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At least 721 records · Page 40

Elucidating Arsenic and Selenium Speciation in Coal Fly Ashes

Coal fly ash (CFA) is produced during the coal combustion process and contains trace elements (<100 ppm) including selenium (Se) and arsenic (As), both detrimental for environmental and human health. Existing management strategies for CFAs involve disposal in landfills and ash ponds, as well as beneficial usage in other applications such as in concrete. Both the direct disposal and beneficial usage of CFA raise concerns for environmental hazards due to the potential leaching of Se and As. CFAs were classified as reusable material by the U.S. Environmental Protection Agency (EPA) with the first federal regulation (Disposal of Coal Combustion Residuals from Electric Utilities, CCR) for its disposal established six years ago. During coal combustion process, parameters such as furnace firing type, emissions controls, coal rank, use of additives, and particulate matter controls, could contribute to significant variability in As/Se concentrations and their speciation. Although there have been a handful of studies on As/Se speciation on small sets of samples, they do not fully represent the current state of coal-fired electrical generating units. Little information exists on the detailed speciation (e.g. oxidation state, complexation state) of As/Se in large set of fly ash samples. To better investigate the role of the potential contributing parameters, a large-scale survey study with representative samples of typical coal source and combustion conditions is highly desired. The overall goal of this research is to systematically characterize As and Se speciation of representative coal fly ash samples using state-of-the-art synchrotron based spectroscopic and microscopic techniques, in order to develop a correlation between coal source/type, operation condition, As/Se speciation, and As/Se mobility. A detailed survey study was conducted documenting the current state-of-knowledge on fossil power generating units as a function of coal type/source, operating conditions, environmental control systems, additive use, and fly ash handling methods. Based on this survey, a matrix of fly ash samples representing a range of conditions were chosen and collected. The collected ash samples were analyzed for bulk characteristics such as elemental composition, microstructure, chemical and mineralogical composition, surface area, and particle size distribution. State-of-the-art synchrotron X-ray microscopy and spectroscopy techniques were applied to reveal the molecular scale speciation information of As and Se, such as oxidation state, association with other elements/minerals, and complexation states.

01 COAL, LIGNITE, AND PEAT↗

Simultaneous Exposure of Cultured Human Lymphoblastic Cells to Simulated Microgravity and Radiation Increases Chromosome Aberrations

During space travel, humans are continuously exposed to two major environmental stresses, microgravity (μG) and space radiation. One of the fundamental questions is whether the two stressors are interactive. For over half a century, many studies were carried out in space, as well as using devices that simulated μG on the ground to investigate gravity effects on cells and organisms, and we have gained insights into how living organisms respond to μG. However, our knowledge on how to assess and manage human health risks in long-term mission to the Moon or Mars is drastically limited. For example, little information is available on how cells respond to simultaneous exposure to space radiation and μG. In this study, we analyzed the frequencies of chromosome aberrations (CA) in cultured human lymphoblastic TK6 cells exposed to X-ray or carbon ion under the simulated μG conditions. A higher frequency of both simple and complex types of CA were observed in cells exposed to radiation and μG simultaneously compared to CA frequency in cells exposed to radiation only. Our study shows that the dose response data on space radiation obtained at the 1G condition could lead to the underestimation of astronauts’ potential risk for health deterioration, including cancer. This study also emphasizes the importance of obtaining data on the molecular and cellular responses to irradiation under μG conditions.

