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At least 721 records · Page 40

Nonlinear dynamics, chaos and complex cardiac arrhythmias

Periodic stimulation of a nonlinear cardiac oscillator in vitro gives rise to complex dynamics that is well described by one-dimensional finite difference equations. As stimulation parameters are varied, a large number of different phase-locked and chaotic rhythms is observed. Similar rhythms can be observed in the intact human heart when there is interaction between two pacemaker sites. Simplified models are analyzed, which show some correspondence to clinical observations.

Glass, L.↗

Performance of cross-flow turbines with varying blade materials and unsupported blade span

Cross-flow turbines could play a larger role in the diversification of the global energy supply if the impact of more cost-competitive design choices on performance and rotor dynamics was better understood. This study focuses on rotor performance and blade strain measurements while varying the following parameters: blade materials and blade free end length by changing strut support position. Towing tank experiments were performed with a modular 1-meter diameter cross-flow turbine consisting of three NACA 0018 blades with two support struts. One strut was fixed at the lower end of the turbine, while the second strut was adjustable, thereby changing the length of the free end. The blade materials tested were carbon, E-glass, and hollow E-glass fiber composites, in decreasing order of stiffness and cost. High-resolution distributed fiber optic sensors were embedded in two of the three rotor blades for each material and provided hundreds of strain measurements per blade. Turbine performance and blade strain were measured while varying tow speed and tip speed ratio. Performance tests were conducted at towing speeds sufficiently high for the performance to be independent of Reynolds number. E-glass blades and carbon blades performed similarly for the most rigid strut configurations. Higher strain was measured on the E-glass blades, and their performance was reduced for less rigid configurations compared to the carbon fiber blades. The performance of the highly deflective hollow E-glass blades was lower overall and became even more degraded for longer unsupported blade span. Furthermore, the results provide insight into the use of various blade materials in cross-flow turbines and guidance on allowable free end length for each material type.

16 TIDAL AND WAVE POWER↗

QCD–Gravity Double Copy in Regge Asymptotics: From \(2\rightarrow n\) Amplitudes to Radiation in Shockwave Collisions

This paper discusses multi-particle production in QCD and in gravity at ultrarelativistic energies, their double-copy relations, and strong parallels in emergent shockwave dynamics. Dispersive techniques are applied to derive the BFKL equation for multi-gluon production in Regge asymptotics. Identical methods apply in gravity and are captured by a gravitational Lipatov equation. The building blocks in both cases are Lipatov vertices and reggeized propagators satisfying double-copy relations; in gravity, Weinberg’s soft theorem is recovered as a limit of the Lipatov framework. BFKL evolution in QCD generates wee parton states of maximal occupancy characterized by an emergent semi-hard saturation scale. Renormalization group equations in the Color Glass Condensate (CGC) EFT describe wee parton correlations and their rapidity evolution. A shockwave picture of deeply inelastic scattering and hadron–hadron collisions follows, with multi-particle production described by Cutkosky’s rules in strong time-dependent fields. Gluon radiation in the CGC EFT has a double copy in gravitational shockwave collisions, with a similar correspondence applicable between gluon and graviton shockwave propagators. Possible extensions of this semi-classical double copy are outlined for computing multi-particle production in gravitational shockwave collisions, self-force and tidal contributions, and classical and quantum noise in the focusing of geodesics.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Direct adaptive impedance control of manipulators

An adaptive scheme for controlling the end-effector impedance of robot manipulators is presented. The proposed control system consists of three subsystems: a simple filter which characterizes the desired dynamic relationship between the end-effector position error and the end-effector/environment contact force, an adaptive controller which produces the Cartesian-space control input required to provide this desired dynamic relationship, and an algorithm for mapping the Cartesian-space control input to a physically realizable joint-space control torque. The controller does not require knowledge of either the structure or the parameter values of the robot dynamics, and it is implemented without calculation of the robot inverse kinematic transformation. As a result, the scheme represents a very general and computationally efficient approach to controlling the impedance of both nonredundant and redundant manipulators. Furthermore, the method can be applied directly to trajectory tracking in free-space motion by removing the impedance filter.

