segregated by metallicity. In comparison to the cooler Preston type A stars, types B and C are shown to be more metal poor by a factor of 10, on average. The results are consistent with the theory that RV Tau type B and C variables are a direct evolutionary analog to the cluster type II Cepheids.

Cardelli, Jason A.↗

Metal-line absorption at Z(sub abs) approximately Z(sub em) from associated galaxies

For a preliminary study of whether C IV absorption at Z(sub abs) approximately Z(sub em) is related to associated galaxy companions, we have collected data from a sample of 10 quasars with 0.15 less than z less than 0.65 for which high-resolution optical and UV spectroscopy is available from the literature, and for which we have deep optical images and limited spectroscopy. We also present new optical spectra for two of our samples. Four of these quasars have associated C IV absorption systems. In thes four fields, there are eight galaxies with M(sub r) less than -19.0 mag within 35 kpc of the quasar (projected distance, assuming they are at the quasar redshift), which may be candidates for the associated C IV absorption. This observed density of galaxies near quasars with associated C IV absorption is significantly greater than that for a control sample of quasars chosen from the literature. This result suggests that galaxies near the quasar line of sight may be linked with associated C IV absorption. None of these quasars show associated Mg II absorption, despite the presence of galaxies very near the line of sight, suggesting a Mg II 'proximity effect,' where ionizing flux from the quasar destroys the Mg(+) from at least the outer parts of the galaxies. Three quasars are located in rich galaxy clusters, but none of these quasars are found to have associated C IV absorption. This suggests that galaxies in rich clusters associated with quasars are less likely to be metal-line absorbers. It is plausible that the extended galaxy halos which may be responsible for the absorptions are stripped from galaxies in these dense environments. While it seems that at Z approximately 0.6 rich clusters do not cause them, associated C IV absorption systems at higher redshift may be explained by associated clusters if there has been evolution in the properties of galaxy halos in dense environments.

Ellingson, E.↗

Motion Imagery and Robotics Application (MIRA)

Objectives include: I. Prototype a camera service leveraging the CCSDS Integrated protocol stack (MIRA/SM&C/AMS/DTN): a) CCSDS MIRA Service (New). b) Spacecraft Monitor and Control (SM&C). c) Asynchronous Messaging Service (AMS). d) Delay/Disruption Tolerant Networking (DTN). II. Additional MIRA Objectives: a) Demo of Camera Control through ISS using CCSDS protocol stack (Berlin, May 2011). b) Verify that the CCSDS standards stack can provide end-to-end space camera services across ground and space environments. c) Test interoperability of various CCSDS protocol standards. d) Identify overlaps in the design and implementations of the CCSDS protocol standards. e) Identify software incompatibilities in the CCSDS stack interfaces. f) Provide redlines to the SM&C, AMS, and DTN working groups. d) Enable the CCSDS MIRA service for potential use in ISS Kibo camera commanding. e) Assist in long-term evolution of this entire group of CCSDS standards to TRL 6 or greater.

Martinez, Lindolfo↗

Small scale wind tunnel model investigation of hybrid high lift systems combining upper surface blowing with the internally blown flap

A small-scale wind tunnel test of a two engine hybrid model with upper surface blowing on a simulated expandable duct internally blown flap was accomplished in a two phase program. The low wing Phase I model utilized 0.126c radius Jacobs/Hurkamp flaps and 0.337c radius Coanda flaps. The high wing Phase II model was utilized for continued studies on the Jacobs/Hurkamp flap. Principal study areas included: basic data both engines operative and with an engine out, control flap utilization, horizontal tail effectiveness, spoiler effectiveness, USB nacelle deflector study and USB/IBF pressure ratio effects.

