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At least 721 records · Page 40

Quantifying Nitrogen Bioextraction by Seaweed Farms – A Real-time Modeling-Monitoring Case Study in Hood Canal, WA

Anthropogenic nitrogen input is the leading cause of increasing marine eutrophication. Cultivating seaweeds at large scales may provide a viable solution for mitigating eutrophication especially when nitrogen extraction is achieved as an added environmental benefit of biofuel and food production. As the first step to promoting and implementing this solution, it is critical to quantify and assess the effectiveness of nitrogen removal by existing seaweed farms. Pacific Northwest National Laboratory and Hood Canal Mariculture Inc. conducted a case study by applying a coupled modeling-monitoring approach to quantify nitrogen bioextraction by a one-hectare commercial sugar kelp farm in Hood Canal, WA. Through this two-year effort, the project team conducted intensive field monitoring of water quality parameters at the farm site and subsequent laboratory analysis. Meanwhile, the team applied a coupled hydrodynamic-macroalgal growth model to simulate kelp growth and nitrogen bioextraction over the two kelp growing seasons. The model results showed an overall good comparison with field monitoring data and showed the effectiveness of nitrogen removal by kelp farms. The established modeling-monitoring approach can also be transferable for supporting broader research activities in macroalgal farming and eutrophication mitigation.

09 BIOMASS FUELS↗

Industry Requirements for Geomagnetic Disturbance Models

This research project will address the most pressing uncertainties in modeling and measuring the electric power grid effects of geomagnetic disturbances (GMDs) and the E3 portion of nuclear electromagnetic pulse (EMP). The primary goal is to help decision-makers in the electric power sector have the knowledge and tools they need to most effectively mitigate GMD effects on our nation’s electric grid, with a secondary focus on EMP. Comprehensive modeling, model assessment through sensitivity analysis, and validation with field measurement data will be the primary tasks undertaken. The goal will be a more widespread adoption of these modeling approaches, namely characterizing the uncertainty associated with these models and how that uncertainty will affect decision-making by industry. This document summarizes industry requirements for better decision-making tools, informed by feedback from an industry advisory board. These requirements help guide planning and execution of the project's remaining tasks.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Deep Vadose Zone Monitoring Test Bed (FY23 Status Report)

A subsurface air injection at the Hanford Site’s Deep Vadose Zone Monitoring Test Bed was completed to realize a change in subsurface hydrologic conditions in accordance with a soil desiccation remedy. The injection mimicked a previous injection at the site that was performed in accordance with a vadose zone treatability study. Unlike the previous test which relied on electrical methods only, the change in hydrologic conditions during the recent test was also monitored using cross-hole seismic sensing methods to assess the ability of the seismic methods to evaluate changes in moisture conditions of desiccated sediment at the field scale. Data from in situ neutron probes indicates a reduction of soil moisture in the vicinity of the injection well due to the air injection. Similar changes were observed in the time-lapse electrical resistivity and seismic data, which indicates a loss of soil moisture over time. Tomographic inversions of the time-lapse geophysical data illustrate the 2D and 3D features of the soil moisture distribution over time. Time-lapse electrical resistivity tomography (ERT) results show a reduction in the electrical conductivity of the subsurface in the vicinity of the injection well, with most changes occurring within the screened interval. Similar patterns are observed in the seismic tomography results, with both methods illustrating two lobe-shaped features of reduced soil moisture. Use of seismic and ERT technologies in tandem takes advantage of two complementary geophysical monitoring technologies, providing increased sensitivity to specific hydrologic conditions. The multiphysics approach, therefore, has the potential to improve the ability to estimate subsurface moisture conditions from sensor-based and remotely sensed geophysical data that will ultimately improve the ability of remediation contractors to evaluate remedy performance.