59 BASIC BIOLOGICAL SCIENCES↗

Versatile soil gas concentration and isotope monitoring: optimization and integration of novel soil gas probes with online trace gas detection

Abstract. Gas concentrations and isotopic signatures can unveil microbial metabolisms and their responses to environmental changes in soil. Currently, few methods measure in situ soil trace gases such as the products of nitrogen and carbon cycling or volatile organic compounds (VOCs) that constrain microbial biochemical processes like nitrification, methanogenesis, respiration, and microbial communication. Versatile trace gas sampling systems that integrate soil probes with sensitive trace gas analyzers could fill this gap with in situ soil gas measurements that resolve spatial (centimeters) and temporal (minutes) patterns. We developed a system that integrates new porous and hydrophobic sintered polytetrafluoroethylene (sPTFE) diffusive soil gas probes that non-disruptively collect soil gas samples with a transfer system to direct gas from multiple probes to one or more central gas analyzer(s) such as laser and mass spectrometers. Here, we demonstrate the feasibility and versatility of this automated multiprobe system for soil gas measurements of isotopic ratios of nitrous oxide (δ18O, δ15N, and the 15N site preference of N2O), methane, carbon dioxide (δ13C), and VOCs. First, we used an inert silica matrix to challenge probe measurements under controlled gas conditions. By changing and controlling system flow parameters, including the probe flow rate, we optimized recovery of representative soil gas samples while reducing sampling artifacts on subsurface concentrations. Second, we used this system to provide a real-time window into the impact of environmental manipulation of irrigation and soil redox conditions on in situ N2O and VOC concentrations. Moreover, to reveal the dynamics in the stable isotope ratios of N2O (i.e., 14N14N16O, 14N15N16O, 15N14N16O, and 14N14N18O), we developed a new high-precision laser spectrometer with a reduced sample volume demand. Our integrated system – a tunable infrared laser direct absorption spectrometry (TILDAS) in parallel with Vocus proton transfer reaction mass spectrometry (PTR-MS), in line with sPTFE soil gas probes – successfully quantified isotopic signatures for N2O, CO2, and VOCs in real time as responses to changes in the dry–wetting cycle and redox conditions. Broadening the collection of trace gases that can be monitored in the subsurface is critical for monitoring biogeochemical cycles, ecosystem health, and management practices at scales relevant to the soil system.

54 ENVIRONMENTAL SCIENCES↗

Baltimore applications project

An update is presented for the following projects: (1) asphalt pavement recycling; (2) data collection platform/water quality monitoring; (3) digital emergency traffic routing; (4) fire department communications and dispatch system; (5) health department management information system; (6) hazardous materials; (7) coal gasification; and (8) emergency vehicle proximity sensing.

Golden, T. S.↗

Program Diagnoses Nickel/Cadmium Batteries

Nickel Cadmium Battery Expert System-2 (NICBES2) computer program is prototype expert-system program for diagnosis and management of health of nickel/cadmium batteries. Intended to support evaluation of performance of batteries in Hubble Space Telescope spacecraft and to alert personnel to possible malfunctions. Oversees status of batteries by evaluating data gathered in orbit packets, and when so merits, raises alarm and provides diagnosis of faults as well as advice on actions to be taken to remedy condition giving rise to alarm. Provides history of statuses of batteries pertaining to health of batteries, and graphical display to help operator assimilate information generated. Written in C language.

Johnson, Yvette B.↗

Medical care delivery in the US space program

The stated goal of this meeting is to examine the use of telemedicine in disaster management, public health, and remote health care. NASA has a vested interest in providing health care to crews in remote environments. NASA has unique requirements for telemedicine support, in that our flight crews conduct their job in the most remote of all work environments. Compounding the degree of remoteness are other environmental concerns, including confinement, lack of atmosphere, spaceflight physiological deconditioning, and radiation exposure, to name a few. In-flight medical care is a key component in the overall support for missions, which also includes extensive medical screening during selection, preventive medical programs for astronauts, and in-flight medical monitoring and consultation. This latter element constitutes the telemedicine aspect of crew health care. The level of in-flight resources dedicated to medical care is determined by the perceived risk of a given mission, which in turn is related to mission duration, planned crew activities, and length of time required for return to definitive medical care facilities.