Colbaugh, R.↗

Drilling Automation Demonstrations in Subsurface Exploration for Astrobiology

This project proposes to study subsurface permafrost microbial habitats at a relevant Arctic Mars-analog site (Haughton Crater, Devon Island, Canada) while developing and maturing the subsurface drilling and drilling automation technologies that will be required by post-2010 missions. It builds on earlier drilling technology projects to add permafrost and ice-drilling capabilities to 5m with a lightweight drill that will be automatically monitored and controlled in-situ. Frozen cores obtained with this drill under sterilized protocols will be used in testing three hypotheses pertaining to near-surface physical geology and ground H2O ice distribution, viewed as a habitat for microbial life in subsurface ice and ice-consolidated sediments. Automation technologies employed will demonstrate hands-off diagnostics and drill control, using novel vibrational dynamical analysis methods and model-based reasoning to monitor and identify drilling fault states before and during faults. Three field deployments, to a Mars-analog site with frozen impact crater fallback breccia, will support science goals, provide a rigorous test of drilling automation and lightweight permafrost drilling, and leverage past experience with the field site s particular logistics.

Glass, Brian↗

Initiator‐Driven Tailoring of Reactivity and Inhibition in Frontally Polymerized Dicyclopentadiene‐Co‐Dihydrofuran Thermosets

Incorporating 2,3‐dihydrofuran (DHF) into dicyclopentadiene (DCPD) enables frontally polymerizable, deconstructible thermosets via acid hydrolysis. At 5–20 mol% DHF and low initiator concentration (~100 ppm), DHF inhibits front propagation, lowers the glass transition temperature ( T g ) by up to 20°C, and quenches the front, especially at 20% DHF. This paper demonstrates that increasing the initiator concentration to 250–1000 ppm overcomes inhibition, enhances front speeds by ~50%, and suppresses quenching at the expense of pot‐life. Above 5 mol% DHF, an emergence of a second exotherm is observed, attributed to increased rate dependence on the inhibition of the initiator by DHF. Void formation from volatile DHF is suppressed by applying 110 kPa nitrogen, though at the cost of reduced front speed. Dynamic mechanical analysis shows that higher initiator concentration produced more highly cross‐linked polymers, with a ~20% increase in storage modulus at 25°C and a 20°C increase in T g .

deconstructible thermosets↗

Magnetic ordering in the Ising antiferromagnetic pyrochlore Nd 2 ScNbO 7

The question of structural disorder and its effects on magnetism is relevant to a number of spin liquid candidate materials. Although commonly thought of as a route to spin glass behaviour, here we describe a system in which the structural disorder results in long-range antiferromagnetic order due to local symmetry breaking. Nd 2 ScNbO 7 is shown to have a dispersionless gapped excitation observed in other neodymium pyrochlores below T N = 0.37 K through polarized and inelastic neutron scattering. However the dispersing spin waves are not observed. This excited mode is shown to occur in only 14(2)% of the neodymium ions through spectroscopy and is consistent with total scattering measurements as well as the magnitude of the dynamic moment 0.26(2) μB . The remaining magnetic species order completely into the all-in all-out Ising antiferromagnetic structure. This can be seen as a result of local symmetry breaking due disordered Sc +3 and Nb +5 ions about the A-site. From this work, it has been established that B-site disorder restores the dipole-like behaviour of the Nd +3 ions compared to the Nd 2 ScNbO 7 parent series.

38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEA↗

Development of test methodology for dynamic mechanical analysis instrumentation

Dynamic mechanical analysis instrumentation was used for the development of specific test methodology in the determination of engineering parameters of selected materials, esp. plastics and elastomers, over a broad range of temperature with selected environment. The methodology for routine procedures was established with specific attention given to sample geometry, sample size, and mounting techniques. The basic software of the duPont 1090 thermal analyzer was used for data reduction which simplify the theoretical interpretation. Clamps were developed which allowed 'relative' damping during the cure cycle to be measured for the fiber-glass supported resin. The correlation of fracture energy 'toughness' (or impact strength) with the low temperature (glassy) relaxation responses for a 'rubber-modified' epoxy system was negative in result because the low-temperature dispersion mode (-80 C) of the modifier coincided with that of the epoxy matrix, making quantitative comparison unrealistic.