58 GEOSCIENCES↗

Carbon Storage Core Characterization Efforts at NETL

The multi-scale Computed Tomography (CT) and core flow facility in the Geocharacterization Laboratory at NETL, Morgantown yields porosity, permeability, and fracture properties of rock core samples obtained from the subsurface while maintaining the integrity of the sample. Additionally, geophysical bulk rock properties are analyzed with the laboratory’s GeoTEK multi-sensor core logger in a comparable fashion to downhole methods. NETL researchers collaborate with stakeholders within the carbon storage, oil and gas, and critical minerals sectors. Since 2017, over 1.88 miles of core have been analyzed within the laboratory and all data is publicly available through the Technical Report Series (TRS) on the Energy Data eXchange (EDX). Additionally, the website, RokBase, was curated to extrapolate and visualize the high-resolution data from field operations. The characterization of the Lively Grove #1 (LG#1) well provides a case study into the full capabilities of the Geocharacterization Laboratory. During the comprehensive study of LG#1 ~1-2 mm in diameter, vertical to bedding, cylindrical structures were identified throughout the St. Peter Formation. These structures are pervasive throughout the St. Peter Formation at depth and are characterized as the trace fossil, Skolithos.

Isom, Shelby L↗

Leveling-Up for Big-Format Modules

Like Mario grabbing a super mushroom, PV modules just keep getting bigger! As they grow, so do the challenges of handling, installing, and testing them in the field. At NREL, we've embarked on our own New Hope - adapting to this size revolution across our tools, transportation, ergonomics, and field compatibility. Join us as we navigate this galactic expansion and keep PV testing at the cutting edge.

14 SOLAR ENERGY↗

A Novel Method for Setting Meaningful Thresholds for RMS-Energy Oscillation Detectors

Oscillation detection and mitigation is a crucial aspect of reliable power system operation. Several transmission system operators and reliability coordinators use the RMS-energy method of oscillation detection, but the process of setting thresholds is time and labor intensive. The current industry practice in the United States is to set thresholds based on the RMS-energy's value during ambient conditions, which can often lead to nuisance alarms that require thresholds to be manually retuned. In this paper, we propose a method for setting RMS-energy thresholds that directly accounts for oscillation amplitudes specified by the user. A theoretical analysis of the statistical properties of the RMS-energy incorporates these user-specified amplitudes, resulting in thresholds that reliably detect oscillations of interest while avoiding nuisance alarms. Theoretical results are validated with simulated measurements and the real-world practicality of the method is established with publicly available field-measured data from the Grid Event Signature Library.

Follum, James D.↗

Mapping of flumioxazin tolerance in a snap bean diversity panel leads to the discovery of a master genomic region controlling multiple stress resistance genes

Effective weed management tools are crucial for maintaining the profitable production of snap bean (Phaseolus vulgaris L.). Preemergence herbicides help the crop to gain a size advantage over the weeds, but the few preemergence herbicides registered in snap bean have poor waterhemp (Amaranthus tuberculatus) control, a major pest in snap bean production. Waterhemp and other difficult-to-control weeds can be managed by flumioxazin, an herbicide that inhibits protoporphyrinogen oxidase (PPO). However, there is limited knowledge about crop tolerance to this herbicide. We aimed to quantify the degree of snap bean tolerance to flumioxazin and explore the underlying mechanisms. We investigated the genetic basis of herbicide tolerance using genome-wide association mapping approach utilizing field-collected data from a snap bean diversity panel, combined with gene expression data of cultivars with contrasting response. The response to a preemergence application of flumioxazin was measured by assessing plant population density and shoot biomass variables. Snap bean tolerance to flumioxazin is associated with a single genomic location in chromosome 02. Tolerance is influenced by several factors, including those that are indirectly affected by seed size/weight and those that directly impact the herbicide's metabolism and protect the cell from reactive oxygen species-induced damage. Transcriptional profiling and co-expression network analysis identified biological pathways likely involved in flumioxazin tolerance, including oxidoreductase processes and programmed cell death. Transcriptional regulation of genes involved in those processes is possibly orchestrated by a transcription factor located in the region identified in the GWAS analysis. Several entries belonging to the Romano class, including Bush Romano 350, Roma II, and Romano Purpiat presented high levels of tolerance in this study. The alleles identified in the diversity panel that condition snap bean tolerance to flumioxazin shed light on a novel mechanism of herbicide tolerance and can be used in crop improvement.