Stewart, Donald F.↗

Biodosimetry as a New Paradigm for Determination of Radiation Risks and Risk-Mitigation in Astronauts Exposed to Space Radiation

Predicting risk of cancer in astronauts exposed to space radiation is challenging partly because uncertainties of absorption of dose and the processing of dose-related damage at the cellular level degrade the confidence of predicting the expression of cancer. Cellular biodosimeters that simultaneously report: 1) the quantity of absorbed dose after exposure to ionizing radiation, 2) the quality of radiation delivering that dose, and 3) the macromolecular profiles related to malignant transformation in cells absorbing that dose would therefore be useful. An approach to such a multiparametric biodosimeter will be reported, This is the demonstration of two dose-responsive field-effects of enhanced protein-expression. In one case, expression of keratin 18 (K18) in cultures of human mammary epithelial cells (HMEC) irradiated with cesium-137 gamma-rays is enhanced following exposure of log phase cells to relatively low doses of 30 to 90 cGy. K18 has been reported by a marker for tumor staging and for apoptosis. In the second case, expression of connexin 43 (Cx43) is increased in irradiated stationary phase cultures of HMEC, indicating enhanced formation of gap junctions. Gap junctions have been reported to be involved in bystander effects following irradiation. It is a biodosimeter for assessing radiogenic damage. It is suggested further that such biomolecular dosimetry may introduce a new paradigm for assessing cancer risk and risk-mitigation in individuals, a requirement for managing radiation health in astronauts during extended missions in space. This new paradigm is built upon the statistical power provided by the use of functional genomics and proteomics represented in combined gene- and protein-expression assays.

Richmond, Robert↗

Engineering sensors for the Cassini spacecraft

The intent of this paper is to review the subsystems of the Cassini spacecraft and to discuss the types of devices that are used to collect engineering data for each of these subsystems.

vehicle health management fault protection spacecr↗

A summary of spacecraft engineering sensors

This paper gives a data table summary of the different types of engineering sensors that are used onboard a typical spacecraft.

vehicle health management fault protection spacecr↗

IVHM Sensors Program

Explore the source record for details and available documents.

sensors integrated vehicle health management↗

Practical Application of Model-based Programming and State-based Architecture to Space Missions

Innovative systems and software engineering solutions are required to meet the increasingly challenging demands of deep-space robotic missions. While recent advances in the development of an integrated systems and software engineering approach have begun to address some of these issues, they are still at the core highly manual and, therefore, error-prone. This paper describes a task aimed at infusing MIT's model-based executive, Titan, into JPL's Mission Data System (MDS), a unified state-based architecture, systems engineering process, and supporting software framework. Results of the task are presented, including a discussion of the benefits and challenges associated with integrating mature model-based programming techniques and technologies into a rigorously-defined domain specific architecture.

state analysis↗

Solutions Network Formulation Report. The Potential Contribution of the Ocean Surface Topography Mission to the General NOAA Oil Monitoring Environment

Data collected by the OSTM could be used to provide a solution for the GNOME DST. GNOME, developed by NOAA?s Office of Response and Restoration Hazardous Materials Response Division, geospatially models oil spill trajectories using wind, current, river flow, and tidal data. Data collected by the OSTM would supply information about ocean currents and wind speeds. This Candidate Solution is in alignment with the Coastal Management, Water Management, Disaster Management, Public Health, Ecological Forecasting, and Homeland Security National Applications and will benefit society by improving the capabilities of emergency responders who evaluate an oil spill?s probable threat.