Allen, V. R.↗

A TEOM (tm) particulate monitor for comet dust, near Earth space, and planetary atmospheres

Scientific missions to comets, near earth space, and planetary atmospheres require particulate and mass accumulation instrumentation for both scientific and navigation purposes. The Rupprecht & Patashnick tapered element oscillating microbalance can accurately measure both mass flux and mass distribution of particulates over a wide range of particle sizes and loadings. Individual particles of milligram size down to a few picograms can be resolved and counted, and the accumulation of smaller particles or molecular deposition can be accurately measured using the sensors perfected and toughened under this contract. No other sensor has the dynamic range or sensitivity attained by these picogram direct mass measurement sensors. The purpose of this contract was to develop and implement reliable and repeatable manufacturing methods; build and test prototype sensors; and outline a quality control program. A dust 'thrower' was to be designed and built, and used to verify performance. Characterization and improvement of the optical motion detection system and drive feedback circuitry was to be undertaken, with emphasis on reliability, low noise, and low power consumption. All the goals of the contract were met or exceeded. An automated glass puller was built and used to make repeatable tapered elements. Materials and assembly methods were standardized, and controllers and calibrated fixtures were developed and used in all phases of preparing, coating and assembling the sensors. Quality control and reliability resulted from the use of calibrated manufacturing equipment with measurable working parameters. Thermal and vibration testing of completed prototypes showed low temperature sensitivity and high vibration tolerance. An electrostatic dust thrower was used in vacuum to throw particles from 2 x 10(exp 6) g to 7 x 10(exp -12) g in size. Using long averaging times, particles as small as 0.7 to 4 x 10(exp 11) g were weighted to resolutions in the 5 to 9 x 10(exp -13) g range. The drive circuit and optics systems were developed beyond what was anticipated in the contract, and are now virtually flight prototypes. There is already commercial interest in the developed capability of measuring picogram mass losses and gains. One area is contamination and outgassing research, both measuring picogram losses from samples and collecting products of outgassing.

Source record↗

Emergent Nanostructure and Ion Transport in Polyzwitterion/Polyanion Blends

Solid polymer electrolytes (SPEs) hold great promise for the advancement of next-generation energy storage devices. However, the ion transport mechanism in SPEs remains poorly understood. In this study, we investigate blends of poly(1-(3-sulfonatopropyl)-2-vinylpyridinium) (P2VPPS) and poly(lithium (trifluoromethane)sulfonimide methacrylate) (P(MTFSI)Li) of varying molar ratios to develop a mechanistic understanding of ionic conductivity in a miscible polyzwitterion/polyanion system. Polyanions can act as single-ion conductors, but conductivity is often prohibitively low due to the decreased segmental mobility and ion aggregation. Here, it is hypothesized that the introduction of a polyzwitterion would competitively interact with the polyanion charge groups to realize improvements in the conductivity. Attractive interactions between the polyanions and polyzwitterions are confirmed by the blend’s increased glass transition temperature using the Gordon–Taylor equation. Notably, an ordered local nanostructure (∼24 Å) emerged in the P2VPPS/P(MTFSI)Li system at certain compositions, as characterized by small-angle X-ray and neutron scattering (SAXS/SANS). Concurrent with the emergence of this structure, broadband dielectric spectroscopy confirmed improvements in ionic conductivity. The highest conductivity is observed at a specific blend ratio P2VPPS:P(MTFSI)Li = 0.2:1 in the glassy state and 0.3:1 in the rubbery state, corresponding to the lowest effective activation energy (E*). Coarse-grained molecular dynamics simulations further emphasize the role of complexation between polyzwitterion and polyanion chains, correlating with the emergence of a new peak in SAXS and SANS for the blends. This work provides a fresh perspective on the role of local structural design in developing SPEs and offers insights into the morphological effects on ionic conductivity.