60 APPLIED LIFE SCIENCES↗

Predicting Field Efficiency of Round-Baling Operations in High-Yielding Biomass Crops

Model simulations for bioenergy harvest planning need to utilize equipment-capacity relationships for equipment operating under the high-yield conditions typical of a biomass crop. These performance assumptions have a direct bearing on the estimates of machine capacity, the number of machines required, and, therefore, the cost to fulfill the biorefinery plant demands for a given harvest window. Typically, two major issues in these models have been poorly understood: the available time required to complete the harvest operation (often called probability of workdays) and the capacity of the harvest equipment as impacted by yield. Simulations use annual yield estimates, which incorporate weather events, to demonstrate year-to-year effects. Some simulations also incorporate potential yield increases from genetically modified energy crops. There are limited field performance data for most current forage equipment used for harvesting high-yield biomass crops. Analysis shows that the impact of wrap/eject time for round balers resulted in a 50% reduction in achieved throughput capacity (Mg/h). After the maximum throughput is reached, the cost of the round bale operation (3.23 USD/Mg) is double that of the large-square baler (1.63 USD/Mg). The round baler achieved throughput capacity is 50% less (32.7 Mg/h compared to 71.0 Mg/h) than the large-square baler.

09 BIOMASS FUELS↗

SrNi(VO 4 )(OH): The High-Temperature Hydrothermal Synthesis and Magnetic Properties of an Adelite-Descloizite-Type Structure

Single crystals of a new transition metal adelite-descloizite-type structure were synthesized using a high temperature (580 °C) high-pressure hydrothermal technique. Single crystal X-ray diffraction and energy dispersive X-ray analysis (EDX) were used to investigate the structure and elemental composition, respectively. SrNi(VO 4 )(OH) crystallizes in an acentric orthorhombic crystal system in the space group P2 1 2 1 2 1 (no. 19); Z = 4, a = 5.9952(4) Å, b = 7.5844(4) Å, c = 9.2240(5) Å. The structure is comprised of a Ni–O–V framework where Sr 2+ ions reside inside the channels. Single-crystal magnetic measurements display a significant anisotropy in both temperature- and field-dependent data. The temperature dependent magnetic measurement shows antiferromagnetic behavior at T N ~8 K. Overall, the magnetic properties indicate the presence of competing antiferromagnetic and ferromagnetic interactions of SrNi(VO 4 )(OH).

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

High-contrast Thermal Infrared Spectroscopy with ALES: The 3–4 μm Spectrum of κ Andromedae b

We present the first L-band (2.8–4.1 μm) spectroscopy of κ Andromedae b, a ~20 M Jup companion orbiting at 1" projected separation from its B9-type stellar host. We combine our Large Binocular Telescope (LBT) Arizona Lenslets for Exoplanet Spectroscopy (ALES) integral field spectrograph data with measurements from other instruments to analyze the atmosphere and physical characteristics of κ And b. We report a discrepancy of ~20% (2σ) in the L' flux of κ And b when comparing to previously published values. We add an additional L' constraint using an unpublished imaging data set collected in 2013 using the LBT Interferometer/LMIRCam, the instrument in which the ALES module has been built. The LMIRCam measurement is consistent with the ALES measurement, both suggesting a fainter L-band scaling than previous studies. The data, assuming the flux scaling measured by ALES and LMIRCam imaging, are well fit by an L3-type brown dwarf. Atmospheric model fits to measurements spanning 0.9–4.8 μm reveal some tension with the predictions of evolutionary models, but the proper choice of cloud parameters can provide some relief. In particular, models with clouds extending to very low pressures composed of grains ≤1 μm appear to be necessary. If the brighter L' photometry is accurate, there is a hint that subsolar metallicity may be required.