Hilbert, Kent↗

Solutions Network Formulation Report. Visible/Infrared Imager/Radiometer Suite and Landsat Data Continuity Mission Simulated Data Products for the Great Lakes Basin Ecological Team

The proposed solution would simulate VIIRS and LDCM sensor data for use in the USGS/USFWS GLBET DST. The VIIRS sensor possesses a spectral range that provides water-penetrating bands that could be used to assess water clarity on a regional spatial scale. The LDCM sensor possesses suitable spectral bands in a range of wavelengths that could be used to map water quality at finer spatial scales relative to VIIRS. Water quality, alongshore sediment transport and pollutant discharge tracking into the Great Lakes system are targeted as the primary products to be developed. A principal benefit of water quality monitoring via satellite imagery is its economy compared to field-data collection methods. Additionally, higher resolution satellite imagery provides a baseline dataset(s) against which later imagery can be overlaid in GIS-based DST programs. Further, information derived from higher resolution satellite imagery can be used to address public concerns and to confirm environmental compliance. The candidate solution supports the Public Health, Coastal Management, and Water Management National Applications.

Estep, Leland↗

Landsat Science: 40 Years of Innovation and Opportunity

Landsat satellites have provided unparalleled Earth-observing data for nearly 40 years, allowing scientists to describe, monitor and model the global environment during a period of time that has seen dramatic changes in population growth, land use, and climate. The success of the Landsat program can be attributed to well-designed instrument specifications, astute engineering, comprehensive global acquisition and calibration strategies, and innovative scientists who have developed analytical techniques and applications to address a wide range of needs at local to global scales (e.g., crop production, water resource management, human health and environmental quality, urbanization, deforestation and biodiversity). Early Landsat contributions included inventories of natural resources and land cover classification maps, which were initially prepared by a visual interpretation of Landsat imagery. Over time, advances in computer technology facilitated the development of sophisticated image processing algorithms and complex ecosystem modeling, enabling scientists to create accurate, reproducible, and more realistic simulations of biogeochemical processes (e.g., plant production and ecosystem dynamics). Today, the Landsat data archive is freely available for download through the USGS, creating new opportunities for scientists to generate global image datasets, develop new change detection algorithms, and provide products in support of operational programs such as Reducing Emissions from Deforestation and Forest Degradation in Developing Countries (REDD). In particular, the use of dense (approximately annual) time series to characterize both rapid and progressive landscape change has yielded new insights into how the land environment is responding to anthropogenic and natural pressures. The launch of the Landsat Data Continuity Mission (LDCM) satellite in 2012 will continue to propel innovative Landsat science.

Cook, Bruce D.↗

America's Next Great Ship: Space Launch System Core Stage Transitioning from Design to Manufacturing

The Space Launch System (SLS) Program is essential to achieving the Nation's and NASA's goal of human exploration and scientific investigation of the solar system. As a multi-element program with emphasis on safety, affordability, and sustainability, SLS is becoming America's next great ship of exploration. The SLS Core Stage includes avionics, main propulsion system, pressure vessels, thrust vector control, and structures. Boeing manufactures and assembles the SLS core stage at the Michoud Assembly Facility (MAF) in New Orleans, LA, a historical production center for Saturn V and Space Shuttle programs. As the transition from design to manufacturing progresses, the importance of a well-executed manufacturing, assembly, and operation (MA&O) plan is crucial to meeting performance objectives. Boeing employs classic techniques such as critical path analysis and facility requirements definition as well as innovative approaches such as Constraint Based Scheduling (CBS) and Cirtical Chain Project Management (CCPM) theory to provide a comprehensive suite of project management tools to manage the health of the baseline plan on both a macro (overall project) and micro level (factory areas). These tools coordinate data from multiple business systems and provide a robust network to support Material & Capacity Requirements Planning (MRP/CRP) and priorities. Coupled with these tools and a highly skilled workforce, Boeing is orchestrating the parallel buildup of five major sub assemblies throughout the factory. Boeing and NASA are transforming MAF to host state of the art processes, equipment and tooling, the most prominent of which is the Vertical Assembly Center (VAC), the largest weld tool in the world. In concert, a global supply chain is delivering a range of structural elements and component parts necessary to enable an on-time delivery of the integrated Core Stage. SLS is on plan to launch humanity into the next phase of space exploration.

Birkenstock, Benjamin↗