chemical structure↗

Diagnosing Barren Plateaus with Tools from Quantum Optimal Control

Variational Quantum Algorithms (VQAs) have received considerable attention due to their potential for achieving near-term quantum advantage. However, more work is needed to understand their scalability. One known scaling result for VQAs is barren plateaus, where certain circumstances lead to exponentially vanishing gradients. It is common folklore that problem-inspired ansatzes avoid barren plateaus, but in fact, very little is known about their gradient scaling. In this work we employ tools from quantum optimal control to develop a framework that can diagnose the presence or absence of barren plateaus for problem-inspired ansatzes. Such ansatzes include the Quantum Alternating Operator Ansatz (QAOA), the Hamiltonian Variational Ansatz (HVA), and others. With our framework, we prove that avoiding barren plateaus for these ansatzes is not always guaranteed. Specifically, we show that the gradient scaling of the VQA depends on the degree of controllability of the system, and hence can be diagnosed through the dynamical Lie algebra $\mathfrak{g}$ obtained from the generators of the ansatz. We analyze the existence of barren plateaus in QAOA and HVA ansatzes, and we highlight the role of the input state, as different initial states can lead to the presence or absence of barren plateaus. Taken together, our results provide a framework for trainability-aware ansatz design strategies that do not come at the cost of extra quantum resources. Moreover, we prove no-go results for obtaining ground states with variational ansatzes for controllable system such as spin glasses. Our work establishes a link between the existence of barren plateaus and the scaling of the dimension of $\mathfrak{g}$.

97 MATHEMATICS AND COMPUTING↗

Electron radiation effects on the thermal expansion of graphite/resin composites

The effects of 1 MeV electron radiation on the thermal expansion characteristics of two graphite reinforced resin matrix composite systems were studied. Specimens of both graphite/epoxy (T300/5208) and graphite/polyimide (C6000/PMR15) were irradiated to a total dose of 6 x 10 to the 9th rads at two different rates. Dynamic mechanical analyses (DMA) were performed to study changes in resin chemistry. Thermal expansion results indicate that radiation did produce permanent residual strains of up to -70 x 10 to the -6th for the graphite/epoxy when exposed to temperatures up to +280 F. However, no permaanent changes in the coefficient of thermal expansion (CTE) were observed. No permanent residual strains or changes in the CTE attributable to radiation were observed for the graphite/polyimide specimens. DMA results indicate that electron radiation caused chemical changes in the epoxy matrix. These changes resulted in a lower glass transition temperature and broader 'rubbery region' which extended into the temperature range of the thermal expansion tests.

Bowles, D. E.↗

Design, Fabrication, and Testing of Composite Energy-Absorbing Keel Beams for General Aviation Type Aircraft

A lightweight energy-absorbing keel-beam concept was developed and retrofitted in a general aviation type aircraft to improve crashworthiness performance. The energy-absorbing beam consisted of a foam-filled cellular structure with glass fiber and hybrid glass/kevlar cell walls. Design, analysis, fabrication and testing of the keel beams prior to installation and subsequent full-scale crash testing of the aircraft are described. Factors such as material and fabrication constraints, damage tolerance, crush stress/strain response, seat-rail loading, and post crush integrity, which influenced the course of the design process are also presented. A theory similar to the one often used for ductile metal box structures was employed with appropriate modifications to estimate the sustained crush loads for the beams. This, analytical tool, coupled with dynamic finite element simulation using MSC.Dytran were the prime design and analysis tools. The validity of the theory as a reliable design tool was examined against test data from static crush tests of beam sections while the overall performance of the energy-absorbing subfloor was assessed through dynamic testing of 24 in long subfloor assemblies.