79 ASTRONOMY AND ASTROPHYSICS↗

Subgalactic Scaling Relations with T e -based Metallicities of Low-metallicity Regions in Galaxies: Metal-poor Gas Inflow May Have Important Effects?

The scaling relationship is a fundamental probe of the evolution of galaxies. Using the integral field spectroscopic data from the Mapping Nearby Galaxies at Apache Point Observatory survey, we select 1698 spaxels with a significant detection of the auroral emission line [O ιιι]λ4363 from 52 galaxies to investigate the scaling relationships at the low-metallicity end. We find that our sample’s star formation rate is higher and its metallicity is lower in the scaling relationship than the star-forming sequence after removing the contribution of the Fundamental Metallicity Relation. We also find that the stellar ages of our sample are younger (<1 Gyr) and the stellar metallicities are also lower. Morphological parameters from the Deep Learning catalog indicate that our galaxies are more likely to be mergers. These results suggest that their low-metallicity regions may be related to interaction; the inflow of metal-poor gas may dilute the interstellar medium and form new metal-poor stars in these galaxies during interactions.

79 ASTRONOMY AND ASTROPHYSICS↗

SDSS-IV MaNGA: Cannibalism Caught in the Act—On the Frequency of Occurrence of Multiple Cores in Brightest Cluster Galaxies

Although it is generally accepted that massive galaxies form in a two-phased fashion, beginning with a rapid mass buildup through intense starburst activities followed by primarily dry mergers that mainly deposit stellar mass at outskirts, the late time stellar mass growth of brightest cluster galaxies (BCGs), the most massive galaxies in the universe, is still not well understood. Several independent measurements have indicated a slower mass growth rate than predictions from theoretical models. We attempt to resolve the discrepancy by measuring the frequency of BCGs with multiple cores, which serve as a proxy of the merger rates in the central region and facilitate a more direct comparison with theoretical predictions. Using 79 BCGs at z = 0.06–0.15 with integral field spectroscopic data from the Mapping Nearby Galaxies at Apache Point Observatory (MaNGA) project, we obtain a multiple-core fraction of 0.11 ± 0.04 at z ≈ 0.1 within an 18 kpc radius from the center, which is comparable to the value of 0.08 ± 0.04 derived from mock observations of 218 simulated BCGs from the cosmological hydrodynamical simulation IllustrisTNG. We find that most cores that appear close to the BCGs from imaging data turn out to be physically associated systems. Anchoring on the similarity in the multiple-core frequency between the MaNGA and IllustrisTNG, we discuss the mass growth rate of BCGs over the past 4.5 Gyr.

79 ASTRONOMY AND ASTROPHYSICS↗

Open cells exhibit weaker entrainment of free-tropospheric biomass burning aerosol into the south-east Atlantic boundary layer