Waites, W. L.↗

Studies of interstellar absorption lines with IUE

The paper deals with a survey of interstellar absorption lines in the wavelength region from 1150 to 3200 A toward 25 stars. The spectra of 10 of these stars show very strong narrow absorption lines of Si IV and C IV. Lines of N V appear in eight directions. The N V lines can arise in the same gas that is responsible for the ubiquitous interstellar lines of O VI, observed previously with a Copernicus spectrometer, but the lines of Si IV and C IV must be formed in a cooler gas. The measured lines of Si IV and C IV can be produced by normal H II regions photoionized by the observed stars.

Black, J. H.↗

On the origin and distribution of C IV and Si IV ions in the neighboring interstellar medium

IUE spectrometer observational data are reported on the C IV, Si IV, and N V absorption lines in 46 distant stars at FWHM resolution of 30 km/sec. A simple analytic theory is given for these contributions, including the effects of ionization by a soft X-ray background. While for some of the most distant field stars a photoionized contribution may be ruled out, C IV absorption lines are detected which are shallow and broad. It is suggested that what are being detected in these cases are contributions from the hot interstellar gas that is responsible for the O VI absorption lines. Most of the Si IV and C IV lines probably arise in the H II regions surrounding the observed star or its neighbors.

Cowie, L. L.↗

Observations of the 145.5 micron O I forbidden emission line in the Orion Nebula

A first set of observations of the forbidden O I 3P0-3P1 (145.5 micron) transition has been obtained. The line was observed both in a 1 x 1 arcmin beam centered on the Trapezium and in a 7 x 7 arcmin beam encompassing most of the Orion Nebula; a wide-beam (7 x 7 arcmin) map of the region has also been constructed which shows that most of the emission is confined to the central regions of the nebula. These observations are consistent with optically thin emission in the 145.5 micron line and self-absorbed 63.2 micron emission lines. Mechanisms for the excitation of neutral oxygen are considered, and it is concluded that much of the observed emission originates in the thin radio recombination line-emitting C II/H I envelope bordering on the H II region.

Stacey, G. J.↗

Recent studies of magnetic canopies

Two current studies are described which stem from Giovanelli's seminal studies of the spreading of chromospheric fields near active regions and active-region network. First, improved observational techniques are described for obtaining magnetograms in the Ca II 8542 A, Fe I 8688 A, and C I 9111 A lines which at least in principle allow for more accurate treatment of instrumental noise and allow better inference of field orientation. Second, a generalized response function is developed for calculating theoretical magnetograph signals from arbitrary line-of-sight variations of magnetic field, and initial applications to two-dimensional, potential-field models of network fields are described. Preliminary indications are that potential-field models can better explain the presence of low-lying, diffuse horizontal fields than can thin flux-tube models, but fail to predict a differential response between the different lines.

Jones, H. P.↗

Doppler tomography of the stellar wind of the Wolf-Rayet binary star V444 Cygni

High dispersion IUE observations of V444 Cyg around its orbit, emphasizing the C IV, N V, N IV, and He II profile variations are presented. The density and velocity structure of the wind, and details of the interaction between the O star and WR wind are discussed. Absorption becomes strongest and most nearly symmetric during primary eclipse, when the line of sight passes through the densest and most sluggish part of the wind. As the orbit progresses through quadrature, the terminal velocity does not change substantially, although the line of sight to the O star intersects more distant portions of the wind at lower velocity, indicating that there is still a considerable absorption in the line being seen toward the WR core. At secondary minimum, the core is partially occulted and the presence of the cavity eliminates the absorption component, while at third quadrature, a profile almost identical in appearance to that at first quadrature is observed.

Brown, Douglas N.↗

Theoretical and material studies on thin-film electroluminescent devices

The effect of surface nucleation processes on the quality of ZnS layers grown on (001) GaAs substrates by molecular beam epitaxy is reported. Reflection high energy electron diffraction indicated that nucleation at high temperatures produced more planar surfaces than nucleation at low temperatures, but the crystalline quality as accessed by x ray double crystal diffractometry is relatively independent of nucleation temperature. A critical factor in layer quality was the initial roughness of the GaAs surfaces.

Summers, C. J.↗