Kellas, Sotiris↗

A review of materials used in tomographic volumetric additive manufacturing

Abstract Volumetric additive manufacturing is a novel fabrication method allowing rapid, freeform, layer-less 3D printing. Analogous to computer tomography (CT), the method projects dynamic light patterns into a rotating vat of photosensitive resin. These light patterns build up a three-dimensional energy dose within the photosensitive resin, solidifying the volume of the desired object within seconds. Departing from established sequential fabrication methods like stereolithography or digital light printing, volumetric additive manufacturing offers new opportunities for the materials that can be used for printing. These include viscous acrylates and elastomers, epoxies (and orthogonal epoxy-acrylate formulations with spatially controlled stiffness) formulations, tunable stiffness thiol-enes and shape memory foams, polymer derived ceramics, silica-nanocomposite based glass, and gelatin-based hydrogels for cell-laden biofabrication. Here we review these materials, highlight the challenges to adapt them to volumetric additive manufacturing, and discuss the perspectives they present. Graphical abstract

36 MATERIALS SCIENCE↗

Influence of physical aging on the time-dependent properties of network epoxies and epoxy-matrix composites

The matrix-dominated properties of a network epoxy and its carbon fiber-reinforced composite are noted to be affected by sub-glass transition temperature T(g) annealing in a nitrogen atmosphere. The damping behavior, stress relaxation rate, and enthalpic state of the matrix material were found to decrease as functions of sub-T(g) annealing time. This time-dependent change in physical properties is explained on the basis of a free-volume collapse which is related to the recovery process of the nonequilibrium glassy network of the epoxy. The physical aging in network epoxies has been demonstrated to be thermoreversible. Aging kinetics are studied by means of differential scanning calorimetry, stress relaxation tests, dynamic mechanical analysis, and thermomechanical analysis.

Kong, E. S. W.↗

Optical array for high-quality imaging in harsh environments

Methods and apparatus are disclosed for producing high quality images in uncontrolled or impaired environments. In some examples of the disclosed technology, groups of cameras for high dynamic range (HDR), polarization diversity, and optional other diversity modes are arranged to concurrently image a common scene. For example, in a vehicle checkpoint application, HDR provides discernment of dark objects inside a vehicle, while polarization diversity aids in rejecting glare. Spectral diversity, infrared imaging, and active illumination can be applied for better imaging through a windshield. Preprocessed single-camera images are registered and fused. Faces or other features of interest can be detected in the fused image and identified in a library. Impairments can include weather, insufficient or interfering lighting, shadows, reflections, window glass, occlusions, or moving objects.

42 ENGINEERING↗

Optical array for high-quality imaging in harsh environments

Methods and apparatus are disclosed for producing high quality images in uncontrolled or impaired environments. In some examples of the disclosed technology, groups of cameras for high dynamic range (HDR), polarization diversity, and optional other diversity modes are arranged to concurrently image a common scene. For example, in a vehicle checkpoint application, HDR provides discernment of dark objects inside a vehicle, while polarization diversity aids in rejecting glare. Spectral diversity, infrared imaging, and active illumination can be applied for better imaging through a windshield. Preprocessed single-camera images are registered and fused. Faces or other features of interest can be detected in the fused image and identified in a library. Impairments can include weather, insufficient or interfering lighting, shadows, reflections, window glass, occlusions, or moving objects.

Baba, Justin S.↗

Analysis of leading edge and trailing edge cover glass samples before and after treatment with advanced satellite contamination removal techniques

Two samples from Long Duration Exposure Facility (LDEF) experiment M0003-4 were analyzed for molecular and particulate contamination prior to and following treatment with advanced satellite contamination removal techniques (CO2 gas/solid jet spray and oxygen ion beam). The pre- and post-cleaning measurements and analyses are presented. The jet spray removed particulates in seconds. The low energy reactive oxygen ion beam removed 5,000 A of photo polymerized organic hydrocarbon contamination in less than 1 hour. Spectroscopic analytical techniques were applied to the analysis of cleaning efficiency including: Fourier transform infrared, Auger, x ray photoemissions, energy dispersive x ray, and ultraviolet/visible. The results of this work suggest that the contamination studied here was due to spacecraft self-contamination enhanced by atomic oxygen plasma dynamics and solar UV radiation. These results also suggest the efficacy for the jet spray and ion beam contamination control technologies for spacecraft optical surfaces.

Hotaling, S. P.↗