This work presents synergistic satellite, airborne and surface-based observations of a pocket of open cells (POC) in the remote south-east Atlantic. The observations were obtained over and upwind of Ascension Island during the CLouds and Aerosol Radiative Impacts and Forcing (CLARIFY) and the Layered Smoke Interacting with Clouds (LASIC) field experiments. A novel aspect of this case study is that an extensive free-tropospheric biomass burning aerosol plume that had been transported from the African continent was observed to be in contact with the boundary layer inversion over the POC and the surrounding closed cellular cloud regime. The in situ measurements show marked contrasts in the boundary layer thermodynamic structure, cloud properties, precipitation and aerosol conditions between the open cells and surrounding overcast cloud field. The data demonstrate that the overlying biomass burning aerosol was mixing down into the boundary layer in the stratocumulus cloud downwind of the POC, with elevated carbon monoxide, black carbon mass loadings and accumulation-mode aerosol concentrations measured beneath the trade-wind inversion. The stratocumulus cloud in this region was moderately polluted and exhibited very little precipitation falling below cloud base. A rapid transition to actively precipitating cumulus clouds and detrained stratiform remnants in the form of thin quiescent veil clouds was observed across the boundary into and deep within the POC. The subcloud layer in the POC was much cleaner than that in the stratocumulus region. The clouds in the POC formed within an ultra-clean layer (accumulation-mode aerosol concentrations of approximately a few cm -3 ) in the upper region of the boundary layer, which was likely to have been formed via efficient collision–coalescence and sedimentation processes. Enhanced Aitken-mode aerosol concentrations were also observed intermittently in this ultra-clean layer, suggesting that new particle formation was taking place. Across the boundary layer inversion and immediately above the ultra-clean layer, accumulation-mode aerosol concentrations were ~1000 cm -3 . Importantly, the air mass in the POC showed no evidence of elevated carbon monoxide over and above typical background conditions at this location and time of year. As carbon monoxide is a good tracer for biomass burning aerosol that is not readily removed by cloud processing and precipitation, it demonstrates that the open cellular convection in the POC is not able to entrain large quantities of the free-tropospheric aerosol that was sitting directly on top of the boundary layer inversion. This suggests that the structure of the mesoscale cellular convection may play an important role in regulating the transport of aerosol from the free troposphere down into the marine boundary layer. We then develop a climatology of open cellular cloud conditions in the south-east Atlantic from 19 years of September Moderate Resolution Imaging Spectroradiometer (MODIS) Terra imagery. This shows that the maxima in open cell frequency (> 0.25) occurs far offshore and in a region where subsiding biomass burning aerosol plumes may often come into contact with the underlying boundary layer cloud. If the results from the observational case study applied more broadly, then the apparent low susceptibility of open cells to free-tropospheric intrusions of additional cloud condensation nuclei could have some important consequences for aerosol–cloud interactions in the region.

54 ENVIRONMENTAL SCIENCES↗

Impact of dry intrusion events on the composition and mixing state of particles during the winter Aerosol and Cloud Experiment in the Eastern North Atlantic (ACE-ENA)

Abstract. Long-range transport of continental emissions has a far-reaching influence over remote regions, resulting in substantial change in the size, morphology, and composition of the local aerosol population and cloud condensation nuclei (CCN) budget. Here, we investigate the physicochemical properties of atmospheric particles collected on board a research aircraft flown over the Azores during the winter 2018 Aerosol and Cloud Experiment in the Eastern North Atlantic (ACE-ENA) campaign. Particles were collected within the marine boundary layer (MBL) and free troposphere (FT) after long-range atmospheric transport episodes facilitated by dry intrusion (DI) events. Chemical and physical properties of individual particles were investigated using complementary capabilities of computer-controlled scanning electron microscopy and X-ray spectromicroscopy to probe particle external and internal mixing state characteristics. Furthermore, real-time measurements of aerosol size distribution, cloud condensation nuclei (CCN) concentration, and back-trajectory calculations were utilized to help bring into context the findings from offline spectromicroscopy analysis. While carbonaceous particles were found to be the dominant particle type in the region, changes in the percent contribution of organics across the particle population (i.e., external mixing) shifted from 68 % to 43 % in the MBL and from 92 % to 46 % in FT samples during DI events. This change in carbonaceous contribution is counterbalanced by the increase in inorganics from 32 % to 57 % in the MBL and 8 % to 55 % in FT. The quantification of the organic volume fraction (OVF) of individual particles derived from X-ray spectromicroscopy, which relates to the multi-component internal composition of individual particles, showed a factor of 2.06 ± 0.16 and 1.11 ± 0.04 increase in the MBL and FT, respectively, among DI samples. We show that supplying particle OVF into the κ-Köhler equation can be used as a good approximation of field-measured in situ CCN concentrations. We also report changes in the κ values in the MBL from κMBL, non-DI=0.48 to κMBL, DI=0.41, while changes in the FT result in κFT, non-DI=0.36 to κFT, DI=0.33, which is consistent with enhancements in OVF followed by the DI episodes. Our observations suggest that entrainment of particles from long-range continental sources alters the mixing state population and CCN properties of aerosol in the region. The work presented here provides field observation data that can inform atmospheric models that simulate sources and particle composition in the eastern North Atlantic.

54 ENVIRONMENTAL SCIENCES↗